CN108273513A - A kind of cuprous oxide is modified the preparation of wolframic acid antimony composite photo-catalyst - Google Patents
A kind of cuprous oxide is modified the preparation of wolframic acid antimony composite photo-catalyst Download PDFInfo
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- CN108273513A CN108273513A CN201711484514.9A CN201711484514A CN108273513A CN 108273513 A CN108273513 A CN 108273513A CN 201711484514 A CN201711484514 A CN 201711484514A CN 108273513 A CN108273513 A CN 108273513A
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- wolframic acid
- acid antimony
- modified
- composite photo
- cuprous oxide
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- 239000002253 acid Substances 0.000 title claims abstract description 55
- 229910052787 antimony Inorganic materials 0.000 title claims abstract description 54
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 239000002131 composite material Substances 0.000 title claims abstract description 36
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 35
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 title claims abstract description 32
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229940112669 cuprous oxide Drugs 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000003756 stirring Methods 0.000 claims description 17
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical class [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 235000010323 ascorbic acid Nutrition 0.000 claims description 6
- 239000011668 ascorbic acid Substances 0.000 claims description 6
- 229960005070 ascorbic acid Drugs 0.000 claims description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 6
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 4
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 4
- 229910020350 Na2WO4 Inorganic materials 0.000 claims description 2
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 229930003268 Vitamin C Natural products 0.000 claims 1
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 235000019154 vitamin C Nutrition 0.000 claims 1
- 239000011718 vitamin C Substances 0.000 claims 1
- 230000001699 photocatalysis Effects 0.000 abstract description 15
- 230000015556 catabolic process Effects 0.000 abstract description 8
- 238000006731 degradation reaction Methods 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 8
- 239000003054 catalyst Substances 0.000 abstract description 7
- 230000003197 catalytic effect Effects 0.000 abstract description 7
- 238000011160 research Methods 0.000 abstract description 6
- 239000004065 semiconductor Substances 0.000 abstract description 3
- 239000002105 nanoparticle Substances 0.000 abstract description 2
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 238000001027 hydrothermal synthesis Methods 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 20
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical group C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229960000907 methylthioninium chloride Drugs 0.000 description 6
- 238000007146 photocatalysis Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 2
- 229940043267 rhodamine b Drugs 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- MCPLVIGCWWTHFH-UHFFFAOYSA-L methyl blue Chemical compound [Na+].[Na+].C1=CC(S(=O)(=O)[O-])=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[NH+]C=2C=CC(=CC=2)S([O-])(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S([O-])(=O)=O)=CC=2)C=C1 MCPLVIGCWWTHFH-UHFFFAOYSA-L 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- C02F1/30—Treatment of water, waste water, or sewage by irradiation
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Abstract
The preparation method for being modified wolframic acid antimony composite photo-catalyst the invention discloses a kind of cuprous oxide and its application in photocatalytic pollutant degradation, belong to material preparation and light-catalysed technical field.The characteristics of catalyst, has：Laminated structure with 2 dimensions, is combined by cuprous nano particle and wolframic acid antimony nanometer sheet.During preparing photochemical catalyst, using hydro-thermal method simple for process, synthesizes cuprous oxide and be modified wolframic acid antimony composite photo-catalyst.Under the action of cuprous oxide, cuprous oxide is modified wolframic acid antimony composite photo-catalyst and shows good visible light catalytic performance, promotes the research of novel semi-conductor wolframic acid antimony photochemical catalyst.
Description
Technical field
The invention belongs to material preparation and photocatalysis technology fields, and it is compound to relate generally to a kind of cuprous oxide modification wolframic acid antimony
The preparation of photochemical catalyst and its research of photocatalytic activity.
Background technology
With industrialized development, people's increasingly concern for the environment pollution problem.Traditional environmental pollution substance treating method
The requirement of people is can not meet.A kind of cleaning is searched out, efficiently, energy-saving and environment-friendly sewage water treatment method is ground at people
The hot spot direction studied carefully.
TiO was found for the first time from 19722Since photocatalytic activity, the research of photocatalysis technology is always investigation of materials
Hot spot direction.Photocatalysis technology by its energy conservation and environmental protection, non-secondary pollution the advantages that for sewage processing provide one it is non-
Often good solution route.Conductor photocatalysis material can utilize in inexhaustible, nexhaustible solar energy processing air or
Poisonous and harmful substance in person's water improves environment, achievees the purpose that utilization of resources ecology.Currently, a variety of different semiconductor lights
Photocatalyst material is widely studied, such as bismuth tungstate, wolframic acid caesium etc..But wolframic acid antimony is extensive by its material source, price is low
It is honest and clean, as one of the hot spot material of photocatalysis research the advantages that no biotoxicity.
But there is also some defects for wolframic acid antimony photochemical catalyst, for example, its visible light utilization efficiency is low, and Gao get Guang
Raw electron-hole recombination rate, these all hinder its further application.In this background, wolframic acid antimony how is improved
Photocatalytic activity, at the Important Problems of research wolframic acid antimony photochemical catalyst.So far, it is used to improve there are many method
Its photocatalytic activity, such as:Pattern control, semiconductors coupling etc..But the photocatalysis efficiency of the modified wolframic acid antimony of the above method,
There are still some defects for stability.
In recent years, compound using other materials and the progress of wolframic acid antimony catalyst, the research for preparing composite photo-catalyst obtains
Certain progress, obtained wolframic acid antimony composite photo-catalyst show good photocatalytic activity under the irradiation of sunlight.
The present invention is compound using the low energy gap of cuprous oxide and the progress of wolframic acid antimony, forms two-dimensional microstructure, effectively improves
The visible light utilization efficiency and photocatalytic activity of wolframic acid antimony.
Invention content
The purpose of the present invention is prepare the wolframic acid antimony complex light with high visible light utilization efficiency and high catalytic activity to urge
Agent promotes the practical application of wolframic acid antimony.
Purpose adopts the following technical scheme that realize the present invention：
Using the narrow band gap of cuprous oxide, cuprous oxide nano-particle is grown in wolframic acid antimony on piece, prepares cuprous oxide modification
Wolframic acid antimony composite photo-catalyst improves the visible light catalysis activity of wolframic acid antimony.
A kind of cuprous oxide is modified the preparation of wolframic acid antimony composite photo-catalyst, and characterization step is as follows：
（1）Weigh a certain amount of SbCl3It is dissolved in 50 mL ethylene glycol, stirs evenly；
（2）To step（1）Appropriate Na in solution2WO4﹒ 2H2O continues to stir evenly；
（3）To step（2）20 mL water are added in solution, stir evenly；
（4）The solution being stirred is transferred in autoclave and is reacted；
（5）By the sample centrifuge washing that the reaction was complete, is ground after dry and obtain wolframic acid antimony；
（6）It takes 0.15 g wolframic acid antimony to be dissolved in 30 mL water, appropriate cupric sulfate pentahydrate is added, stirs evenly；
（7）To step（6）4 mL sodium hydroxides (1.0mol/L) solution are added in solution；
（8）To step（7）A certain amount of ascorbic acid, heating stirring certain time are added in solution；
（9）By the sample centrifuge washing that the reaction was complete, is ground after dry and obtain composite photo-catalyst.
SbCl in step (1)3Quality be 0.9125g.
Na in step (2)2WO4﹒ 2H2The quality of O is 0.066g.
Reaction temperature is 180 DEG C in step (4), reaction time 20h.
Cupric sulfate pentahydrate quality is 0.5g in step (6).
Ascorbic acid quality is 1.0g in step (8).
90 DEG C of stability, reaction time 10h are heated in step (8).
Eccentric cleaning process in step (9) is first to be cleaned 4 times with ethyl alcohol, then clean 2 times with deionized water, centrifugation rate
8000rpm, time 6min.
The cuprous oxide is modified visible light catalytic of the wolframic acid antimony composite photo-catalyst for organic pollution in aqueous solution
Degradation.
Target contaminant is methylene blue.
The invention has the advantages that：
1. prepared by the present invention is a kind of cuprous oxide modification wolframic acid antimony composite photo-catalyst, belong to new compound system；
2. the cuprous oxide in the present invention, which is modified wolframic acid antimony composite photo-catalyst, has good photocatalytic activity and absorption property.
It degrades under the irradiation of the artificial visible light sources of 180min methylene blue dye, degradation rate reaches 80%, higher than the wolframic acid antimony studied
Monomer catalytic activity.
Description of the drawings
Fig. 1 is the scanning electron microscope (SEM) photograph that cuprous oxide is modified wolframic acid antimony composite photo-catalyst.
Fig. 2 is the photocatalytic degradation figure that cuprous oxide is modified wolframic acid antimony composite photo-catalyst.
Specific implementation mode
A kind of cuprous oxide is modified the preparation of wolframic acid antimony composite photo-catalyst, and characterization step is as follows：
（1）Weigh a certain amount of SbCl3It is dissolved in 50 mL ethylene glycol, stirs evenly；
（2）To step（1）Appropriate Na in solution2WO4﹒ 2H2O continues to stir evenly；
（3）To step（2）20 mL water are added in solution, stir evenly；
（4）The solution being stirred is transferred in autoclave and is reacted；
（5）By the sample centrifuge washing that the reaction was complete, is ground after dry and obtain wolframic acid antimony；
（6）It takes 0.15 g wolframic acid antimony to be dissolved in 30 mL water, appropriate cupric sulfate pentahydrate is added, stirs evenly；
（7）To step（6）4 mL sodium hydroxides (1.0mol/L) solution are added in solution；
（8）To step（7）A certain amount of ascorbic acid, heating stirring certain time are added in solution；
（9）By the sample centrifuge washing that the reaction was complete, is ground after dry and obtain composite photo-catalyst.
SbCl in step (1)3Quality be 0.9125g.
Na in step (2)2WO4﹒ 2H2The quality of O is 0.066g.
Reaction temperature is 180 DEG C in step (4), reaction time 20h.
Cupric sulfate pentahydrate quality is 0.5g in step (6).
Ascorbic acid quality is 1.0g in step (8).
90 DEG C of stability, reaction time 10h are heated in step (8).
Eccentric cleaning process in step (9) is first to be cleaned 4 times with ethyl alcohol, then clean 2 times with deionized water, centrifugation rate
8000rpm, time 6min.
The cuprous oxide is modified visible light catalytic of the wolframic acid antimony composite photo-catalyst for organic pollution in aqueous solution
Degradation.
Specific embodiment prepares cuprous oxide and is modified wolframic acid antimony composite photo-catalyst below.
Case study on implementation 1
Cuprous oxide is modified the preparation of wolframic acid antimony composite photo-catalyst
Weigh SbCl30.9125g is added in 50 mL ethylene glycol, is stirred evenly, is added Na2WO4﹒ 2H2O 0.066g, are stirred
It mixes uniformly；Then solution is poured into reaction kettle, is heated, heating temperature is 200 DEG C, time 20h.After the completion of reaction, centrifugation
Washing, is first cleaned 4 times with ethyl alcohol, is being washed with water 2 times, centrifugal speed 8000rpm, time 6min.60 DEG C in last baking oven
Dry, grinding obtains wolframic acid antimony.
It weighs 0.15 g wolframic acid antimony to be dissolved in 30 mL water, 0.5g cupric sulfate pentahydrates is added, stir evenly；Add 4 mL
Sodium hydroxide (1.0mol/L) solution, is subsequently added into ascorbic acid 1.0g, 10h is stirred at 90 DEG C.By the sample that the reaction was complete
Centrifuge washing grinds after dry and obtains composite photo-catalyst.
Case study on implementation 2
Cuprous oxide is modified wolframic acid antimony composite photo-catalyst rhodamine B degradation under visible light illumination
It is modified wolframic acid antimony composite photo-catalyst by cuprous oxide made from 1 method of case study on implementation and carries out rhodamine B degradation experiment.It is sub-
The concentration of methyl blue solution is 1 × 10-4mol L-1；Composite material powder 50mg is taken, the above-mentioned methylene blue solutions of 100mL are placed in
In, it stirs 40 minutes in darkroom, is then placed in solution in the visible light source that ultraviolet light is filtered, take 5mL within every 10 minutes
Methylene blue solution measures the characteristic peaks of Methylene Blue in Solution with ultraviolet-visible spectrophotometer.
The degradation that cuprous oxide is modified wolframic acid antimony composite photo-catalyst Visible Light Induced Photocatalytic methylene blue is obtained by case study on implementation 2
Curve is shown in Fig. 2.The composite material powder that as can be seen from Figure 2 prepared by case study on implementation 1 catalytic degradation after 180 min of illumination reaches
To 80% or more, high catalytic activity is shown.
Claims (8)
1. a kind of cuprous oxide is modified the preparation of wolframic acid antimony composite photo-catalyst, feature includes the following steps：
（1）Weigh a certain amount of SbCl3It is dissolved in 50 mL ethylene glycol, stirs evenly；
（2）To step（1）Appropriate Na in solution2WO4﹒ 2H2O continues to stir evenly；
（3）To step（2）20mL is added in solution, stirs evenly；
（4）The solution being stirred is transferred in autoclave and is reacted；
（5）By the sample centrifuge washing that the reaction was complete, is ground after dry and obtain wolframic acid antimony；
（6）It takes 0.15g wolframic acid antimony to be dissolved in 30 mL water, appropriate cupric sulfate pentahydrate is added, stirs evenly；
（7）To step（6）4mL sodium hydroxides (1.0mol/L) solution is added in solution；
（8）To step（7）A certain amount of ascorbic acid, heating stirring certain time are added in solution；
（9）By the sample centrifuge washing that the reaction was complete, is ground after dry and obtain composite photo-catalyst.
2. being modified the preparation of wolframic acid antimony composite photo-catalyst according to a kind of cuprous oxide of claim 1, it is characterised in that SbCl3's
Quality is 0.9125g.
3. being modified the preparation of wolframic acid antimony composite photo-catalyst according to a kind of cuprous oxide of claim 1, it is characterised in that Na2WO4﹒
2H2The quality of O is 0.066g.
4. being modified the preparation of wolframic acid antimony composite photo-catalyst according to a kind of cuprous oxide of claim 1, it is characterised in that wolframic acid antimony
The reaction temperature of synthesis is 180 DEG C, reaction time 20h.
5. being modified the preparation of wolframic acid antimony composite photo-catalyst according to a kind of cuprous oxide of claim 1, it is characterised in that five water sulphur
Sour copper mass is 0.5g.
6. being modified the preparation of wolframic acid antimony composite photo-catalyst according to a kind of cuprous oxide of claim 1, it is characterised in that Vitamin C
Sour quality is 1.0g.
7. being modified the preparation of wolframic acid antimony composite photo-catalyst according to a kind of cuprous oxide of claim 1, it is characterised in that heating is stirred
It is 90 DEG C to mix temperature, reaction time 10h.
8. being modified the preparation of wolframic acid antimony composite photo-catalyst according to a kind of cuprous oxide of claim 1, it is characterised in that oxidation is sub-
Copper, which is modified wolframic acid antimony composite photo-catalyst, has two-dimensional appearance.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113976138A (en) * | 2021-11-29 | 2022-01-28 | 辽宁大学 | Cu2O/CuWO4Acoustic catalyst, preparation method and application thereof |
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2017
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113976138A (en) * | 2021-11-29 | 2022-01-28 | 辽宁大学 | Cu2O/CuWO4Acoustic catalyst, preparation method and application thereof |
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