CN108277540A - A kind of integral type blowing electrostatic spinning device - Google Patents

A kind of integral type blowing electrostatic spinning device Download PDF

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Publication number
CN108277540A
CN108277540A CN201710173291.8A CN201710173291A CN108277540A CN 108277540 A CN108277540 A CN 108277540A CN 201710173291 A CN201710173291 A CN 201710173291A CN 108277540 A CN108277540 A CN 108277540A
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CN
China
Prior art keywords
nozzle
stainless steel
voltage
spinning
fan
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710173291.8A
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Chinese (zh)
Inventor
吴强
刘清杰
宋小杰
王若鑫
孙浩然
张永强
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Individual
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Individual
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Priority to CN201710173291.8A priority Critical patent/CN108277540A/en
Publication of CN108277540A publication Critical patent/CN108277540A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0069Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0076Electro-spinning characterised by the electro-spinning apparatus characterised by the collecting device, e.g. drum, wheel, endless belt, plate or grid
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0092Electro-spinning characterised by the electro-spinning apparatus characterised by the electrical field, e.g. combined with a magnetic fields, using biased or alternating fields
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/088Cooling filaments, threads or the like, leaving the spinnerettes

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

The invention belongs to electrostatic spinning technique field, a kind of integral type blowing electrostatic spinning device provides power supply by battery for high-voltage d. c inverse transform device, propeller, fan, controller;High-voltage d. c inverse transform device, propeller, fan are controlled and adjusted by controller;In spinning process, spinning solution is flowed out by propeller fltting speed from stainless pin head, and under the high pressure that high-voltage d. c inverse transform device provides, stainless steel syringe needle forms highfield with conductive interannular, and stainless steel syringe needle sprays jet stream;Fan generates the air-flow of orientation in upper insulation crust simultaneously, and converges at nozzle and quickly flow out, and accelerates the volatilization of solvent in jet stream and guides fiber from nozzle target object.It is this integral type blowing electrostatic spinning device using flexible, simple in structure, small portable, at low cost, safer, fiber collecting device is without connecing electricity, it increases spinning safety and reduces fiber defect, it both can field teaching, wound reparation, it can also be used in laboratory and production.

Description

A kind of integral type blowing electrostatic spinning device
Technical field
The invention belongs to electrostatic spinning apparatus technical fields, and in particular to and one kind being integrated with traditional spinning equipment feature, and The electrostatic spinning device that small, light is portable, can be carried around, dries secondary injection nanofiber.
Background technology
Method of electrostatic spinning is one of Process Technology of Polymer method, and making nanofiber is at low cost, processing method is simple, in recent years To be reported by extensive research both domestic and external.The micro nanometer fiber prepared using electrostatic spinning technique processing has high-ratio surface The good characteristics such as long-pending, larger length/diameter ratio and unique physicochemical properties, bioengineered tissue, wound dressing, The fields such as filter protection, medicament slow release, flexible device show great application potential.Method of electrostatic spinning principle is very simple, Summary is:Under high voltage electric field effect, electricity, which connects, forms high voltage electric field between the nozzle of high voltage power supply and receiver board, and the shape at nozzle At taylor cone, make nozzle spinning solution by electric field force stretching to prepare nanofiber and be deposited on receiver board, and prepares nanometer The most direct simplest method of fiber.
Existing electrospinning device is mainly made of high voltage power supply, micro propeller, nozzle, reception device etc., and fiber is received What acquisition means and nozzle were separate from, and electricity connects DC high-voltage output end the two poles of the earth, common electrostatic spinning equipment body respectively The limitations such as product is big, quality is big, not portable, solvent volatilization is slow, seriously constrain the popularization and application of electrostatic spinning technique.In order to Solution electrospinning device volume is not larger portable, and correlative study worker has carried out many improvement to electrostatic spinning apparatus. As report changes traditional spinning nozzle in Chinese patent " a kind of handheld portable electrospinning device " (201220605695.2) It is portable, light to achieve the purpose that with this into for hand-held nozzle pattern, but the device still needs external power supply, limits Its use environment cannot meet the needs of practical application;Long Yunze in 2012 etc. reports a kind of " portable hand-held electrostatic for the first time Device for spinning " (201210229010.3), the device use rectangular cell to provide power supply for high-voltage d. c inverse transform device, overcome existing There is equipment can not portable defect so that portable to be really possibly realized.But the device structure is relatively simple, cannot adjust spinning The parameters such as silk liquid push-in stroke, output voltage, it is weaker to different spinning solution applicabilities, and High voltage output one end and human contact, Make its apply and safety be all restricted, meanwhile, the device be mainly used for field teaching, the wounded rescue etc. it is of short duration use field It closes, application range is also restricted, and present electrospinning device remains on that there are many problems not to solve, electrostatic spinning process one As be all that spinning solution is spun into nanofiber using electrospinning device and is deposited on collection device, but collection device is necessary Then conductive and electrical connection high-field electrode is then transferred to using position, transfer process attaches effect to the pattern and fiber of fiber Fruit has a significant impact, and volatilize slow spinning solution of solvent is made fiber and is unevenly distributed etc. with a beading, diameter and lacks It falls into, therefore a kind of flexible integral type blowing electrostatic spinning device of novel use environment of exploitation is very necessary, integral type is blown Wind electrostatic spinning device light weight is small easy to carry, is not necessarily to external power supply, can be sprayed to any direction, arbitrary isolated objects Nanofiber does not require fiber collecting device conductive, considerably increases the applicable flexibility of electrospinning device, and gas is generated in fan Under the auxiliary of stream, solvent evaporation rate is also increased, avoids a beading, the phenomenon that the defects of diameter is unevenly distributed occurs;Together When, it also can use lower nozzle and fiber collected using conductive receiver device.
Invention content
It is an object of the invention to overcome shortcoming and defect of the existing technology, seek to design a kind of light weight, volume The integral type blowing electrostatic spinning device small, spinning is stable, safe and reliable, application flexibility is big, the spinning that high direct voltage is generated are strong Field distribution reduces external disturbance inside integral type blowing electrostatic spinning device.It can be achieved directly to receive arbitrary objects injection Rice fiber, integrates traditional spinning equipment function, and is generated using fan and to orient uniform air-flow and guide fiber, reduces pair The requirement of fiber collecting device avoids fiber and a beading occurs and the defects of diameter is unevenly distributed.
To achieve the above object, the present invention provides the following technical solutions:Main body of the present invention includes battery, high-voltage d. c inverse transform Device, syringe, pusher, fan, controller, stainless steel syringe needle, nozzle, upper insulation crust, nozzle is by same in lower insulation crust Conducting ring composition is fixedly mounted in axis;It is co-axially mounted syringe in upper insulation crust, fan is installed on rear side of syringe;It is upper exhausted The fixation of edge outer casing inner wall is formed with propeller, and the push rod connection of syringe is mounted on propeller, is pushed away by controller control and regulation Into device fltting speed and fan velocity of rotation;It is equipped with spinning solution in the front end inner cavity of syringe, plug-in type on the bottom end of syringe It is formed with the stainless steel syringe needle for spinneret, stainless steel syringe needle is matched using conventional medical injecting head structure and with combinations of syringe Set, syringe are also the injector for medical purpose of routine;Nozzle with thread fiting mode be mounted on upper insulation crust on, nozzle with it is upper absolutely Edge shell is coaxial;Dock fixation is formed with rectangular cell and high-voltage d. c inverse transform device, controller on upper insulation crust side wall;Using 12 volts of batteries provide power supply for high-voltage d. c inverse transform device and fan, propeller, controller, also can external 12-volt dc power supply confession Electricity;Input voltage output voltage after high-voltage d. c inverse transform device reaches number KV level, and high straightening is controlled by controller upper switch Inverter is flowed to open and close;High-voltage d. c inverse transform device anode is electrically connected with stainless steel syringe needle, high-voltage d. c inverse transform device cathode with Fixed conducting ring is electrically connected on nozzle.
The present invention in loadings in insulation crust, and is opened by controller and is pushed away in use, spinning solution is first packed into syringe Into device, fltting speed is set;When occurring spinning solution drop at stainless steel needle tip, by nozzle towards fiber gleanings, spacing It it is 1-15 centimetres, it is the nonisulated property substances such as metal foil or human skin to collect object;Then fan is opened, controller tune is passed through Save wind speed;High-voltage d. c inverse transform device is connected, stainless steel syringe needle sprays nanofiber, the orientation that fan generates in upper insulation crust Air-flow, and sprayed after nozzle convergence, so that the air pressure of nozzle air-flow and wind speed is all increased, not only guides the injection of fiber, but also The volatilization for accelerating solvent, largely avoided a beading and the defects of diameter is unevenly distributed fiber appearance, fiber sprays from nozzle It is deposited on and collects on object;By changing nozzle at a distance from stainless steel syringe needle, formed between stainless steel syringe needle and nozzle to adjust Spinning electric field strength, and adjust the parameters such as fan wind speed to adapt to different spinning conditions, to obtain the fiber of needs.
The present invention changes the structure of traditional spinning equipment, simple in structure, it is small be easy to carry about with one, it is hand-held it is easy to use, At low cost, it concentrates on the spinning electric field that high-voltage d. c inverse transform device output end the two poles of the earth are formed in electrostatic spinning structure, and increases Fan, improves the safety of equipment, using flexibility, fiber quality etc.;When removing nozzle, high-voltage output end the two poles of the earth are distinguished Electric connection stainless steel syringe needle and other fiber collecting devices, similar tradition spinning equipment is, it can be achieved that such as directional fiber, patterning The collections such as fiber;Also can external 9 volts of DC power supplies for integral type dry electrostatic spinning device power supply is provided.
Description of the drawings
Fig. 1 is the agent structure principle schematic of the present invention.
Fig. 2 is that electrostatic spinning nano fiber of the present invention is deposited on the schematic diagram in isolated objects.
Fig. 3 is electrostatic spinning schematic diagram of the present invention after removing nozzle.
Fig. 4 is PEO nanofiber electron scanning micrographs prepared by the present invention.
Specific implementation mode
The following describes the present invention in detail with reference to the accompanying drawings and specific embodiments.
The structural schematic diagram of the present invention is as shown in Figure 1, by battery 1, controller 2, high-voltage d. c inverse transform device 3, fan 4, push away Dynamic device 5, upper insulation crust 6, syringe 7, spinning solution 8, stainless steel syringe needle 9, lower insulation crust 10, conducting ring 11, nozzle 12;Often It advises in the front end inner cavity of medical syringe 7 and is equipped with spinning solution 8;It is inserted into and is connected with for spinneret on the bottom end of syringe 7 Stainless steel syringe needle 9, stainless steel syringe needle 9 form a complete set of using conventional medical injecting head structure and with syringe;Syringe 7 Push rod top is mounted on propeller 5, pushes spinning solution 8 in syringe 7 slowly to be flowed out from stainless pin head 9 by propeller 5; The 6 outside dock fixation of upper insulation crust is formed with high-voltage d. c inverse transform device 3, and 3 high-voltage output end of high-voltage d. c inverse transform device is electric respectively It is connected to stainless steel syringe needle 9 and conducting ring 11;Battery 1 is high-voltage d. c inverse transform high-voltage device 3, pusher 5, fan 4, controller 2 carry Power supply source;Controller 2 is for switch DC inversion high pressure 3,5 fltting speed of adjusting propeller, 4 rotating speed of fan.
The insertion of stainless steel syringe needle 9 is connected to syringe 7 by the present invention in use, first by the injection syringe 7 of spinning solution 8 On, then syringe 7 is packed into upper insulation crust 6,9 electric connection high-voltage d. c inverse transform device of stainless steel syringe needle, 3 high-voltage output end Anode, cathode electric connection conducting ring 11 open propeller 5 on controller 2 and set the fltting speed of propeller 5, when stainless When spinning solution 8 occurs in 9 needle point of draw point head, fan 4 is opened, adjusts wind speed, high-voltage d. c inverse transform device 3 is opened, then adjusts nozzle 12 with the spacing of stainless steel syringe needle 9;Electrostatic spinning starts, stainless steel syringe needle 9 spray nanofiber, and under the guiding of air-flow from The ejection of spout 12, which is deposited on, to be received on object;After waiting for spinning, high direct voltage inverter 3 is closed, closes propeller 5, is closed Fan 4, spinning solution stop outflow, and spinning stops;It is apparent that nanofiber pattern by electronic scanner microscope, such as schemes 4, fiber morphology is preferable, even thickness, zero defect.
The deionized water solution for the polyethylene glycol oxide (PEO) that spinning solution 8 selected by the present invention is 6wt%, first by 0.3 gram Polyethylene glycol oxide (PEO) powder is mixed with 4.7 grams of deionized waters, at room temperature magnetic agitation 4 hours, then stands 0.5 hour, is obtained The PEO spinning solutions 8 of uniform 6wt%;
The present invention is in use, remove nozzle 12,3 output head anode electric connection stainless steel syringe needle 9 of high direct voltage inverter, Cathode is electrically connected fiber collecting board;Insulation crust 6 is first grasped, stainless steel syringe needle 9 is placed in apart from collecting board 5-20 Centimeters, collecting board are conductive metal foil or metallic plate;Then spinning solution 8 is injected in syringe 7, stainless steel syringe needle 9 is inserted Enter to be connected on syringe 7, then syringe 7 is packed into upper insulation crust 6, it is inverse that stainless steel syringe needle 9 is electrically connected high voltage direct current Become 3 output head anode of device, propeller 5 is opened on controller 2 and setting promotes rate;When 9 needle point of stainless steel syringe needle is spun When silk liquid 8, opens fan 4 and high-voltage d. c inverse transform device 3, electrostatic spinning process start.Spinning solution 8 in propeller 5 enters not High-pressure electrostatic can be taken after rust draw point head 9, the spinning solution 8 of electrification forms taylor cone under the action of high-voltage electricity field force, works as electric field When power is sufficiently large, spinning solution drop overcome surface tension formed injection thread, thread evaporation of the solvent or solidification in course of injection, Nanofiber or the tunica fibrosa of similar non-woven cloth-like are formed on collecting board.
Insulation crust 6 and lower insulation crust 10 use high voltage insulating materials in the present invention, while in 6 side of upper insulation crust Abutting joint has battery 1, controller 2, high direct voltage inverter 3;User can hold insulation crust 6 and operate, can To form film to any position jet fiber, the spinning in open environment is realized, fiber gleanings, fiber size and shape are not By equipment limit, solvent evaporation rate is increased, largely avoided the appearance of defect fiber;It is also possible to which grafting is external straight Power supply power supply is flowed, it is flexible to increase using for spinning equipment.

Claims (6)

  1. The electrostatic spinning device 1. a kind of integral type is dried, it is characterised in that including battery, high-voltage d. c inverse transform device, syringe, promotion Device, fan, controller, stainless steel syringe needle, nozzle, upper insulation crust, the nozzle are installed on by conducting ring in lower insulation crust Composition;Battery provides power supply, electricity after high-voltage dc voltage inversion for high-voltage d. c inverse transform device, propeller and fan, controller For pressure up to number KV level, high-voltage output end anode is electrically connected stainless steel syringe needle, and cathode is electrically connected conducting ring;After fan is located at syringe Side adjusts rotation speed of the fan by controller;Syringe is coaxially fixedly mounted in insulation crust, the push rod assembly connection of syringe On propeller, fltting speed is adjusted from the micro regulation and control realized to spinning solution push-in stroke by controller;In the front end of syringe Spinning solution is housed, the head plug-in type of syringe is formed with the stainless steel syringe needle for spinneret, and stainless steel syringe needle is using conventional in chamber Medical injecting head structure is simultaneously mating with combinations of syringe;The output end of high-voltage d. c inverse transform device is electrically connected stainless pin Head and conducting ring;Dock fixation is formed with battery and high-voltage d. c inverse transform device, controller on upper insulation crust side;Nozzle with it is upper Insulation crust screw-thread fit connects and stainless steel syringe needle and nozzle are coaxial.
  2. The electrostatic spinning device 2. integral type as described in claim 1 is dried, which is characterized in that distance between stainless steel syringe needle and nozzle Can adjust, between stainless steel syringe needle and nozzle distance refer to stainless steel needle tip with the conducting ring installed on nozzle it is axial away from From distance range is 1 centimetre to 5 centimetres.
  3. The electrostatic spinning device 3. integral type as described in claim 1 is dried, which is characterized in that nozzle can be torn open from upper insulation crust Under.
  4. The electrostatic spinning device 4. integral type as described in claim 1 is dried, which is characterized in that fan, upper insulation crust, nozzle are same Axis is installed, and makes the air-flow that fan generates along upper insulation crust inner homogeneous directed flow, and converge and spray in spout.
  5. 5. the application method of integral type blowing electrostatic spinning device as described in claim 1, which is characterized in that will prepare first Electrospinning liquid be added in syringe, open propeller, adjust fltting speed, spinning solution is slowly pushed into stainless steel needle tip Place;It is then turned on fan, the air-flow that fan generates enters in upper insulation crust, and axially flowing converges at spray along upper insulation crust Head outflow;Finally open high-voltage d. c inverse transform device, make to take 3-10 kilovolt of high pressure at stainless steel needle tip, adjusting shower nozzle and Stainless steel syringe needle spacing is from stainless pin capitiform at jet stream, under airflow function, fiber is sprayed from nozzle, i.e., is sprayed in target It applies and forms micro nanometer fiber film on position;After waiting for spinning, power supply is closed, spinning solution stops outflow, and spinning terminates.
  6. 6. the application method of integral type blowing electrostatic spinning device as described in claim 1, which is characterized in that from upper insulation crust After removing nozzle, direct-flow inverter output end is electrically connected stainless steel syringe needle and fiber collecting device, prepared spinning Silk liquid is added in syringe, opens propeller, adjusts propeller fltting speed, and spinning solution is slowly pushed into spinning needle tip; Fan is opened, high direct voltage inverter is opened, jet stream is sprayed from nozzle, i.e., forms micro nanometer fiber on target spraying position Film.
CN201710173291.8A 2017-03-22 2017-03-22 A kind of integral type blowing electrostatic spinning device Pending CN108277540A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201710173291.8A CN108277540A (en) 2017-03-22 2017-03-22 A kind of integral type blowing electrostatic spinning device

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113215666A (en) * 2020-02-06 2021-08-06 株式会社爱茉莉太平洋 Portable electrospinning device
CN115142143A (en) * 2022-04-12 2022-10-04 浙江技立新材料股份有限公司 Electrostatic auxiliary solution jet spinning device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040094873A1 (en) * 2001-03-20 2004-05-20 Alexander Dubson Portable electrospinning device
CN102776583A (en) * 2012-07-04 2012-11-14 青岛大学 Portable handheld electrostatic spinning device
CN104790049A (en) * 2015-04-29 2015-07-22 青岛新智源健康科技有限公司 Portable electrostatic spinning equipment and using method thereof
CN105113028A (en) * 2015-08-19 2015-12-02 广东工业大学 Portable handheld spinning device
WO2016075688A1 (en) * 2014-11-11 2016-05-19 Nicast Ltd. Portable electrospinning device
CN207031615U (en) * 2017-03-22 2018-02-23 吴强 A kind of integral type blowing electrostatic spinning device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040094873A1 (en) * 2001-03-20 2004-05-20 Alexander Dubson Portable electrospinning device
CN102776583A (en) * 2012-07-04 2012-11-14 青岛大学 Portable handheld electrostatic spinning device
WO2016075688A1 (en) * 2014-11-11 2016-05-19 Nicast Ltd. Portable electrospinning device
CN104790049A (en) * 2015-04-29 2015-07-22 青岛新智源健康科技有限公司 Portable electrostatic spinning equipment and using method thereof
CN105113028A (en) * 2015-08-19 2015-12-02 广东工业大学 Portable handheld spinning device
CN207031615U (en) * 2017-03-22 2018-02-23 吴强 A kind of integral type blowing electrostatic spinning device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113215666A (en) * 2020-02-06 2021-08-06 株式会社爱茉莉太平洋 Portable electrospinning device
CN115142143A (en) * 2022-04-12 2022-10-04 浙江技立新材料股份有限公司 Electrostatic auxiliary solution jet spinning device

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Application publication date: 20180713

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