CN108250992A - A kind of adhesive of stabilization - Google Patents
A kind of adhesive of stabilization Download PDFInfo
- Publication number
- CN108250992A CN108250992A CN201810092953.3A CN201810092953A CN108250992A CN 108250992 A CN108250992 A CN 108250992A CN 201810092953 A CN201810092953 A CN 201810092953A CN 108250992 A CN108250992 A CN 108250992A
- Authority
- CN
- China
- Prior art keywords
- parts
- adhesive
- adipic acid
- stabilization
- propanediol polyester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to adhesive fields, disclose a kind of adhesive of stabilization, are made of the raw material of following parts by weight：17 26 parts of styrene, 10 14 parts of neoprene CR121,17 25 parts of adipic acid propanediol polyester, 36 parts of modified starch, 10 17 parts of 4,4' methyl diphenylene diisocyanates, 6 11 parts of toughener, 11 14 parts of anti-aging agent RD, 10 15 parts of phenolic resin glue, 10 12 parts of phthalic anhydride, 15 24 parts of adipic acid propanediol polyester, 15 21 parts of titanate coupling agent.A kind of adhesive of stabilization provided by the present invention, heat resistance and cold resistance greatly improve, water-tolerant, and adhesive is not easy degumming cracking, and stability is high, and service life is long.
Description
Technical field
The present invention relates to adhesive field, more particularly to a kind of adhesive of stabilization.
Background technology
In modern shoemaking industry, the key positions overwhelming majority such as footwear sole and upper is connected with adhesive, clean and tidy to product
It is beautiful, comfortable endurable, lightweight is reliable, due to only needing to bond, so manufacture craft is simple, it can be achieved that automation and continuous
Change operation.But the heat resistance and cold resistance of existing adhesive are bad, poor water resistance.In the storage of adhesive, stability
Also it is poor；In production, reaction speed when adhesive bonds is difficult to control, and easy gel is unfavorable for producing.Moreover, adhesive has
There is volatile smell, toxicity is also larger, on the choosing of consumer, using there is certain influence；It is also difficult to degrade, it is not friendly to environment
It is good.
Invention content
The present invention is intended to provide a kind of adhesive of stabilization, to solve the above problem of the prior art.
The technical solution adopted by the present invention is：A kind of adhesive of stabilization, is made of the raw material of following parts by weight：Styrene
17-26 parts, 10-14 parts of neoprene CR121,17-25 parts of adipic acid propanediol polyester, 3-6 parts of modified starch, 4,4'- hexichol
10-17 parts of dicyclohexylmethane diisocyanate, 6-11 parts of toughener, 11-14 parts of anti-aging agent RD, 10-15 parts of phenolic resin glue, adjacent benzene
10-12 parts of dicarboxylic acid anhydride, 15-24 parts of adipic acid propanediol polyester, 15-21 parts of titanate coupling agent.
Preferably, a kind of adhesive of stabilization, is made of the raw material of following parts by weight：24 parts of styrene, neoprene
12 parts of CR121,21 parts of adipic acid propanediol polyester, 5 parts of modified starch, 15 parts of 4,4'- methyl diphenylene diisocyanates, increase
Tough dose 10 parts, 12 parts of anti-aging agent RD, 13 parts of phenolic resin glue, 10 parts of phthalic anhydride, 20 parts of adipic acid propanediol polyester,
18 parts of titanate coupling agent.
The beneficial effects of the invention are as follows：It is common industrial chemicals that the present invention, which uses raw material, and production cost is low, is suitable for
It promotes, the market competitiveness is strong.Importantly, the heat resistance and cold resistance of adhesive greatly improve, and water-tolerant, adhesive
It is not easy degumming cracking, service life is long.By the improvement of formula, there has also been good suppressions for the smell and toxicity of adhesive release
System.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with specific embodiment
The present invention is further described.
Embodiment 1：A kind of adhesive of stabilization, is made of the raw material of following parts by weight：17 parts of styrene, neoprene
10 parts of CR121,17 parts of adipic acid propanediol polyester, 3 parts of modified starch, 10 parts of 4,4'- methyl diphenylene diisocyanates, increase
Tough dose 6 parts, 11 parts of anti-aging agent RD, 10 parts of phenolic resin glue, 10 parts of phthalic anhydride, 15 parts of adipic acid propanediol polyester, titanium
15 parts of acid esters coupling agent.
Embodiment 2：A kind of adhesive of stabilization, is made of the raw material of following parts by weight：26 parts of styrene, neoprene
14 parts of CR121,25 parts of adipic acid propanediol polyester, 6 parts of modified starch, 17 parts of 4,4'- methyl diphenylene diisocyanates, increase
Tough dose 11 parts, 14 parts of anti-aging agent RD, 15 parts of phenolic resin glue, 12 parts of phthalic anhydride, 24 parts of adipic acid propanediol polyester,
21 parts of titanate coupling agent.
Embodiment 3：A kind of adhesive of stabilization, is made of the raw material of following parts by weight：24 parts of styrene, neoprene
12 parts of CR121,21 parts of adipic acid propanediol polyester, 5 parts of modified starch, 15 parts of 4,4'- methyl diphenylene diisocyanates, increase
Tough dose 10 parts, 12 parts of anti-aging agent RD, 13 parts of phenolic resin glue, 10 parts of phthalic anhydride, 20 parts of adipic acid propanediol polyester,
18 parts of titanate coupling agent.
The foregoing is merely the preferred embodiments of the present invention, are not intended to limit the scope of the invention, every utilization
The present invention description made equivalent structure, equivalent process transformation or directly, be used in other relevant technologies indirectly
Field is included within the scope of the present invention.
Claims (2)
1. a kind of adhesive of stabilization, which is characterized in that be made of the raw material of following parts by weight：17-26 parts of styrene, neoprene rubber
10-14 parts of glue CR121,17-25 parts of adipic acid propanediol polyester, 3-6 parts of modified starch, 4,4'- diphenylmethane diisocyanates
10-17 parts of ester, 6-11 parts of toughener, 11-14 parts of anti-aging agent RD, 10-15 parts of phenolic resin glue, phthalic anhydride 10-12
Part, 15-24 parts of adipic acid propanediol polyester, 15-21 parts of titanate coupling agent.
2. the adhesive of stabilization according to claim 1, which is characterized in that be made of the raw material of following parts by weight：Benzene second
24 parts of alkene, 12 parts of neoprene CR121,21 parts of adipic acid propanediol polyester, 5 parts of modified starch, 4,4'- diphenyl methanes two
15 parts of isocyanates, 10 parts of toughener, 12 parts of anti-aging agent RD, 13 parts of phenolic resin glue, 10 parts of phthalic anhydride, adipic acid
20 parts of propanediol polyester, 18 parts of titanate coupling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810092953.3A CN108250992A (en) | 2018-01-31 | 2018-01-31 | A kind of adhesive of stabilization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810092953.3A CN108250992A (en) | 2018-01-31 | 2018-01-31 | A kind of adhesive of stabilization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108250992A true CN108250992A (en) | 2018-07-06 |
Family
ID=62742920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810092953.3A Withdrawn CN108250992A (en) | 2018-01-31 | 2018-01-31 | A kind of adhesive of stabilization |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108250992A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093117A (en) * | 2019-05-06 | 2019-08-06 | 湖北君邦新材料科技有限公司 | A kind of high-elastic glue of environment-friendly type and its production technology |
-
2018
- 2018-01-31 CN CN201810092953.3A patent/CN108250992A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093117A (en) * | 2019-05-06 | 2019-08-06 | 湖北君邦新材料科技有限公司 | A kind of high-elastic glue of environment-friendly type and its production technology |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180706 |