CN108252102A - The silicon rubber leather and its coating process of a kind of UV resistant and hydrolysis - Google Patents
The silicon rubber leather and its coating process of a kind of UV resistant and hydrolysis Download PDFInfo
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- CN108252102A CN108252102A CN201810021899.3A CN201810021899A CN108252102A CN 108252102 A CN108252102 A CN 108252102A CN 201810021899 A CN201810021899 A CN 201810021899A CN 108252102 A CN108252102 A CN 108252102A
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- hydrolysis
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Abstract
The invention discloses a kind of UV resistants and the silicon rubber leather of hydrolysis, it is figured by mass parts, constitutive material includes 0.01 0.05 parts of 100 200 parts of vinylsiloxane rubber base rubber, 20 30 parts of vinyl silicone oil, 10 20 parts of dimethicone, 10 30 parts of containing hydrogen silicone oil, 0.1 0.5 parts of thickener, 0.1 0.3 parts of platinum catalyst, 5 20 parts of color pigment and inhibitor.Present invention process is simple, production efficiency is high, and production cost is low, and obtained silicon rubber leather has both UV resistant and anti-hydrolytic performance simultaneously, change colour, and there is good anti-hydrolytic performance in moist or water so as to which use for a long time will not turn to be yellow because of action of ultraviolet radiation.
Description
Technical field
The present invention relates to organosilicon and leather manufacture technical fields, and in particular to the silicon rubber of a kind of UV resistant and hydrolysis
Rubber is removed from office and the coating process of the silicon rubber leather of the UV resistant and hydrolysis.
Background technology
For conventional synthesis leather mainly based on PU synthetic leather, PU synthetic leather is with isocyanates, macromolecular polyol and small point
Sub- polyol chain extender is made for primary raw material.
Isocyanates mainly selects TDI or MDI as raw material, since its phenyl ring is directly ined succession isocyanide ester group, phenyl ring
On big PI keys formed and be conjugated with neighbouring-NCO, in light, heat, oxygen, particularly under the action of ultraviolet light, ammonia ester bond can be caused
It decomposes, generates arylamine, after the oxidized rearrangement of benzene nucleus on arylamine, the chromophoric groups such as generation quinoid structure, so as to produce
The PU leather products come are easy to turn to be yellow, and ultraviolet-resistant capacity is poor.
Meanwhile the main chain that isocyano and hydroxy combining are formed in PU synthetic leather have it is highly polar, easily in moist or water
Middle hydrolysis so that PU synthetic leather anti-hydrolytic performances are poor.
Invention content
It is an object of the present invention to the silicon rubber leather of a kind of UV resistant and hydrolysis is provided regarding to the issue above,
Have both UV resistant and anti-hydrolytic performance simultaneously.
The present invention also aims to, the coating process of the silicon rubber leather of UV resistant and hydrolysis a kind of is provided,
Its preparation process is simple, production efficiency is high, production cost is low.
Present invention technical solution used for the above purpose is：
The silicon rubber leather of a kind of UV resistant and hydrolysis, is figured by mass parts, and constitutive material includes vinyl silicon
100-200 parts of rubber-based adhesive, 20-30 parts of vinyl silicone oil, 10-20 parts of dimethicone, 10-30 parts of containing hydrogen silicone oil, thickener
0.01-0.05 parts of 0.1-0.5 parts, 0.1-0.3 parts of platinum catalyst, 5-20 parts of color pigment and inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-50A, contents of ethylene 0.2-1%.
The vinyl silicone oil viscosity is 500-5000cs；
The dimethyl-silicon oil viscosity is 100-1000cs.
The containing hydrogen silicone oil be silicon oil of low hydrogen content, hydrogeneous ranging from 0.18-0.36%.
The inhibitor is methyl butynol, the one or more of ethynylcyclohexanol, more vinyl polysiloxanes
Mixture.
The platinum catalyst is 5000ppm, is diluted by ethyl alcohol, isopropanol, dimethicone or vinyl silicone oil.
The thickener is polyether-modified containing hydrogen silicone oil, polyacrylate modified containing hydrogen silicone oil, polyurethane-modified Silicon Containing Hydrogen
One kind in oil.
A kind of coating process of the silicon rubber leather of aforementioned UV resistant and hydrolysis, includes the following steps：
Step 1: the preparation of the silicon rubber of UV resistant and hydrolysis；
Step 2: the coating of the silicon rubber leather of UV resistant and hydrolysis.
In step 1, by 100-200 parts of vinylsiloxane rubber base rubber, 20-30 parts of vinyl silicone oil, dimethicone 10-
20 parts, 10-30 parts of containing hydrogen silicone oil, 0.1-0.5 parts of thickener, 0.1-0.3 parts of platinum catalyst, 5-20 parts of color pigment and inhibition
0.01-0.05 parts of agent is put into planet dispersator, leads to cooling water, opens vacuum equipment, dispersion stirring 10 minutes.
In step 2, by the Silicone Rubber Coated of UV resistant and hydrolysis in release paper or leather paper, and with base material cloth
Material fitting, then passes to continuous tunnel furnace, vulcanizes 5-10 minutes at a temperature of 100-140 DEG C, and release paper or leather paper are removed,
Obtain the silicon rubber leather with UV resistant and anti-hydrolytic performance.
In the present invention, the main chain of organosilicon is Si-O-Si, and no double bond exists, therefore is not easy to be divided by ultraviolet light and ozone
Solution.Meanwhile the chain length of Si-O keys is about 1.5 times of the key length of C-C keys, chain length is longer to make organosilicon have than other
The better thermal stability of high molecular material and resistance to irradiation and weather-proof ability, the service life of organosilicon in a natural environment are reachable
Decades.Since the force ratio hydrocarbon between silicone molecules wants much weaker, than the nytron of same molecular weight
Object viscosity is low, surface tension is weak, surface energy is small, and this low surface tension and low-surface-energy cause organosilicon product with fabulous
Hydrophobic and anti-hydrolytic performance.
Beneficial effects of the present invention are：Present invention process is simple, and production efficiency is high, and production cost is low, obtained silicon rubber
Rubber leather has both UV resistant and anti-hydrolytic performance simultaneously, changes colour so as to which use for a long time will not turn to be yellow because of action of ultraviolet radiation,
And there is good anti-hydrolytic performance in moist or water.
Specific embodiment
The present invention provides a kind of UV resistants and the silicon rubber leather of hydrolysis, are figured by mass parts, constitutive material
Including 100-200 parts of vinylsiloxane rubber base rubber, 20-30 parts of vinyl silicone oil, 10-20 parts of dimethicone, containing hydrogen silicone oil 10-
0.01-0.05 parts of 30 parts, 0.1-0.5 parts of thickener, 0.1-0.3 parts of platinum catalyst, 5-20 parts of color pigment and inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-50A, contents of ethylene 0.2-1%.
The vinyl silicone oil viscosity is 500-5000cs；
The dimethyl-silicon oil viscosity is 100-1000cs.
The containing hydrogen silicone oil be silicon oil of low hydrogen content, hydrogeneous ranging from 0.18-0.36%.
The inhibitor is methyl butynol, the one or more of ethynylcyclohexanol, more vinyl polysiloxanes
Mixture.
The platinum catalyst is 5000ppm, is diluted by ethyl alcohol, isopropanol, dimethicone or vinyl silicone oil.
The thickener is polyether-modified containing hydrogen silicone oil, polyacrylate modified containing hydrogen silicone oil, polyurethane-modified Silicon Containing Hydrogen
One kind in oil.
A kind of coating process of the silicon rubber leather of aforementioned UV resistant and hydrolysis, includes the following steps：
Step 1: the preparation of the silicon rubber of UV resistant and hydrolysis；
Step 2: the coating of the silicon rubber leather of UV resistant and hydrolysis.
In step 1, by 100-200 parts of vinylsiloxane rubber base rubber, 20-30 parts of vinyl silicone oil, dimethicone 10-
20 parts, 10-30 parts of containing hydrogen silicone oil, 0.1-0.5 parts of thickener, 0.1-0.3 parts of platinum catalyst, 5-20 parts of color pigment and inhibition
0.01-0.05 parts of agent is put into planet dispersator, leads to cooling water, opens vacuum equipment, dispersion stirring 10 minutes.
In step 2, by the Silicone Rubber Coated of UV resistant and hydrolysis in release paper or leather paper, and with base material cloth
Material fitting, then passes to continuous tunnel furnace, vulcanizes 5-10 minutes at a temperature of 100-140 DEG C, and release paper or leather paper are removed,
Obtain the silicon rubber leather with UV resistant and anti-hydrolytic performance.
In the present invention, the main chain of organosilicon is Si-O-Si, and no double bond exists, therefore is not easy to be divided by ultraviolet light and ozone
Solution.Meanwhile the chain length of Si-O keys is about 1.5 times of the key length of C-C keys, chain length is longer to make organosilicon have than other
The better thermal stability of high molecular material and resistance to irradiation and weather-proof ability, the service life of organosilicon in a natural environment are reachable
Decades.Since the force ratio hydrocarbon between silicone molecules wants much weaker, than the nytron of same molecular weight
Object viscosity is low, surface tension is weak, surface energy is small, and this low surface tension and low-surface-energy cause organosilicon product with fabulous
Hydrophobic and anti-hydrolytic performance.
Present invention process is simple, and production efficiency is high, and production cost is low, and obtained silicon rubber leather has both resistance to ultraviolet simultaneously
Line and anti-hydrolytic performance change colour, and have in moist or water so as to which use for a long time will not turn to be yellow because of action of ultraviolet radiation
Good anti-hydrolytic performance.
The present invention is described in detail below.
Embodiment 1, present embodiment discloses a kind of UV resistants and the silicon rubber leather of hydrolysis, are figured by mass parts,
Its constitutive material includes 100 parts of vinylsiloxane rubber base rubber, 20 parts of vinyl silicone oil, 10 parts of dimethicone, containing hydrogen silicone oil 10
Part, 0.1 part of thickener, 0.1 part of platinum catalyst, 5 parts of color pigment and 0.01 part of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-50A, contents of ethylene 0.2-1%.
The vinyl silicone oil viscosity is 500-5000cs；
The dimethyl-silicon oil viscosity is 100-1000cs.
The containing hydrogen silicone oil be silicon oil of low hydrogen content, hydrogeneous ranging from 0.18-0.36%.
The inhibitor is methyl butynol, the one or more of ethynylcyclohexanol, more vinyl polysiloxanes
Mixture.
The platinum catalyst is 5000ppm, is diluted by ethyl alcohol, isopropanol, dimethicone or vinyl silicone oil.
The thickener is polyether-modified containing hydrogen silicone oil, polyacrylate modified containing hydrogen silicone oil, polyurethane-modified Silicon Containing Hydrogen
One kind in oil.
A kind of coating process of the silicon rubber leather of aforementioned UV resistant and hydrolysis, includes the following steps：
Step 1: the preparation of the silicon rubber of UV resistant and hydrolysis；
Step 2: the coating of the silicon rubber leather of UV resistant and hydrolysis.
In step 1, by 100 parts of vinylsiloxane rubber base rubber, 20 parts of vinyl silicone oil, 10 parts of dimethicone, Silicon Containing Hydrogen
0.01 part of 10 parts of oil, 0.1 part of thickener, 0.1 part of platinum catalyst, 5 parts of color pigment and inhibitor are put into planet dispersion and are stirred
It mixes in machine, leads to cooling water, open vacuum equipment, dispersion stirring 10 minutes.
In step 2, by the Silicone Rubber Coated of UV resistant and hydrolysis in release paper or leather paper, and with base material cloth
Material fitting, then passes to continuous tunnel furnace, vulcanizes 5 minutes at a temperature of 100 DEG C, and release paper or leather paper are removed, had
There is the silicon rubber leather of UV resistant and anti-hydrolytic performance.
In the present invention, the main chain of organosilicon is Si-O-Si, and no double bond exists, therefore is not easy to be divided by ultraviolet light and ozone
Solution.Meanwhile the chain length of Si-O keys is about 1.5 times of the key length of C-C keys, chain length is longer to make organosilicon have than other
The better thermal stability of high molecular material and resistance to irradiation and weather-proof ability, the service life of organosilicon in a natural environment are reachable
Decades.Since the force ratio hydrocarbon between silicone molecules wants much weaker, than the nytron of same molecular weight
Object viscosity is low, surface tension is weak, surface energy is small, and this low surface tension and low-surface-energy cause organosilicon product with fabulous
Hydrophobic and anti-hydrolytic performance.
Present invention process is simple, and production efficiency is high, and production cost is low, and obtained silicon rubber leather has both resistance to ultraviolet simultaneously
Line and anti-hydrolytic performance change colour, and have in moist or water so as to which use for a long time will not turn to be yellow because of action of ultraviolet radiation
Good anti-hydrolytic performance.
Embodiment 2, present embodiment discloses a kind of UV resistants and the silicon rubber leather of hydrolysis, are figured by mass parts,
Its constitutive material includes 200 parts of vinylsiloxane rubber base rubber, 30 parts of vinyl silicone oil, 20 parts of dimethicone, containing hydrogen silicone oil 30
Part, 0.5 part of thickener, 0.3 part of platinum catalyst, 20 parts of color pigment and 0.05 part of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-50A, contents of ethylene 0.2-1%.
The vinyl silicone oil viscosity is 500-5000cs；
The dimethyl-silicon oil viscosity is 100-1000cs.
The containing hydrogen silicone oil be silicon oil of low hydrogen content, hydrogeneous ranging from 0.18-0.36%.
The inhibitor is methyl butynol, the one or more of ethynylcyclohexanol, more vinyl polysiloxanes
Mixture.
The platinum catalyst is 5000ppm, is diluted by ethyl alcohol, isopropanol, dimethicone or vinyl silicone oil.
The thickener is polyether-modified containing hydrogen silicone oil, polyacrylate modified containing hydrogen silicone oil, polyurethane-modified Silicon Containing Hydrogen
One kind in oil.
A kind of coating process of the silicon rubber leather of aforementioned UV resistant and hydrolysis, includes the following steps：
Step 1: the preparation of the silicon rubber of UV resistant and hydrolysis；
Step 2: the coating of the silicon rubber leather of UV resistant and hydrolysis.
In step 1, by 200 parts of vinylsiloxane rubber base rubber, 30 parts of vinyl silicone oil, 20 parts of dimethicone, Silicon Containing Hydrogen
0.05 part of 30 parts of oil, 0.5 part of thickener, 0.3 part of platinum catalyst, 20 parts of color pigment and inhibitor are put into planet dispersion and are stirred
It mixes in machine, leads to cooling water, open vacuum equipment, dispersion stirring 10 minutes.
In step 2, by the Silicone Rubber Coated of UV resistant and hydrolysis in release paper or leather paper, and with base material cloth
Material fitting, then passes to continuous tunnel furnace, vulcanizes 10 minutes at a temperature of 140 DEG C, and release paper or leather paper are removed, had
There is the silicon rubber leather of UV resistant and anti-hydrolytic performance.
In the present invention, the main chain of organosilicon is Si-O-Si, and no double bond exists, therefore is not easy to be divided by ultraviolet light and ozone
Solution.Meanwhile the chain length of Si-O keys is about 1.5 times of the key length of C-C keys, chain length is longer to make organosilicon have than other
The better thermal stability of high molecular material and resistance to irradiation and weather-proof ability, the service life of organosilicon in a natural environment are reachable
Decades.Since the force ratio hydrocarbon between silicone molecules wants much weaker, than the nytron of same molecular weight
Object viscosity is low, surface tension is weak, surface energy is small, and this low surface tension and low-surface-energy cause organosilicon product with fabulous
Hydrophobic and anti-hydrolytic performance.
Present invention process is simple, and production efficiency is high, and production cost is low, and obtained silicon rubber leather has both resistance to ultraviolet simultaneously
Line and anti-hydrolytic performance change colour, and have in moist or water so as to which use for a long time will not turn to be yellow because of action of ultraviolet radiation
Good anti-hydrolytic performance.
Embodiment 3, present embodiment discloses a kind of UV resistants and the silicon rubber leather of hydrolysis, are figured by mass parts,
Its constitutive material includes 150 parts of vinylsiloxane rubber base rubber, 25 parts of vinyl silicone oil, 15 parts of dimethicone, containing hydrogen silicone oil 20
Part, 0.3 part of thickener, 0.2 part of platinum catalyst, 12.5 parts of color pigment and 0.03 part of inhibitor.
The vinylsiloxane rubber base rubber hardness range 30-50A, contents of ethylene 0.2-1%.
The vinyl silicone oil viscosity is 500-5000cs；
The dimethyl-silicon oil viscosity is 100-1000cs.
The containing hydrogen silicone oil be silicon oil of low hydrogen content, hydrogeneous ranging from 0.18-0.36%.
The inhibitor is methyl butynol, the one or more of ethynylcyclohexanol, more vinyl polysiloxanes
Mixture.
The platinum catalyst is 5000ppm, is diluted by ethyl alcohol, isopropanol, dimethicone or vinyl silicone oil.
The thickener is polyether-modified containing hydrogen silicone oil, polyacrylate modified containing hydrogen silicone oil, polyurethane-modified Silicon Containing Hydrogen
One kind in oil.
A kind of coating process of the silicon rubber leather of aforementioned UV resistant and hydrolysis, includes the following steps：
Step 1: the preparation of the silicon rubber of UV resistant and hydrolysis；
Step 2: the coating of the silicon rubber leather of UV resistant and hydrolysis.
In step 1, by 150 parts of vinylsiloxane rubber base rubber, 25 parts of vinyl silicone oil, 15 parts of dimethicone, Silicon Containing Hydrogen
0.03 part of 20 parts of oil, 0.3 part of thickener, 0.2 part of platinum catalyst, 12.5 parts of color pigment and inhibitor put into planet dispersion
In blender, lead to cooling water, open vacuum equipment, dispersion stirring 10 minutes.
In step 2, by the Silicone Rubber Coated of UV resistant and hydrolysis in release paper or leather paper, and with base material cloth
Material fitting, then passes to continuous tunnel furnace, vulcanizes 7.5 minutes at a temperature of 120 DEG C, and release paper or leather paper are removed, obtained
Silicon rubber leather with UV resistant and anti-hydrolytic performance.
In the present invention, the main chain of organosilicon is Si-O-Si, and no double bond exists, therefore is not easy to be divided by ultraviolet light and ozone
Solution.Meanwhile the chain length of Si-O keys is about 1.5 times of the key length of C-C keys, chain length is longer to make organosilicon have than other
The better thermal stability of high molecular material and resistance to irradiation and weather-proof ability, the service life of organosilicon in a natural environment are reachable
Decades.Since the force ratio hydrocarbon between silicone molecules wants much weaker, than the nytron of same molecular weight
Object viscosity is low, surface tension is weak, surface energy is small, and this low surface tension and low-surface-energy cause organosilicon product with fabulous
Hydrophobic and anti-hydrolytic performance.
Present invention process is simple, and production efficiency is high, and production cost is low, and obtained silicon rubber leather has both resistance to ultraviolet simultaneously
Line and anti-hydrolytic performance change colour, and have in moist or water so as to which use for a long time will not turn to be yellow because of action of ultraviolet radiation
Good anti-hydrolytic performance.
The above described is only a preferred embodiment of the present invention, not make limitation in any form to the present invention.Appoint
What those skilled in the art, without departing from the scope of the technical proposal of the invention, all using the skill of the disclosure above
Art means and technology contents technical solution of the present invention is made many possible changes and modifications or be revised as equivalent variations etc.
Imitate embodiment.Therefore every content without departing from technical solution of the present invention, what shape, construction and principle according to the present invention were made etc.
Effect variation, should all be covered by protection scope of the present invention.
Claims (10)
1. the silicon rubber leather of a kind of UV resistant and hydrolysis, which is characterized in that figured by mass parts, constitutive material includes
100-200 parts of vinylsiloxane rubber base rubber, 20-30 parts of vinyl silicone oil, 10-20 parts of dimethicone, containing hydrogen silicone oil 10-30
Part, 0.1-0.5 parts of thickener, 0.1-0.3 parts of platinum catalyst, 5-20 parts of color pigment and 0.01-0.05 parts of inhibitor.
2. the silicon rubber leather of UV resistant according to claim 1 and hydrolysis, which is characterized in that the vinyl silicon
Rubber-based adhesive hardness range 30-50A, contents of ethylene 0.2-1%.
3. the silicon rubber leather of UV resistant according to claim 1 and hydrolysis, which is characterized in that the vinyl silicon
Oil viscosity is 500-5000cs；
The dimethyl-silicon oil viscosity is 100-1000cs.
4. the silicon rubber leather of UV resistant according to claim 1 and hydrolysis, which is characterized in that the containing hydrogen silicone oil
For silicon oil of low hydrogen content, hydrogeneous ranging from 0.18-0.36%.
5. the silicon rubber leather of UV resistant according to claim 1 and hydrolysis, which is characterized in that the inhibitor is
Methyl butynol, ethynylcyclohexanol, more vinyl polysiloxanes one or more kinds of mixtures.
6. the silicon rubber leather of UV resistant according to claim 1 and hydrolysis, which is characterized in that the platinum catalysis
Agent is 5000ppm, is diluted by ethyl alcohol, isopropanol, dimethicone or vinyl silicone oil.
7. the silicon rubber leather of UV resistant according to claim 1 and hydrolysis, which is characterized in that the thickener is
One kind in polyether-modified containing hydrogen silicone oil, polyacrylate modified containing hydrogen silicone oil, polyurethane-modified containing hydrogen silicone oil.
8. the coating process of the silicon rubber leather of UV resistant described in a kind of claim 1 and hydrolysis, which is characterized in that it is wrapped
Include following steps：
Step 1: the preparation of the silicon rubber of UV resistant and hydrolysis；
Step 2: the coating of the silicon rubber leather of UV resistant and hydrolysis.
9. the coating process of the silicon rubber leather of UV resistant according to claim 8 and hydrolysis, which is characterized in that step
In rapid one, by 100-200 parts of vinylsiloxane rubber base rubber, 20-30 parts of vinyl silicone oil, 10-20 parts of dimethicone, Silicon Containing Hydrogen
10-30 parts oily, 0.1-0.5 parts of thickener, 0.1-0.3 parts of platinum catalyst, 5-20 parts of color pigment and inhibitor 0.01-0.05
Part is put into planet dispersator, leads to cooling water, opens vacuum equipment, dispersion stirring 10 minutes.
10. the coating process of the silicon rubber leather of UV resistant according to claim 9 and hydrolysis, which is characterized in that
In step 2, by the Silicone Rubber Coated of UV resistant and hydrolysis in release paper or leather paper, and with base material cloth pasting, so
After be sent to continuous tunnel furnace, vulcanize 5-10 minutes at a temperature of 100-140 DEG C, release paper or leather paper removed, had
The silicon rubber leather of UV resistant and anti-hydrolytic performance.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108824000A (en) * | 2018-08-14 | 2018-11-16 | 广东天跃新材料股份有限公司 | Using on the medical instrument silicon rubber synthetic leather and its manufacturing technology |
| CN111267436A (en) * | 2020-01-17 | 2020-06-12 | 江西赛欧特科新材料有限公司 | Organosilicon sun-shading material and preparation method thereof |
| CN113512890A (en) * | 2021-07-26 | 2021-10-19 | 广东天跃新材料股份有限公司 | Silicone rubber leather material for outdoor furniture and preparation method thereof |
| CN113584898A (en) * | 2021-08-06 | 2021-11-02 | 广东省硅革科技有限公司 | Silica gel leather for automobile seat and preparation method thereof |
| CN113698769A (en) * | 2021-07-26 | 2021-11-26 | 广东天跃新材料股份有限公司 | Silicone rubber leather material for medical industry and preparation method thereof |
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| CN103821008A (en) * | 2014-03-12 | 2014-05-28 | 李江群 | Organosilicon synthetic leather adopting three-layer structure and preparation method thereof |
| CN107129576A (en) * | 2017-01-13 | 2017-09-05 | 东莞市柏力有机硅科技有限公司 | A kind of high permeability silicones and its production and use |
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| CN101280521A (en) * | 2008-05-16 | 2008-10-08 | 卢儒 | Liquid silastic for artificial leather |
| CN103687989A (en) * | 2012-07-19 | 2014-03-26 | 大宇国际株式会社 | Synthetic leather production method using different liquid silicone rubber coating solutions |
| CN103821008A (en) * | 2014-03-12 | 2014-05-28 | 李江群 | Organosilicon synthetic leather adopting three-layer structure and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108824000A (en) * | 2018-08-14 | 2018-11-16 | 广东天跃新材料股份有限公司 | Using on the medical instrument silicon rubber synthetic leather and its manufacturing technology |
| CN111267436A (en) * | 2020-01-17 | 2020-06-12 | 江西赛欧特科新材料有限公司 | Organosilicon sun-shading material and preparation method thereof |
| CN111267436B (en) * | 2020-01-17 | 2022-10-11 | 江西赛欧特科新材料有限公司 | Organosilicon sun-shading material and preparation method thereof |
| CN113512890A (en) * | 2021-07-26 | 2021-10-19 | 广东天跃新材料股份有限公司 | Silicone rubber leather material for outdoor furniture and preparation method thereof |
| CN113698769A (en) * | 2021-07-26 | 2021-11-26 | 广东天跃新材料股份有限公司 | Silicone rubber leather material for medical industry and preparation method thereof |
| CN113584898A (en) * | 2021-08-06 | 2021-11-02 | 广东省硅革科技有限公司 | Silica gel leather for automobile seat and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN108252102B (en) | 2019-04-30 |
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