CN108285328A - A kind of building ceramics of environment friendly corrosion protection and preparation method thereof - Google Patents
A kind of building ceramics of environment friendly corrosion protection and preparation method thereof Download PDFInfo
- Publication number
- CN108285328A CN108285328A CN201711494833.8A CN201711494833A CN108285328A CN 108285328 A CN108285328 A CN 108285328A CN 201711494833 A CN201711494833 A CN 201711494833A CN 108285328 A CN108285328 A CN 108285328A
- Authority
- CN
- China
- Prior art keywords
- parts
- environment friendly
- corrosion protection
- glair
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1315—Non-ceramic binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Finishing Walls (AREA)
Abstract
Include being prepared by the raw material of following parts by weight the invention discloses a kind of building ceramics of environment friendly corrosion protection and preparation method thereof：20 35 parts of zirconium dioxide, 20 30 parts of calcite in powder, 15 30 parts of agricultural crop straw, 10 20 parts of glair, 8 15 parts of ball clay, 20 35 parts of bentonite, 10 12 parts of flint clay, 11 22 parts of cyclohexane solution, 7 15 parts of aluminium oxide, 8 18 parts of sodium borohydride, 5 10 parts of trade waste, 5 10 parts of reinforcing fiber.The present invention is integrally made of ceramic material, and temperature in use is up to 900 DEG C, is prevented fires completely, and the high service life of intensity is long, alternative existing materials for wall and inflammable thermal insulation material substantially increase the safety of building construction；Ceramic waste greatly reduces the production cost of heat-insulating construction material as raw materials for production；Ceramic waste occupies a large amount of soils, causes environmental pollution, and the present invention realizes that the comprehensive utilization to trade waste, energy conservation and environmental protection reduce pollution using it as a kind of raw material of industry.
Description
Technical field
The present invention relates to technical field of ceramic preparation, and in particular to a kind of building ceramics of environment friendly corrosion protection and its preparation
Method.
Background technology
With increasing with wall heat insulation material associated fire disaster accident, building field is proposed in exterior insulation
Using fire prevention isolation and without ways such as cavitys in system, organic insulation material combustion characteristics Flame can be solved in this way and is easily passed
The defect broadcast, easily spread, to avoid the fire incident caused by causing flame spread, propagation inflammable thermal insulation material.But
It is that temperature tolerance, flame resistance and organic guarantor of the organic insulation material on wall body structure are not researched and solved in fireproof construction
Adiabator discharges cigarette poison gas in a fire, and the thermoplasticity such as EPS, XPS organic insulation material itself generates molten in combustion
The problems such as melting, dripping.This mean that fire-protection rating is low existing for organic insulation material technology, stability and durability difference
Inherent shortcoming has not adapted to requirement of the society to building thermal insulation material.
With social economy and the fast development of ceramic industry, ceramic industry waste material is increasing, and handling these waste materials needs
A large amount of social resources are expended, the sustainable development of development and the ceramic industry of urban economy is limited on partial extent.Mesh
Before, the processing of China's ceramic industry waste material and producing level are relatively low, and a large amount of waste residue ties up public resource, make environment by
Pollution.With the increase of ceramics production capacity, the quantity of waste material is more and more, and a large amount of zirconium dioxide has not been simply to fill
Soluble problem, the accumulation of zirconium dioxide tie up soil, and fine dust influences the quality of local air, and zirconium dioxide
Landfill expend a large amount of manpower and materials, go back polluted underground water matter, how to turn waste into wealth, zirconium dioxide is subjected to resource chemical combination
Reason utilizes, and has become the task of top priority of science and technology and environmental protection administration.
Ceramic material has many advantages, such as, such as beautiful and generous, acid and alkali-resistance, high temperature resistant, adds in daily necessities, building materials, machinery
The various fields such as work have extensive use.Aluminium oxide and zirconium oxide are two kinds of components common in ceramic material, and aluminium oxide has
The excellent properties such as the low, high temperature resistant of proportion have extensive use in ceramic material field, but its flexural strength and fracture toughness are relatively low
；Zirconium oxide has good flexural strength, is known as " Ceramo-steel ", but its proportion is larger, it will usually increase the weight of finished product.Oxygen
The combination for changing both zirconium and aluminium oxide, prepares composite ceramic material technology and receives more and more attention.Nickel oxide is logical
It is commonly used for the pigment of ceramic material.
Invention content
To solve the above problems, the present invention provides a kind of building waste utilization rate height, product water absorption rate is low, antifouling property
The building ceramics of environment friendly corrosion protection and preparation method thereof good, intensity is high.
To achieve the above object, the technical solution that the present invention takes is：
A kind of building ceramics of environment friendly corrosion protection and preparation method thereof, include being prepared by the raw material of following parts by weight：Two
20-35 parts of zirconium oxide, 20-30 parts of calcite in powder, 15-30 parts of agricultural crop straw, 10-20 parts of glair, 8-15 parts of ball clay, bentonite
20-35 parts, 10-12 parts of flint clay, 11-22 parts of cyclohexane solution, 7-15 parts of aluminium oxide, 8-18 parts of sodium borohydride, industrial waste
It is 5-10 parts of object, 5-10 parts of reinforcing fiber, 4-8 parts of sintering aid, gelling agent 5-9 parts additional.
Further, a kind of building ceramics of environment friendly corrosion protection include being prepared by the raw material of following parts by weight：Two
21-34 parts of zirconium oxide, 21-28 parts of calcite in powder, 16-27 parts of agricultural crop straw, 11-19 parts of glair, 9-14 parts of ball clay, bentonite
22-33 parts, 11-12 parts of flint clay, 15-20 parts of cyclohexane solution, 8-14 parts of aluminium oxide, 9-17 parts of sodium borohydride, industrial waste
It is 6-8 parts of object, 6-9 parts of reinforcing fiber, 5-7 parts of sintering aid, gelling agent 6-8 parts additional.
Further, the glair is one or more in silica, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
Further, a kind of preparation method of the building ceramics of environment friendly corrosion protection, includes the following steps：
S1, by 21-34 parts of zirconium dioxide, 21-28 parts of calcite in powder, 16-27 parts of agricultural crop straw, 8-15 parts of ball clay, bentonite
20-35 parts, after the mixing of 11-12 parts of flint clay, be added after pulverizer crushes, cross 100-130 mesh screens, obtain material；
S2, step S1 is obtained material add water carry out ball milling, then be added 11-19 parts of glair, 15-20 parts of cyclohexane solution, oxygen
Change 6-9 parts of 8-14 parts of aluminium, 9-17 parts of sodium borohydride, 6-8 parts of trade waste, reinforcing fiber progress wet ball mill 10-20min, instead
Multiple ball milling 2-3 times, obtains ceramic slurry；
S3,5-7 parts of sintering aid, additional gelling agent 6-8 parts are added into water stirring, is heated up to 30-40 DEG C, stirs evenly；Changed
Property solution；
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
Further, a kind of building ceramics of environment friendly corrosion protection include being prepared by the raw material of following parts by weight：Two
28 parts of zirconium oxide, 25 parts of calcite in powder, 19 parts of agricultural crop straw, 17 parts of glair, 11 parts of ball clay, 27 parts of bentonite, flint clay 11
Part, 18 parts of cyclohexane solution, 11 parts of aluminium oxide, 15 parts of sodium borohydride, 7 parts of trade waste, 8 parts of reinforcing fiber, sintering aid 6
Part, 7 parts of additional gelling agent.
The present invention is using zirconium dioxide, calcite in powder, agricultural crop straw, glair, ball clay, bentonite, flint clay, hexamethylene
Solution, aluminium oxide, sodium borohydride, trade waste, reinforcing fiber effectively match, and obtain building ceramics, and temperature in use is high
Up to 900 DEG C, prevent fires completely, and the high service life of intensity is long, alternative existing materials for wall and inflammable thermal insulation material, significantly
The safety enhancing ceramics strength that improves building construction is high, compactness is good, toughness significantly improves, and high temperature resistant and wear-resisting excellent
It is different, can be widely used for it is various to the strength of materials require high field use mineral and industrial chemicals.
The present invention is integrally made of ceramic material, and temperature in use is up to 900 DEG C, is prevented fires completely, and the high service life of intensity
Long, alternative existing materials for wall and inflammable thermal insulation material substantially increase the safety of building construction；Ceramic waste
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced；Ceramic waste occupies a large amount of soils, causes ring
Border is polluted, and the present invention realizes that the comprehensive utilization to trade waste, energy conservation and environmental protection are reduced dirty using it as a kind of raw material of industry
Dye；Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources；Cheap, production
It is simple for process, it is suitble to large-scale production.
Specific implementation mode
In order to make objects and advantages of the present invention be more clearly understood, the present invention is carried out with reference to embodiments further detailed
Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being prepared by the raw material of following parts by weight：20-35 parts of zirconium dioxide, 20-30 parts of calcite in powder,
15-30 parts of agricultural crop straw, 10-20 parts of glair, 8-15 parts of ball clay, 20-35 parts of bentonite, 10-12 parts of flint clay, hexamethylene are molten
11-22 parts of liquid, 7-15 parts of aluminium oxide, 8-18 parts of sodium borohydride, 5-10 parts of trade waste, 5-10 parts of reinforcing fiber, sintering help
It is 4-8 parts of agent, gelling agent 5-9 parts additional.
A kind of building ceramics of environment friendly corrosion protection include being prepared by the raw material of following parts by weight：Zirconium dioxide 21-
34 parts, 21-28 parts of calcite in powder, 16-27 parts of agricultural crop straw, 11-19 parts of glair, 9-14 parts of ball clay, 22-33 parts of bentonite,
11-12 parts of flint clay, 15-20 parts of cyclohexane solution, 8-14 parts of aluminium oxide, 9-17 parts of sodium borohydride, 6-8 parts of trade waste,
It is 6-9 parts of reinforcing fiber, 5-7 parts of sintering aid, gelling agent 6-8 parts additional.
The glair is one or more in silica, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
A kind of preparation method of the building ceramics of environment friendly corrosion protection, includes the following steps：
S1, by 21-34 parts of zirconium dioxide, 21-28 parts of calcite in powder, 16-27 parts of agricultural crop straw, 8-15 parts of ball clay, bentonite
20-35 parts, after the mixing of 11-12 parts of flint clay, be added after pulverizer crushes, cross 100-130 mesh screens, obtain material；
S2, step S1 is obtained material add water carry out ball milling, then be added 11-19 parts of glair, 15-20 parts of cyclohexane solution, oxygen
Change 6-9 parts of 8-14 parts of aluminium, 9-17 parts of sodium borohydride, 6-8 parts of trade waste, reinforcing fiber progress wet ball mill 10-20min, instead
Multiple ball milling 2-3 times, obtains ceramic slurry；
S3,5-7 parts of sintering aid, additional gelling agent 6-8 parts are added into water stirring, is heated up to 30-40 DEG C, stirs evenly；Changed
Property solution；
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
It grinds, crosses 100 mesh sieve, the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
Embodiment 1：
A kind of preparation method of the building ceramics of environment friendly corrosion protection, includes the following steps：
S1, by 26 parts of zirconium dioxide, 26 parts of calcite in powder, 19 parts of agricultural crop straw, 12 parts of ball clay, 28 parts of bentonite, flint clay
After 11 parts of mixing, after addition pulverizer crushes, 120 mesh screens is crossed, material is obtained；
S2, step S1 is obtained material add water carry out ball milling, then be added 17 parts of glair, 17 parts of cyclohexane solution, aluminium oxide 11
7 parts of part, 15 parts of sodium borohydride, 7 parts of trade waste, reinforcing fiber progress wet ball mill 16min, repeatedly ball milling 2-3 times are made pottery
Porcelain slurry；
S3,6 parts of sintering aid, 7 parts of additional gelling agent plus water are stirred, is heated up to 36 DEG C, stirs evenly；Obtain modified solution；
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
Embodiment 2：
A kind of preparation method of the building ceramics of environment friendly corrosion protection, includes the following steps：
S1, by 34 parts of zirconium dioxide, 28 parts of calcite in powder, 27 parts of agricultural crop straw, 15 parts of ball clay, 35 parts of bentonite, flint clay
After 12 parts of mixing, after addition pulverizer crushes, 130 mesh screens is crossed, material is obtained；
S2, step S1 is obtained material add water carry out ball milling, then be added 19 parts of glair, 20 parts of cyclohexane solution, aluminium oxide 14
9 parts of part, 17 parts of sodium borohydride, 8 parts of trade waste, reinforcing fiber progress wet ball mill 20min, ball milling 3 times, obtain ceramics repeatedly
Slurry；
S3,7 parts of sintering aid, 8 parts of additional gelling agent plus water are stirred, is heated up to 40 DEG C, stirs evenly；Obtain modified solution；
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
Embodiment 3：
A kind of preparation method of the building ceramics of environment friendly corrosion protection, includes the following steps：
S1, by 21 parts of zirconium dioxide, 21 parts of calcite in powder, 16 parts of agricultural crop straw, 8 parts of ball clay, 20 parts of bentonite, flint clay 11
After part mixing, after addition pulverizer crushes, 100 mesh screens is crossed, material is obtained；
S2, step S1 is obtained material add water carry out ball milling, then be added 11 parts of glair, 15 parts of cyclohexane solution, aluminium oxide 8
6 parts of part, 9 parts of sodium borohydride, 6 parts of trade waste, reinforcing fiber progress wet ball mill 10min, ball milling 2 times, obtain ceramics repeatedly
Slurry；
S3,5 parts of sintering aid, 6 parts of additional gelling agent plus water are stirred, is heated up to 30 DEG C, stirs evenly；Obtain modified solution；
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
The present invention is using zirconium dioxide, calcite in powder, agricultural crop straw, glair, ball clay, bentonite, flint clay, hexamethylene
Solution, aluminium oxide, sodium borohydride, trade waste, reinforcing fiber effectively match, and obtain building ceramics, and temperature in use is high
Up to 900 DEG C, prevent fires completely, and the high service life of intensity is long, alternative existing materials for wall and inflammable thermal insulation material, significantly
The safety enhancing ceramics strength that improves building construction is high, compactness is good, toughness significantly improves, and high temperature resistant and wear-resisting excellent
It is different, can be widely used for it is various to the strength of materials require high field use mineral and industrial chemicals.
The present invention is integrally made of ceramic material, and temperature in use is up to 900 DEG C, is prevented fires completely, and the high service life of intensity
Long, alternative existing materials for wall and inflammable thermal insulation material substantially increase the safety of building construction；Ceramic waste
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced；Ceramic waste occupies a large amount of soils, causes ring
Border is polluted, and the present invention realizes that the comprehensive utilization to trade waste, energy conservation and environmental protection are reduced dirty using it as a kind of raw material of industry
Dye；Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources；Cheap, production
It is simple for process, it is suitble to large-scale production.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of building ceramics of environment friendly corrosion protection, which is characterized in that include being prepared by the raw material of following parts by weight：Two
20-35 parts of zirconium oxide, 20-30 parts of calcite in powder, 15-30 parts of agricultural crop straw, 10-20 parts of glair, 8-15 parts of ball clay, bentonite
20-35 parts, 10-12 parts of flint clay, 11-22 parts of cyclohexane solution, 7-15 parts of aluminium oxide, 8-18 parts of sodium borohydride, industrial waste
It is 5-10 parts of object, 5-10 parts of reinforcing fiber, 4-8 parts of sintering aid, gelling agent 5-9 parts additional.
2. a kind of building ceramics of environment friendly corrosion protection according to claim 1, which is characterized in that including by following weight
The raw material of part is prepared：21-34 parts of zirconium dioxide, 21-28 parts of calcite in powder, 16-27 parts of agricultural crop straw, glair 11-19
Part, 9-14 parts of ball clay, 22-33 parts of bentonite, 11-12 parts of flint clay, 15-20 parts of cyclohexane solution, 8-14 parts of aluminium oxide, boron hydrogen
Change 9-17 parts of sodium, 6-8 parts of trade waste, 6-9 parts of reinforcing fiber, 5-7 parts of sintering aid, gelling agent 6-8 parts additional.
3. a kind of building ceramics of environment friendly corrosion protection according to claim 1, which is characterized in that the glair is oxidation
It is one or more in silicon, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
4. a kind of preparation method of the building ceramics of environment friendly corrosion protection according to claim 1, which is characterized in that including
Following steps：
S1, by 21-34 parts of zirconium dioxide, 21-28 parts of calcite in powder, 16-27 parts of agricultural crop straw, 8-15 parts of ball clay, bentonite
20-35 parts, after the mixing of 11-12 parts of flint clay, be added after pulverizer crushes, cross 100-130 mesh screens, obtain material；
S2, step S1 is obtained material add water carry out ball milling, then be added 11-19 parts of glair, 15-20 parts of cyclohexane solution, oxygen
Change 6-9 parts of 8-14 parts of aluminium, 9-17 parts of sodium borohydride, 6-8 parts of trade waste, reinforcing fiber progress wet ball mill 10-20min, instead
Multiple ball milling 2-3 times, obtains ceramic slurry；
S3,5-7 parts of sintering aid, additional gelling agent 6-8 parts are added into water stirring, is heated up to 30-40 DEG C, stirs evenly；Changed
Property solution；
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
5. a kind of building ceramics of environment friendly corrosion protection according to claim 1, which is characterized in that including by following weight
The raw material of part is prepared：28 parts of zirconium dioxide, 25 parts of calcite in powder, 19 parts of agricultural crop straw, 17 parts of glair, 11 parts of ball clay,
27 parts of bentonite, 18 parts of cyclohexane solution, 11 parts of aluminium oxide, 15 parts of sodium borohydride, 7 parts of trade waste, increases 11 parts of flint clay
Strong 8 parts of fiber, 6 parts of sintering aid, 7 parts of additional gelling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711494833.8A CN108285328A (en) | 2017-12-31 | 2017-12-31 | A kind of building ceramics of environment friendly corrosion protection and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711494833.8A CN108285328A (en) | 2017-12-31 | 2017-12-31 | A kind of building ceramics of environment friendly corrosion protection and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108285328A true CN108285328A (en) | 2018-07-17 |
Family
ID=62819457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711494833.8A Pending CN108285328A (en) | 2017-12-31 | 2017-12-31 | A kind of building ceramics of environment friendly corrosion protection and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108285328A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109133979A (en) * | 2018-10-17 | 2019-01-04 | 阜阳市卓创科技服务生产力促进中心 | A kind of stalk exterior wall thermal insulation brick and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002321965A (en) * | 2001-04-24 | 2002-11-08 | Matsushita Electric Works Ltd | Waste material-utilizing brick and method for manufacturing the same |
| CN106565211A (en) * | 2016-10-28 | 2017-04-19 | 芜湖浩权建筑工程有限公司 | High-performance environment-friendly building-use ceramic material and preparation method thereof |
| CN106747309A (en) * | 2016-12-15 | 2017-05-31 | 芜湖浩权建筑工程有限公司 | A kind of building composite ceramics of environment protection type heat insulating insulation and preparation method thereof |
-
2017
- 2017-12-31 CN CN201711494833.8A patent/CN108285328A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002321965A (en) * | 2001-04-24 | 2002-11-08 | Matsushita Electric Works Ltd | Waste material-utilizing brick and method for manufacturing the same |
| CN106565211A (en) * | 2016-10-28 | 2017-04-19 | 芜湖浩权建筑工程有限公司 | High-performance environment-friendly building-use ceramic material and preparation method thereof |
| CN106747309A (en) * | 2016-12-15 | 2017-05-31 | 芜湖浩权建筑工程有限公司 | A kind of building composite ceramics of environment protection type heat insulating insulation and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109133979A (en) * | 2018-10-17 | 2019-01-04 | 阜阳市卓创科技服务生产力促进中心 | A kind of stalk exterior wall thermal insulation brick and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103342468B (en) | Composite sheet of foam pyroceram and pure devitrified glass and preparation method thereof | |
| CN105367024B (en) | A kind of external-wall heat-insulation material | |
| CN103553458B (en) | C180 strength-grade concrete for formed steel concrete composite structure | |
| CN105084833B (en) | High-strength insulation full lightweight concrete and its preparation method and application | |
| CN101514089B (en) | Self-insulation external wallboard for buildings | |
| CN103304255A (en) | Innovative flame-retardant, water-proof, mildew-proof and radiation-proof insulating mortar and product | |
| CN104829263B (en) | A kind of light ceramics composite heat-insulating construction material and preparation method | |
| CN102797299A (en) | Insulation board made of fiber reinforced composites and preparation method of insulation board | |
| CN104563425B (en) | Integration board for decorating, preventing fire and keeping warm | |
| CN108298948A (en) | A kind of high-strength composite building ceramics and preparation method thereof | |
| CN106747309A (en) | A kind of building composite ceramics of environment protection type heat insulating insulation and preparation method thereof | |
| CN101585671A (en) | Compound admixture for concrete and preparation method thereof | |
| CN101585687A (en) | Insulation and fire-proof material and production method thereof | |
| CN102173717B (en) | Production method of high-strength light environment-friendly insulation fire-proof plate | |
| CN105669146A (en) | Autoclaved aerated concrete block containing neutral sodium-salt alkali activated slag concrete and preparation method of autoclaved aerated concrete block | |
| CN105236893B (en) | One kind mixes ultralight pearlite heat-insulation plate of iron tailings and preparation method thereof | |
| CN106348662A (en) | Ceramsite with slag and building waste and method for preparing ceramsite | |
| CN108558208A (en) | A kind of environment protection architecture ceramic glaze and preparation method thereof | |
| CN108285328A (en) | A kind of building ceramics of environment friendly corrosion protection and preparation method thereof | |
| CN106242618A (en) | A kind of self-cleaning ecological permeable bricks and preparation method thereof | |
| CN103992071A (en) | Fabrication process for producing concrete brick by using polished tile waste residue | |
| CN106167361A (en) | A kind of alkaline residue building waste haydite and preparation method thereof | |
| CN107417167A (en) | A kind of Novel fireproof material and preparation method thereof | |
| CN107500586A (en) | One kind exempts from the Environment-friendlyceramsite ceramsite for building that foams | |
| CN108046746A (en) | A kind of ceramic material of modified composite environmental-friendly for building and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180717 |
|
| RJ01 | Rejection of invention patent application after publication |