CN108276848A - A kind of LED light heat radiation coating not easily to fall off - Google Patents

A kind of LED light heat radiation coating not easily to fall off Download PDF

Info

Publication number
CN108276848A
CN108276848A CN201711433470.7A CN201711433470A CN108276848A CN 108276848 A CN108276848 A CN 108276848A CN 201711433470 A CN201711433470 A CN 201711433470A CN 108276848 A CN108276848 A CN 108276848A
Authority
CN
China
Prior art keywords
parts
titanium dioxide
led light
heat radiation
fall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711433470.7A
Other languages
Chinese (zh)
Inventor
茆文斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JINLING ELECTRONIC CO Ltd
Original Assignee
JINLING ELECTRONIC CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JINLING ELECTRONIC CO Ltd filed Critical JINLING ELECTRONIC CO Ltd
Priority to CN201711433470.7A priority Critical patent/CN108276848A/en
Publication of CN108276848A publication Critical patent/CN108276848A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18—Homopolymers or copolymers of tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Luminescent Compositions (AREA)
  • Led Device Packages (AREA)

Abstract

The invention discloses a kind of LED light heat radiation coating not easily to fall off, raw material includes by weight：85 95 parts of major ingredient, 26 parts of nanometer titanium dioxide compound, 560 12 parts of silane coupling agent KH, 14 parts of epoxy-capped polyetheramine, 12 parts of maleic anhydride, 12 parts of calcium lignosulfonate, 1,512 parts of naphthalenedisulfonic acid, 24 parts of sodium lauryl sulfate, 10 20 parts of glycerine, 12 parts of magnesium stearate, 0.5 1 parts of pigment, 1 1.5 parts of dispersant, 12 parts of levelling agent, 30 60 parts of water.Nanometer titanium dioxide compound is prepared using following technique：Nano-titanium dioxide, styrene, acrylic acid, talcum powder are uniformly mixed, under nitrogen protection, potassium peroxydisulfate, water, heating stirring is added, centrifugation is demulsified, washing, adds butanol solution, toluene stirring, centrifugation, and washing obtains nanometer titanium dioxide compound.

Description

A kind of LED light heat radiation coating not easily to fall off
Technical field
The present invention relates to LED light technical field more particularly to a kind of LED light heat radiation coatings not easily to fall off.
Background technology
Under the raised once again background of worry of Present Global energy shortage, energy saving to be that we will face in future important Problem, in lighting area, the application of LED luminous products is just attract the sight of common people, LED is high with light efficiency, service life is long, The many merits such as energy-saving and environmental protection, are more and more widely used in various fields.
But current LED light generally can coat heat radiation coating on surface and carry out heat transfer, but current LED light to internal heat Heat radiation coating there is also adhesive strengths low, caducous technical problem.
Invention content
Technical problems based on background technology, the present invention propose a kind of LED light heat radiation coating not easily to fall off, fit For various environment and temperature, avoidable high temperature be long placed in caused by epidermis tilt, the defects of falling off, excellent adsorption, with ground Adhesion strength is high, and elasticity is good, and excellent thermal conductivity, while service life is long, strong beneficial to body and mind almost without Form aldehyde release Health has the effect of environmental protection.
A kind of LED light heat radiation coating not easily to fall off proposed by the present invention, raw material include by weight：Major ingredient 85-95 Part, 2-6 parts of nanometer titanium dioxide compound, 1-2 parts of silane coupling agent KH-560, epoxy-capped polyetheramine 1-4 parts, maleic 1-2 parts of dicarboxylic anhydride, 1-2 parts of calcium lignosulfonate, 1,5- 1-2 parts of naphthalenedisulfonic acid, 2-4 parts of sodium lauryl sulfate, glycerine 10-20 Part, 1-2 parts of magnesium stearate, 0.5-1 parts of pigment, 1-1.5 parts of dispersant, 1-2 parts of levelling agent, 30-60 parts of water.
Preferably, nanometer titanium dioxide compound is prepared using following technique：By nano-titanium dioxide, styrene, propylene Acid, talcum powder are uniformly mixed, and under nitrogen protection, potassium peroxydisulfate, water is added, and heating is stirred, and centrifugation demulsification, washing adds fourth Alcoholic solution, toluene stirring, centrifugation, washing obtain nanometer titanium dioxide compound.
Preferably, in the preparation process of nanometer titanium dioxide compound, potassium peroxydisulfate, water is added, is warming up to 80-90 DEG C and stirs Mix 2-4h, mixing speed 300-600r/min.
Preferably, in the preparation process of nanometer titanium dioxide compound, nano-titanium dioxide, styrene, acrylic acid, talcum Powder, potassium peroxydisulfate, water, butanol solution, toluene weight ratio be 20-30：2-6：2-4：1-2：0.1-0.2：60-80：60-80： 2-4, a concentration of 55-62wt% of butanol solution.
Preferably, major ingredient includes by weight：30-50 parts of polytetrafluoroethylgranule granule, 25-35 parts of acrylic resin, silicon third 15-26 parts of lotion.
The present invention has the advantages that high temperature resistant, ageing-resistant, high adhesion force, good heat dissipation effect, wherein epoxy-capped polyetheramine Containing a large amount of hydroxyl, high with the combination degree of polytetrafluoroethylgranule granule, acrylic resin, silicone acrylic emulsion, the long-chain of formation is big Molecule is mutually interspersed, and strong with the cohesive force of ground, ageing-resistant performance is strong, and nanometer titanium dioxide compound dispersion is wherein, in silicon The effect of alkane coupling agent KH-560 is strong with the binding force of other Organic Ingredients, can improve the distance of strand, further increase High temperature resistance and adhesive strength.
In the nanometer titanium dioxide compound of the present invention, nano-titanium dioxide is dispersed in benzene second under the cooperation of talcum powder In alkene, acrylic acid, styrene, acrylic acid cause crosslinking using potassium peroxydisulfate, and are coated on nano-titanium dioxide surface, then uses Toluene keeps the hole depth of thus obtained microsphere and aperture good as pore-foaming agent, and on the one hand gained nanometer titanium dioxide compound has high hard Kernel is spent, with soft shell, in the premise for ensureing hardness just with the degree of adhesion of ground height, on the other hand its absorption property is excellent Different, high-temperature resistant result is good, not easily to fall off even if adhesive ability is strong under the condition of high temperature.
The present invention is suitable for various environment and temperature, avoidable high temperature be long placed in caused by epidermis tilt, the defects of falling off, Excellent adsorption, high with ground adhesion strength, elasticity is good, and excellent thermal conductivity, while service life is long, almost formaldehydeless to release It puts, beneficial to physical and mental health, has the effect of environmental protection.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of LED light heat radiation coating not easily to fall off, raw material include：Major ingredient 85kg, nanometer titanium dioxide compound 6kg, silane coupling agent KH-560 1kg, epoxy-capped polyetheramine 4kg, maleic anhydride 1kg, calcium lignosulfonate 2kg, 1, 5- naphthalenedisulfonic acid 1kg, sodium lauryl sulfate 4kg, glycerine 10kg, magnesium stearate 2kg, pigment 0.5kg, dispersant 1.5kg, levelling Agent 1kg, water 60kg.
Major ingredient includes：Polytetrafluoroethylgranule granule 30kg, acrylic resin 35kg, silicone acrylic emulsion 15kg.
Nanometer titanium dioxide compound is prepared using following technique：By 30kg nano-titanium dioxides, 2kg styrene, 4kg third Olefin(e) acid, 1kg talcum powder are uniformly mixed, and under nitrogen protection, 0.2kg potassium peroxydisulfates, 60kg water is added, and are warming up to 90 DEG C of stirring 2h, Mixing speed is 600r/min, centrifugation demulsification, washing, adds a concentration of 62wt% butanol solutions of 60kg, the stirring of 2kg toluene 12min, centrifugation, washing obtain nanometer titanium dioxide compound.
Embodiment 2
A kind of LED light heat radiation coating not easily to fall off, raw material include：Major ingredient 95kg, nanometer titanium dioxide compound 2kg, silane coupling agent KH-560 2kg, epoxy-capped polyetheramine 1kg, maleic anhydride 2kg, calcium lignosulfonate 1kg, 1, 5- naphthalenedisulfonic acid 2kg, sodium lauryl sulfate 2kg, glycerine 20kg, magnesium stearate 1kg, pigment 1kg, dispersant 1kg, levelling agent 2kg, water 30kg.
Major ingredient includes：Polytetrafluoroethylgranule granule 50kg, acrylic resin 25kg, silicone acrylic emulsion 26kg.
Nanometer titanium dioxide compound is prepared using following technique：By 20kg nano-titanium dioxides, 6kg styrene, 2kg third Olefin(e) acid, 2kg talcum powder are uniformly mixed, and under nitrogen protection, 0.1kg potassium peroxydisulfates, 80kg water is added, and are warming up to 80 DEG C of stirring 4h, Mixing speed is 300r/min, centrifugation demulsification, washing, adds a concentration of 55wt% butanol solutions of 80kg, the stirring of 4kg toluene 5min, centrifugation, washing obtain nanometer titanium dioxide compound.
Embodiment 3
A kind of LED light heat radiation coating not easily to fall off, raw material include：Major ingredient 88kg, nanometer titanium dioxide compound 5kg, silane coupling agent KH-560 1.2kg, epoxy-capped polyetheramine 3kg, maleic anhydride 1.3kg, calcium lignosulfonate 1.6kg, 1,5- naphthalenedisulfonic acid 1.2kg, sodium lauryl sulfate 3.5kg, glycerine 12kg, magnesium stearate 1.7kg, pigment 0.6kg, point Powder 1.4kg, levelling agent 1.3kg, water 50kg.
Major ingredient includes：Polytetrafluoroethylgranule granule 35kg, acrylic resin 32kg, silicone acrylic emulsion 18kg.
Nanometer titanium dioxide compound is prepared using following technique：By 28kg nano-titanium dioxides, 3kg styrene, 3.5kg Acrylic acid, 1.2kg talcum powder are uniformly mixed, and under nitrogen protection, 0.18kg potassium peroxydisulfates, 65kg water are added, is warming up to 88 DEG C and stirs 2.5h, mixing speed 500r/min, centrifugation demulsification are mixed, washing adds a concentration of 60wt% butanol solutions of 65kg, 2.5kg Toluene stirs 10min, centrifugation, and washing obtains nanometer titanium dioxide compound.
Embodiment 4
A kind of LED light heat radiation coating not easily to fall off, raw material include：Major ingredient 92kg, nanometer titanium dioxide compound 3kg, silane coupling agent KH-560 1.8kg, epoxy-capped polyetheramine 2kg, maleic anhydride 1.7kg, calcium lignosulfonate 1.4kg, 1,5- naphthalenedisulfonic acid 1.8kg, sodium lauryl sulfate 2.5kg, glycerine 18kg, magnesium stearate 1.3kg, pigment 0.8kg, point Powder 1.2kg, levelling agent 1.7kg, water 40kg.
Major ingredient includes：Polytetrafluoroethylgranule granule 45kg, acrylic resin 28kg, silicone acrylic emulsion 24kg.
Nanometer titanium dioxide compound is prepared using following technique：By 22kg nano-titanium dioxides, 5kg styrene, 2.5kg Acrylic acid, 1.8kg talcum powder are uniformly mixed, and under nitrogen protection, 0.12kg potassium peroxydisulfates, 75kg water are added, is warming up to 82 DEG C and stirs 3.5h, mixing speed 400r/min, centrifugation demulsification are mixed, washing adds a concentration of 58wt% butanol solutions of 75kg, 3.5kg Toluene stirs 8min, centrifugation, and washing obtains nanometer titanium dioxide compound.
4 gained LED light heat radiation coating of embodiment is tested for the property, result is as follows：
Embodiment 4 Common heat radiation coating
Adhesive force 3 grades 1 grade
Acid proof test (3wt% hydrochloric acid solutions × 250h) Pass through Do not pass through
Alkaline-resisting test (5wt% sodium hydroxide solutions × 180h) Pass through Do not pass through
Thermal coefficient, W/mK 280 200
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of LED light heat radiation coating not easily to fall off, which is characterized in that its raw material includes by weight：85-95 parts of major ingredient, 2-6 parts of nanometer titanium dioxide compound, 1-2 parts of silane coupling agent KH-560, epoxy-capped polyetheramine 1-4 parts, maleic acid 1-2 parts of acid anhydride, 1-2 parts of calcium lignosulfonate, 1,5- 1-2 parts of naphthalenedisulfonic acid, 2-4 parts of sodium lauryl sulfate, 10-20 parts of glycerine, firmly 1-2 parts of fatty acid magnesium, 0.5-1 parts of pigment, 1-1.5 parts of dispersant, 1-2 parts of levelling agent, 30-60 parts of water.
2. LED light heat radiation coating not easily to fall off according to claim 1, which is characterized in that nanometer titanium dioxide compound It is prepared using following technique：Nano-titanium dioxide, styrene, acrylic acid, talcum powder are uniformly mixed, under nitrogen protection, are added Potassium peroxydisulfate, water, heating stirring, centrifugation demulsification, washing add butanol solution, toluene stirring, centrifugation, and washing obtains nanometer Titanium dioxide compound.
3. LED light heat radiation coating not easily to fall off according to claim 2, which is characterized in that nanometer titanium dioxide compound Preparation process in, be added potassium peroxydisulfate, water, be warming up to 80-90 DEG C stirring 2-4h, mixing speed 300-600r/min.
4. according to LED light heat radiation coating not easily to fall off described in Claims 2 or 3, which is characterized in that nano-titanium dioxide is compound In the preparation process of object, nano-titanium dioxide, styrene, acrylic acid, talcum powder, potassium peroxydisulfate, water, butanol solution, toluene Weight ratio is 20-30：2-6：2-4：1-2：0.1-0.2：60-80：60-80：2-4, a concentration of 55-62wt% of butanol solution.
5. according to any one of the claim 1-4 LED light heat radiation coatings not easily to fall off, which is characterized in that major ingredient is by weight Part include：30-50 parts of polytetrafluoroethylgranule granule, 25-35 parts of acrylic resin, 15-26 parts of silicone acrylic emulsion.
CN201711433470.7A 2017-12-26 2017-12-26 A kind of LED light heat radiation coating not easily to fall off Withdrawn CN108276848A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711433470.7A CN108276848A (en) 2017-12-26 2017-12-26 A kind of LED light heat radiation coating not easily to fall off

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711433470.7A CN108276848A (en) 2017-12-26 2017-12-26 A kind of LED light heat radiation coating not easily to fall off

Publications (1)

Publication Number Publication Date
CN108276848A true CN108276848A (en) 2018-07-13

Family

ID=62802168

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711433470.7A Withdrawn CN108276848A (en) 2017-12-26 2017-12-26 A kind of LED light heat radiation coating not easily to fall off

Country Status (1)

Country Link
CN (1) CN108276848A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109539191A (en) * 2018-11-19 2019-03-29 安徽蓝锐电子科技有限公司 A kind of LED lamp that heat dissipation performance is outstanding

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555125A (en) * 2013-09-25 2014-02-05 天长市天泰光电科技有限公司 Anti ultraviolet heat radiation paint for LED lamp and preparation method thereof
CN106752452A (en) * 2016-12-07 2017-05-31 江西龙正科技发展有限公司 A kind of LED lamp heat radiation coating
CN107057523A (en) * 2017-05-05 2017-08-18 安徽兆利光电科技有限公司 A kind of LED heat radiation coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555125A (en) * 2013-09-25 2014-02-05 天长市天泰光电科技有限公司 Anti ultraviolet heat radiation paint for LED lamp and preparation method thereof
CN106752452A (en) * 2016-12-07 2017-05-31 江西龙正科技发展有限公司 A kind of LED lamp heat radiation coating
CN107057523A (en) * 2017-05-05 2017-08-18 安徽兆利光电科技有限公司 A kind of LED heat radiation coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
林润惠等: "《包装材料测试技术》", 31 May 2008, 中国轻工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109539191A (en) * 2018-11-19 2019-03-29 安徽蓝锐电子科技有限公司 A kind of LED lamp that heat dissipation performance is outstanding

Similar Documents

Publication Publication Date Title
CN102898926B (en) Coating of a kind of high temperature resistant, wear-resisting, heavy antisepsis and preparation method thereof
CN106186900B (en) A kind of Green environmental-protection building material and preparation method thereof
CN104058681B (en) Anti-cracking heat insulation mortar
CN102234492A (en) Plant non-toxic adhesive used for indoor decoration and preparation method thereof
CN101913820A (en) Heat-preserving decorative mortar and preparation method thereof
CN104692747A (en) Energy-saving environment-friendly inorganic building coating
CN104387885A (en) Natural-fiber-added anti-aging high-weather-resistance outer wall paint and preparation method thereof
CN108276848A (en) A kind of LED light heat radiation coating not easily to fall off
CN104876491A (en) Mortar used for phenolic foam insulation board construction
CN103922628A (en) Anti-freezing type polycarboxylic acid high-performance water reducer and preparation method thereof
CN105417986A (en) Early-strength waterproof agent for ordinary Portland cement
CN104673087A (en) Anti-flaking waterproof coating material for buildings and preparation method thereof
CN102352204B (en) Preparation method for bonding material for energy-saving lamp
CN102352202B (en) Method for preparing bonding material
CN106631151A (en) Thermal insulation material
CN103483893A (en) Waterproof paint and preparation method thereof
CN106747077A (en) A kind of ceramic tile adhesive of waterproof and heat conduction dual-use function
CN105505114A (en) High-temperature-resistant powder coating
CN102532445A (en) Foaming phenolic resin and phenolic foam with foaming phenolic resin
CN105347757B (en) A kind of inorganic heat insulation mortar
CN107163630A (en) A kind of environmental protection coating material and preparation method thereof
CN103288387A (en) Energy-saving high-intensity ceramic paint
CN102352203B (en) Preparation method of novel adhesive for energy-saving lamps
CN106497201A (en) A kind of mildew-proof flame retarded Thermal insulating putty for exterior wall of building
CN106084405A (en) A kind of heat insulation pressure resistant type construction material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20180713