CN108262334A - A kind of dangerous solid wastes recycling processing method of organic matter - Google Patents

A kind of dangerous solid wastes recycling processing method of organic matter Download PDF

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Publication number
CN108262334A
CN108262334A CN201810050918.5A CN201810050918A CN108262334A CN 108262334 A CN108262334 A CN 108262334A CN 201810050918 A CN201810050918 A CN 201810050918A CN 108262334 A CN108262334 A CN 108262334A
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China
Prior art keywords
organic matter
crystallization
processing method
salt
water
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CN201810050918.5A
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Chinese (zh)
Inventor
何昭纯
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Guangzhou Leaf Forest Environmental Protection & Technology Co Ltd
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Guangzhou Leaf Forest Environmental Protection & Technology Co Ltd
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Priority to CN201810050918.5A priority Critical patent/CN108262334A/en
Publication of CN108262334A publication Critical patent/CN108262334A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Fertilizers (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of dangerous solid wastes recycling processing methods of organic matter, specifically include following steps:First cutting process;Its humidity condition is detected again, evaporation process is carried out after humidity is up to standard, the hot gas after evaporation is recycled, and the hot gas of recycling carries out carrying out crystallization treatment again after air purification removes impurity, and a small amount of salt after crystallization is spare;And crystallize after water be filtered it is spare;Solid after evaporation is sent into elevated temperature desorption to handle, the waste residue after desorption is stirred dissolving;Dissolved mixed liquor is filtered to obtain liquid and residue, to becoming fertilizer by microbial fermentation after burning;Obtained liquid is purified with activated carbon adsorption, carries out burning disposal to the activated carbon isolated, the liquid by the saliferous after adsorption cleaning is filtered, then carries out crystallization treatment again, dissolving position can be returned after the water filtration of crystallization;The crystal salt of acquisition carries out washing and obtains final useful salt.This method is easy to operate, realizes using energy source, realizes harmless treatment.

Description

A kind of dangerous solid wastes recycling processing method of organic matter
Technical field
The present invention relates to a kind of technical field of waste processing, the dangerous solid wastes recycling processing of especially a kind of organic matter Method.
Background technology
It is essential in life to will appear solid waste, and the solid waste that we often say is in addition to house refuse, kitchen Rubbish etc. is outer, generally further includes electron wastes, Biohazard Waste etc., and different solid waste substance treating methods is also different, It is producing methane through anaerobic fermentation etc. that for example electron wastes, which are usually recycling, kitchen garbage popular at present,.Consider To general public's degree of attentiveness, what I tentatively guessed that you may ask is house refuse.
If house refuse, four classes can also be roughly divided into according to processing method, to fill, burning, compost and synthesis Processing, each technique respectively have its advantage, also have its deficiency, in actual process, need to be selected according to actual conditions.Such as Landfill is longer in China's development time, and technology is also relatively simple, and cost of investment is relatively low, these are all its advantages, but insufficient also very bright Aobvious, if floor space is larger, especially in the popular city of soil an inch of land is an inch of gold, it is very fatal that this is insufficient.And landfill is dirty Dye is not easy to control, and especially to underground water and atmosphere pollution, this requires it is anti-, to blend peculiar smell control preferable, but so into This also corresponding increase.Landfill is to gradually decrease trend in China at present.Burning is China's garbage disposal more popular in recent years Technique, because its minimizing is significantly just recommended to the utmost at present by some experts, but pollution problem caused by burning is more tight The pollution of the toxic elements such as weight , bioxin is at present or it is difficult to control, the common people currently still hold resistance attitude.For economically, burn It is maximum to burn early investment, but later stage income is also more apparent, especially public subsidies are more, and this point is also current construction incineration plant One of the major reasons.Rubbish heap is exactly set to fertilizer by compost, but China's component of refuse is complicated, the fertilizer generally banked up not by Peasant approves, therefore the current situation of compost is more awkward.Integrated treatment is current newer treatment technology, and rubbish need to be filled Point sorting, from environmental protection for, it should be safer, also easily received by the common people, but its deficiency is skill Art is complex, and also not as good as burning in income.
And hazardous waste is also existing in junk, and every year with the development of industry, solid waste rubbish Constantly increasing.According to the survey report of green peace organization, developed country is with annual 50000000 tons of scale into development Country's transhipment hazardous waste, from 1986 to 1992 year, developed country is to developing country and East European countries' transfer total amount 1.63 hundred million tons of hazardous waste.The transboundary movement of hazardous waste all has very important to developing country or even global environment Harm.
Firstly, since the importer of waste is substantially all the technological means and Economic Energy for lacking processing and disposition hazardous waste Power, the input of hazardous waste inevitably result in the damage to local environment and population health.Secondly, hazardous waste is not to sending out Diffusion up to area is actually to escape disposition responsibility as defined in this country, and hazardous waste is made not obtain due processing and disposition And be diffused among environment, the result of long-term accumulation will necessarily generate harm to global environment.The transboundary movement of hazardous waste Harm also resides in, these wastes are entered in the case where the name of trade is covered, and importer is in order to fish for economic interests, not Its issuable influence on environmental and human health impacts is cared for, so all cannot get due processing and disposition.Hazardous waste is got over Border transfer has become one of serious Global Environmental Problems, such as takes no action to be controlled, global environment certainly will be caused sternly It endangers again, and solid waste land-fill method most at present, lead to secondary pollution, while many organic matters are also landfilled in solid waste, Therefore the recycling that organic matter realizes the energy how is handled the dangerous solid waste of organic matter and is obtained, it is quite important.
Invention content
The dangerous solid waste of a kind of organic matter provided the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art Recycling processing method.
To achieve these goals, the dangerous solid wastes recycling processing method of a kind of organic matter designed by the present invention, tool Body includes the following steps:
S1, cutting process is carried out to the mixing hazardous waste of saliferous and organic matter;
S2 and then its humidity condition is detected, if humidity is less than specified value, be first filled with pure water, and sent after standing a period of time Enter step S3;If humidity is more than specified value, it is sent directly into step S3;
S3, processing is evaporated to liquid mixture, then recycles the hot gas after evaporation, the hot gas of recycling carries out Air purification after removing impurity, then carries out crystallization treatment, and a small amount of salt after crystallization is spare;And after the water after crystallizing is filtered It is spare;
S4, the solid after evaporation is sent into elevated temperature desorption processing, will be discharged after the air purification after elevated temperature desorption, after desorption Waste residue solid organic matters be stirred dissolving using the water after the crystallization in step S3;
S5, dissolved mixed liquor are filtered to obtain liquid and water-insoluble salt and debris, to water-insoluble Salt and debris are burned, and become fertilizer by microbial fermentation after burning;
S6, obtained liquid are purified with activated carbon adsorption, burning disposal are carried out to the activated carbon isolated, to passing through absorption The liquid of purified saliferous is filtered, and is then carried out crystallization treatment again, can be returned in step S4 after the water filtration of crystallization Dissolve position;
S7, the crystal salt obtained carry out washing and obtain final useful salt.
Further, desorption temperature is 400-480 DEG C in step s 4.
Further, above-mentioned crystallization is crystallized by cooling down crystallization mode.
Further, the activated carbon adsorption link that a small amount of salt after being crystallized in S3 is sent into step S6 is mixed.
Further, quality is detected to salt after being washed during step S7, continues to filter, tie if quality is below standard Brilliant, washing, makes its requisite quality.
Further, the pure water added in step s 2 is the water used after being filtered from the above-mentioned water crystallized out.
Further, separating step S8 is added between step S1 and step S2, separation is fuel-displaced, and removes oil content, then will The substance of taking-up is sent into step S2.
A kind of dangerous solid wastes recycling processing method for organic matter that the present invention obtains, the configuration of the present invention is simple, operation side Just, and high treating effect, effective desalination can be carried out, while will be last to the hazardous waste mixed containing brine, organic matter Organic matter product carries out ferment making into organic manure, and the salt purified can recycle, final to realize using energy source, in fact Existing harmless treatment.
Description of the drawings
Fig. 1 is a kind of process schematic diagram of the dangerous solid wastes recycling processing method for organic matter that embodiment 1 provides;
Fig. 2 is a kind of process schematic diagram of the dangerous solid wastes recycling processing method for organic matter that embodiment 2 provides.
Specific embodiment
With reference to embodiment, the present invention is further described.
Embodiment 1:
As shown in Figure 1, a kind of dangerous solid wastes recycling processing method of organic matter provided in this embodiment, specifically include with Lower step:
S1, cutting process is carried out to the mixing hazardous waste of saliferous and organic matter;
S2 and then its humidity condition is detected, if humidity is less than specified value, be first filled with pure water, and sent after standing a period of time Enter step S3;If humidity is more than specified value, it is sent directly into step S3;
S3, processing is evaporated to liquid mixture, then recycles the hot gas after evaporation, the hot gas of recycling carries out Air purification after removing impurity, then carries out crystallization treatment, and a small amount of salt after crystallization is spare;And after the water after crystallizing is filtered It is spare;
S4, the solid after evaporation is sent into elevated temperature desorption processing, will be discharged after the air purification after elevated temperature desorption, after desorption Waste residue solid organic matters be stirred dissolving using the water after the crystallization in step S3;
S5, dissolved mixed liquor are filtered to obtain liquid and water-insoluble salt and debris, to water-insoluble Salt and debris are burned, and become fertilizer by microbial fermentation after burning;
S6, obtained liquid are purified with activated carbon adsorption, burning disposal are carried out to the activated carbon isolated, to passing through absorption The liquid of purified saliferous is filtered, and is then carried out crystallization treatment again, can be returned in step S4 after the water filtration of crystallization Dissolve position;
S7, the crystal salt obtained carry out washing and obtain final useful salt.
Further, desorption temperature is 400-480 DEG C in step s 4.
Further, above-mentioned crystallization is crystallized by cooling down crystallization mode.
Further, the activated carbon adsorption link that a small amount of salt after being crystallized in S3 is sent into step S6 is mixed.
Further, quality is detected to salt after being washed during step S7, continues to filter, tie if quality is below standard Brilliant, washing, makes its requisite quality.
Further, the pure water added in step s 2 is the water used after being filtered from the above-mentioned water crystallized out.
As shown in Fig. 2, a kind of general configuration of the dangerous solid wastes recycling processing method of organic matter provided in this embodiment It is same as Example 1, the difference is that in order to remove the oil in the solid waste containing oil, the effect of withdrawing deposit in later stage is improved, Specifically include following steps:
S1, cutting process is carried out to the mixing hazardous waste of saliferous and organic matter;
S8, separating step is added in, separation is fuel-displaced, and removes oil content, and the substance of taking-up then is sent into step S2;
S2 and then its humidity condition is detected, if humidity is less than specified value, be first filled with pure water, and sent after standing a period of time Enter step S3;If humidity is more than specified value, it is sent directly into step S3;
S3, processing is evaporated to liquid mixture, then recycles the hot gas after evaporation, the hot gas of recycling carries out Air purification after removing impurity, then carries out crystallization treatment, and a small amount of salt after crystallization is spare;And after the water after crystallizing is filtered It is spare;
S4, the solid after evaporation is sent into elevated temperature desorption processing, will be discharged after the air purification after elevated temperature desorption, after desorption Waste residue solid organic matters be stirred dissolving using the water after the crystallization in step S3;
S5, dissolved mixed liquor are filtered to obtain liquid and water-insoluble salt and debris, to water-insoluble Salt and debris are burned, and become fertilizer by microbial fermentation after burning;
S6, obtained liquid are purified with activated carbon adsorption, burning disposal are carried out to the activated carbon isolated, to passing through absorption The liquid of purified saliferous is filtered, and is then carried out crystallization treatment again, can be returned in step S4 after the water filtration of crystallization Dissolve position;
S7, the crystal salt obtained carry out washing and obtain final useful salt.

Claims (8)

1. a kind of dangerous solid wastes recycling processing method of organic matter, it is characterised in that:Specifically include following steps:
S1, cutting process is carried out to the mixing hazardous waste of saliferous and organic matter;
S2 and then its humidity condition is detected, if humidity is less than specified value, be first filled with pure water, and step is sent into after standing a period of time Rapid S3;If humidity is more than specified value, it is sent directly into step S3;
S3, processing is evaporated to liquid mixture, then recycles the hot gas after evaporation, the hot gas of recycling carries out air Purification after removing impurity, then carries out crystallization treatment, and a small amount of salt after crystallization is spare;And crystallize after water be filtered it is rear spare;
S4, the solid after evaporation is sent into elevated temperature desorption processing, will be discharged after the air purification after elevated temperature desorption, it is useless after desorption Slag solid organic matters are stirred dissolving using the water after the crystallization in step S3;
S5, dissolved mixed liquor are filtered to obtain liquid and water-insoluble salt and debris, to water-insoluble salt and Debris is burned, and becomes fertilizer by microbial fermentation after burning;
S6, obtained liquid are purified with activated carbon adsorption, burning disposal are carried out to the activated carbon isolated, to passing through adsorption cleaning The liquid of saliferous afterwards is filtered, and then carries out crystallization treatment again, and the dissolving in step S4 can be returned after the water filtration of crystallization Position;
S7, the crystal salt obtained carry out washing and obtain final useful salt.
2. a kind of dangerous solid wastes recycling processing method of organic matter according to claim 1, it is characterised in that:In step Desorption temperature is 400-480 DEG C in S4.
3. a kind of dangerous solid wastes recycling processing method of organic matter according to claim 1 or 2, it is characterised in that:On The crystallization stated is crystallized by cooling down crystallization mode.
4. a kind of dangerous solid wastes recycling processing method of organic matter according to claim 1 or 2, it is characterised in that: The activated carbon adsorption link that a small amount of salt after being crystallized in S3 is sent into step S6 is mixed.
5. a kind of dangerous solid wastes recycling processing method of organic matter according to claim 1 or 2, it is characterised in that: Quality is detected to salt after being washed during step S7, continues to filter, crystallizes, washs if quality is below standard, reaching its quality Mark.
6. a kind of dangerous solid wastes recycling processing method of organic matter according to claim 1 or 2, it is characterised in that: The pure water added in step S2 is the water used after being filtered from the above-mentioned water crystallized out.
7. a kind of dangerous solid wastes recycling processing method of organic matter according to claim 1 or 2, it is characterised in that: Separating step S8 is added between step S1 and step S2, separation is fuel-displaced, and removes oil content, and the substance of taking-up then is sent into step S2。
8. a kind of dangerous solid wastes recycling processing method of organic matter according to claim 3, it is characterised in that:In step Separating step S8 is added between S1 and step S2, separation is fuel-displaced, and removes oil content, and the substance of taking-up then is sent into step S2.
CN201810050918.5A 2018-01-18 2018-01-18 A kind of dangerous solid wastes recycling processing method of organic matter Pending CN108262334A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108728140A (en) * 2018-08-13 2018-11-02 湖南叶林环保科技有限公司 Organic dangerous waste low temperature pyrogenation electricity generation system
CN112605094A (en) * 2020-11-26 2021-04-06 重庆创绿环境保护有限公司 Harmless treatment and green cyclic resource utilization method for high-salt-content hazardous waste

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US5562834A (en) * 1995-02-14 1996-10-08 The Standard Oil Company Waste concentration and destruction process
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CN106495384A (en) * 2016-11-03 2017-03-15 南京格洛特环境工程股份有限公司 The technique that a kind of utilization organic contamination high-salt wastewater prepares industrial purified salt
CN106914474A (en) * 2017-04-17 2017-07-04 辽宁东大粉体工程技术有限公司 A kind of Processes and apparatus of industrial waste salt decomposition carbonization harmless treatment
CN106966550A (en) * 2017-04-28 2017-07-21 南京环保产业创新中心有限公司 The method of the high nitrate nitrogen desorption liquid processing of high salt
CN107140703A (en) * 2017-05-09 2017-09-08 北京国电富通科技发展有限责任公司 The method that high organic matter carnallite removing organic matter reclaims inorganic salts

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5562834A (en) * 1995-02-14 1996-10-08 The Standard Oil Company Waste concentration and destruction process
DE102013100081A1 (en) * 2013-01-07 2014-07-10 Patrick von Hertzberg, Stefan Bothur und Thomas Müller Rechteverwertung GbR (vertretungsberechtigte Gesellschafter: Patrick von Hertzberg, 14469 Potsdam, Thomas Müller, 01129 Dresden) Process for solvolysis of aqueous organic suspensions and solutions to concentrated, aqueous, black liquor-like and / or salt-like solutions of organic compounds
CN104190697A (en) * 2014-09-19 2014-12-10 山东腾跃化学危险废物研究处理有限公司 Resourceful treatment method for hazardous wastes containing water soluble salts and organic matters
CN106495384A (en) * 2016-11-03 2017-03-15 南京格洛特环境工程股份有限公司 The technique that a kind of utilization organic contamination high-salt wastewater prepares industrial purified salt
CN106914474A (en) * 2017-04-17 2017-07-04 辽宁东大粉体工程技术有限公司 A kind of Processes and apparatus of industrial waste salt decomposition carbonization harmless treatment
CN106966550A (en) * 2017-04-28 2017-07-21 南京环保产业创新中心有限公司 The method of the high nitrate nitrogen desorption liquid processing of high salt
CN107140703A (en) * 2017-05-09 2017-09-08 北京国电富通科技发展有限责任公司 The method that high organic matter carnallite removing organic matter reclaims inorganic salts

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108728140A (en) * 2018-08-13 2018-11-02 湖南叶林环保科技有限公司 Organic dangerous waste low temperature pyrogenation electricity generation system
CN108728140B (en) * 2018-08-13 2024-02-06 湖南叶林环保科技有限公司 Organic hazardous waste low-temperature pyrolysis power generation system
CN112605094A (en) * 2020-11-26 2021-04-06 重庆创绿环境保护有限公司 Harmless treatment and green cyclic resource utilization method for high-salt-content hazardous waste
CN112605094B (en) * 2020-11-26 2023-04-18 重庆创绿环境保护有限公司 Harmless treatment and green cyclic resource utilization method for high-salt-content hazardous waste

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Application publication date: 20180710