CN108258083A - A kind of preparation process of silicon chip laser doping SE - Google Patents

A kind of preparation process of silicon chip laser doping SE Download PDF

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Publication number
CN108258083A
CN108258083A CN201810052422.1A CN201810052422A CN108258083A CN 108258083 A CN108258083 A CN 108258083A CN 201810052422 A CN201810052422 A CN 201810052422A CN 108258083 A CN108258083 A CN 108258083A
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Prior art keywords
laser
silicon chip
range
sheet resistance
ablation
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CN201810052422.1A
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Inventor
刘阳
吴家宏
张凯胜
姚伟忠
孙铁囤
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Changzhou EGing Photovoltaic Technology Co Ltd
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Changzhou EGing Photovoltaic Technology Co Ltd
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Priority to CN201810052422.1A priority Critical patent/CN108258083A/en
Publication of CN108258083A publication Critical patent/CN108258083A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/268Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
    • H01L31/068Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN homojunction type, e.g. bulk silicon PN homojunction solar cells or thin film polycrystalline silicon PN homojunction solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic Table
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
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  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
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Abstract

The present invention relates to a kind of preparation processes of silicon chip laser doping SE, including being cleaned, spreading successively to silicon chip, laser ablation, wash phosphorus, back of the body passivation, front side of silicon wafer plated film, silicon chip back side plated film, laser opening and silk-screen printing, wherein ablation when laser energy attenuation in the range of 30W~50W, the sheet resistance of ablated area is located in the range of 20~50 Ω.The present invention carries out SE laser ablations in diffusion technique using low square resistance, solves diffusion for high square resistance instability problem, also solves the problems such as diffused surface concentration is inadequate, laser ablation phosphorus source is inadequate and laser ablation easily forms dead and wounded layer.

Description

A kind of preparation process of silicon chip laser doping SE
Technical field
The present invention relates to solar cell preparing technical field more particularly to a kind of systems for silicon chip laser doping SE Standby technique.
Background technology
Current technical field of solar batteries, high-efficiency battery technology application are constantly progressive, such as the high-efficiency batteries such as PERC, The transfer efficiency of its battery is constantly being promoted, and in continuous superimposing technique, one of them can be doped using laser, Prepare selective emission electrode (SE) battery.SE batteries are prepared mainly to have there are two feature:1) metal grid lines and silicon chip contact zone Domain is heavily doped region, can form good Ohmic contact, improves fill factor;2) light area is lightly doped district, can To improve the response of shortwave, low surface concentration reduces the compound of few son, so as to improve open-circuit voltage and short circuit current.Swash Light phosphorosilicate glass doping method is the more SE new technologies of recent research, it mainly by the use of phosphorosilicate glass (PSG) as phosphorus source, is used The mode of laser ablation forms heavily doped, and the characteristics of technology is that technological process is simple, it is easy to accomplish.Common process is to prepare at present The phosphorus source of the phosphorosilicate glass on surface by laser ablation in silicon chip is promoted, ultimately forms heavy doping by high square resistance silicon chip again.But At present this technique there are the problem of have:First, laser ablated region easily forms dead and wounded layer, and it is bad to eventually lead to Ohmic contact, leads Send a telegraph performance parameter decline;2nd, because surface needs enough phosphorus sources, so very high surface concentration is needed in silicon face, so Increase the surface concentration after diffusion, but this way easily increases the surface concentration of shallow junction, eventually leads to SE and fails to realize it Function;3rd, higher sheet resistance, sheet resistance its stability for holding that pressure and electric current can be better but higher are more difficult to control.
Invention content
The technical problem to be solved by the present invention is to:In order to overcome deficiency in the prior art, the present invention provides a kind of silicon chip The preparation process of laser doping SE, with solve in prior art diffusion for high square resistance unstability, diffused surface concentration not enough, Laser ablation phosphorus source is inadequate and the problem of laser ablation easily forms dead and wounded layer.
The technical solution adopted by the present invention to solve the technical problems is:A kind of preparation process of silicon chip laser doping SE, Including being cleaned, spreading successively to silicon chip, laser ablation, wash phosphorus, is back of the body passivation, front side of silicon wafer plated film, silicon chip back side plated film, sharp Light trepanning and silk-screen printing, the diffusion technique have following steps:
(1), it cleans:By silicon chip in HF/HNO3It is cleaned in mixed solution, removal surface damage layer, cutting stria and gold Belong to ion;
(2), it spreads:Silicon chip after cleaning is subjected to low pressure DIFFUSION TREATMENT, sheet resistance during diffusion is controlled in 50~80 Ω models In enclosing;
(3), laser ablation:Silicon chip after diffusion is subjected to front laser ablation, during ablation laser energy attenuation 30W~ In the range of 50W, and the sheet resistance of ablated area is made to reach in the range of 20~50 Ω;
(4), phosphorus is washed:It is cleaned and is etched using HF/HNO3 and KOH, remove the PSG on surface and carry out polished backside, And the sheet resistance of its heavily doped region is made to control in 50~90 Ω, the sheet resistance in shallow junction region is in the range of 100~150 Ω;
(5), back of the body passivation:Back of the body passivation is carried out using MAIA or ideal, deposition prepares AlOx layer, is then plated with SiNx layer, the back of the body The overall thickness of AlOx layer and SiNx layer after passivation is controlled between 50nm~300nm;
(6), front plated film:Front plated film is carried out using tubular type PECVD, film thickness monitoring is between 50nm~120nm;
(7), laser grooving:By silicon chip back side carry out laser cutting, wherein laser dig bore dia control 20um~ Between 100um;
(8), silk-screen printing:Silicon chip after cutting is subjected to silk-screen printing sintering back of the body aluminium paste, back electrode and positive electrode.
The beneficial effects of the invention are as follows:The present invention carries out SE laser ablations in diffusion technique using low square resistance, solves Diffusion for high square resistance instability problem, also solve diffused surface concentration not enough, laser ablation phosphorus source not enough and laser Ablation easily forms the problems such as dead and wounded layer.
Specific embodiment
A kind of preparation process of silicon chip laser doping SE has following steps:
(1), it cleans:By silicon chip in HF/HNO3It is cleaned in mixed solution, removal surface damage layer, cutting stria and gold Belong to ion;
(2), it spreads:Silicon chip after cleaning is subjected to low pressure DIFFUSION TREATMENT, sheet resistance during diffusion is controlled in 50~80 Ω models In enclosing;
(3), laser ablation:Silicon chip after diffusion is subjected to front laser ablation, during ablation laser energy attenuation 30W~ In the range of 50W, and the sheet resistance of ablated area is made to reach in the range of 20~50 Ω;
(4), phosphorus is washed:It is cleaned and is etched using HF/HNO3 and KOH, remove the PSG on surface and carry out polished backside, And the sheet resistance of its heavily doped region is made to control in 50~90 Ω, the sheet resistance in shallow junction region is in the range of 100~150 Ω;
(5), back of the body passivation:Back of the body passivation is carried out using MAIA or ideal, deposition prepares AlOx layer, is then plated with SiNx layer, the back of the body The overall thickness of AlOx layer and SiNx layer is controlled after passivation between 50nm~300nm;
(6), front plated film:Using tubular type PECVD carry out front plated film, film thickness monitoring between 50nm~120nm, To reduce head-on reflection, increase carrier lifetime, improve electric current;
(7), laser grooving:By silicon chip back side carry out laser cutting, wherein laser dig bore dia control 20um~ Between 100um;Since laser is a branch of hot spot, the quality that detects laser is illustrated with spot size, and cutting width is exactly The diameter of laser facula, length are accordingly converted with die size, and therefore, cutting is defined using bore dia;
(8), silk-screen printing:Silicon chip after cutting is subjected to silk-screen printing sintering back of the body aluminium paste, back electrode and positive electrode.
The present invention carries out SE laser ablations in diffusion technique using low square resistance, and it is unstable for high square resistance to solve diffusion Sex chromosome mosaicism, also solve diffused surface concentration not enough, laser ablation phosphorus source is inadequate and laser ablation easily forms dead and wounded layer etc. and asks Topic.
Using above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property range is not limited to the content on specification, it is necessary to determine its technical scope according to right.

Claims (1)

1. a kind of preparation process of silicon chip laser doping SE, it is characterized in that:With following steps:
(1), it cleans:By silicon chip in HF/HNO3Cleaned in mixed solution, removal surface damage layer, cutting stria and metal from Son;
(2), it spreads:Silicon chip after cleaning is subjected to low pressure DIFFUSION TREATMENT, sheet resistance during diffusion is controlled in the range of 50~80 Ω;
(3), laser ablation:Silicon chip after diffusion is subjected to front laser ablation, laser energy attenuation is in 30W~50W during ablation In the range of, and the sheet resistance of ablated area is made to reach in the range of 20~50 Ω;
(4), phosphorus is washed:It is cleaned and is etched using HF/HNO3 and KOH, remove the PSG on surface and carry out polished backside, and The sheet resistance of its heavily doped region is made to control in 50~90 Ω, the sheet resistance in shallow junction region is in the range of 100~150 Ω;
(5), back of the body passivation:Back of the body passivation is carried out using MAIA or ideal, deposition prepares AlOx layer, is then plated with SiNx layer, back of the body passivation AlOx layer and the overall thickness of SiNx layer afterwards is controlled between 50nm~300nm;
(6), front plated film:Front plated film is carried out using tubular type PECVD, film thickness monitoring is between 50nm~120nm;
(7), laser grooving:Silicon chip back side is subjected to laser cutting, the bore dia that wherein laser is dug is controlled in 20um~100um Between;
(8), silk-screen printing:Silicon chip after cutting is subjected to silk-screen printing sintering back of the body aluminium paste, back electrode and positive electrode.
CN201810052422.1A 2018-01-19 2018-01-19 A kind of preparation process of silicon chip laser doping SE Pending CN108258083A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109873042A (en) * 2019-03-28 2019-06-11 深圳市拉普拉斯能源技术有限公司 One kind being suitable for selection emitter solar battery diffusion technique

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101997060A (en) * 2010-10-25 2011-03-30 山东力诺太阳能电力股份有限公司 Selective diffusion technology for crystalline silicon solar cell
CN103151428A (en) * 2013-03-26 2013-06-12 浙江晶科能源有限公司 Method for realizing selective emitter of crystalline silicon solar cell

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101997060A (en) * 2010-10-25 2011-03-30 山东力诺太阳能电力股份有限公司 Selective diffusion technology for crystalline silicon solar cell
CN103151428A (en) * 2013-03-26 2013-06-12 浙江晶科能源有限公司 Method for realizing selective emitter of crystalline silicon solar cell

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109873042A (en) * 2019-03-28 2019-06-11 深圳市拉普拉斯能源技术有限公司 One kind being suitable for selection emitter solar battery diffusion technique

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