CN108264859B - Sublimation-proof washable decorative film for textiles and preparation method thereof - Google Patents
Sublimation-proof washable decorative film for textiles and preparation method thereof Download PDFInfo
- Publication number
- CN108264859B CN108264859B CN201810024776.5A CN201810024776A CN108264859B CN 108264859 B CN108264859 B CN 108264859B CN 201810024776 A CN201810024776 A CN 201810024776A CN 108264859 B CN108264859 B CN 108264859B
- Authority
- CN
- China
- Prior art keywords
- sublimation
- layer
- glue
- decorative film
- proof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/005—Presence of polyester in the release coating
Abstract
The invention belongs to the fields of polymer decoration and garment technology, and particularly relates to a sublimation-proof washable decorative film for textiles and a preparation method thereof. The sublimation-proof washable decorative film for the textile comprises a matte PET release film and a glue coating layer coated on the matte surface of the matte PET release film, wherein the glue coating layer sequentially comprises an sublimation-proof layer, an intermediate treatment layer and a glue layer from inside to outside. The anti-sublimation washable decorative film disclosed by the invention is soft in hand feeling, has good washing resistance and dry-cleaning performance, can effectively prevent the color of a textile fabric from sublimating and migrating, can be suitable for the design of textile clothes in various styles and styles, and can be suitable for the decoration of textiles with 1-5 levels of color fastness. The sublimation-proof washable decorative film is simple and convenient to operate when used, and has a good application prospect.
Description
Technical Field
The invention belongs to the fields of polymer decoration and garment technology, and particularly relates to a sublimation-proof washable decorative film for textiles and a preparation method thereof.
Background
With the improvement of living standard and aesthetic appreciation of people, people tend to have higher living quality, garment decoration materials, especially heat transfer decoration films, can meet various garment design requirements due to simple and convenient operation and high flexibility of color and patterns, are popularized in a large amount, and personalized characteristic decoration is deeply loved by consumers. The decorative film products in the market are mainly PVC and TPU, and in practical application, partial terylene, cotton, nylon and blended fabrics, particularly dark-color fabrics are found, after the decorative film is pressed, the colors of the fabrics are sublimated and transferred to the surface of the decorative film, yellow points, black points or other color points appear, the appearance quality of the product is seriously influenced, and the decorative film effect of clothes is influenced.
Disclosure of Invention
Aiming at the defects of the prior art, the invention aims to provide a sublimation-proof water-fast decorative film for textiles and a preparation method thereof.
The invention is realized by the following technical scheme:
the anti-sublimation washable decorative film for the textile comprises a matte PET release film and a glue coating layer coated on the matte surface of the matte PET release film, wherein the glue coating layer sequentially comprises an anti-sublimation layer, an intermediate treatment layer and a glue layer from inside to outside; wherein the content of the first and second substances,
the anti-sublimation layer comprises the following components in parts by weight:
the intermediate treatment layer comprises the following components in parts by weight:
80-95 parts of polyurethane glue with the solid content of 35 percent,
1-5 parts of a coupling agent,
55-70 parts of nylon glue with the solid content of 40 percent,
the glue layer comprises the following components in parts by weight:
80-95 parts of polyurethane glue with the solid content of 35 percent,
0.5-3 parts of polycarbodiimide.
Preferably, the liquid silicone rubber comprises one of polydimethylsiloxane liquid silicone rubber, polymethylsiloxane liquid silicone rubber, alpha, omega-dihydroxy polysiloxane liquid silicone rubber, polymethylethylene rubber liquid silicone rubber, polymethylphenyl liquid silicone rubber or a mixture of at least two of the polydimethylsiloxane liquid silicone rubber, the polymethylethylene rubber liquid silicone rubber and the polymethylphenyl liquid silicone rubber.
Further preferably, the viscosity of the liquid silicone rubber is 30000-70000 mpa.s.
Preferably, the coupling agent is a silane coupling agent or an oligomer of the silane coupling agent, and comprises one or a mixture of at least two of gamma-glycidoxypropyltrimethoxysilane (KH-560), 3-aminopropyltriethoxysilane (KH-550), gamma-aminoethylaminopropyltrimethoxysilane (KH-792), vinyltrimethoxysilane (A-171), hydroxysilane oligomer (6650) and fluorocarbon silane oligomer (6656F).
Preferably, the catalyst is one or a mixture of at least two of a platinum complex catalyst, an organic tin catalyst, an amine catalyst and a titanate catalyst.
Preferably, the crosslinking agent comprises a mixture of at least two of a polyalkoxysilane crosslinking agent, a polybutanone oxime silane crosslinking agent, a polyacetoxysilane crosslinking agent, a polyamine silane crosslinking agent, a polyamidosilane crosslinking agent, a polyisoacryloxysilane crosslinking agent and a hydrogen-containing silicone oil crosslinking agent.
Preferably, the polyurethane glue with the solid content of 35% comprises one or a mixture of at least two of polyester polyurethane glue, polycaprolactone polyurethane glue, polycarbonate polyurethane glue, polyether polyurethane glue and copolyether polyurethane glue.
Preferably, the nylon glue with the solid content of 40% comprises one or a mixture of at least two of nylon 6, nylon 66, nylon 1010 and nylon 1013.
Preferably, the thickness of the anti-sublimation layer is 0.08-0.2mm, the thickness of the intermediate treatment layer is 0.01-0.03mm, and the thickness of the glue layer is not less than 0.07 mm.
The preparation method of the sublimation-proof washable decorative film for the textile comprises the following steps:
(1) preparing an anti-sublimation layer: uniformly stirring liquid silicon rubber, titanium dioxide pigment paste with solid content of 45%, a coupling agent, a catalyst and a crosslinking agent, and vacuumizing;
(2) preparing an intermediate treatment layer: uniformly stirring polyurethane glue with the solid content of 35%, a coupling agent and nylon glue with the solid content of 40%, and vacuumizing;
(3) preparing a glue layer: uniformly stirring polyurethane glue with the solid content of 35% and polycarbodiimide, and vacuumizing;
(4) coating an anti-sublimation layer on the matte surface of the matte PET release film, and drying;
(5) coating an intermediate treatment layer on the surface of the anti-sublimation layer, and drying;
(6) and coating a glue layer on the surface of the intermediate treatment layer, and drying to obtain the sublimation-proof water-washing-resistant decorative film for the textile.
Preferably, the anti-sublimation layer prepared in the step (1) is coated within 1 h.
Preferably, the coating in steps (4), (5), (6) is applied using a circular knife blade coater, the circular knife blade coater process being set up as follows:
and (4): the temperature of the drying tunnel is 120-;
and (5): baking at 90-120 deg.C for 5-10 min;
and (6): the baking tunnel temperature is 90-140 deg.C, and the baking time is 10-15 min.
The invention has the beneficial effects that:
the sublimation-proof washing-resistant decorative film disclosed by the invention is soft in hand feeling, has good washing resistance and dry-cleaning performance, can effectively prevent the sublimation and migration of the color of the textile fabric, can adapt to the design of textile clothes in various styles and styles, and can adapt to the decoration of textiles with 1-5 levels of color fastness. The sublimation-proof washable decorative film is simple and convenient to operate when used, and has a good application prospect.
Drawings
FIG. 1 is a schematic view of an anti-sublimation water-fast-wash decorative film of the present invention;
FIG. 2 is a schematic view of the application of the anti-sublimation water-fast-washing decoration film of the invention on textile decoration.
Detailed Description
The present invention will be further described with reference to the following examples.
The sublimation-proof washable decorative film is composed of a matte PET release film 1 and a glue coating layer 2 coated on the matte surface of the matte PET release film 1, wherein the glue coating layer 2 is sequentially provided with an sublimation-proof layer 21, an intermediate treatment layer 22 and a glue layer 23 from inside to outside; when the anti-sublimation washable decorative film is applied to textile decoration, the anti-sublimation washable decorative film is hot-pressed on an easy-sublimation textile fabric 3 by a flat plate pressing machine under the conditions of temperature of 150 ℃, pressure of 0.4mPa and time of 15 seconds, and the matte PET release film 1 is torn off after cooling for 30 minutes, wherein a glue layer 23, an intermediate treatment layer 22 and an anti-sublimation layer 21 are sequentially arranged on the textile fabric 3 from inside to outside.
Example 1
An anti-sublimation washable decorative film for textiles comprises a matte PET release film and a glue coating layer coated on the matte surface of the matte PET release film, wherein the glue coating layer sequentially comprises an anti-sublimation layer, an intermediate treatment layer and a glue layer from inside to outside,
the anti-sublimation layer comprises the following components in parts by weight:
the intermediate treatment layer comprises the following components in parts by weight:
the glue layer comprises the following components in parts by weight:
85 parts of polyester type polyurethane glue with the solid content of 35 percent,
1 part of polycarbodiimide.
The preparation method of the sublimation-proof washable decorative film for the textile comprises the following steps:
(1) uniformly stirring the components of the anti-sublimation layer, and vacuumizing; coating the anti-sublimation layer on the matte surface of the matte PET release film by using a circular knife blade coating machine, wherein the coating thickness is 0.08-0.12 mm; the drying tunnel temperature for coating the coating machine with the circular knife blade coating is 120-;
(2) uniformly stirring the components of the intermediate treatment layer, and vacuumizing; coating the intermediate treatment layer on the surface of the anti-sublimation layer by using a circular knife blade coating machine, wherein the coating thickness is 0.01-0.03 mm; the temperature of a drying tunnel for coating by a circular knife blade coating coater is 90-120 ℃, and the baking time is 5 min;
(3) uniformly stirring the components of the glue layer, and vacuumizing; coating the glue layer on the surface of the intermediate treatment layer by using a circular knife blade coating coater, and drying to obtain the anti-sublimation water-washing-resistant decorative film; the coating thickness is 0.07-0.1mm, the temperature of the drying tunnel of the round knife blade coating coater is 90-140 ℃, and the baking time is 10 min.
Example 2
An anti-sublimation washable decorative film for textiles comprises a matte PET release film and a glue coating layer coated on the matte surface of the matte PET release film, wherein the glue coating layer sequentially comprises an anti-sublimation layer, an intermediate treatment layer and a glue layer from inside to outside,
the anti-sublimation layer comprises the following components in parts by weight:
the intermediate treatment layer comprises the following components in parts by weight:
90 parts of polyester type polyurethane glue with the solid content of 35 percent,
1.5 parts of gamma-glycidoxypropyltrimethoxysilane (KH-560),
670 portions of nylon with the solid content of 40 percent;
the glue layer comprises the following components in parts by weight:
90 parts of polyester type polyurethane glue with the solid content of 35 percent,
1.5 parts of polycarbodiimide.
The preparation method of the sublimation-proof washable decorative film for the textile comprises the following steps:
(1) uniformly stirring the components of the anti-sublimation layer, and vacuumizing; coating the anti-sublimation layer on the matte surface of the matte PET release film by using a circular knife blade coating machine, wherein the coating thickness is 0.08-0.12 mm; the drying tunnel temperature for coating the coating machine with the circular knife blade coating is 120-;
(2) uniformly stirring the components of the intermediate treatment layer, and vacuumizing; coating the intermediate treatment layer on the surface of the anti-sublimation layer by using a circular knife blade coating machine, wherein the coating thickness is 0.01-0.03 mm; the temperature of a drying tunnel for coating by a circular knife blade coating coater is 90-120 ℃, and the baking time is 7 min;
(3) uniformly stirring the components of the glue layer, and vacuumizing; coating the glue layer on the surface of the intermediate treatment layer by using a circular knife blade coating coater, and drying to obtain the anti-sublimation water-washing-resistant decorative film; the coating thickness is 0.07-0.1mm, the temperature of the drying tunnel of the round knife blade coating coater is 90-140 ℃, and the baking time is 12 min.
Example 3
An anti-sublimation washable decorative film for textiles comprises a matte PET release film and a glue coating layer coated on the matte surface of the matte PET release film, wherein the glue coating layer sequentially comprises an anti-sublimation layer, an intermediate treatment layer and a glue layer from inside to outside,
the anti-sublimation layer comprises the following components in parts by weight:
the intermediate treatment layer comprises the following components in parts by weight:
the glue layer comprises the following components in parts by weight:
90 parts of polyester type polyurethane glue with the solid content of 35 percent,
2 parts of polycarbodiimide.
The preparation method of the sublimation-proof washable decorative film for the textile comprises the following steps:
(1) uniformly stirring the components of the anti-sublimation layer, and vacuumizing; coating the anti-sublimation layer on the matte surface of the matte PET release film by using a circular knife blade coating machine, wherein the coating thickness is 0.08-0.12 mm; the drying tunnel temperature for coating the coating machine with the circular knife blade coating is 120-;
(2) uniformly stirring the components of the intermediate treatment layer, and vacuumizing; coating the intermediate treatment layer on the surface of the anti-sublimation layer by using a circular knife blade coating machine, wherein the coating thickness is 0.01-0.03 mm; the temperature of a drying tunnel for coating by a circular knife blade coating coater is 90-120 ℃, and the baking time is 10 min;
(3) uniformly stirring the components of the glue layer, and vacuumizing; coating the glue layer on the surface of the intermediate treatment layer by using a circular knife blade coating coater, and drying to obtain the anti-sublimation water-washing-resistant decorative film; the coating thickness is 0.07-0.1mm, the temperature of the drying tunnel of the round knife blade coating coater is 90-140 ℃, and the baking time is 15 min.
Performance testing
Properties of the sublimation-preventing and water-resistant decorative films obtained in examples 1 to 3 and those of commercially available decorative films were measured in the following manner, and the results are shown in Table 1.
(1) And (3) water washability test: the washing was carried out 100 times for 60 minutes each in a 40 ℃ washing machine in accordance with JIS L0217103.
(2) Dry cleaning resistance test: according to GB/T19981.2-2005 part 2 of professional maintenance, dry cleaning and wet cleaning of textiles, fabrics and garments, dry cleaning was performed 15 times using the procedure standard for the dry cleaning and the press performance tests of tetrachloroethylene.
(3) Testing the wet heat aging sublimation resistance: the test environment temperature is 70 ℃, the humidity is 95% or more, and the test is carried out for 30 days.
(4) High-temperature thermal aging sublimation resistance test: baking in a blast oven at 100 ℃ for 7 days.
(5) High-temperature thermal aging sublimation resistance test: and (3) carrying out hot pressing on the anti-sublimation water-fast-washing decorative film product on the textile fabric easy to sublimate by using a flat plate pressing machine under the conditions of temperature of 150 ℃, pressure of 0.4mPa and time of 15 seconds, cooling for 30 minutes, and tearing off the matte PET release film to test according to the test standard.
TABLE 1 Properties of anti-sublimation water-resistant decorative films prepared in examples 1 to 3 and commercial decorative films
As can be seen from the above table, the anti-sublimation water-resistant decorative films prepared in examples 1 to 3 all have soft hand feeling, good dry-cleaning resistance and water-cleaning resistance, and can effectively prevent the sublimation and migration of the color of the textile fabric; however, sublimation color points appear in the commercially available decorative film in a water washing resistance test, a damp-heat aging sublimation resistance test and a high-temperature heat aging sublimation resistance test, which seriously affects the appearance quality of the product and the decorative film effect of the clothes. Therefore, the sublimation-proof water-resistant decorative film has excellent comprehensive performance and good application prospect.
Claims (10)
1. The sublimation-proof washable decorative film for the textile is characterized by comprising a matte PET release film and a glue coating layer coated on the matte surface of the matte PET release film, wherein the glue coating layer sequentially comprises a sublimation-proof layer, an intermediate treatment layer and a glue layer from inside to outside; wherein the content of the first and second substances,
the anti-sublimation layer comprises the following components in parts by weight:
the intermediate treatment layer comprises the following components in parts by weight:
80-95 parts of polyurethane glue with the solid content of 35 percent,
1-5 parts of a coupling agent,
55-70 parts of nylon glue with the solid content of 40 percent,
the glue layer comprises the following components in parts by weight:
80-95 parts of polyurethane glue with the solid content of 35 percent,
0.5-3 parts of polycarbodiimide.
2. The anti-sublimation washable decorative film for textiles as claimed in claim 1, wherein said liquid silicone rubber is selected from the group consisting of those having a viscosity of 45000mPa.s polydimethylsiloxane liquid silicone rubber and viscosity of 35000mPa.s one or at least two of polymethylsiloxane liquid silicone rubbers.
3. The anti-sublimation washable decorative film for textiles as claimed in claim 1, wherein the coupling agent is a silane coupling agent or an oligomer of a silane coupling agent, and comprises one or a mixture of at least two of gamma-glycidoxypropyltrimethoxysilane, 3-aminopropyltriethoxysilane, gamma-aminoethylaminopropyltrimethoxysilane, vinyltrimethoxysilane, hydroxysilane oligomer and fluorocarbon silane oligomer.
4. The anti-sublimation and washing-resistant decorative film for textiles according to claim 1, wherein the catalyst is one or a mixture of at least two of a platinum complex catalyst, an organotin catalyst, an amine catalyst and a titanate catalyst; the cross-linking agent comprises one or a mixture of at least two of a polyalkoxysilane cross-linking agent, a polybutanone oxime silane cross-linking agent, a polyacetyloxy silane cross-linking agent, a polyaminosilane cross-linking agent, a polyamidylsilane cross-linking agent, a polyisopropenoxysilane cross-linking agent and a hydrogen-containing silicone oil cross-linking agent.
5. The anti-sublimation and washing-resistant decorative film for textile use according to claim 1, wherein the polyurethane glue with a solid content of 35% comprises one or a mixture of at least two of polyester polyurethane glue and polyether polyurethane glue; the nylon glue with the solid content of 40% comprises one or a mixture of at least two of nylon 6, nylon 66, nylon 1010 and nylon 1013.
6. The sublimation-proof water-washing-resistant decorative film for textiles according to claim 5, wherein the polyester type polyurethane glue comprises polycaprolactone type polyurethane glue, polycarbonate type polyurethane glue; the polyether polyurethane glue comprises copolyether polyurethane glue.
7. The anti-sublimation and water-washing-resistant decorative film for textiles as claimed in claim 1, wherein the thickness of the anti-sublimation layer is 0.08-0.2mm, the thickness of the intermediate treatment layer is 0.01-0.03mm, and the thickness of the glue layer is not less than 0.07 mm.
8. The method for preparing the sublimation-proof water-fast decorative film for the textile according to any one of claims 1 to 7, which comprises the following steps:
(1) preparing an anti-sublimation layer: uniformly stirring liquid silicon rubber, titanium dioxide pigment paste with solid content of 45%, a coupling agent, a catalyst and a crosslinking agent, and vacuumizing;
(2) preparing an intermediate treatment layer: uniformly stirring polyurethane glue with the solid content of 35%, a coupling agent and nylon glue with the solid content of 40%, and vacuumizing;
(3) preparing a glue layer: uniformly stirring polyurethane glue with the solid content of 35% and polycarbodiimide, and vacuumizing;
(4) coating an anti-sublimation layer on the matte surface of the matte PET release film, and drying;
(5) coating an intermediate treatment layer on the surface of the anti-sublimation layer, and drying;
(6) and coating a glue layer on the surface of the intermediate treatment layer, and drying to obtain the sublimation-proof water-washing-resistant decorative film for the textile.
9. The method for preparing a sublimation-proof washable decorative film for textiles according to claim 8, wherein the sublimation-proof layer prepared in step (1) is coated within 1 hour.
10. The method of claim 8, wherein the coating steps (4), (5) and (6) are performed using a knife coater with a circular knife coater, wherein the knife coater is configured as follows:
and (4): the temperature of the drying tunnel is 120-;
and (5): baking at 90-120 deg.C for 5-10 min;
and (6): the baking tunnel temperature is 90-140 deg.C, and the baking time is 10-15 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810024776.5A CN108264859B (en) | 2018-01-11 | 2018-01-11 | Sublimation-proof washable decorative film for textiles and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810024776.5A CN108264859B (en) | 2018-01-11 | 2018-01-11 | Sublimation-proof washable decorative film for textiles and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108264859A CN108264859A (en) | 2018-07-10 |
| CN108264859B true CN108264859B (en) | 2020-08-28 |
Family
ID=62773494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810024776.5A Active CN108264859B (en) | 2018-01-11 | 2018-01-11 | Sublimation-proof washable decorative film for textiles and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108264859B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102240072B1 (en) * | 2018-09-28 | 2021-04-14 | 주식회사 엘지화학 | Composition for release layer and release film comprising cured product of the same |
| CN111334107A (en) * | 2020-04-23 | 2020-06-26 | 福建华峰运动用品科技有限公司 | Coating and working solution for 3D painting and preparation and use methods thereof |
| CN113246503A (en) * | 2021-04-21 | 2021-08-13 | 郑锡来 | Method for making imitation leather |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100421644B1 (en) * | 2001-02-22 | 2004-03-10 | 주성화학(주) | The surface treatment material for heat-sublimated transcription printing of cloth |
| CN106367985A (en) * | 2016-08-25 | 2017-02-01 | 安徽安利材料科技股份有限公司 | Preparation method for silicone rubber polyurethane synthetic leather |
| CN106564317A (en) * | 2016-10-27 | 2017-04-19 | 东莞市良展有机硅科技有限公司 | Thermal transfer printing system and positive transfer printing process |
| CN107264161A (en) * | 2017-07-01 | 2017-10-20 | 东莞市良展有机硅科技有限公司 | A kind of manufacture method of silica gel thermally transferred pattern |
-
2018
- 2018-01-11 CN CN201810024776.5A patent/CN108264859B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN108264859A (en) | 2018-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108264859B (en) | Sublimation-proof washable decorative film for textiles and preparation method thereof | |
| CN106521986B (en) | A kind of water-based two-sided matte woven fabric PU synthetic leather and preparation method thereof | |
| US20180195233A1 (en) | Scald-resistant synthetic leather and preparing method | |
| CN104691125B (en) | Gold stamping process | |
| KR100922297B1 (en) | Coating materials of nylon woven fabrics for transfer-print and manufacturing method of nylon woven fabrics for transfer-print | |
| CN105274871A (en) | Invisible pattern surface treatment technology for cloth showing patterns meeting water | |
| CN104499293A (en) | Waterproof and moisture permeable grid printed fabric and preparation method thereof | |
| CN112760995A (en) | Water-based matte oil-stain-proof synthetic leather and preparation method thereof | |
| CN110318261A (en) | A kind of waterproof cloth leather and preparation method thereof | |
| CN113462270A (en) | PU and PVC treating agent and preparation method thereof | |
| CN109680509B (en) | Silica gel leather applied to interior trim or seat of vehicle and preparation method thereof | |
| CN103603217A (en) | Color fixing agent and preparation method thereof | |
| CN206086036U (en) | Silica gel heat transfer is turned over to print and is pasted | |
| CN105644125B (en) | A kind of preparation method of suede nap composite polyurethane sofa cloth | |
| CN105774185A (en) | Production process of composite fabric of shu velveteen and plain fleece | |
| CN203807860U (en) | Waterproof and moisture permeable grid printed fabric | |
| CN112596136B (en) | Washable reflective decorative film for textiles and preparation method thereof | |
| CA1100256A (en) | Process for printing on solid molded articles made from urea formaldehyde resin or melamine formaldehyde resin | |
| CN110423553B (en) | Heat transfer printing metal zipper cloth belt coating liquid, heat transfer printing metal zipper and preparation method thereof | |
| CN210667492U (en) | Silica gel heat-transfer seal sign that clothing was used and preparation equipment thereof | |
| CN113306249A (en) | Water-based coating PVC artificial leather and preparation method thereof | |
| CN109466200B (en) | Anti-color-penetration thermal transfer printing process | |
| CN108914603A (en) | Aqueous knife patch clothing leather of one kind and preparation method thereof | |
| CN205688263U (en) | A kind of synthetic leather of resistance to scald | |
| CN107419561B (en) | A kind of preparation method of albumen base weaving pigment printing binding agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 529000 Duruan Town North Ring Road Double Floor Industrial Zone, Pengjiang District, Jiangmen City, Guangdong Province Applicant after: Guangdong Yingtong New Materials Co., Ltd. Address before: 529000 No. 70, North Third Road, Duruan Town, Pengjiang District, Jiangmen City, Guangdong Province Applicant before: Jiangmen city Pengjiang District Ying Tong plasthetics Co., Ltd |
|
| CB02 | Change of applicant information | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |