CN108250618A - A kind of automobile-used high-temperature resistant isolated film manufacturing method - Google Patents

A kind of automobile-used high-temperature resistant isolated film manufacturing method Download PDF

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Publication number
CN108250618A
CN108250618A CN201810050933.XA CN201810050933A CN108250618A CN 108250618 A CN108250618 A CN 108250618A CN 201810050933 A CN201810050933 A CN 201810050933A CN 108250618 A CN108250618 A CN 108250618A
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parts
automobile
temperature resistant
used high
film manufacturing
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CN201810050933.XA
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邹广
邹友
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Quanjiao Guang Tai Adhesive Products Co Ltd
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Quanjiao Guang Tai Adhesive Products Co Ltd
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Priority to CN201810050933.XA priority Critical patent/CN108250618A/en
Publication of CN108250618A publication Critical patent/CN108250618A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/002Methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2427/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2463/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2471/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2293Oxides; Hydroxides of metals of nickel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/524Esters of phosphorous acids, e.g. of H3PO3

Abstract

The invention discloses a kind of automobile-used high-temperature resistant isolated film manufacturing method, the isolation film is made by the material of following component:5 15 parts of Corvic, 5 10 parts of epoxy resin, 38 parts of diethyl phosphite, 26 parts of polyethylene glycol, 5 20 parts of silica, 3 10 parts of calcium oxide, 25 parts of potassium bichromate, 14 parts of nickel oxide;The present invention can provide a kind of high temperature resistant, anti-scratch new automobile isolation films, and preferably car surface can be protected, and production is easy to implement, and cost is relatively low, easy to operation.

Description

A kind of automobile-used high-temperature resistant isolated film manufacturing method
Technical field
The present invention relates to automobiles to be isolated technical field of membrane, specially a kind of automobile-used high-temperature resistant isolated film manufacturing method.
Background technology
Automobile film its basic performance include safety, clear, anti-dazzle, every ultraviolet light, heat-insulated, anti-scratch, enough guarantee the quality Phase and protection privacy etc..Automobile film can classify four classes, the first automobile film is coating and combination process film, and main effect is Strong sunlight is blocked, this kind of automobile film is to produce relatively early stage, does not have heat-insulated effect substantially, is sun paper in early days, Also tea paper is, second of automobile film is dyeing film, and seen dyeing automobile film is mostly deep layer dyeing in the market, is contaminated with deep layer Color gimmick filling heat absorbent, absorb sunlight in infrared ray achieve the effect that it is heat-insulated.Because it also absorbs visible ray simultaneously, Cause visible light transmittance inadequate, in addition technique itself is limited, clarity is poor.Another big weakness of such film is heat insulating function Attenuation quickly, and is easily faded, and price is relatively relatively inexpensive, the third automobile film is vacuum thermal evaporation film, using vacuum Thermal evaporation process is to evaporate aluminium layer on base material, reaches heat insulation.This also usually said metal film field, have compared with Lasting thermal insulation, but weakness is that clarity is not high, influences visual field comfort, another big prominent weakness is reflective higher. 4th kind of automobile film is metal magnetic control sputtered film.This is the highest technique of glass-film, results from phase late 1990s, experience Multiple technologies innovations.Using electric field and the high strength of magnetic principles high speed by metallic uniform sputter in high-tension In PET base material.The product of magnetron sputtering technique is in addition to the heat-proof quality for having good metal-like, stabilization, also with other The clarity that technique is unable to reach and low reflective and lasting color and luster.Magic card intelligent color-changing film is exactly this technique life used Production manufacture.
Existing its production technology of automobile isolation film is more mature, automobile isolation film it is heat-insulated, protection etc. all Had an effect more highlighted, but existing automobile isolation film its also have the defects of itself can not overcome, existing automobile It is more flexible for isolation film, causes what it can not cope with pointed object to scrape cunning, so that often it automobile film damage is in the presence of, So causing often to replace pad pasting, larger repair is caused to put into, it is therefore desirable to which a kind of novel isolation film causes it meeting Under the premise of heat safe, there is higher protective.
Invention content
The purpose of the present invention is to provide a kind of automobile-used high-temperature resistant isolated film manufacturing method, to solve above-mentioned background technology The problem of middle proposition.
To achieve the above object, the present invention provides following technical solution:A kind of automobile-used high-temperature resistant isolated film manufacturing method, The isolation film is made by the material of following component:5-15 parts of Corvic, 5-10 parts of epoxy resin, diethyl phosphite 3-8 parts, 2-6 parts of polyethylene glycol, 5-20 parts of silica, 3-10 parts of calcium oxide, 2-5 parts of potassium bichromate, 1-4 parts of nickel oxide;
S1, silica, calcium oxide, potassium bichromate and nickel oxide are uniformly mixed, is heated, obtain mixture A;
S2, by mixture A carry out cooling treatment, by Corvic, epoxy resin, diethyl phosphite and polyethylene glycol into The uniform mixing of row, heat treatment obtain mixture B;
S3, mixture B is placed in extruser mixing extrusion, obtains extruded stock;
S4, extruded stock is subjected to the isolation film that is heating and curing to obtain.
As a preferred technical solution of the present invention, can be added in the step S2 0.1-0.5 parts of plant essence and 0.05-0.2 parts of zwitterionic surfactant.
As a preferred technical solution of the present invention, the plant essence is preferably fragrant for jasmine flower essence or orchid Essence.
As a preferred technical solution of the present invention, heat treatment in the step S1 is divided into be heat-treated twice, and The temperature being once heat-treated is 500-800 DEG C, and second of heat treatment temperature is 800-1200 DEG C.
As a preferred technical solution of the present invention, needed in the step S2 in the environment of 100-200 DEG C into Row cooling needs to be filled with inert gas in the environment while cooling.
As a preferred technical solution of the present invention, the heat treatment temperature in the step S2 is 100-120 DEG C.
As a preferred technical solution of the present invention, the thickness of the isolation film is 0.2-0.8 ㎜.
As a preferred technical solution of the present invention, the isolation film is made by the material of following component:Polyvinyl chloride 5 parts of resin, 10 parts of epoxy resin, 3 parts of diethyl phosphite, 6 parts of polyethylene glycol, 5 parts of silica, 10 parts of calcium oxide, again 2 parts of potassium chromate, 4 parts of nickel oxide.
As a preferred technical solution of the present invention, the isolation film is made by the material of following component:Polyvinyl chloride 15 parts of resin, 5 parts of epoxy resin, 8 parts of diethyl phosphite, 2 parts of polyethylene glycol, 20 parts of silica, 3 parts of calcium oxide, again 5 parts of potassium chromate, 1 part of nickel oxide.
As a preferred technical solution of the present invention, the isolation film is made by the material of following component:Polyvinyl chloride 10 parts of resin, 8 parts of epoxy resin, 5 parts of diethyl phosphite, 4 parts of polyethylene glycol, 2 parts of silica 1,6 parts of calcium oxide, weight chromium Sour 3.5 parts of potassium, 2.5 parts of nickel oxide.
Compared with prior art, the beneficial effects of the invention are as follows:Orthodox car film heat-resisting, uvioresistant etc. have compared with Good performance, but be more short of in terms of scratch, the present invention add in silica etc. by its characteristic without definite melting point, As the base of isolation film so that isolation film has cut preferable resistant function, while is additionally added in isolation film Auxiliary material so that isolation film itself carries certain plant breath, has preferable effect in reply mosquito etc., prevents mosquito Worm, which climbs, is attached to the spot that car surface causes the more difficult cleaning in surface, graphic appearance;The present invention can provide a kind of high temperature resistants, anti-scratch New automobile isolation film, preferably car surface can be protected, production it is easy to implement, cost is relatively low, easy to operation.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based in the present invention Embodiment, those of ordinary skill in the art's all other embodiments obtained without making creative work, all Belong to the scope of protection of the invention.
Embodiment 1
The present invention provides a kind of technical solution:A kind of automobile-used high-temperature resistant isolated film manufacturing method, the isolation film is by following group The material divided is made:5 parts of Corvic, 10 parts of epoxy resin, 3 parts of diethyl phosphite, 6 parts of polyethylene glycol, dioxy 5 parts of SiClx, 10 parts of calcium oxide, 2 parts of potassium bichromate, 4 parts of nickel oxide;
S1, silica, calcium oxide, potassium bichromate and nickel oxide are uniformly mixed, is heated, obtain mixture A;
S2, by mixture A carry out cooling treatment, by Corvic, epoxy resin, diethyl phosphite and polyethylene glycol into The uniform mixing of row, heat treatment obtain mixture B;
S3, mixture B is placed in extruser mixing extrusion, obtains extruded stock;
S4, extruded stock is subjected to the isolation film that is heating and curing to obtain.
0.1 part of plant essence can be added in the step S2 and 0.2 part of the zwitterionic surfactant plant is fragrant Smart is preferably jasmine flower essence or orchid compound, both plant essences have effects that mosquito proof, can prevent mosquito from climbing It is attached to car surface and causes spot, it is difficult to clean.Heat treatment in the step S1 is divided into be heat-treated twice, for the first time at heat The temperature of reason is 500-800 DEG C, and second of heat treatment temperature is 800-1200 DEG C.It is needed in the step S2 in 100-200 It is cooled down in the environment of DEG C, needs to be filled with inert gas in the environment while cooling;Heat treatment in the step S2 Temperature is 100-120 DEG C;The thickness of the isolation film is 0.2-0.8 ㎜.
Embodiment 2
A kind of automobile-used high-temperature resistant isolated film manufacturing method, it is characterised in that:The isolation film is made by the material of following component: 15 parts of Corvic, 5 parts of epoxy resin, 8 parts of diethyl phosphite, 2 parts of polyethylene glycol, 20 parts of silica, oxidation 3 parts of calcium, 5 parts of potassium bichromate, 1 part of nickel oxide.
S1, silica, calcium oxide, potassium bichromate and nickel oxide are uniformly mixed, is heated, must be mixed Object A;
S2, by mixture A carry out cooling treatment, by Corvic, epoxy resin, diethyl phosphite and polyethylene glycol into The uniform mixing of row, heat treatment obtain mixture B;
S3, mixture B is placed in extruser mixing extrusion, obtains extruded stock;
S4, extruded stock is subjected to the isolation film that is heating and curing to obtain.
0.05 part of 0.5 part of plant essence and zwitterionic surfactant can be added in the step S2.
Embodiment 3
A kind of automobile-used high-temperature resistant isolated film manufacturing method, the isolation film are made by the material of following component:Polyvinyl chloride tree 10 parts of fat, 8 parts of epoxy resin, 5 parts of diethyl phosphite, 4 parts of polyethylene glycol, 2 parts of silica 1,6 parts of calcium oxide, dichromic acid 3.5 parts of potassium, 2.5 parts of nickel oxide.
S1, silica, calcium oxide, potassium bichromate and nickel oxide are uniformly mixed, is heated, must be mixed Object A;
S2, by mixture A carry out cooling treatment, by Corvic, epoxy resin, diethyl phosphite and polyethylene glycol into The uniform mixing of row, heat treatment obtain mixture B;
S3, mixture B is placed in extruser mixing extrusion, obtains extruded stock;
S4, extruded stock is subjected to the isolation film that is heating and curing to obtain.
0.1 part of 0.3 part of plant essence and zwitterionic surfactant can be added in step s 2.
Orthodox car film has preferable performance in heat-resisting, uvioresistant etc., but is more short of in terms of scratch, The present invention adds in silica etc. by its characteristic without definite melting point, as the base of isolation film so that isolation film pair Cut has preferable resistant function, while auxiliary material is also added into isolation film so that isolation film itself carries certain Plant breath has preferable effect in reply mosquito etc., prevents mosquito from climbing and is attached to car surface and causes the more difficult cleaning in surface Spot, graphic appearance;The present invention can provide a kind of high temperature resistant, anti-scratch new automobile isolation films, can be preferably to vapour Vehicle surface is protected, and production is easy to implement, and cost is relatively low, easy to operation.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (10)

1. a kind of automobile-used high-temperature resistant isolated film manufacturing method, it is characterised in that:The isolation film by following component material system :5-15 parts of Corvic, 5-10 parts of epoxy resin, 3-8 parts of diethyl phosphite, 2-6 parts of polyethylene glycol, titanium dioxide 5-20 parts of silicon, 3-10 parts of calcium oxide, 2-5 parts of potassium bichromate, 1-4 parts of nickel oxide;
S1, silica, calcium oxide, potassium bichromate and nickel oxide are uniformly mixed, is heated, obtain mixture A;
S2, by mixture A carry out cooling treatment, by Corvic, epoxy resin, diethyl phosphite and polyethylene glycol into The uniform mixing of row, heat treatment obtain mixture B;
S3, mixture B is placed in extruser mixing extrusion, obtains extruded stock;
S4, extruded stock is subjected to the isolation film that is heating and curing to obtain.
2. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:In the step 0.05-0.2 parts of 0.1-0.5 parts of plant essence and zwitterionic surfactant can be added in S2.
3. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 2, it is characterised in that:The plant is fragrant Smart is preferably jasmine flower essence or orchid compound.
4. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:In the step Heat treatment in S1 is divided into be heat-treated twice, and the temperature of heat treatment is 500-800 DEG C for the first time, and second of heat treatment temperature is 800-1200℃。
5. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:In the step It needs to be cooled down in the environment of 100-200 DEG C in S2, needs to be filled with inert gas in the environment while cooling.
6. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:In the step Heat treatment temperature in S2 is 100-120 DEG C.
7. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:The isolation film Thickness be 0.2-0.8 ㎜.
8. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:The isolation film It is made by the material of following component:5 parts of Corvic, 10 parts of epoxy resin, 3 parts of diethyl phosphite, polyethylene glycol 6 Part, 5 parts of silica, 10 parts of calcium oxide, 2 parts of potassium bichromate, 4 parts of nickel oxide.
9. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:The isolation film It is made by the material of following component:15 parts of Corvic, 5 parts of epoxy resin, 8 parts of diethyl phosphite, polyethylene glycol 2 Part, 20 parts of silica, 3 parts of calcium oxide, 5 parts of potassium bichromate, 1 part of nickel oxide.
10. a kind of automobile-used high-temperature resistant isolated film manufacturing method according to claim 1, it is characterised in that:The isolation Film is made by the material of following component:10 parts of Corvic, 8 parts of epoxy resin, 5 parts of diethyl phosphite, polyethylene glycol 4 parts, 2 parts of silica 1,6 parts of calcium oxide, 3.5 parts of potassium bichromate, 2.5 parts of nickel oxide.
CN201810050933.XA 2018-01-19 2018-01-19 A kind of automobile-used high-temperature resistant isolated film manufacturing method Pending CN108250618A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1951985A (en) * 2006-10-20 2007-04-25 南京工业大学 Transparent heat-insulating film and its preparing process
CN104945642A (en) * 2014-03-11 2015-09-30 康拉德霍恩舒赫公司 Method for making a breathable film
CN105086237A (en) * 2015-08-12 2015-11-25 宁波申山新材料科技有限公司 Self-cleaning automobile paint surface film and preparation method thereof
CN107298816A (en) * 2017-08-18 2017-10-27 苏州卡佩罗尔高分子材料有限公司 One kind has high water-disintegrable thin-film material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1951985A (en) * 2006-10-20 2007-04-25 南京工业大学 Transparent heat-insulating film and its preparing process
CN104945642A (en) * 2014-03-11 2015-09-30 康拉德霍恩舒赫公司 Method for making a breathable film
CN105086237A (en) * 2015-08-12 2015-11-25 宁波申山新材料科技有限公司 Self-cleaning automobile paint surface film and preparation method thereof
CN107298816A (en) * 2017-08-18 2017-10-27 苏州卡佩罗尔高分子材料有限公司 One kind has high water-disintegrable thin-film material

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