CN107964381A - A kind of high-low temperature resistant overlay film packaging glue and preparation method thereof - Google Patents
A kind of high-low temperature resistant overlay film packaging glue and preparation method thereof Download PDFInfo
- Publication number
- CN107964381A CN107964381A CN201711328942.2A CN201711328942A CN107964381A CN 107964381 A CN107964381 A CN 107964381A CN 201711328942 A CN201711328942 A CN 201711328942A CN 107964381 A CN107964381 A CN 107964381A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- packaging glue
- low temperature
- overlay film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention discloses a kind of high-low temperature resistant overlay film packaging glue, it includes each component of following parts by weight：AFFINITYTMGA polyolefin plastomers (POP) are 35 45 parts by weight, hydrogenated styrene-butadiene rubber is 19 parts by weight, wax is 15 25 parts by weight, hydrogenated petroleum resin is 30 40 parts by weight, rosin modified phenolic resin is 19 parts by weight, 0.3 1 parts by weight of antioxidant, invention additionally discloses a kind of preparation method of high-low temperature resistant overlay film packaging glue, the hot melt packaging glue of the overlay film of the present invention has excellent fast viscosity and resistant of high or low temperature, it is very good to the adhesion strength of tectorial backing material, the hot melt packaging glue of the present invention is used as main polymer using the GA polyolefin plastomers (POP) of AFFINITY companies production, and introduce a small amount of SEBS, spray bar/specking is carried out in the molten state, it can reach short time fitting material after cooling and solidifying and break effect.
Description
Technical field
The present invention relates to hot melt adhesive technical field, and in particular to a kind of high-low temperature resistant overlay film packaging glue and preparation method thereof.
Background technology
Hot melt adhesive is a kind of new type bonding agent, wherein the hot melt adhesive using EVA as basis is most widely used, and is packed
Industry is that current EVA hot-melt adhesive applies a very big field.This glue is free of any solvent, nontoxic, quick-drying, production technology letter
Single, of low cost, equipment investment is few when client uses, easy to use, and production efficiency is high.
And it is main polymers that the hot melt adhesive that existing overlay film is packed for, which generally selects common EVA, common EVA shortcomings are itself
It is poor to the wellability of PE/PP materials.Particularly when temperature is less than -5 DEG C, with common EVA pack glue occur it is brittle, open
Phenomena such as case.Since the hydrogenated styrene-butadiene rubber (SEBS) containing maleic anhydride has the spy of excellent adhesion and high molecular weight
Property, so that the PE/PP material materials of fitting can be allowed to break at a higher temperature.And Tao Shi series of polyolefins plastic bodies
(POP) it is with the InSite of metallocene catalysis processTMPolymer based on technology, it is with excellent weatherability and attachment
Property, with reference to the packaging glue worked it out, high temperature resistant and low temperature resistant performance are obviously improved two serial raw materials.
The content of the invention
In order to overcome above-mentioned shortcoming existing in the prior art, have it is an object of the invention to provide one kind excellent
High temperature resistant, resistance to low temperature and to the extraordinary overlay film of PE/PP base material cohesive forces pack glue.
To achieve the above object, the technical solution adopted by the present invention is as follows：A kind of high-low temperature resistant overlay film packs glue, it includes
The each component of following parts by weight：AFFINITYTMGA polyolefin plastomers (POP) are 35-45 parts by weight, and hydrogenated styrene-butadiene rubber is
1-9 parts by weight, wax are 15-25 parts by weight, and hydrogenated petroleum resin is 30-40 parts by weight, and rosin modified phenolic resin is 1-9 weight
Part, antioxidant 0.3-1 parts by weight.
Preferably, antioxidant of the present invention is antioxidant 1010.
It is a further object of the present invention to provide a kind of preparation method of high-low temperature resistant overlay film packaging glue, which includes
Following steps：
A, by the AFFINITY of 10-20 parts by weightTMThe hydrogenation butylbenzene rubber of GA polyolefin plastomers (POP), 1-9 parts by weight
Glue, the wax of 1-10 parts by weight are put into reaction kettle, are begun to warm up and are stirred evenly, and material temperature control is in 150-160 in reaction kettle
DEG C, heating 50-70min to material all melts；
B, the AFFINITY of 25-35 parts by weight is put into the reaction kettle of step aTMGA polyolefin plastomers (POP) are simultaneously stirred
Mix uniformly, mixing speed control is all melted in 60-100r/min, stirring 20-30min to material；
C, the wax of 15-25 parts by weight, the hydrogenated petroleum resin of 30-40 parts by weight, 1-9 are put into the reaction kettle of step b
The rosin modified phenolic resin of parts by weight simultaneously stirs evenly, and mixing speed control is closed anti-in 60-100r/min, stopping heating
Kettle is answered, pressure will be evacuated in reaction kettle and is less than -0.09Mpa, pumpdown time control is in 40-60min, pumpdown time knot
Beam puts vacuum, obtains hot melt packaging glue coarse fodder；
D, three bag filter of hot melt packaging glue coarse fodder 200-400 mesh obtained step c discharges, and is covered up to PE/PP
The hot melt packaging glue finished product of film.
Compared with prior art, the invention has the advantages that：
1st, the hot melt packaging glue of overlay film of the invention has excellent fast viscosity and resistant of high or low temperature, to tectorial backing material
Adhesion strength is very good, and hot melt packaging glue of the invention uses GA polyolefin plastomers (POP) conduct of AFFINITY companies production
Main polymer, and a small amount of SEBS is introduced, spray bar/specking is carried out in the molten state, can reach in short-term after cooling and solidifying
Between fitting material break effect.
2nd, preparation method of the present invention is simple, the discharge of production process unharmful substance, without using any solvent, belongs to environment friend
Good type adhesive.When in use, operating procedure is simple, and equipment investment is few.Products and marketing prepared by the present invention is existing common
EVA packaging glue compares, its density is small, and resistant of high or low temperature is good, and glue consumption is few, good weatherability, and carbonization is few.
Embodiment
With reference to embodiment, the invention will be further described, and mode of the invention includes but are not limited to following implementation
Example.
Embodiment 1
A kind of preparation method of high-low temperature resistant overlay film packaging glue comprises the following steps：
A, by the AFFINITY of 20gTMGA polyolefin plastomers (POP), the hydrogenated styrene-butadiene rubber of 1g, the wax of 5g, 1g it is anti-
Oxidant 1010 is put into reaction kettle, is begun to warm up and is stirred evenly, and material temperature control heats 70min at 160 DEG C in reaction kettle
All melted to material；
B, the AFFINITY of 25g is put into the reaction kettle of step aTMGA polyolefin plastomers (POP) simultaneously stir evenly,
Mixing speed control is all melted in 60r/min, stirring 30min to material；
C, the wax of 10g, the hydrogenated petroleum resin of 30g, the rosin modified phenolic resin of 9g are put into the reaction kettle of step b
And stir evenly, mixing speed control is small by pressure is evacuated in reaction kettle in 60r/min, stopping heating, closed reactor
In -0.09Mpa, the pumpdown time is controlled in 40min, and the pumpdown time terminates to put vacuum, obtains hot melt packaging glue coarse fodder；
D, the hot melt packaging glue coarse fodder obtained step c is discharged with 200 mesh, three bag filter, is used up to PE/PP overlay films
Hot melt packaging glue finished product.
The hot melt packaging glue end properties of PE/PP overlay films made from embodiment 1 is shown in Table 1.
Embodiment 2
A kind of preparation method of high-low temperature resistant overlay film packaging glue comprises the following steps：
A, by the AFFINITY of 20gTMGA polyolefin plastomers (POP), the hydrogenated styrene-butadiene rubber of 3g, the wax of 5g, 0.6g
In antioxidant 1010 input reaction kettle, begin to warm up and stir evenly, material temperature control is at 160 DEG C in reaction kettle, heating
70min is all melted to material；
B, the AFFINITY of 20g is put into the reaction kettle of step aTMGA polyolefin plastomers (POP) simultaneously stir evenly,
Mixing speed control is all melted in 60r/min, stirring 30min to material；
C, the wax of 15g, the hydrogenated petroleum resin of 35g, the rosin modified phenolic resin of 2g are put into the reaction kettle of step b
And stir evenly, mixing speed control is small by pressure is evacuated in reaction kettle in 60r/min, stopping heating, closed reactor
In -0.09Mpa, the pumpdown time is controlled in 40min, and the pumpdown time terminates to put vacuum, obtains hot melt packaging glue coarse fodder；
D, the hot melt packaging glue coarse fodder obtained step c is discharged with 200 mesh, three bag filter, is used up to PE/PP overlay films
Hot melt packaging glue finished product.
The hot melt packaging glue end properties of PE/PP overlay films made from embodiment 2 is shown in Table 1.
Embodiment 3
A kind of preparation method of high-low temperature resistant overlay film packaging glue comprises the following steps：
A, by the AFFINITY of 15gTMGA polyolefin plastomers (POP), the hydrogenated styrene-butadiene rubber of 9g, the wax of 10g, 0.3g
Antioxidant 1010 input reaction kettle in, begin to warm up and stir evenly, material temperature control is at 160 DEG C in reaction kettle, heating
70min is all melted to material；
B, the AFFINITY of 20g is put into the reaction kettle of step aTMGA polyolefin plastomers (POP) simultaneously stir evenly,
Mixing speed control is all melted in 60r/min, stirring 30min to material；
C, the wax of 15g, the hydrogenated petroleum resin of 30g, the rosin modified phenolic resin of 1g are put into the reaction kettle of step b
And stir evenly, mixing speed control is small by pressure is evacuated in reaction kettle in 60r/min, stopping heating, closed reactor
In -0.09Mpa, the pumpdown time is controlled in 40min, and the pumpdown time terminates to put vacuum, obtains hot melt packaging glue coarse fodder；
D, the hot melt packaging glue coarse fodder obtained step c is discharged with 200 mesh, three bag filter, is used up to PE/PP overlay films
Hot melt packaging glue finished product.
The hot melt packaging glue end properties of PE/PP overlay films made from embodiment 3 is shown in chart 1.
Above-described embodiment is only the preferred embodiment of the present invention, should not be taken to limit protection scope of the present invention, but
All body design thought in the present invention and that mentally makes have no the change of essential meaning or polishing, its technology solved
Problem is still consistent with the present invention, should be included within protection scope of the present invention.
Claims (3)
1. a kind of high-low temperature resistant overlay film packs glue, it is characterised in that：It includes each component of following parts by weight：AFFINITYTMGA
Polyolefin plastomers (POP) are 35-45 parts by weight, and hydrogenated styrene-butadiene rubber is 1-9 parts by weight, and wax is 15-25 parts by weight, hydrogenate stone
Oleoresin is 30-40 parts by weight, and rosin modified phenolic resin is 1-9 parts by weight, antioxidant 0.3-1 parts by weight.
A kind of 2. high-low temperature resistant overlay film packaging glue according to claim 18, it is characterised in that：The antioxidant is anti-
Oxidant 1010.
3. the preparation method of a kind of high-low temperature resistant overlay film packaging glue according to claim 1, it is characterised in that including following
Step：
A, by the AFFINITY of 10-20 parts by weightTMGA polyolefin plastomers (POP), the hydrogenated styrene-butadiene rubber of 1-9 parts by weight, 1-
In the wax input reaction kettle of 10 parts by weight, begin to warm up and stir evenly, material temperature control adds at 150-160 DEG C in reaction kettle
Hot 50-70min is all melted to material；
B, the AFFINITY of 25-35 parts by weight is put into the reaction kettle of step aTMGA polyolefin plastomers (POP) simultaneously stir equal
Even, mixing speed control is all melted in 60-100r/min, stirring 20-30min to material；
C, the wax of 15-25 parts by weight, the hydrogenated petroleum resin of 30-40 parts by weight, 1-9 weight are put into the reaction kettle of step b
The rosin modified phenolic resin of part simultaneously stirs evenly, and mixing speed control is heated in 60-100r/min, stopping, closed reactor,
Pressure will be evacuated in reaction kettle and is less than -0.09Mpa, the pumpdown time is controlled in 40-60min, and the pumpdown time terminates to put
Vacuum, obtains hot melt packaging glue coarse fodder；
D, three bag filter of hot melt packaging glue coarse fodder 200-400 mesh obtained step c discharges, and is used up to PE/PP overlay films
Hot melt packaging glue finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711328942.2A CN107964381A (en) | 2017-12-13 | 2017-12-13 | A kind of high-low temperature resistant overlay film packaging glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711328942.2A CN107964381A (en) | 2017-12-13 | 2017-12-13 | A kind of high-low temperature resistant overlay film packaging glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107964381A true CN107964381A (en) | 2018-04-27 |
Family
ID=61994988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711328942.2A Pending CN107964381A (en) | 2017-12-13 | 2017-12-13 | A kind of high-low temperature resistant overlay film packaging glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107964381A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735265A (en) * | 2019-01-17 | 2019-05-10 | 福建省昌德胶业科技有限公司 | A kind of high-temperature-resistance polyolefin hot fusible adhesive for package and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020120024A1 (en) * | 2001-02-23 | 2002-08-29 | Phat Cushion Llc | Foam cushion and method of making and using the same |
| CN103897634A (en) * | 2014-04-14 | 2014-07-02 | 太仓环亚包装制品有限公司 | High-performance hot-melt pressure-sensitive adhesive |
| CN106244049A (en) * | 2016-08-30 | 2016-12-21 | 华威粘结材料（上海）股份有限公司 | A kind of polyolefin joint sealing glue and preparation method thereof |
-
2017
- 2017-12-13 CN CN201711328942.2A patent/CN107964381A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020120024A1 (en) * | 2001-02-23 | 2002-08-29 | Phat Cushion Llc | Foam cushion and method of making and using the same |
| CN103897634A (en) * | 2014-04-14 | 2014-07-02 | 太仓环亚包装制品有限公司 | High-performance hot-melt pressure-sensitive adhesive |
| CN106244049A (en) * | 2016-08-30 | 2016-12-21 | 华威粘结材料（上海）股份有限公司 | A kind of polyolefin joint sealing glue and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735265A (en) * | 2019-01-17 | 2019-05-10 | 福建省昌德胶业科技有限公司 | A kind of high-temperature-resistance polyolefin hot fusible adhesive for package and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102786895B (en) | Hot-melt adhesive for transparent PP (polypropylene) boxes and preparation method of hot-melt adhesive | |
| JP5990519B2 (en) | Method for producing an adhesive using extrusion | |
| CN105647461B (en) | It a kind of hot melt adhesive and its is applied in wood plastic composite | |
| JP2000507283A (en) | Olefin polymer-containing adhesive | |
| CN109054688B (en) | Heat aging non-sticking hot melt pressure-sensitive adhesive and preparation method thereof | |
| EP2861685B1 (en) | Adhesive compositions containing modified ethylene-based polymers | |
| CN107083213B (en) | A kind of dairy products adhesive for packaging and preparation method thereof | |
| CN108949046B (en) | EVA hot melt adhesive film for wall cloth and preparation method thereof | |
| CA3096804C (en) | Hot-melt formulations utilizing depolymerized polymeric material | |
| WO2017107859A1 (en) | Novel hot-melt adhesive and preparation method therefor | |
| CN110461979A (en) | Adhesive composite | |
| JP2013151630A (en) | Aqueous emulsion, method for forming coating film and coating film | |
| CN107964381A (en) | A kind of high-low temperature resistant overlay film packaging glue and preparation method thereof | |
| CN102925087B (en) | Hot melt adhesive composition for sealing automobile lamp and preparation method thereof | |
| CN107118714B (en) | A kind of Antibacterial hot melt adhesive and preparation method thereof | |
| TWI828829B (en) | Hot melt adhesive composition | |
| US20150337186A1 (en) | Hot melt adhesive containing a polyamide/ polyolefin hybrid polymer | |
| JP2013151139A (en) | Method for producing laminate structure | |
| CN110746907A (en) | Hot-melt pressure-sensitive adhesive suitable for bonding polyolefin woven cloth and metal plate and preparation method thereof | |
| JPH0286676A (en) | Hot-melt adhesive composition | |
| CN107109159B (en) | Adhesive composite | |
| JP2013151142A (en) | Laminated structure | |
| CN110484174A (en) | A kind of heat molten type mattress screen cloth glue and its production technology | |
| EP2875085A1 (en) | Protective elements made of polyolefin hot-melt adhesives | |
| JP2013151634A (en) | Aqueous adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180427 |
|
| RJ01 | Rejection of invention patent application after publication |