CN101113570A - Organosilicon flexible smooth agent and process for preparing the same - Google Patents
Organosilicon flexible smooth agent and process for preparing the same Download PDFInfo
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- CN101113570A CN101113570A CNA2007100292531A CN200710029253A CN101113570A CN 101113570 A CN101113570 A CN 101113570A CN A2007100292531 A CNA2007100292531 A CN A2007100292531A CN 200710029253 A CN200710029253 A CN 200710029253A CN 101113570 A CN101113570 A CN 101113570A
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Abstract
The invention relates to the technical field of a soft stiffening agent, in particular to an organic silicone soft stiffening agent and a preparation technology thereof, which aims at providing a novel material formula and a novel double emulsification technology to change the defects of the silicone stiffening agent on the present market of the background technologies such as easy phase separation, bad emulsion steadiness, emulsion breaking easily, high demand to environment, floating oil easily in use, destructive damage to textile, etc. The obtained products have the advantages of no phase separation after long-term storage, steady property, easy operation, which can fully improve serviceability and added value of textile.
Description
Technical field:
The present invention relates to a kind of flexible smooth agent technical field, refer in particular to a kind of organosilicon flexible smooth agent and preparation technology thereof.
Background technology:
In order to make fabric have softness, lubricious or plentiful feel, except adopting mechanical finishing, also can in the finishing process of textile production, add flexible smooth agent and put in order.Early stage silicone softening agent is the mechanical impurity of dimethicone and containing hydrogen silicone oil, and this organosilicon does not contain active gene, combine with fabric firm inadequately, come off easily and feel poor.Smooth agent on the market belongs to organosilicon flexible smooth agent more at present, and this type of smooth agent effect is general, but has easy layering, and stability of emulsion is poor, and breakdown of emulsion requires height to environment for use easily, and easy floating oil can damage textiles in the use.
Summary of the invention:
The objective of the invention is to, provide a kind of organosilicon flexible smooth agent and preparation technology thereof at the deficiencies in the prior art.
For achieving the above object, the present invention takes following technical scheme:
Each component of described invention comprises following composition by weight percentage:
Amino silicon oil emulsion A 15%～25%,
Amino silicon oil emulsion B 20%～30%,
Epoxy radicals silicone oil emulsion 6%～15%,
107 latex solutions 25%～45%,
Fatty acid triethanolamine ester 3%～8%,
Fatty alcohol-polyoxyethylene ether 2%～6%,
α-Qiang Jibingsuan 0.5%～2%,
Deionized water 15%～25%.
Described amino silicon oil emulsion A is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.6～0.8, viscosity 1500～3000mP.s.
Described amino silicon oil emulsion B is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.2～0.4, viscosity 15000～20000mP.s.
Described epoxy radicals silicone oil emulsion is the emulsion that contains epoxy radicals silicone oil 30%, and epoxide number is 0.3～0.6, viscosity 1500～3000mP.s.
Described 107 latex solutions are the emulsion that contains 107 latex solutions 30%.
The technology of preparation organosilicon flexible smooth agent is: at first, deionized water, fatty alcohol-polyoxyethylene ether, fatty acid triethanolamine ester are dropped in the reactor successively, and add thermal agitation and make its dissolving; Second step when the temperature in the reactor is raised to 40 ℃, added amino silicon oil emulsion A, amino silicon oil emulsion B, epoxy radicals silicone oil emulsion, 107 latex solutions, and heating is simultaneously stirred, and temperature remains on 40～50 ℃, and mixing speed is 60～100r/min; In the 3rd step, when temperature was raised to 50～55 ℃, mixing speed was 90～130r/min; In the 4th step, persistently overheating 1 hour, insulation was 30 minutes after temperature rose to 55～70 ℃, and mixing speed is after the above-mentioned reaction of 150～190r/min is finished, and with below the cooling water rapid cooling to 40 ℃, mixing speed reduces with temperature; At last, temperature remains on 36～40 ℃, and mixing speed remains on reacted under 20～40r/min condition 30～60 minutes, filters discharging.
The invention has the beneficial effects as follows, this organosilicon flexible smooth agent long-term storage is not stratified, stable performance, use simple, be difficult for breakdown of emulsion,, set up new emulsion equilibrium system stable performance by this technology to the textiles excellent affinity, use simple to operately, improved the taking and the added value of textiles effectively comprehensively.
The specific embodiment:
Embodiment 1, forms each component of the present invention by weight percentage, comprises following composition:
Amido silicon oil 30% latex A 16%,
Amido silicon oil 30% emulsion B 20%,
Epoxy radicals silicone oil 30% emulsion 8%,
107 glue, 30% emulsion 32%,
Fatty acid triethanolamine ester 3%,
Fatty alcohol-polyoxyethylene ether 2%,
α-Qiang Jibingsuan 1%,
Deionized water 15%.
Described amino silicon oil emulsion A is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.6～0.8, viscosity 1500～3000mP.s.
Described amino silicon oil emulsion B is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.2～0.4, viscosity 15000～20000mP.s.
Described epoxy radicals silicone oil emulsion is the emulsion that contains epoxy radicals silicone oil 30%, and epoxide number is 0.3～0.6, viscosity 1500～3000mP.s.
Described 107 latex solutions are the emulsion that contains 107 latex solutions 30%.
Preparation technology of the present invention is: at first, deionized water, fatty alcohol-polyoxyethylene ether, fatty acid triethanolamine ester are dropped in the reactor successively, and add thermal agitation and make its dissolving; Second step when the temperature in the reactor is raised to 40 ℃, added amino silicon oil emulsion A, amino silicon oil emulsion B, epoxy radicals silicone oil emulsion, 107 latex solutions, and heating is simultaneously stirred, and temperature remains on 40～50 ℃, and mixing speed is 60～100r/min; In the 3rd step, when temperature was raised to 50～55 ℃, mixing speed was 90～130r/min; In the 4th step, persistently overheating 1 hour, insulation was 30 minutes after temperature rose to 55～70 ℃, and mixing speed is 150～190r/min; After above-mentioned reaction was finished, with below the cooling water rapid cooling to 40 ℃, mixing speed reduced with temperature; At last, temperature remains on 36～40 ℃, and mixing speed remains on reacted under 20～40r/min condition 30～60 minutes, filters discharging.
Embodiment 2, and the preparation technology of present embodiment is identical with embodiment 1, no longer repeat here, and different is the percentage difference of forming material of the present invention, specific as follows:
Amido silicon oil 30% latex A 18%,
Amido silicon oil 30% emulsion B 22%,
Epoxy radicals silicone oil 30% emulsion 7%,
107 glue, 30% emulsion 30%,
Fatty acid triethanolamine ester 5%,
Fatty alcohol-polyoxyethylene ether 2%,
α-Qiang Jibingsuan 1%,
Deionized water 15%.
Embodiment 3, and the preparation technology of present embodiment is identical with embodiment 1, no longer repeat here, and different is the percentage difference of forming material of the present invention, specific as follows:
Amido silicon oil 30% latex A 22%,
Amido silicon oil 30% emulsion B 20%,
Epoxy radicals silicone oil 30% emulsion 10%,
107 glue, 30% emulsion 25%,
Fatty acid triethanolamine ester 4%,
Fatty alcohol-polyoxyethylene ether 3%,
α-Qiang Jibingsuan 1%,
Deionized water 15%.
Certainly, the embodiment of the above is a preferred embodiments of the present invention, is not to limit practical range of the present invention, so all equivalences of doing according to the described prescription of the present patent application claim, technology change or modify, and are included in the present patent application claim.
Claims (6)
1. organosilicon flexible smooth agent, it is characterized in that: each component of described invention comprises following composition by weight percentage:
Amino silicon oil emulsion A 15%～25%,
Amino silicon oil emulsion B 20%～30%,
Epoxy radicals silicone oil emulsion 6%～15%,
107 latex solutions 25%～45%,
Fatty acid triethanolamine ester 3%～8%,
Fatty alcohol-polyoxyethylene ether 2%～6%,
α-Qiang Jibingsuan 0.5%～2%,
Deionized water 15%～25%.
2. a kind of organosilicon flexible smooth agent according to claim 1 is characterized in that: described amino silicon oil emulsion A is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.6～0.8, viscosity 1500～3000mP.s.
3. a kind of organosilicon flexible smooth agent according to claim 1 is characterized in that: described amino silicon oil emulsion B is the emulsion that contains amido silicon oil 30%, and the ammonia value is 0.2～0.4, viscosity 15000～20000mP.s.
4. a kind of organosilicon flexible smooth agent according to claim 1 is characterized in that: described epoxy radicals silicone oil emulsion is the emulsion that contains epoxy radicals silicone oil 30%, and epoxide number is 0.3～0.6, viscosity 1500～3000mP.s.
5. a kind of organosilicon flexible smooth agent according to claim 1 is characterized in that: described 107 latex solutions are the emulsion that contains 107 latex solutions 30%.
6. the preparation technology of an organosilicon flexible smooth agent is characterized in that: at first, deionized water, fatty alcohol-polyoxyethylene ether, fatty acid triethanolamine ester are dropped in the reactor successively, and add thermal agitation and make its dissolving; Second step when the temperature in the reactor is raised to 40 ℃, added amino silicon oil emulsion A, amino silicon oil emulsion B, epoxy radicals silicone oil emulsion, 107 latex solutions, and heating is simultaneously stirred, and temperature remains on 40～50 ℃, and mixing speed is 60～100r/min; In the 3rd step, when temperature was raised to 50～55 ℃, mixing speed was 90～130r/min; In the 4th step, persistently overheating 1 hour, insulation was 30 minutes after temperature rose to 55～70 ℃, and mixing speed is 150～190r/min; After above-mentioned reaction was finished, with below the cooling water rapid cooling to 40 ℃, mixing speed reduced with temperature; At last, temperature remains on 36～40 ℃, and mixing speed remains on reacted under 20～40r/min condition 30～60 minutes, filters discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100292531A CN101113570B (en) | 2007-07-20 | 2007-07-20 | Organosilicon flexible smooth agent and process for preparing the same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100292531A CN101113570B (en) | 2007-07-20 | 2007-07-20 | Organosilicon flexible smooth agent and process for preparing the same |
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| CN101113570A true CN101113570A (en) | 2008-01-30 |
| CN101113570B CN101113570B (en) | 2012-11-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2007100292531A Expired - Fee Related CN101113570B (en) | 2007-07-20 | 2007-07-20 | Organosilicon flexible smooth agent and process for preparing the same |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102787502A (en) * | 2012-07-24 | 2012-11-21 | 苏州市华元化工有限公司 | Composite smoothing agent |
| CN102839545A (en) * | 2012-09-01 | 2012-12-26 | 中山市巴斯基化工有限公司 | Ice-feeling silicone oil for continuous dip padding process |
| CN106400508A (en) * | 2016-09-14 | 2017-02-15 | 清远市宏图助剂有限公司 | Smooth and elastic finishing agent for nylon-cotton fabrics, and preparation method thereof |
| CN106835713A (en) * | 2017-02-10 | 2017-06-13 | 深圳天鼎新材料有限公司 | A kind of organosilicon high-elastic smooth finishing agent and preparation method thereof |
| CN108385386A (en) * | 2018-04-10 | 2018-08-10 | 清远市恩科材料科技有限公司 | Super fluffy silicon soft oil and preparation method thereof |
| CN110791965A (en) * | 2019-10-12 | 2020-02-14 | 苏州联胜化学有限公司 | Fabric softener and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4024403A1 (en) * | 1990-08-01 | 1992-02-06 | Pfersee Chem Fab | AQUEOUS DISPERSION BASED ON SILICONES, THEIR PRODUCTION AND USE |
| CN1584191A (en) * | 2004-05-28 | 2005-02-23 | 刘国平 | Nanometer softening smoothing agent and preparing method thereof |
| CN100412262C (en) * | 2006-09-07 | 2008-08-20 | 浙江传化股份有限公司 | Method for preparing smoothing agent for fabric of organosilicon |
-
2007
- 2007-07-20 CN CN2007100292531A patent/CN101113570B/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102787502A (en) * | 2012-07-24 | 2012-11-21 | 苏州市华元化工有限公司 | Composite smoothing agent |
| CN102839545A (en) * | 2012-09-01 | 2012-12-26 | 中山市巴斯基化工有限公司 | Ice-feeling silicone oil for continuous dip padding process |
| CN102839545B (en) * | 2012-09-01 | 2014-08-06 | 中山市巴斯基化工有限公司 | Ice-feeling silicone oil for continuous dip padding process |
| CN106400508A (en) * | 2016-09-14 | 2017-02-15 | 清远市宏图助剂有限公司 | Smooth and elastic finishing agent for nylon-cotton fabrics, and preparation method thereof |
| CN106400508B (en) * | 2016-09-14 | 2019-05-07 | 清远市宏图助剂有限公司 | A kind of nylon-cotton fabric sliding bullet finishing agent and preparation method thereof |
| CN106835713A (en) * | 2017-02-10 | 2017-06-13 | 深圳天鼎新材料有限公司 | A kind of organosilicon high-elastic smooth finishing agent and preparation method thereof |
| CN106835713B (en) * | 2017-02-10 | 2019-07-09 | 深圳天鼎新材料有限公司 | A kind of organosilicon high-elastic smooth finishing agent and preparation method thereof |
| CN108385386A (en) * | 2018-04-10 | 2018-08-10 | 清远市恩科材料科技有限公司 | Super fluffy silicon soft oil and preparation method thereof |
| CN110791965A (en) * | 2019-10-12 | 2020-02-14 | 苏州联胜化学有限公司 | Fabric softener and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101113570B (en) | 2012-11-07 |
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