CN108264225A - A kind of low melting point coloured glaze and preparation method thereof - Google Patents
A kind of low melting point coloured glaze and preparation method thereof Download PDFInfo
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- CN108264225A CN108264225A CN201810265432.3A CN201810265432A CN108264225A CN 108264225 A CN108264225 A CN 108264225A CN 201810265432 A CN201810265432 A CN 201810265432A CN 108264225 A CN108264225 A CN 108264225A
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- parts
- coloured glaze
- melting point
- low melting
- colorant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
- C03C3/111—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B9/00—Blowing glass; Production of hollow glass articles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/004—Refining agents
Abstract
The invention discloses a kind of low melting point coloured glazes and preparation method thereof, are related to coloured glaze field.The low melting point coloured glaze in parts by weight, including following components：60 80 parts of silica, 20 30 parts of diboron trioxide, 20 30 parts of zinc oxide, 20 30 parts of magnesia, 10 20 parts of lithium molybdate, 10 20 parts of vanadic anhydride, 5 15 parts of lithia, 8 18 parts of sodium oxide molybdena, 4 12 parts of barium monoxide, 4 12 parts of sodium nitrate, 5 10 parts of colorant, 5 10 parts of fining agent.The beneficial effects of the present invention are：The present invention mixes silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, lithia, sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent according to a certain ratio, scientific formulation, the particularly addition of lithium molybdate, vanadic anhydride, smelting temperature can be significantly reduced, save the melt time, reach energy-saving, reduce the effect of cost.
Description
Technical field
The invention mainly relates to coloured glaze field, specifically a kind of low melting point coloured glaze and preparation method thereof.
Background technology
Coloured glaze is a kind of silicate product, is the characteristic conventional industries of Zibo City, is had in the whole province or even the whole nation certain
Popularity, quality is glittering and translucent, bright and glittering, change is magnificent, fully demonstrates the exquisiteness of Asians, exquisiteness and implicit, is
A wonderful work in important decoration element and artistic decoration in building.2013, coloured glaze was published as by Government of Shandong Province
Three batches of provincial non-material cultural heritage register projects.2014, pass through the 4th batch of List of National Intangible Cultural Heritage project
Publicity.
The main component of coloured glaze is silica, while adds in various flux, stabilizer, bridging agent etc..Silica
Fusing point be about 1700 DEG C, with prior art, using sodium matter as fluxing agent, the fusing point of the coloured glaze of formation can be controlled in 1450 DEG C of left sides
The right side, since smelting temperature is higher, smelting time is longer in process of production, and energy consumption is bigger, and therefore, it is necessary to study exploitations one
Kind novel coloured glaze formula reduces the fusing point of coloured glaze glassware, it is made to reduce smelting temperature in this process procedure of coloured glaze melt,
Smelting time is saved, reaches energy-saving, reduces the effect of cost.
Invention content
To solve the deficiencies in the prior art, the present invention provides a kind of low melting point coloured glaze and preparation method thereof, which leads to
The formula for changing coloured glaze is crossed, making it, reduction smelting temperature saves smelting time, reaches section in this process procedure of coloured glaze material
It can lower consumption, reduce the effect of cost.
The present invention to achieve the above object, is achieved through the following technical solutions：
A kind of low melting point coloured glaze, in parts by weight, including following components：60-80 parts of silica, diboron trioxide
20-30 parts, 20-30 parts of zinc oxide, 20-30 parts of magnesia, 10-20 parts of lithium molybdate, 10-20 parts of vanadic anhydride, lithia 5-
15 parts, 8-18 parts of sodium oxide molybdena, 4-12 parts of barium monoxide, 4-12 parts of sodium nitrate, 5-10 parts of colorant, 5-10 parts of fining agent.
Than more preferably scheme, the low melting point coloured glaze in parts by weight, including following components：Silica
65-75 parts, 23-27 parts of diboron trioxide, 23-27 parts of zinc oxide, 23-27 parts of magnesia, 12-18 parts of lithium molybdate, five oxidation two
It is 12-18 parts of vanadium, 8-12 parts of lithia, 8-12 parts of sodium oxide molybdena, 6-10 parts of barium monoxide, 6-10 parts of sodium nitrate, 6-8 parts of colorant, clear
Clear 6-8 parts of agent.
Most preferred scheme, the low melting point coloured glaze in parts by weight, including following components：Silica 70
Part, 25 parts of diboron trioxide, 25 parts of zinc oxide, 25 parts of magnesia, 15 parts of lithium molybdate, 15 parts of vanadic anhydride, 10 parts of lithia,
10 parts of sodium oxide molybdena, 8 parts of barium monoxide, 8 parts of sodium nitrate, 7 parts of colorant, 7 parts of fining agent.
Preferably, the fining agent presses quality proportioning 3 for antimony oxide and sodium chloride：1 is combined.
Preferably, the colorant is manganese dioxide.
The preparation method of above-mentioned low melting point coloured glaze, step are as follows：
1) raw material mixes：By silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, oxidation
Lithium, sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent are mixed after being crushed respectively with pulverizer, obtain mixed raw material；
2) melt：Mixed raw material obtained by step 1) is sent into melting in 1100-1300 DEG C of stove, the coloured glaze melted
Glass has kept temperature, is rotated on the iron staff of stove with the coloured glaze of melting, forms colored glaze body；
3) material blowing is chosen：Colored glaze body obtained by step 2) is taken out from stove with the cylinder that blows of 1-1.5m long, and by colored glaze body
It is placed on slewing, is blown while rotating, obtain molding coloured glaze；
4) it anneals：Coloured glaze molding in step 3) is put into inside 300-400 DEG C of heat preservation kiln and carries out annealing 2-3
My god；
5) it cools down：Coloured glaze after step 4) is made annealing treatment takes out from heat preservation kiln carries out natural cooling 12-24h to room
Temperature, polishing, polishing are got product.
Mixed raw material melting in 1200 DEG C of stove in the step 2).
The rotary speed of slewing is 150-200r/min in the step 3).
The prior art is compared, the beneficial effects of the invention are as follows：
The present invention is by silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, lithia, oxygen
Change sodium, barium monoxide, sodium nitrate, colorant, fining agent to mix according to a certain ratio, scientific formulation, particularly lithium molybdate, five oxygen
To change the addition of two vanadium, fusing point can be reduced to 1100 DEG C or so, the melt time shortens to 3-4h, significantly reduces smelting temperature,
The melt time is saved, reaches energy-saving, reduces the effect of cost.
Specific embodiment
In conjunction with specific embodiments, the invention will be further described.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after the content that the present invention is told about has been read, people in the art
Member can make various changes or modifications the present invention, and such equivalent forms equally fall within range defined herein.
Embodiment 1
A kind of low melting point coloured glaze, in parts by weight, including following components：60 parts of silica, diboron trioxide 20
Part, 20 parts of zinc oxide, 20 parts of magnesia, 10 parts of lithium molybdate, 10 parts of vanadic anhydride, 15 parts of lithia, 18 parts of sodium oxide molybdena, oxidation
12 parts of barium, 12 parts of sodium nitrate, 5 parts of colorant, 5 parts of fining agent.
The fining agent presses quality proportioning 3 for antimony oxide and sodium chloride：1 is combined.
The colorant is manganese dioxide.
The preparation method of above-mentioned low melting point coloured glaze, step are as follows：
1) raw material mixes：By silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, oxidation
Lithium, sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent are mixed after being crushed respectively with pulverizer, obtain mixed raw material；
2) melt：Mixed raw material obtained by step 1) is sent into melting in 1300 DEG C of stove, the coloured glaze melted is protected
Temperature has been held, has been rotated on the iron staff of stove with the coloured glaze of melting, has formed colored glaze body；
3) material blowing is chosen：Colored glaze body obtained by step 2) is taken out from stove, and colored glaze body is put with the cylinder that blows of 1.5m long
It puts on slewing, is blown while rotating, obtain molding coloured glaze；
4) it anneals：Coloured glaze molding in step 3) is put into inside 400 DEG C of heat preservation kiln and carries out annealing 2 days；
5) it cools down：Coloured glaze after step 4) is made annealing treatment takes out from heat preservation kiln carries out natural cooling 12h to room temperature, beats
Mill, polishing are got product.
Embodiment 2
A kind of low melting point coloured glaze, in parts by weight, including following components：80 parts of silica, diboron trioxide 30
Part, 30 parts of zinc oxide, 30 parts of magnesia, 20 parts of lithium molybdate, 20 parts of vanadic anhydride, 5 parts of lithia, 8 parts of sodium oxide molybdena, barium monoxide
4 parts, 4 parts of sodium nitrate, 10 parts of colorant, 10 parts of fining agent.
The fining agent presses quality proportioning 3 for antimony oxide and sodium chloride：1 is combined.
The colorant is manganese dioxide.
The preparation method of above-mentioned low melting point coloured glaze, step are as follows：
1) raw material mixes：By silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, oxidation
Lithium, sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent are mixed after being crushed respectively with pulverizer, obtain mixed raw material；
2) melt：Mixed raw material obtained by step 1) is sent into melting in 1200 DEG C of stove, the coloured glaze melted is protected
Temperature has been held, has been rotated on the iron staff of stove with the coloured glaze of melting, has formed colored glaze body；
3) material blowing is chosen：Colored glaze body obtained by step 2) is taken out from stove, and colored glaze body is put with the cylinder that blows of 1.5m long
It puts on slewing, is blown while rotating, obtain molding coloured glaze；
4) it anneals：Coloured glaze molding in step 3) is put into inside 400 DEG C of heat preservation kiln and carries out annealing 2 days；
5) it cools down：Coloured glaze after step 4) is made annealing treatment takes out from heat preservation kiln carries out natural cooling for 24 hours to room temperature, beats
Mill, polishing are got product.
Embodiment 3
A kind of low melting point coloured glaze, in parts by weight, including following components：65 parts of silica, diboron trioxide 23
Part, 23 parts of zinc oxide, 23 parts of magnesia, 12 parts of lithium molybdate, 12 parts of vanadic anhydride, 12 parts of lithia, 12 parts of sodium oxide molybdena, oxidation
10 parts of barium, 10 parts of sodium nitrate, 6 parts of colorant, 6 parts of fining agent.
The fining agent presses quality proportioning 3 for antimony oxide and sodium chloride：1 is combined.
The colorant is manganese dioxide.
The preparation method of above-mentioned low melting point coloured glaze, step are as follows：
1) raw material mixes：By silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, oxidation
Lithium, sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent are mixed after being crushed respectively with pulverizer, obtain mixed raw material；
2) melt：Mixed raw material obtained by step 1) is sent into melting in 1300 DEG C of stove, the coloured glaze melted is protected
Temperature has been held, has been rotated on the iron staff of stove with the coloured glaze of melting, has formed colored glaze body；
3) material blowing is chosen：Colored glaze body obtained by step 2) is taken out from stove, and colored glaze body is put with the cylinder that blows of 1.5m long
It puts on slewing, is blown while rotating, obtain molding coloured glaze；
4) it anneals：Coloured glaze molding in step 3) is put into inside 300 DEG C of heat preservation kiln and carries out annealing 3 days；
5) it cools down：Coloured glaze after step 4) is made annealing treatment takes out from heat preservation kiln carries out natural cooling 12h to room temperature, beats
Mill, polishing are got product.
Embodiment 4
A kind of low melting point coloured glaze, in parts by weight, including following components：75 parts of silica, diboron trioxide 27
Part, 27 parts of zinc oxide, 27 parts of magnesia, 18 parts of lithium molybdate, 18 parts of vanadic anhydride, 8 parts of lithia, 8 parts of sodium oxide molybdena, barium monoxide
6 parts, 6 parts of sodium nitrate, 8 parts of colorant, 8 parts of fining agent.
The fining agent presses quality proportioning 3 for antimony oxide and sodium chloride：1 is combined.
The colorant is manganese dioxide.
The preparation method of above-mentioned low melting point coloured glaze, step are as follows：
1) raw material mixes：By silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, oxidation
Lithium, sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent are mixed after being crushed respectively with pulverizer, obtain mixed raw material；
2) melt：Mixed raw material obtained by step 1) is sent into melting in 1200 DEG C of stove, the coloured glaze melted is protected
Temperature has been held, has been rotated on the iron staff of stove with the coloured glaze of melting, has formed colored glaze body；
3) material blowing is chosen：Colored glaze body obtained by step 2) is taken out from stove, and colored glaze body is placed with the cylinder that blows of 1m long
It onto slewing, is blown while rotating, obtains molding coloured glaze；
4) it anneals：Coloured glaze molding in step 3) is put into inside 300 DEG C of heat preservation kiln and carries out annealing 3 days；
5) it cools down：Coloured glaze after step 4) is made annealing treatment takes out from heat preservation kiln carries out natural cooling for 24 hours to room temperature, beats
Mill, polishing are got product.
Embodiment 5
A kind of low melting point coloured glaze, in parts by weight, including following components：70 parts of silica, diboron trioxide 25
Part, 25 parts of zinc oxide, 25 parts of magnesia, 15 parts of lithium molybdate, 15 parts of vanadic anhydride, 10 parts of lithia, 10 parts of sodium oxide molybdena, oxidation
8 parts of barium, 8 parts of sodium nitrate, 7 parts of colorant, 7 parts of fining agent.
The fining agent presses quality proportioning 3 for antimony oxide and sodium chloride：1 is combined.
The colorant is manganese dioxide.
The preparation method of above-mentioned low melting point coloured glaze, step are as follows：
1) raw material mixes：By silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, oxidation
Lithium, sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent are mixed after being crushed respectively with pulverizer, obtain mixed raw material；
2) melt：Mixed raw material obtained by step 1) is sent into melting in 1100 DEG C of stove, the coloured glaze melted is protected
Temperature has been held, has been rotated on the iron staff of stove with the coloured glaze of melting, has formed colored glaze body；
3) material blowing is chosen：Colored glaze body obtained by step 2) is taken out from stove, and colored glaze body is put with the cylinder that blows of 1.5m long
It puts on slewing, is blown while rotating, obtain molding coloured glaze；
4) it anneals：Coloured glaze molding in step 3) is put into inside 350 DEG C of heat preservation kiln and carries out annealing 2.5 days；
5) it cools down：Coloured glaze after step 4) is made annealing treatment takes out from heat preservation kiln carries out natural cooling 18h to room temperature, beats
Mill, polishing are got product.
Claims (8)
1. a kind of low melting point coloured glaze, it is characterised in that：In parts by weight, including following components：60-80 parts of silica,
20-30 parts of diboron trioxide, 20-30 parts of zinc oxide, 20-30 parts of magnesia, 10-20 parts of lithium molybdate, vanadic anhydride 10-20
Part, 5-15 parts of lithia, 8-18 parts of sodium oxide molybdena, 4-12 parts of barium monoxide, 4-12 parts of sodium nitrate, 5-10 parts of colorant, fining agent 5-
10 parts.
2. low melting point coloured glaze according to claim 1, it is characterised in that：In parts by weight, including following components：Two
65-75 parts of silica, 23-27 parts of diboron trioxide, 23-27 parts of zinc oxide, 23-27 parts of magnesia, 12-18 parts of lithium molybdate, five
12-18 parts of V 2 O, 8-12 parts of lithia, 8-12 parts of sodium oxide molybdena, 6-10 parts of barium monoxide, 6-10 parts of sodium nitrate, colorant 6-8
Part, 6-8 parts of fining agent.
3. low melting point coloured glaze according to claim 1, it is characterised in that：In parts by weight, including following components：Two
70 parts of silica, 25 parts of diboron trioxide, 25 parts of zinc oxide, 25 parts of magnesia, 15 parts of lithium molybdate, 15 parts of vanadic anhydride, oxygen
Change 10 parts of lithium, 10 parts of sodium oxide molybdena, 8 parts of barium monoxide, 8 parts of sodium nitrate, 7 parts of colorant, 7 parts of fining agent.
4. low melting point coloured glaze according to claim 1, it is characterised in that：The fining agent is antimony oxide and sodium chloride
By quality proportioning 3：1 is combined.
5. low melting point coloured glaze according to claim 1, it is characterised in that：The colorant is manganese dioxide.
6. according to a kind of preparation method of low melting point coloured glaze of claim 1-5 any one of them, it is characterised in that：Step is such as
Under：
1) raw material mixes：By silica, diboron trioxide, zinc oxide, magnesia, lithium molybdate, vanadic anhydride, lithia,
Sodium oxide molybdena, barium monoxide, sodium nitrate, colorant, fining agent are mixed after being crushed respectively with pulverizer, obtain mixed raw material；
2) melt：By melting in the stove of 1100-1300 DEG C of mixed raw material feeding obtained by step 1), the coloured glaze melted,
Temperature has been kept, has been rotated on the iron staff of stove with the coloured glaze of melting, has formed colored glaze body；
3) material blowing is chosen：Colored glaze body obtained by step 2) is taken out from stove, and colored glaze body is placed with the cylinder that blows of 1-1.5m long
It onto slewing, is blown while rotating, obtains molding coloured glaze；
4) it anneals：Coloured glaze molding in step 3) is put into inside 300-400 DEG C of heat preservation kiln and carries out annealing 2-3 days；
5) it cools down：Coloured glaze after step 4) is made annealing treatment takes out from heat preservation kiln carries out natural cooling 12-24h to room temperature, beats
Mill, polishing are got product.
7. a kind of preparation method of low melting point coloured glaze according to claim 6, it is characterised in that：It is mixed in the step 2)
Raw material melting in 1200 DEG C of stove.
8. a kind of preparation method of low melting point coloured glaze according to claim 6, it is characterised in that：Slewing in step 3)
Rotary speed be 150-200r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810265432.3A CN108264225A (en) | 2018-03-28 | 2018-03-28 | A kind of low melting point coloured glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810265432.3A CN108264225A (en) | 2018-03-28 | 2018-03-28 | A kind of low melting point coloured glaze and preparation method thereof |
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| CN108264225A true CN108264225A (en) | 2018-07-10 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102503122A (en) * | 2011-09-29 | 2012-06-20 | 大连工业大学 | Leadless, cadmium-free and strontium-free glass and manufacture process thereof |
| CN104193166A (en) * | 2014-09-05 | 2014-12-10 | 广东风华高新科技股份有限公司 | Glass frit and preparation method thereof |
| CN106277776A (en) * | 2016-08-23 | 2017-01-04 | 太仓市双凤镇薄彩工艺品厂 | A kind of argentum powder coloured glaze and preparation method thereof |
| CN106316111A (en) * | 2016-08-23 | 2017-01-11 | 太仓市双凤镇薄彩工艺品厂 | Fluorescent translucent colored glaze and manufacturing method thereof |
| CN107417254A (en) * | 2017-06-28 | 2017-12-01 | 常州市沃兰特电子有限公司 | A kind of easy fired antique glazed tile and preparation method thereof |
| CN107601821A (en) * | 2017-09-27 | 2018-01-19 | 太仓经济开发区坚毅工艺美术品工作室 | A kind of preparation method of coloured glaze |
-
2018
- 2018-03-28 CN CN201810265432.3A patent/CN108264225A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102503122A (en) * | 2011-09-29 | 2012-06-20 | 大连工业大学 | Leadless, cadmium-free and strontium-free glass and manufacture process thereof |
| CN104193166A (en) * | 2014-09-05 | 2014-12-10 | 广东风华高新科技股份有限公司 | Glass frit and preparation method thereof |
| CN106277776A (en) * | 2016-08-23 | 2017-01-04 | 太仓市双凤镇薄彩工艺品厂 | A kind of argentum powder coloured glaze and preparation method thereof |
| CN106316111A (en) * | 2016-08-23 | 2017-01-11 | 太仓市双凤镇薄彩工艺品厂 | Fluorescent translucent colored glaze and manufacturing method thereof |
| CN107417254A (en) * | 2017-06-28 | 2017-12-01 | 常州市沃兰特电子有限公司 | A kind of easy fired antique glazed tile and preparation method thereof |
| CN107601821A (en) * | 2017-09-27 | 2018-01-19 | 太仓经济开发区坚毅工艺美术品工作室 | A kind of preparation method of coloured glaze |
Non-Patent Citations (1)
| Title |
|---|
| 韩宗珠等: "《宝石学与宝石鉴定》", 31 March 2003, 中国海洋大学出版社 * |
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