CN108249882A - A kind of new modified graphite external-wall heat-insulation material and preparation method thereof - Google Patents
A kind of new modified graphite external-wall heat-insulation material and preparation method thereof Download PDFInfo
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- CN108249882A CN108249882A CN201810272474.XA CN201810272474A CN108249882A CN 108249882 A CN108249882 A CN 108249882A CN 201810272474 A CN201810272474 A CN 201810272474A CN 108249882 A CN108249882 A CN 108249882A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
Abstract
The present invention provides a kind of new modified graphite external-wall heat-insulation materials and preparation method thereof, the thermal insulation material is using modified graphite as base-material, add aeroge, waterglass, graphite polystyrene, metal component, anion filler, YAG powder, continuous carbon fibre, aluminosilicate fiber cotton, interface modifier, accelerating agent, water-repellent agent, magnalium mixture simultaneously, by heating, being molded, the processes such as being ultrasonically treated, thermal insulation material is made.Wherein, since modified graphite is inorganic material, have and be not easy to be ignited, combustion process can discharge pernicious gas.Meanwhile and be added to continuous carbon fibre, aluminosilicate fiber cotton and can improve the heat-insulating property of thermal insulation material, reduce thermal conductivity factor.Meet China's building energy conservation requirement, and Current Building ' energy saving igniter requirement can be met.
Description
Technical field
The invention belongs to thermal insulation material technical fields, and in particular, to a kind of new modified graphite external-wall heat-insulation material and
Preparation method.
Background technology
With the fast development of industry, building energy consumption is especially big, accounts for about the 11-25% of total energy consumption, at present effective side
Method is exactly to use heat insulating energy saving material.
The organic heat-insulatings materials such as polyurethane rigid foam plastic plate, polystyrol plastic foam plate or phenolic foam plate
Material, because its thermal and insulating performance is excellent, has obtained relatively broad application in building heat preservation engineering.But polyurethane foam is fatal
Weakness be exactly that combustibility is poor, be easily ignited, and combustion process can discharge pernicious gas;And cement insulation board, expansion
The inorganic heat insulation materials such as pearlite heat-insulation plate or inorganic material package polyphenylene granule heat-insulating plate, although combustibility point can be reached
The A grade incombustible materials standard requirement of grade, more universal application has also been obtained in building field, but due to its heat insulation property
Can be less than organic insulation material, thermal conductivity factor is 1.5-2 times of organic insulation material, and thermal conductivity factor is bigger, and heat-insulating property is poorer.
And its density it is big, from great.With stepping up for China's building energy conservation requirement, tend not to meet Current Building ' energy-saving design
Standard requirement.
In order to overcome above-mentioned deficiency, need to research and develop a kind of new modified graphite external-wall heat-insulation material and preparation method thereof.
Invention content
For the defects in the prior art, the object of the present invention is to provide a kind of new modified graphite external-wall heat-insulation material and
Preparation method.
According to a kind of new modified graphite external-wall heat-insulation material provided by the invention, the new modified graphite exterior wall is protected
Adiabator includes the raw material of following parts by weight:41-62 parts of modified graphite, 5-13 parts of aeroge, 2-5 parts of waterglass, graphite gather
2-7 parts of styrene, 2-6 parts of metal component, 9-15 parts of anion filler, 3-13 parts of YAG powder, continuous carbon fibre 7-
14 parts, 3-7 parts of aluminosilicate fiber cotton, 1.2-2.4 parts of interface modifier, 2.1-3.6 parts of accelerating agent, 1.2-3.1 parts of water-repellent agent, aluminium
2-7 parts of magnesium compound.
Preferably, the new modified graphite external-wall heat-insulation material includes the raw material of following parts by weight:Modified graphite
41-52 parts, 6-13 parts of aeroge, 3-5 parts of waterglass, 3-7 parts of graphite polystyrene, 4-6 parts of metal component, anion filler
11-15 parts, 7-13 parts of YAG powder, 8-14 parts of continuous carbon fibre, 4-7 parts of aluminosilicate fiber cotton, interface modifier
1.9-2.4 parts, 2.5-3.6 parts of accelerating agent, 1.8-3.1 parts of water-repellent agent, 3-7 parts of magnalium mixture.
Preferably, the new modified graphite external-wall heat-insulation material includes the raw material of following parts by weight:Modified graphite
44 parts, 13 parts of aeroge, 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, 13 parts of anion filler, yttroalumite pomegranate
8 parts of mountain flour body, 12 parts of continuous carbon fibre, 5 parts of aluminosilicate fiber cotton, 2.1 parts of interface modifier, 2.7 parts of accelerating agent, water-repellent agent
2.3 parts, 4 parts of magnalium mixture.
Preferably, the metal component is copper, aluminium, manganese, nickel, iron and tin, the copper, aluminium, manganese, nickel, iron and tin weight
Number matches:7-21 parts of 2-5 parts of copper, 3-11 parts of aluminium, 1-6 parts of manganese, 3-7 parts of nickel, 3-14 parts of iron and tin.
Preferably, the anion filler is tourmaline particle.
Preferably, the magnalium mixture is magnesia, aluminium oxide, alundum (Al2O3), magnesium hydroxide, aluminium hydroxide.
A kind of preparation method of new modified graphite external-wall heat-insulation material, includes the following steps:
Step 1: aluminosilicate fiber cotton and water are configured to the aluminosilicate fiber cotton solution of mass content 10-15%;
Step 2: modified graphite and anion filler are added in aluminosilicate fiber cotton solution, 65-70 DEG C is heated to, and at this
At a temperature of stir process 65-75min, then add in interface modifier, accelerating agent, water-repellent agent and aeroge, stirred at 85-90 DEG C
Processing 25-30min is mixed, is down to 40-55 DEG C, adds in 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, yttroalumite pomegranate
8 parts of mountain flour body, 12 parts of continuous carbon fibre, magnalium mixture, after stirring evenly, carry out supersound process 1.5-2.5h, and mixing is made
Material;
Step 3: mixed material is placed in building materials panel moulding apparatus, it is compound through hot pressing.
Preferably, ultrasonic power is 800-1000W in the step 2, and being molded built-in temperature in the step 3 is set as
80-150℃。
Compared with prior art, the present invention has following advantageous effect:
1st, a kind of new modified graphite external-wall heat-insulation material provided by the invention, thermal insulation material of the invention is using modified graphite as base
Material, while add aeroge, waterglass, graphite polystyrene, metal component, anion filler, YAG powder, continuous
Carbon fiber, aluminosilicate fiber cotton, interface modifier, accelerating agent, water-repellent agent, magnalium mixture, by heating, being molded, at ultrasound
Thermal insulation material is made in the processes such as reason.Wherein, since modified graphite is inorganic material, have and be not easy to be ignited, combustion process can be released
Pernicious gas is put, overcoming polyurethane rigid foam plastic plate, polystyrol plastic foam plate or phenolic foam plate etc. has
The flammable deficiency of machine thermal insulation material.Meanwhile it and is added to continuous carbon fibre, aluminosilicate fiber cotton and can improve thermal insulation material
Heat-insulating property, reduce thermal conductivity factor.Meet China's building energy conservation requirement, and Current Building ' energy saving igniter can be met and wanted
It asks.
2nd, a kind of new modified graphite external-wall heat-insulation material provided by the invention, anion filler-tourmaline in formula
The effects that particle has and adjusts human body ionic equilibrium effect, can loosen body and mind, activating cell, raising nature cure rate, by it
It is added in the formula of thermal insulation material and makes external-wall heat-insulation material, the living environment of indoor resident population can be improved, promote health.
3rd, a kind of new modified graphite external-wall heat-insulation material provided by the invention, the new modified graphite external-wall heat-insulation material yttrium aluminium
Garnet powder, magnalium mixture not only with superior heat insulation effect, while have good compression strength and the tension strong
Degree, service life are long.
Specific embodiment
With reference to specific embodiment, the present invention is further explained.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.
Embodiment 1
A kind of new modified graphite external-wall heat-insulation material provided in this embodiment, the new modified graphite external-wall heat-insulation material
Include the raw material of following parts by weight:62 parts of modified graphite, 5 parts of aeroge, 5 parts of waterglass, 2 parts of graphite polystyrene, metal
6 parts of ingredient, 9 parts of anion filler, 13 parts of YAG powder, 7 parts of continuous carbon fibre, 7 parts of aluminosilicate fiber cotton, interface change
1.2 parts of agent of property, 3.6 parts of accelerating agent, 1.2 parts of water-repellent agent, 7 parts of magnalium mixture.
Preferably, the metal component be copper, aluminium, manganese, nickel, iron and tin, the copper, aluminium, manganese, nickel, iron and tin
Parts by weight proportioning be:7 parts of 5 parts of copper, 3 parts of aluminium, 6 parts of manganese, 3 parts of nickel, 14 parts of iron and tin.
Preferably, the anion filler is tourmaline particle.
Preferably, the magnalium mixture is magnesia, aluminium oxide, alundum (Al2O3), magnesium hydroxide, hydroxide
Aluminium.
A kind of preparation method of new modified graphite external-wall heat-insulation material, includes the following steps:
Step 1: aluminosilicate fiber cotton and water are configured to the aluminosilicate fiber cotton solution of mass content 15%;
Step 2: modified graphite and anion filler are added in aluminosilicate fiber cotton solution, 70 DEG C are heated to, and in the temperature
Then lower stir process 65min adds in interface modifier, accelerating agent, water-repellent agent and aeroge, the stir process at 90 DEG C
25min is down to 55 DEG C, adds in 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, 8 parts of YAG powder, connects
Continuous 12 parts of carbon fiber, magnalium mixture, after stirring evenly, carry out supersound process 2.5h, and mixed material is made;
Step 3: mixed material is placed in building materials panel moulding apparatus, it is compound through hot pressing.
Preferably, ultrasonic power is 1000W in the step 2, and built-in temperature setting is molded in the step 3
It is 150 DEG C.
Embodiment 2
A kind of new modified graphite external-wall heat-insulation material provided in this embodiment, the new modified graphite external-wall heat-insulation material
Include the raw material of following parts by weight:41 parts of modified graphite, 13 parts of aeroge, 2 parts of waterglass, 7 parts of graphite polystyrene, metal
2 parts of ingredient, 15 parts of anion filler, 3 parts of YAG powder, 14 parts of continuous carbon fibre, 3 parts of aluminosilicate fiber cotton, interface
2.4 parts of modifying agent, 2.1 parts of accelerating agent, 3.1 parts of water-repellent agent, 2 parts of magnalium mixture.
Preferably, the metal component be copper, aluminium, manganese, nickel, iron and tin, the copper, aluminium, manganese, nickel, iron and tin
Parts by weight proportioning be:21 parts of 2 parts of copper, 11 parts of aluminium, 1 part of manganese, 7 parts of nickel, 3 parts of iron and tin.
Preferably, the anion filler is tourmaline particle.
Preferably, the magnalium mixture is magnesia, aluminium oxide, alundum (Al2O3), magnesium hydroxide, hydroxide
Aluminium.
A kind of preparation method of new modified graphite external-wall heat-insulation material, includes the following steps:
Step 1: aluminosilicate fiber cotton and water are configured to the aluminosilicate fiber cotton solution of mass content 13%;
Step 2: modified graphite and anion filler are added in aluminosilicate fiber cotton solution, 70 DEG C are heated to, and in the temperature
Then lower stir process 75min adds in interface modifier, accelerating agent, water-repellent agent and aeroge, the stir process at 90 DEG C
30min is down to 55 DEG C, adds in 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, 8 parts of YAG powder, connects
Continuous 12 parts of carbon fiber, magnalium mixture, after stirring evenly, carry out supersound process 2.5h, and mixed material is made;
Step 3: mixed material is placed in building materials panel moulding apparatus, it is compound through hot pressing.
Preferably, ultrasonic power is 1000W in the step 2, and built-in temperature setting is molded in the step 3
It is 150 DEG C.
Embodiment 3
A kind of new modified graphite external-wall heat-insulation material provided in this embodiment, the new modified graphite external-wall heat-insulation material
Include the raw material of following parts by weight:52 parts of modified graphite, 6 parts of aeroge, 5 parts of waterglass, 3 parts of graphite polystyrene, metal
6 parts of ingredient, 11 parts of anion filler, 13 parts of YAG powder, 8 parts of continuous carbon fibre, 7 parts of aluminosilicate fiber cotton, interface
1.9 parts of modifying agent, 3.6 parts of accelerating agent, 1.8 parts of water-repellent agent, 7 parts of magnalium mixture.
Preferably, the metal component be copper, aluminium, manganese, nickel, iron and tin, the copper, aluminium, manganese, nickel, iron and tin
Parts by weight proportioning be:21 parts of 5 parts of copper, 11 parts of aluminium, 6 parts of manganese, 7 parts of nickel, 14 parts of iron and tin.
Preferably, the anion filler is tourmaline particle.
Preferably, the magnalium mixture is magnesia, aluminium oxide, alundum (Al2O3), magnesium hydroxide, hydroxide
Aluminium.
A kind of preparation method of new modified graphite external-wall heat-insulation material, includes the following steps:
Step 1: aluminosilicate fiber cotton and water are configured to the aluminosilicate fiber cotton solution of mass content 15%;
Step 2: modified graphite and anion filler are added in aluminosilicate fiber cotton solution, 70 DEG C are heated to, and in the temperature
Then lower stir process 75min adds in interface modifier, accelerating agent, water-repellent agent and aeroge, the stir process at 90 DEG C
30min is down to 55 DEG C, adds in 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, 8 parts of YAG powder, connects
Continuous 12 parts of carbon fiber, magnalium mixture, after stirring evenly, carry out supersound process 2.5h, and mixed material is made;
Step 3: mixed material is placed in building materials panel moulding apparatus, it is compound through hot pressing.
Preferably, ultrasonic power is 1000W in the step 2, and built-in temperature setting is molded in the step 3
It is 150 DEG C.
Embodiment 4
A kind of new modified graphite external-wall heat-insulation material provided in this embodiment, the new modified graphite external-wall heat-insulation material
Include the raw material of following parts by weight:41 parts of modified graphite, 13 parts of aeroge, 3 parts of waterglass, 7 parts of graphite polystyrene, metal
4 parts of ingredient, 15 parts of anion filler, 7 parts of YAG powder, 14 parts of continuous carbon fibre, 4 parts of aluminosilicate fiber cotton, interface
2.4 parts of modifying agent, 2.5 parts of accelerating agent, 3.1 parts of water-repellent agent, 3 parts of magnalium mixture.
Preferably, the metal component be copper, aluminium, manganese, nickel, iron and tin, the copper, aluminium, manganese, nickel, iron and tin
Parts by weight proportioning be:21 parts of 5 parts of copper, 11 parts of aluminium, 6 parts of manganese, 7 parts of nickel, 14 parts of iron and tin.
Preferably, the anion filler is tourmaline particle.
Preferably, the magnalium mixture is magnesia, aluminium oxide, alundum (Al2O3), magnesium hydroxide, hydroxide
Aluminium.
A kind of preparation method of new modified graphite external-wall heat-insulation material, includes the following steps:
Step 1: aluminosilicate fiber cotton and water are configured to the aluminosilicate fiber cotton solution of mass content 15%;
Step 2: modified graphite and anion filler are added in aluminosilicate fiber cotton solution, 70 DEG C are heated to, and in the temperature
Then lower stir process 75min adds in interface modifier, accelerating agent, water-repellent agent and aeroge, the stir process at 90 DEG C
30min is down to 55 DEG C, adds in 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, 8 parts of YAG powder, connects
Continuous 12 parts of carbon fiber, magnalium mixture, after stirring evenly, carry out supersound process 2.5h, and mixed material is made;
Step 3: mixed material is placed in building materials panel moulding apparatus, it is compound through hot pressing.
Preferably, ultrasonic power is 1000W in the step 2, and built-in temperature setting is molded in the step 3
It is 150 DEG C.
Embodiment 5
A kind of new modified graphite external-wall heat-insulation material provided in this embodiment, the new modified graphite external-wall heat-insulation material
Include the raw material of following parts by weight:44 parts of modified graphite, 13 parts of aeroge, 4 parts of waterglass, 4 parts of graphite polystyrene, metal
5 parts of ingredient, 13 parts of anion filler, 8 parts of YAG powder, 12 parts of continuous carbon fibre, 5 parts of aluminosilicate fiber cotton, interface
2.1 parts of modifying agent, 2.7 parts of accelerating agent, 2.3 parts of water-repellent agent, 4 parts of magnalium mixture.
Preferably, the metal component be copper, aluminium, manganese, nickel, iron and tin, the copper, aluminium, manganese, nickel, iron and tin
Parts by weight proportioning be:7 parts of 2 parts of copper, 3 parts of aluminium, 1 part of manganese, 3 parts of nickel, 3 parts of iron and tin.
Preferably, the anion filler is tourmaline particle.
Preferably, the magnalium mixture is magnesia, aluminium oxide, alundum (Al2O3), magnesium hydroxide, hydroxide
Aluminium.
A kind of preparation method of new modified graphite external-wall heat-insulation material, includes the following steps:
Step 1: aluminosilicate fiber cotton and water are configured to the aluminosilicate fiber cotton solution of mass content 10%;
Step 2: modified graphite and anion filler are added in aluminosilicate fiber cotton solution, 65 DEG C are heated to, and in the temperature
Then lower stir process 75min adds in interface modifier, accelerating agent, water-repellent agent and aeroge, the stir process at 85 DEG C
30min is down to 40 DEG C, adds in 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, 8 parts of YAG powder, connects
Continuous 12 parts of carbon fiber, magnalium mixture, after stirring evenly, carry out supersound process 1.5h, and mixed material is made;
Step 3: mixed material is placed in building materials panel moulding apparatus, it is compound through hot pressing.
Preferably, ultrasonic power is 800W in the step 2, and built-in temperature setting is molded in the step 3
It is 80 DEG C.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of new modified graphite external-wall heat-insulation material, it is characterised in that:The new modified graphite external-wall heat-insulation material
Include the raw material of following parts by weight:41-62 parts of modified graphite, 5-13 parts of aeroge, 2-5 parts of waterglass, graphite polystyrene
2-7 parts, 2-6 parts of metal component, 9-15 parts of anion filler, 3-13 parts of YAG powder, 7-14 parts of continuous carbon fibre, silicon
Sour 3-7 parts of aluminum fiber cotton, 1.2-2.4 parts of interface modifier, 2.1-3.6 parts of accelerating agent, 1.2-3.1 parts of water-repellent agent, magnalium mixing
2-7 parts of object.
2. a kind of new modified graphite external-wall heat-insulation material according to claim 1, it is characterised in that:It is described novel to change
Property graphite external-wall heat-insulation material includes the raw material of following parts by weight:41-52 parts of modified graphite, 6-13 parts of aeroge, waterglass
3-5 parts, 3-7 parts of graphite polystyrene, 4-6 parts of metal component, 11-15 parts of anion filler, 7-13 parts of YAG powder,
8-14 parts of continuous carbon fibre, 4-7 parts of aluminosilicate fiber cotton, 1.9-2.4 parts of interface modifier, 2.5-3.6 parts of accelerating agent, water-repellent agent
1.8-3.1 parts, 3-7 parts of magnalium mixture.
3. a kind of new modified graphite external-wall heat-insulation material according to claim 1, it is characterised in that:It is described novel to change
Property graphite external-wall heat-insulation material includes the raw material of following parts by weight:44 parts of modified graphite, 13 parts of aeroge, 4 parts of waterglass, stone
Black 4 parts of polystyrene, 5 parts of metal component, 13 parts of anion filler, 8 parts of YAG powder, 12 parts of continuous carbon fibre, silicon
Sour 5 parts of aluminum fiber cotton, 2.1 parts of interface modifier, 2.7 parts of accelerating agent, 2.3 parts of water-repellent agent, 4 parts of magnalium mixture.
4. a kind of new modified graphite external-wall heat-insulation material according to claim 1, it is characterised in that:The metal component
For copper, aluminium, manganese, nickel, iron and tin, the copper, aluminium, manganese, nickel, iron and tin parts by weight proportioning be:2-5 parts of copper, 3-11 parts of aluminium,
7-21 parts of 1-6 parts of manganese, 3-7 parts of nickel, 3-14 parts of iron and tin.
5. a kind of new modified graphite external-wall heat-insulation material according to claim 1, it is characterised in that:The anion is filled out
Expect for tourmaline particle.
6. a kind of new modified graphite external-wall heat-insulation material according to claim 5, it is characterised in that:The magnalium mixing
Object is magnesia, aluminium oxide, alundum (Al2O3), magnesium hydroxide, aluminium hydroxide.
7. such as a kind of preparation method of new modified graphite external-wall heat-insulation material of claim 1-6 any one of them, feature
It is:Include the following steps:
Step 1: aluminosilicate fiber cotton and water are configured to the aluminosilicate fiber cotton solution of mass content 10-15%;
Step 2: modified graphite and anion filler are added in aluminosilicate fiber cotton solution, 65-70 DEG C is heated to, and at this
At a temperature of stir process 65-75min, then add in interface modifier, accelerating agent, water-repellent agent and aeroge, stirred at 85-90 DEG C
Processing 25-30min is mixed, is down to 40-55 DEG C, adds in 4 parts of waterglass, 4 parts of graphite polystyrene, 5 parts of metal component, yttroalumite pomegranate
8 parts of mountain flour body, 12 parts of continuous carbon fibre, magnalium mixture, after stirring evenly, carry out supersound process 1.5-2.5h, and mixing is made
Material;
Step 3: mixed material is placed in building materials panel moulding apparatus, it is compound through hot pressing.
8. a kind of preparation method of new modified graphite external-wall heat-insulation material according to claim 7, it is characterised in that:Institute
It is 800-1000W to state ultrasonic power in step 2, and being molded built-in temperature in the step 3 is set as 80-150 DEG C.
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CN107572938A (en) * | 2017-10-19 | 2018-01-12 | 江苏绿悦保温材料有限公司 | A kind of modified graphite aeroge self-insulation wall material |
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CN106396535A (en) * | 2016-08-26 | 2017-02-15 | 安庆市金鹰新型建材科技股份有限公司 | Building external wall thermal insulation material and preparation method thereof |
CN106904889A (en) * | 2017-03-13 | 2017-06-30 | 上海浦东易祥保温材料有限公司 | A kind of inorganic modified graphite polystyrene fire-retardant heat insulation plate and preparation method thereof |
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