CN103897634B - A kind of high-performance hot-fusible pressure-sensitive adhesive - Google Patents
A kind of high-performance hot-fusible pressure-sensitive adhesive Download PDFInfo
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- CN103897634B CN103897634B CN201410146720.9A CN201410146720A CN103897634B CN 103897634 B CN103897634 B CN 103897634B CN 201410146720 A CN201410146720 A CN 201410146720A CN 103897634 B CN103897634 B CN 103897634B
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- Prior art keywords
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- sensitive adhesive
- fusible pressure
- performance hot
- butadiene rubber
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- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid group Chemical group C(C=1C(C(=O)O)=CC=CC1)(=O)O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 16
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 16
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 16
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 2-ethylhexyl Chemical group 0.000 claims abstract description 13
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 13
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 13
- 150000002148 esters Chemical class 0.000 claims abstract description 13
- 235000013312 flour Nutrition 0.000 claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 13
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- 239000007822 coupling agent Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 11
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- 150000003568 thioethers Chemical class 0.000 claims abstract description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000000654 additive Substances 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
Abstract
Present invention is disclosed a kind of high-performance hot-fusible pressure-sensitive adhesive, including thermoplastic styrene butadiene rubber, viscosifier, plasticizer, filler, antioxidant and coupling agent, described viscosifier are rosin modified phenolic resin, described plasticizer is phthalic acid two (2-ethylhexyl) ester, described filler is silica flour, described antioxidant is double; two (3,5-tri-grades of butyl-4-hydroxy phenyls) thioethers, and described coupling agent is aminopropyl triethoxysilane。This product adopts thermoplastic styrene butadiene rubber and viscosifier, plasticizer, filler, antioxidant and five kinds of additives of coupling agent to prepare, the adhesive prepared has that viscosity is good, tack strong, environmental protection, safety is high, production efficiency is high and production cost is low feature。
Description
Technical field
The present invention relates to chemical products, be specifically related to a kind of high-performance hot-fusible pressure-sensitive adhesive。
Background technology
At present, the pressure sensitive adhesive kind that market uses is different, uses field also different。The pressure sensitive adhesive of existing use, the raw material types of pressure sensitive adhesive is various, and the function possessed is also different。Hot-fusible pressure-sensitive adhesive is the third generation pressure sensitive adhesive product after solvent-borne type and emulsion-type pressure-sensitive, instantly the raw material that pressure sensitive adhesive uses cannot meet user demand when processing, user demand all can not be met particularly in viscosity, tack, Environmental Safety performance aspect, and the block copolymer of styrene and isoprene is as a kind of New Pressure-Sensitive Adhesion matrix, although performance meets the user demand of various product, but production cost is high, production efficiency is relatively poor, does not meet management philosophy。
Summary of the invention
It is an object of the invention to provide that a kind of viscosity is good, tack strong, environmental protection, safety is high, production efficiency is high and production cost is low high-performance hot-fusible pressure-sensitive adhesive。
The technical scheme is that, a kind of high-performance hot-fusible pressure-sensitive adhesive, including thermoplastic styrene butadiene rubber, viscosifier, plasticizer, filler, antioxidant and coupling agent, described viscosifier are rosin modified phenolic resin, described plasticizer is phthalic acid two (2-ethylhexyl) ester, described filler is silica flour, described antioxidant is double, two (3, tri-grades of butyl-4-hydroxy phenyls of 5-) sulfur ether, described coupling agent is aminopropyl triethoxysilane, percentage by weight shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive is respectively as follows: described thermoplastic styrene butadiene rubber and accounts for 75.3%-79.8%, described rosin modified phenolic resin accounts for 1.6%-2.5%, described phthalic acid two (2-ethylhexyl) ester accounts for 1.9%-2.8%, described silica flour accounts for 12.5%-13.4%, described double, two (3, tri-grades of butyl-4-hydroxy phenyls of 5-) thioether accounts for 1.4%-2.3%, described aminopropyl triethoxysilane accounts for 2.8%-3.7%。
In a preferred embodiment of the present invention, shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive, percentage by weight is particularly as follows: described thermoplastic styrene butadiene rubber accounts for 79.2%, described rosin modified phenolic resin accounts for 1.7%, described phthalic acid two (2-ethylhexyl) ester accounts for 2.1%, described silica flour accounts for 12.6%, described double; two (3,5-tri-grades of butyl-4-hydroxy phenyls) thioethers account for 1.5%, and described aminopropyl triethoxysilane accounts for 2.9%。
In a preferred embodiment of the present invention, shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive, percentage by weight is particularly as follows: described thermoplastic styrene butadiene rubber accounts for 75.8%, described rosin modified phenolic resin accounts for 2.4%, described phthalic acid two (2-ethylhexyl) ester accounts for 2.7%, described silica flour accounts for 13.3%, described double; two (3,5-tri-grades of butyl-4-hydroxy phenyls) thioethers account for 2.2%, and described aminopropyl triethoxysilane accounts for 3.6%。
Of the present invention is a kind of high-performance hot-fusible pressure-sensitive adhesive, this product adopts thermoplastic styrene butadiene rubber and viscosifier, plasticizer, filler, antioxidant and five kinds of additives of coupling agent to prepare, the adhesive prepared has that viscosity is good, tack strong, environmental protection, safety is high, production efficiency is high and production cost is low feature。
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention being made apparent clear and definite defining。
Of the present invention is a kind of high-performance hot-fusible pressure-sensitive adhesive, including thermoplastic styrene butadiene rubber, viscosifier, plasticizer, filler, antioxidant and coupling agent, described viscosifier are rosin modified phenolic resin, described plasticizer is phthalic acid two (2-ethylhexyl) ester, described filler is silica flour, described antioxidant is double, two (3, tri-grades of butyl-4-hydroxy phenyls of 5-) sulfur ether, described coupling agent is aminopropyl triethoxysilane, percentage by weight shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive is respectively as follows: described thermoplastic styrene butadiene rubber and accounts for 75.3%-79.8%, described rosin modified phenolic resin accounts for 1.6%-2.5%, described phthalic acid two (2-ethylhexyl) ester accounts for 1.9%-2.8%, described silica flour accounts for 12.5%-13.4%, described double, two (3, tri-grades of butyl-4-hydroxy phenyls of 5-) thioether accounts for 1.4%-2.3%, described aminopropyl triethoxysilane accounts for 2.8%-3.7%。
Further, shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive, percentage by weight is particularly as follows: described thermoplastic styrene butadiene rubber accounts for 79.2%, described rosin modified phenolic resin accounts for 1.7%, described phthalic acid two (2-ethylhexyl) ester accounts for 2.1%, described silica flour accounts for 12.6%, described double; two (3,5-tri-grades of butyl-4-hydroxy phenyls) thioethers account for 1.5%, and described aminopropyl triethoxysilane accounts for 2.9%。
Further, shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive, percentage by weight is particularly as follows: described thermoplastic styrene butadiene rubber accounts for 75.8%, described rosin modified phenolic resin accounts for 2.4%, described phthalic acid two (2-ethylhexyl) ester accounts for 2.7%, described silica flour accounts for 13.3%, described double; two (3,5-tri-grades of butyl-4-hydroxy phenyls) thioethers account for 2.2%, and described aminopropyl triethoxysilane accounts for 3.6%。
Proportioning is carried out so that the properties of product height obtained differs by each composition Different Weight percentage ratio。
Of the present invention is a kind of high-performance hot-fusible pressure-sensitive adhesive, this product adopts thermoplastic styrene butadiene rubber and viscosifier, plasticizer, filler, antioxidant and five kinds of additives of coupling agent to prepare, the adhesive prepared has that viscosity is good, tack strong, environmental protection, safety is high, production efficiency is high and production cost is low feature。
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the present invention to make or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, all in like manner include in the scope of patent protection of the present invention。
Claims (3)
1. a high-performance hot-fusible pressure-sensitive adhesive, it is characterized in that: include thermoplastic styrene butadiene rubber, viscosifier, plasticizer, filler, antioxidant and coupling agent, described viscosifier are rosin modified phenolic resin, described plasticizer is phthalic acid two (2-ethylhexyl) ester, described filler is silica flour, described antioxidant is double, two (3, tri-grades of butyl-4-hydroxy phenyls of 5-) sulfur ether, described coupling agent is aminopropyl triethoxysilane, percentage by weight shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive is respectively as follows: described thermoplastic styrene butadiene rubber and accounts for 75.3%-79.8%, described rosin modified phenolic resin accounts for 1.6%-2.5%, described phthalic acid two (2-ethylhexyl) ester accounts for 1.9%-2.8%, described silica flour accounts for 12.5%-13.4%, described double, two (3, tri-grades of butyl-4-hydroxy phenyls of 5-) thioether accounts for 1.4%-2.3%, described aminopropyl triethoxysilane accounts for 2.8%-3.7%。
2. high-performance hot-fusible pressure-sensitive adhesive according to claim 1, it is characterized in that: shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive, percentage by weight is particularly as follows: described thermoplastic styrene butadiene rubber accounts for 79.2%, described rosin modified phenolic resin accounts for 1.7%, described phthalic acid two (2-ethylhexyl) ester accounts for 2.1%, described silica flour accounts for 12.6%, described double; two (3,5-tri-grades of butyl-4-hydroxy phenyls) thioethers account for 1.5%, and described aminopropyl triethoxysilane accounts for 2.9%。
3. high-performance hot-fusible pressure-sensitive adhesive according to claim 1, it is characterized in that: shared by the described each composition of high-performance hot-fusible pressure-sensitive adhesive, percentage by weight is particularly as follows: described thermoplastic styrene butadiene rubber accounts for 75.8%, described rosin modified phenolic resin accounts for 2.4%, described phthalic acid two (2-ethylhexyl) ester accounts for 2.7%, described silica flour accounts for 13.3%, described double; two (3,5-tri-grades of butyl-4-hydroxy phenyls) thioethers account for 2.2%, and described aminopropyl triethoxysilane accounts for 3.6%。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410146720.9A CN103897634B (en) | 2014-04-14 | 2014-04-14 | A kind of high-performance hot-fusible pressure-sensitive adhesive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410146720.9A CN103897634B (en) | 2014-04-14 | 2014-04-14 | A kind of high-performance hot-fusible pressure-sensitive adhesive |
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| Publication Number | Publication Date |
|---|---|
| CN103897634A CN103897634A (en) | 2014-07-02 |
| CN103897634B true CN103897634B (en) | 2016-06-22 |
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| CN201410146720.9A Expired - Fee Related CN103897634B (en) | 2014-04-14 | 2014-04-14 | A kind of high-performance hot-fusible pressure-sensitive adhesive |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106217276A (en) * | 2016-08-25 | 2016-12-14 | 江苏牡丹亭农业科技发展有限公司 | A kind of high-temperaure coating formula |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153980B (en) * | 2015-10-20 | 2017-02-22 | 湖南金化科技集团有限公司 | Salt spray resistant SBS adhesive and preparation method thereof |
| CN105936813A (en) * | 2016-06-07 | 2016-09-14 | 刘伟 | Plate adhesive with good corrosion resistance |
| CN105936812A (en) * | 2016-06-07 | 2016-09-14 | 刘伟 | High temperature resistant sheet adhesive |
| CN107964381A (en) * | 2017-12-13 | 2018-04-27 | 福建省昌德胶业科技有限公司 | A kind of high-low temperature resistant overlay film packaging glue and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709201A (en) * | 2009-12-14 | 2010-05-19 | 上海应用技术学院 | Method for preparing polystyrene-polyisoprene-polystyrene ternary segmented copolymer hot melt pressure-sensitive adhesive |
| CN102559112A (en) * | 2011-12-27 | 2012-07-11 | 上海康达化工新材料股份有限公司 | Thermoplastic elastomer styrene-butadiene-styrene (SBS) adhesive and preparation method thereof |
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2014
- 2014-04-14 CN CN201410146720.9A patent/CN103897634B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709201A (en) * | 2009-12-14 | 2010-05-19 | 上海应用技术学院 | Method for preparing polystyrene-polyisoprene-polystyrene ternary segmented copolymer hot melt pressure-sensitive adhesive |
| CN102559112A (en) * | 2011-12-27 | 2012-07-11 | 上海康达化工新材料股份有限公司 | Thermoplastic elastomer styrene-butadiene-styrene (SBS) adhesive and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106217276A (en) * | 2016-08-25 | 2016-12-14 | 江苏牡丹亭农业科技发展有限公司 | A kind of high-temperaure coating formula |
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| CN103897634A (en) | 2014-07-02 |
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Effective date of registration: 20160526 Address after: No. 66 Xiangcheng District road Weitang town Suzhou city Jiangsu province 215100 longlifu Applicant after: Suzhou Wantuming Electronic Software Co.,Ltd. Address before: 215400, Jiangsu, Suzhou province Taicang town Chengxiang emerging village Mao roadside Applicant before: Taicang Huanya Packaging Products Co., Ltd. |
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Effective date of registration: 20161220 Address after: 215400 Taicang Economic Development Zone, Jiangsu, Beijing West Road, No. 6, No. Patentee after: Taicang hope Machinery Technology Co., Ltd. Address before: No. 66 Xiangcheng District road Weitang town Suzhou city Jiangsu province 215100 longlifu Patentee before: Suzhou Wantuming Electronic Software Co.,Ltd. |
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Inventor after: Li Changgen Inventor before: Lu Minjie |
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Effective date of registration: 20170418 Address after: Baiyun District of Guangzhou City, Guangdong province 510080 Zhongluotan Zhuliao Avenue in the middle of Tang Dou heart road No. 1 two factory Patentee after: Guangzhou Qi Qi Industrial Co., Ltd. Address before: 215400 Taicang Economic Development Zone, Jiangsu, Beijing West Road, No. 6, No. Patentee before: Taicang hope Machinery Technology Co., Ltd. |
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