CN108289469A - Cladding fat or oil composition - Google Patents
Cladding fat or oil composition Download PDFInfo
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- CN108289469A CN108289469A CN201680070245.9A CN201680070245A CN108289469A CN 108289469 A CN108289469 A CN 108289469A CN 201680070245 A CN201680070245 A CN 201680070245A CN 108289469 A CN108289469 A CN 108289469A
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- Prior art keywords
- fat
- grease
- cladding
- mass
- oil composition
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Edible Oils And Fats (AREA)
- Confectionery (AREA)
- Fats And Perfumes (AREA)
- Grain Derivatives (AREA)
Abstract
It is good it is an object of the invention to develop coating adaptability, it is not likely to produce rupture, mouthfeel in circulation and preservation and what is melted in mouth feel excellent cladding fat or oil composition.The present invention is following cladding fat or oil composition：In grease, following fat As containing 0.1~60 mass %, and total content (L2U+LU2) of shared L2U and LU2 in the grease is 10 mass % or more.Fat A is the grease that total content (L2M+LM2) comprising L2M and LM2 and L2M and LM2 is 50 mass % or more.
Description
Technical field
The present invention relates to the fat or oil composition of the coating of the ices such as suitable ice cream and with the fat or oil composition
The food of cladding.
Background technology
The ices such as ice cream are coated with claddings such as coating chocolates with fat or oil composition sometimes.By having coating,
Improve the taste and mouthfeel of ices.In addition, being also used for preventing the moisture of ice cream class from shifting to beaker flask moisture-proof
Purpose.The adaptability required cladding fat or oil composition can enumerate following property.One be can it is thin and equably cladding,
Dry (solidification) fast so-called " coating adaptability ".In addition it is " crack resistance " not ruptured after solidifying.In mouth when having edible in addition
Middle thawing is felt good.Due to can thin and equably cladding, fast drying and what is melted in mouth feel good, so conduct
For the grease of cladding fat or oil composition, mainly using lauric acid system greases such as coconut oil and palm-kernel oils.But lauric acid
It is grease to have the shortcomings that easy to produce rupture after solidification.
Therefore, in the grease of cladding fat or oil composition, the liquid oils such as big polyhybird lauric acid system's grease and soya-bean oil.It can
It is that, for the method for mixing liquid oil, if its combined amount is big, although can inhibit rupture, drying is slack-off.In addition,
The mouthfeel of the coating portion of solidification can be tacky.Therefore, the production efficiency of ices is deteriorated, and the oil of the mouthfeel of ices
Sexuality becomes strong.On the other hand, if the combined amount of unthickened fuel is few, rupture prevents effect poor, it is difficult to say it is effective method.
In Japanese Laid-Open Patent Publication 2004-65070, the carbon atom of 90 weight % or more is contained by using composition aliphatic acid
The grease of the unsaturated fatty acid (containing cis trans body simultaneously) of 16 or more number is attempted to reduce oiliness sense as liquid oil.It can
It is, it is ineffective.Even if therefore, it is intended that the packet excellent if feeling that exploitation is mixed with liquid oil mouthfeel and melts in mouth
It covers and uses fat or oil composition.
In addition, other than lauric acid system grease, such as such as Japanese Patent Public List bulletin special table level No. 10-506285, day
Shown in this patent public affairs table bulletin special table level 10-506286, also using rich in SUS triacylglycerols in cladding fat or oil composition
Grease.But there is a problem of that the case where with using lauric acid system grease is same.Therefore, it is intended that even if exploitation is in liquid oil
Proportioning it is few in the case of, can also inhibit rupture and mouthfeel and what is melted in mouth feel excellent cladding fat or oil composition.
Existing technical literature
Patent document
Patent document 1：Japanese Laid-Open Patent Publication 2004-65070
Patent document 2：Japanese Patent Public List bulletin special table level 10-506285
Patent document 3：Japanese Patent Public List bulletin special table level 10-506286
Invention content
The technical problem to be solved in the present invention
The object of the present invention is to provide coating adaptability, and coating portion that is good, being solidified in circulation and preservation is not likely to produce
Rupture, mouthfeel and what is melted in mouth feel excellent cladding fat or oil composition.Solve the technical solution of technical problem
The present inventor to solve the above-mentioned problems, has carried out wholwe-hearted research.Itself as a result, it has been found that, in cladding grease group
Close object grease in, by the fat A containing specific quantity, the fat A contain specific quantity by long chain fatty acid residues and in
Chain fatty acid residue constitute mixing acidic group triacylglycerol (L2M, LM2), and by it is in the grease, by long-chain saturated fat
The content for the triacylglycerol (L2U, LU2) that fat acid and long-chain unsaturated fatty acid are constituted is set as specific quantity, can solve above-mentioned ask
Topic.It has thus completed the present invention.
That is, the present invention provides the following technical solution.
(1) a kind of cladding fat or oil composition, in grease, following fat As containing 0.1~60 mass %, and institute
The total content (L2U+LU2) for stating L2U shared in grease and LU2 is 10 mass % or more,
Fat A：It is the oil that total content (L2M+LM2) comprising L2M and LM2 and L2M and LM2 is 50 mass % or more
Fat,
Wherein, the meaning of L, M, U, L2U, LU2, L2M and LM2 are as follows：
L：The saturated fatty acid of carbon atom number 16~24；
M：The aliphatic acid of carbon atom number 6~10；
U：The unsaturated fatty acid of carbon atom number 16~24；
L2U：The triacylglycerol that the U of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LU2：The triacylglycerol that the U of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule；
L2M：The triacylglycerol that the M of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LM2：The triacylglycerol that the M of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule.
(2) in the cladding fat or oil composition of (1), the content of the content and LM2 of shared L2M in the fat A
Mass ratio (L2M/LM2) is 0.05~4.5.
(3) it in the cladding fat or oil composition of (1) or (2), constitutes shared in the full dose of the M of the L2M and the LM2
Capric acid content be 20 mass % or more.
(4) in the cladding fat or oil composition of any one of (1)~(3), shared fat A contains in the grease
The mass ratio (fat A/(L2U+LU2)) of amount and total content (L2U+LU2) of L2U and LU2 is 0.01~2.0.
(5) in the cladding fat or oil composition of any one of (1)~(4), shared palm system oil in the grease
The content of fat is 5 mass % or more.
(6) in the cladding fat or oil composition of any one of (1)~(5), shared cocoa butter in the grease
Content is 0.5~50 mass %.
(7) in the cladding fat or oil composition of any one of (1)~(6), the content of shared MMM in the grease
For 0.01~12 mass %, wherein the meaning of MMM is as follows：MMM：The trigalloyl that the M of 3 molecules is combined with the glycerine of 1 molecule
Glycerine.
(8) in the cladding fat or oil composition of any one of (1)~(7), the cladding fat or oil composition is skilful
Gram force.
(9) a kind of food is in and is coated with fat or oil composition by the cladding described in any one of claim 1~8
State.
(10) a kind of manufacturing method of the food coated with fat or oil composition, is coated with fat or oil composition using cladding and is eaten
Product, in the cladding fat or oil composition, following fat As containing 0.1~60 mass % in grease, and the grease
In total content (L2U+LU2) of shared L2U and LU2 be 10 mass % or more,
Fat A：It is the oil that total content (L2M+LM2) comprising L2M and LM2 and L2M and LM2 is 50 mass % or more
Fat,
Wherein, the meaning of L, M, U, L2U, LU2, L2M and LM2 are as follows：
L：The saturated fatty acid of carbon atom number 16~24；
M：The aliphatic acid of carbon atom number 6~10；
U：The unsaturated fatty acid of carbon atom number 16~24；
L2U：The triacylglycerol that the U of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LU2：The triacylglycerol that the U of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule；
L2M：The triacylglycerol that the M of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LM2：The triacylglycerol that the M of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule.
Invention effect
According to the present invention, it is capable of providing good coating adaptability, circulation and is not likely to produce rupture, mouthfeel and in mouth when preserving
The food for feeling excellent cladding fat or oil composition and the use cladding fat or oil composition of middle thawing.According to this hair
It is bright, it is capable of providing the cladding fat or oil composition that rupture is not easy to produce although the content of cocoa butter is high.
Specific implementation mode
Hereinafter, further illustrating the present invention.
The cladding fat or oil composition of the present invention contains following fat As in grease.Fat A be comprising L2M and LM2 and
Total content (L2M+LM2) of L2M and LM2 is the grease of 50 mass % or more.Here, the meaning of L, M, L2M and LM2 are as follows.L
It is the saturated fatty acid of carbon atom number 16~24.L is preferably the saturated fatty acid of carbon atom number 16~20, more preferably carbon
The saturated fatty acid of atomicity 16~18.L is preferably linear saturated fatty acids.M is the aliphatic acid of carbon atom number 6~10.M is excellent
Choosing is linear saturated fatty acids.L2M is the triacylglycerol that the L of 2 molecules and the M of 1 molecule are combined with the glycerine of 1 molecule.
LM2 is the triacylglycerol that the L of 1 molecule and the M of 2 molecules are combined with the glycerine of 1 molecule.L2M's and LM2 contained by fat A
Total content (L2M+LM2) is preferably 60 mass % or more, more than more preferably 65 mass.Although the upper limit does not limit especially
System, but fat A for economy is manufactured, preferably 90 mass % are hereinafter, more preferably 80 mass % or less.
The content of shared above-mentioned fat A is 0.1~60 matter in grease contained by the cladding fat or oil composition of the present invention
Measure %.The content of fat A is preferably 0.5~40 mass %, more preferably 0.5~20 mass %, it is further preferred that 1
~14 mass %, most preferably 2~10 mass %.If shared fat A in the grease contained by cladding fat or oil composition
Content and fat A contained by L2M and LM2 total content within the above range, then can effectively inhibit on food
The rupture of the cladding fat or oil composition of cladding.
For the L2M and LM2 contained by above-mentioned fat A, the mass ratio of the content of the content and LM2 of shared L2M in fat A
(L2M/LM2) it is preferably 0.05~4.5.L2M/LM2 is more preferably 0.3~3, it is further preferred that 0.55~2.5.Such as
The L2M/LM2 of fruit fat A within the above range, then can effectively inhibit the cladding fat or oil composition coated on food
Rupture.
For the L2M and LM2 contained by above-mentioned fat A, in the full dose that the M in aliphatic acid is constituted possessed by them, carbon is former
Ratio shared by the aliphatic acid of subnumber 6 is preferably 10 mass % hereinafter, more preferably 5 mass % or less.In addition, fat A
In the full dose for constituting the M in aliphatic acid possessed by contained L2M and LM2, the ratio shared by the aliphatic acid of carbon atom number 10 is excellent
Choosing is 20 mass % or more, more preferably 30~100 mass %, it is further preferred that 40~100 mass %, most preferably
Be 60~100 mass %.
Grease contained by the cladding fat or oil composition of the present invention, can contain the MMM of 0.01~12 mass %.Hereinafter,
MMM indicates the M of 3 molecules and the triacylglycerol that the glyceride bond of 1 molecule is closed.Above-mentioned 3 aliphatic acid (M) of MMM can be whole
It is identical, can also include different aliphatic acid.In addition, MMM can be the mixture of multiple and different compounds.As this mixed
The example for closing object, can enumerate the mixture of three decoyl glycerine and tridecanoyl glycerine.The composition of the carbon atom number 6~10 of MMM
Aliphatic acid, the preferably saturated fatty acid of straight chain.The content of the MMM in grease contained by cladding fat or oil composition is preferred
It is 0.08~8 mass %, more preferably 0.08~4 mass %, it is further preferred that 0.15~3 mass %, most preferably
It is 0.3~2 mass %.If the content of the MMM in grease contained by cladding fat or oil composition is within the above range, wrap
Clothing adaptability is good.
For above-mentioned MMM, in the full dose that aliphatic acid is constituted possessed by MMM, the aliphatic acid of carbon atom number 6 is preferably
10 mass % are hereinafter, more preferably 5 mass % or less.In addition, for above-mentioned MMM, the complete of aliphatic acid is constituted possessed by MMM
In amount, the aliphatic acid of carbon atom number 10 is preferably 10 mass % or more, more preferably 20~100 mass %, most preferably
It is 40~80 mass %.
As the above-mentioned MMM contained by any ingredient in the cladding of the present invention uses the grease of fat or oil composition, can use previous
Method known to the public is manufactured.For example, by the way that the aliphatic acid of carbon atom number 6~10 and glycerine are heated to 120~180
DEG C, dehydrating condensation is carried out, above-mentioned MMM can be manufactured.The condensation reaction preferably carries out under reduced pressure.Above-mentioned condensation is anti-
Catalyst can be used in answering.But above-mentioned condensation reaction is preferably carried out under no catalyst.
L2M and LM2 contained in the grease of the cladding fat or oil composition of the present invention, with total 50 mass % or more
Above-mentioned fat A, can be manufactured with previous method known to the public.That is, fat A can be in constituting aliphatic acid full dose
The composition aliphatic acid of carbon atom number 6~10 accounts for 20~65 mass %, the composition aliphatic acid of saturation of carbon atom number 16~24 accounts for 35
The transesterification grease of~80 mass %.Alternatively, can carry grease dividing for the transesterification grease.It more specifically, such as can
Be by the MMM of 20~65 mass parts (more preferably 25~55 mass parts) and 35~80 mass parts (be more preferably 45~
75 mass parts) 5 or less iodine number and as constitute aliphatic acid carbon atom number 16~24 saturated fatty acid content be 90 matter
Grease (for example, being the extreme fixed oil of raw material with rapeseed oil, the soya-bean oil, palm oil etc.) mixing for measuring % or more, then carries out ester
Exchange obtained grease.As needed, can also be point to carry grease by what the oil fractionation of the transesterification obtained.In addition,
Can be by the MMM of 20~65 mass parts (more preferably 25~55 mass parts) and 35~80 mass parts (more preferably 45
~75 mass parts) as constitute aliphatic acid carbon atom number 16~24 aliphatic acid content be 90 mass % or more grease
(for example, rapeseed oil, soya-bean oil, palm oil etc.) mixes and has carried out the grease extremely hardened after transesterification.It can also be basis
The grease for needing the oil fractionation for hardening the extreme to obtain.
Hardening (hydrogenation) reaction involved by the manufacture of above-mentioned fat A and ester exchange reaction, can be by being the public in the past
Known method carries out.Ester exchange reaction can by using the synthetic catalysts such as sodium methoxide chemical method transesterification and
It is carried out by any method of the enzyme process transesterification of catalyst of lipase.Divide and carries and can be divided by previous dry type known to the public
It carries and (divides naturally and carry), emulsification point carries (surfactant point carries) and solvent point carries and usual ways is waited to carry out.In addition, above-mentioned oil
Transesterification grease involved by the manufacture of fat A, can be above-mentioned composition, the composition aliphatic acid with carbon atom number 6~10 and
The saturation of carbon atom number 16~24 constitutes the Lipase absobed grease of aliphatic acid.Conjunction of the Lipase absobed grease for example with above-mentioned MMM
At same, previous method manufacture known to the public can be passed through.
The cladding fat or oil composition of the present invention adds up to L2U and LU2 containing 10 mass % or more in its grease.U、
The meaning of L2U and LU2 is as follows.U is the unsaturated fatty acid of carbon atom number 16~24.U is preferably carbon atom number 16~20
Unsaturated fatty acid, the more preferably unsaturated fatty acid of carbon atom number 16~18.U is preferably straight chain unsaturated fat
Acid.L2U is that U by the L of 2 molecules and 1 molecule and 1 molecule glyceride bond close obtained triacylglycerol.LU2 is by the L of 1 molecule
Obtained triacylglycerol is closed with the U of 2 molecules and the glyceride bond of 1 molecule.L2U and LU2 is brought to cladding with fat or oil composition
Ideal mouthfeel and the feeling melted in mouth.But the conjunction of shared L2U and LU2 in the grease of cladding fat or oil composition
If meter content becomes larger, the cladding coated on food becomes easy rupture with fat or oil composition.Therefore, cladding is combined with grease
Total content (hereinafter, also being indicated as L2U+L2U) of the L2U and LU2 in grease contained by object is preferably 20~90 mass %,
More preferably 25~80 mass %, it is further preferred that 30~70 mass %.
As the grease contained by cladding fat or oil composition, it is preferred to use the grease rich in L2U and LU2 (includes 40
The grease of quality % or more, the preferably L2U+LU2 comprising 60 mass % or more) so that the cladding grease group of the present invention
It closes the grease contained by object and contains above-mentioned L2U and LU2.As the grease rich in L2U and LU2 (hereinafter, also being indicated as L2U+LU2 oil
Fat) example, cocoa butter, palm oil, shea butter, thayer fat (sal tree fat), sub- blue blood fat (ア ラ Application Block can be enumerated
ラ ッ キ ア fat), Mowrahbutter, mist ice multitude fat, mango kernel oil, lard and butter and they point carry oil etc..In addition, being public
It is known to the public to be, it can use in palmitic acid, stearic acid or the high oleic acids such as their low-carbon-ester and high oleic sunflower oil
After carrying out ester exchange reaction using 1,3 selected fat enzyme preparations between grease, divide the grease raised as needed.This
Outside, the 90 mass % or more that can be the aliphatic acid for constituting grease are that the ester of the non-lauric acid system grease of 16 or more carbon atom number is handed over
It changes oil fat, alternatively, can be that its point carries oil.In the present invention, a kind or more of above-mentioned L2U+LU2 greases can be used.
In addition, as above-mentioned L2U+LU2 greases, palm system grease can be especially used.Here, palm system grease comes
Derived from the grease of palm oil, may be exemplified palm oil, palm oil point carry oil and their processing oil (has carried out hardening, ester is handed over
Change and divide the grease of the processing one or more of carried).More specifically, may be exemplified as 1 fraction carry oil palm olein oil,
Palmitic stearin；2 fractions as palm olein oil carry fraction leach-s/tive among the palm olein oil (the super olein of palm) and palm oil of oil；
2 fractions as palmitic stearin carry palm olein oil (soft palm oil) and palmitic stearin (hard stearic) of oil etc..Furthermore, it is possible to
It illustrates using the miscella of the grease other than above-mentioned a kind or more and palm system grease as the ester-exchanged oil of feedstock oil and fixed oil.
In the grease of the cladding fat or oil composition of the present invention, it is generally desirable to the above-mentioned L2U+ containing 20 mass % or more
LU2 greases.The content of shared above-mentioned L2U+LU2 greases is preferably 25 in the grease of the cladding fat or oil composition of the present invention
~90 mass %, more preferably 25~80 mass %, it is further preferred that 30~70 mass %.In particular, as L2U
In the case that+LU2 greases use cocoa butter, the content of shared cocoa butter in the grease of cladding fat or oil composition of the invention
Preferably 0.5~50 mass %, more preferably 3~43 mass %, it is further preferred that 4~40 mass %.If packet
It covers with the contents of L2U+LU2 greases shared in the grease of fat or oil composition and the content of cocoa butter within the above range, then
It is difficult to rupture if even if being coated on the fat or oil composition of the cladding on food rich in cocoa butter in grease.
The cladding fat or oil composition of the present invention, shared, fat A content and L2U's and LU2 is total in its grease
The mass ratio (hereinafter, also being indicated as fat A/(L2U+LU2)) of content (L2U+LU2) is preferably 0.01~3.0.Fat A/
(L2U+LU2) it is more preferably 0.03~2.0, it is further preferred that 0.05~1.5.If fat A/(L2U+LU2) is in
In above range, even if be then rich in L2U+LU2 greases in grease, the cladding being coated on food is combined with grease
Object is also difficult to rupture.
The cladding fat or oil composition of the present invention, as long as the content of fat A shared in its grease is 0.1~60 matter
Amount %, L2U and LU2 is total containing 10 mass % or more in the grease, then can also include the grease commonly used in eating.
As commonly used in edible grease, for example, can enumerate rapeseed oil, corn oil, continuous seed oil, safflower oil, sunflower oil, rice bran oil,
Greases such as sesame oil, olive oil, grape seed oil, peanut oil, linseed oil, coconut oil, palm-kernel oil and butter oil and to this
A little greases carried from mixed splitting or integrating, have hydrogenated, the grease etc. of selected in transesterification etc. a kind of or two kinds or more of processing.
The cladding fat or oil composition of the present invention, in its grease the content of shared U3 be preferably 49 mass % with
Under.Hereinafter, U3 is that the glyceride of the U of 3 molecules and 1 molecule bond is closed obtained triacylglycerol.The cladding grease of the present invention
The content of shared U3, more preferably 0~45 mass %, it is further preferred that 0~35 mass % in the grease of composition.
If the content of U3 is within the above range, it is coated on the fast drying of the cladding fat or oil composition on food.
The cladding fat or oil composition of the present invention, the content of shared lauric acid system grease is preferably 45 matter in grease
Measure % or less.The content of shared lauric acid system grease in the grease of the cladding fat or oil composition of the present invention, more preferably 0
~40 mass %, it is further preferred that 5~35 mass %.If the content of lauric acid system grease is within the above range,
Even if including L2U and LU2 are difficult to rupture if being coated on the fat or oil composition of the cladding on food in grease.
The cladding fat or oil composition of the present invention can also contain other ingredients other than grease according to its purposes.Make
To can serve as the substance of other ingredients, such as can enumerate (can as the cocoa ingredient for the chocolate ingredients being well known
Can block, cocoa power etc.), dairy products (whole milk powder, skimmed milk power, lactalbumin, powder cheese etc.), sweet taste class (granulated sugar, breast
Sugar, xylitol, antierythrite etc.), food materials (such as starch, dextrin, the soybean being well known can also be enumerated in addition to this
Albumen, nut fruits etc.), taste composition (fragrance, hot flavorings etc.), emulsifier, coloured material etc..The cladding oil of the present invention
Oil/fat composition, fat content are preferably 30~100 mass %, more preferably 40~100 mass %, and most preferably 50
~100 mass %.
Grease contained by the cladding fat or oil composition of the present invention also includes from original other than the grease of supplying
The grease of material.For example, in general, the content of cocoa grease in the block (cocoa butter) is 55 mass % (oil content 0.55), cocoa power
In the content of grease (cocoa butter) be 11 mass % (oil content 0.11), the content of the grease (butterfat) in whole milk powder is 25
Quality % (oil content 0.11).Therefore, the content of the grease of cladding fat or oil composition is by cladding fat or oil composition
The proportional quantity (quality %) of each raw material is multiplied by the value after the value that oil content obtains adds up to.
The cladding of the present invention is preferably chocolate with fat or oil composition.Chocolate is not limited to " チ ョ Us レ in the present invention
ー ト Class indicate the just Competing Zheng Regulations Approximately " of に Seki The Ru (the just Qu Yin Association Meetings meetings of national チ ョ コ レ ー ト industry) and jural rule
It is fixed.The chocolate of the present invention is to be added as needed on cocoa ingredient (cocoa mass, cocoa using edible oil and fat, carbohydrate as main material
Powder etc.), dairy products, fragrance, emulsifier etc., it is (mixed processes, micronized process, refining procedure, cold by chocolate manufacturing process
But process etc.) the substance that manufactures of part or all of process.In addition, the chocolate of the present invention, in addition to dark chocolate bar, ox
Further include white chocolate, colored chocolate other than milk chocolate.The content of the grease of the chocolate of the present invention is preferably 30~
70 mass %, more preferably 35~65 mass %, it is further preferred that 40~60 mass %.
The chocolate of the present invention preferably also contains carbohydrate other than grease.As carbohydrate, sugarcane can be used for example
Sugared (granulated sugar and pulverized sugar), lactose, glucose, fructose, maltose, reduction starch sugar compound, liquid sugar, enzyme converted syrup, isomery
Change liquid sugar, sucrose combination syrup, reduced sugar polydextrose, oligosaccharide, D-sorbite, reduction lactose, trehalose, xylose, wood
Sugar alcohol, maltitol, antierythrite, mannitol, gossypose and dextrin etc..The content of carbohydrate in the chocolate of the present invention is preferred
Be 20~60 mass %, more preferably 25~55 mass %, it is further preferred that 30~50 mass %.
The chocolate of the present invention can also use the raw material being generally mated in chocolate other than grease and carbohydrate.Tool
It says to body, the cocoas such as dairy products, cocoa mass and cocoa power ingredient, soybean such as whole milk powder and skimmed milk power can be used
Various powder, glue class, starch, the breasts such as powder, soybean protein, fruit processed goods, fruits and vegetables product, matcha powder end and coffee powder
Agent, antioxidant, coloured material and fragrance etc..
As the cladding fat or oil composition of the present invention or the purposes of chocolate, can enumerate to refrigeration and frozen food
Cladding.Specifically, can enumerate to ice cream class (ice cream, lactic acid ice cream (ラ Network ト ア イ ス) etc.), ice fruit (ice
Freeze fruit syrup etc.) cladding.Furthermore, it is possible to enumerate for preventing the moisture of ice cream class to beaker flask and crackling (モ Na カ)
Inner surface transfer, moisture-proof inner surface coating；And the packet of the bakery of freezen protectives such as freezing cake, freezing pie
Clothing.In addition, the coating of the present invention includes the mode of local coated foods.In addition, including sandwich, dispensing (topping), dispersion etc.
Mode.
The preparation method of cladding fat or oil composition as the present invention, without solid constituent other than grease the case where
Under, grease can be heated and be melted, be added as needed on allotment emulsifier etc., thus be prepared.Such as it can be according to skilful
The conventional method of gram force manufacture by mixing raw material, roller mill, refines, thus contains grease as chocolate to prepare
The cladding fat or oil composition of solid constituent in addition.
The application method of cladding fat or oil composition as the present invention, can enumerate will be as the food leaching of cladding object
Stain is in the cladding fat or oil composition in melting liquid in a manner of (hot submersion).Alternatively, can enumerate by becoming cladding
The food of the object side coated with the methods of fat or oil composition in the cladding for melting liquid of pouring, be coated with or spray from above
Formula.
Then, by being coated with fat or oil composition with the cladding of the present invention, it can be circulated and be coated when preserving
It is not likely to produce rupture, mouthfeel with fat or oil composition and what is melted feel excellent food in mouth.In addition, including Gao Shui at the same time
Divide in the food with low moisture raw material, by using the cladding fat or oil composition of the present invention, helps to prevent water transport.It is special
It is not the packet of the invention in the case where being coated to the freezings such as ice cream class, finger type chocolate puff or chilled food
Cover the significant effect with fat or oil composition.
Embodiment
Embodiment is enumerated below further illustrates the present invention.But the present invention is not restricted to these illustrates.
[analysis method]
MMM contents, L2M contents, LM2 contents, L2U contents, LU2 contents and the U3 contents of grease, according to gas chromatography
(JAOCS, vol 70,11,1111-1114 (1993)) are determined.
[test oil fat]
As experiment with having used grease below.
MMM-1：Synthesize that composition aliphatic acid is octanoic acid and capric acid, its mass ratio are 75：25 MMM, as MMM-1.
MMM-2：Synthesize that composition aliphatic acid is octanoic acid and capric acid, its mass ratio are 3：7 MMM, as MMM-2.
Fat A -1：The rapeseed oil of 86 mass parts and the MMM-1 of 14 mass parts are mixed.Then, using sodium methoxide as catalysis
Agent carries out random transesterification, has obtained transesterification grease.Then, extreme hardening is carried out to transesterification grease, then carried out molten
Agent point carries.Using obtained grease as fat A -1.The L2M+LM2 of fat A -1 is 95.4 mass %, L2M/LM2 4.1.
Fat A -2：The extreme fixed oil of the rapeseed oil of 50 mass parts and the MMM-2 of 50 mass parts are mixed.Then, by first
Sodium alkoxide has carried out random transesterification as catalyst, has obtained transesterification grease.Using obtained grease as fat A -2.Grease
The content of the MMM of A-2 is that 19.9 mass %, L2M+LM2 are 74.6 mass %, L2M/LM2 0.7.
L2U+LU2 greases -1：It regard cocoa butter (L2U+LU2 is 96.6 mass %) as L2U+LU2 greases -1.
L2U+LU2 greases -2：It regard palm olein oil (L2U+LU2 is 90.6 mass %) as L2U+LU2 greases -2.
Vegetable fat -1：It regard coconut oil (U3 contents are 0 mass %) as vegetable fat -1.
Vegetable fat -2：It regard rapeseed oil (U3 contents are 78.3 mass %) as vegetable fat -2.
[preparation 1 of chocolate]
According to the proportioning of 1~table of table 4, comparative example 1~8 and the ice cream of embodiment 1~12 are coated chocolate according to normal
The mixing of rule method, micronized, refining.Each chocolate of melt liquid state after refining is maintained at 35 DEG C, with each 7g's
Mode injects the culture dish for the diameter 90mm being stored at -20 DEG C.The rate of drying of the chocolate of injection is evaluated, into
And the chocolate being prepared is preserved 7 days at -20 DEG C, have rated apply stress when level of breakage, taste, mouthfeel and
The feeling melted in mouthful.Evaluation is carried out (◎ and zero is qualified) by 5 professional group personnel according to benchmark below synthesis.Evaluation
As a result as shown in 1~table of table 4.In addition, by chocolate in culture dish fixed evaluation method, become than being actually coated to ice
Evaluation in the case of food processed more under critical conditions.
[assessment item and benchmark]
[rate of drying]
◎：Fast drying is very good
○：Drying is relatively fast, well
△：Generally
×：It is dry slow, it is bad
[rupture after preservation]
◎：Crack-free is very good
○：Crack-free, well
△：Slightly rupture
×：It is bad in the presence of substantially rupturing
[taste]
◎：Chocolate taste is strong, very good
○：Chocolate taste is stronger, well
△：Generally
×：Lack chocolate taste, it is bad
[mouthfeel (tooth sense)]
◎：Brittleness with appropriateness is very good
○：With weaker brittleness, well
△：Generally
×：Toughness, it is bad
[feeling melted in mouth]
◎：There is the feeling of fast melt in mouth, it is very good
○：There is the feeling of relatively rapid thawing in mouth, well
△：Generally
×：Oiliness sense is strong, bad
[table 1]
Table 1
[table 2]
Table 2
[table 3]
Table 3
[table 4]
Table 4
[preparation 2 of chocolate]
Each chocolate in melt liquid state of above-mentioned comparative example 1 and embodiment 1 is maintained at 35 DEG C, by product temperature
The rodlike lactic acid ice cream of -20 DEG C of degree is immersed in each chocolate, has coated chocolate.The ice cream packet of comparative example 1
Clothing chocolate obviously peels off when edible, it is difficult to eat.On the other hand, the ice cream of embodiment 1 is coated chocolate crispy in taste, and
And it is not peeled off when edible.
Claims (10)
1. a kind of cladding fat or oil composition, which is characterized in that
In grease, following fat As containing 0.1~60 mass %, and L2U's and LU2 shared in the grease is total
Content (L2U+LU2) is 10 mass % or more,
Fat A：It is the grease that total content (L2M+LM2) comprising L2M and LM2 and L2M and LM2 is 50 mass % or more,
Wherein, the meaning of L, M, U, L2U, LU2, L2M and LM2 are as follows：
L：The saturated fatty acid of carbon atom number 16~24；
M：The aliphatic acid of carbon atom number 6~10；
U：The unsaturated fatty acid of carbon atom number 16~24；
L2U：The triacylglycerol that the U of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LU2：The triacylglycerol that the U of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule；
L2M：The triacylglycerol that the M of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LM2：The triacylglycerol that the M of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule.
2. cladding fat or oil composition according to claim 1, which is characterized in that shared L2M's contains in the fat A
The mass ratio (L2M/LM2) of amount and the content of LM2 is 0.05~4.5.
3. cladding fat or oil composition according to claim 1 or 2, which is characterized in that constitute the L2M and the LM2
M full dose in the content of shared capric acid be 20 mass % or more.
4. cladding fat or oil composition according to any one of claims 1 to 3, which is characterized in that in the grease
The mass ratio (fat A/(L2U+LU2)) of the content of shared fat A and total content (L2U+LU2) of L2U and LU2 is 0.01
~2.0.
5. the cladding fat or oil composition according to any one of Claims 1 to 4, which is characterized in that in the grease
The content of shared palm system grease is 5 mass % or more.
6. the cladding fat or oil composition according to any one of Claims 1 to 5, which is characterized in that in the grease
The content of shared cocoa butter is 0.5~50 mass %.
7. the cladding fat or oil composition according to any one of claim 1~6, which is characterized in that
The content of shared MMM is 0.01~12 mass % in the grease,
Wherein, the meaning of MMM is as follows：
MMM：The triacylglycerol that the M of 3 molecules is combined with the glycerine of 1 molecule.
8. the cladding fat or oil composition according to any one of claim 1~7, which is characterized in that the cladding is used
Fat or oil composition is chocolate.
9. a kind of food, which is characterized in that the food is in by the cladding oil described in any one of claim 1~8
The state of oil/fat composition cladding.
10. a kind of manufacturing method of the food coated with fat or oil composition, which is characterized in that
The manufacturing method uses cladding fat or oil composition coated foods, in the cladding fat or oil composition, in grease
In following fat As containing 0.1~60 mass %, and total content (L2U+ of L2U and LU2 shared in the grease
LU2) it is 10 mass % or more,
Fat A：It is the grease that total content (L2M+LM2) comprising L2M and LM2 and L2M and LM2 is 50 mass % or more,
Wherein, the meaning of L, M, U, L2U, LU2, L2M and LM2 are as follows：
L：The saturated fatty acid of carbon atom number 16~24；
M：The aliphatic acid of carbon atom number 6~10；
U：The unsaturated fatty acid of carbon atom number 16~24；
L2U：The triacylglycerol that the U of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LU2：The triacylglycerol that the U of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule；
L2M：The triacylglycerol that the M of the L of 2 molecules and 1 molecule is combined with the glycerine of 1 molecule；
LM2：The triacylglycerol that the M of the L of 1 molecule and 2 molecules is combined with the glycerine of 1 molecule.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-236067 | 2015-12-02 | ||
| JP2015236067 | 2015-12-02 | ||
| PCT/JP2016/085678 WO2017094818A1 (en) | 2015-12-02 | 2016-12-01 | Oil/fat coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108289469A true CN108289469A (en) | 2018-07-17 |
Family
ID=58797386
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680070245.9A Pending CN108289469A (en) | 2015-12-02 | 2016-12-01 | Cladding fat or oil composition |
Country Status (4)
| Country | Link |
|---|---|
| JP (2) | JP6154091B1 (en) |
| CN (1) | CN108289469A (en) |
| MY (1) | MY184263A (en) |
| WO (1) | WO2017094818A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110959739A (en) * | 2019-12-06 | 2020-04-07 | 内蒙古蒙牛乳业（集团）股份有限公司 | Binding layer and frozen beverage |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110996672B (en) * | 2017-08-01 | 2023-06-13 | 日清奥利友集团株式会社 | Oil and fat composition, oil-based food and method for producing the same, and bloom and granulating inhibitor and method |
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Also Published As
| Publication number | Publication date |
|---|---|
| MY184263A (en) | 2021-03-30 |
| JP2017143837A (en) | 2017-08-24 |
| JP6154091B1 (en) | 2017-06-28 |
| JPWO2017094818A1 (en) | 2017-11-30 |
| WO2017094818A1 (en) | 2017-06-08 |
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