CN108226245B - Method for detecting corrosion resistance of 304 stainless steel under high temperature condition - Google Patents
Method for detecting corrosion resistance of 304 stainless steel under high temperature condition Download PDFInfo
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- CN108226245B CN108226245B CN201810046391.9A CN201810046391A CN108226245B CN 108226245 B CN108226245 B CN 108226245B CN 201810046391 A CN201810046391 A CN 201810046391A CN 108226245 B CN108226245 B CN 108226245B
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- 238000005260 corrosion Methods 0.000 title claims abstract description 23
- 239000010963 304 stainless steel Substances 0.000 title claims abstract description 22
- 230000007797 corrosion Effects 0.000 title claims abstract description 22
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 18
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 101
- 239000010959 steel Substances 0.000 claims abstract description 101
- 239000000919 ceramic Substances 0.000 claims abstract description 31
- 238000007789 sealing Methods 0.000 claims abstract description 20
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 238000001228 spectrum Methods 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 14
- 239000000084 colloidal system Substances 0.000 claims description 12
- 239000010935 stainless steel Substances 0.000 claims description 10
- 229910001220 stainless steel Inorganic materials 0.000 claims description 10
- 239000004744 fabric Substances 0.000 claims description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
- -1 polytetrafluoroethylene Polymers 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 8
- 238000013461 design Methods 0.000 claims description 6
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical group [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 238000002791 soaking Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000002848 electrochemical method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- G01—MEASURING; TESTING
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- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
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Abstract
The invention discloses a method for detecting the corrosion resistance of 304 stainless steel under high temperature, which comprises the steps of installing an electrode system in a high-temperature high-pressure reaction kettle, and measuring the electrochemical noise spectrum of the 304 stainless steel in 1500ppmH3BO3+2.3ppmLiOH aqueous solution by using an Autolab302N electrochemical workstation, wherein the electrode system comprises a working electrode device and a reference-counter electrode device; the upper end of the working electrode device is provided with an upper screw structure, the lower end of the working electrode device is provided with a lower screw structure, a wiring rod is arranged in the steel pipe, a first screw cap, a second screw cap and a third screw cap are arranged on the steel pipe at one time, the lower end of the wiring rod is connected with a working electrode sample, a reference electrode and a counter electrode are arranged in the reference-counter electrode device, an upper insulating layer, an upper sealing layer, a double-hole ceramic plate, a lower sealing layer and a lower insulating layer are sequentially arranged in the steel pipe from top to bottom, an upper fastening nut is arranged at the upper end of the steel pipe, and a lower fastening; the corrosion resistance of the 304 stainless steel is continuously reduced along with the temperature increase under the condition of 25-250 ℃.
Description
The invention relates to a divisional application of a parent application 'an electrode system for electrochemical measurement in high-temperature and high-pressure water environment and application thereof', wherein the application date of the parent application is 2016, 7 and 22 days, and the application number of the parent application is 2016105993363.
Technical Field
The invention belongs to the technical field of electrochemical electrode materials, and particularly relates to a method for detecting the corrosion resistance of 304 stainless steel under a high-temperature condition.
Background
The special sensor which can resist high temperature, high pressure and corrosion is a high-technology product of various high and new scientific technologies including advanced high-temperature materials science, precision machining, electronics, fine chemistry and the like. The sensor which can work in the harsh environment of high temperature, high pressure and strong corrosion has great production difficulty. Since there has been no domestic progress in developing the key technology for such sensors, import has been relied upon almost entirely for many years. In the fields of petroleum, chemical industry, nuclear energy and the like, a plurality of important processes must be implemented in high-temperature and high-pressure and strong-corrosion environments.
Disclosure of Invention
The invention overcomes the defects in the prior art and provides an electrode system for electrochemical measurement in a high-temperature and high-pressure water environment and application thereof.
In order to solve the technical problems, the invention is realized by the following technical scheme:
an electrode system for corrosion resistance detection of 304 stainless steel comprises a working electrode device and a reference-counter electrode device;
the working electrode device is characterized in that the main body of the working electrode device is a steel pipe, an upper screw structure is arranged at the upper end of the steel pipe, a lower screw structure is arranged at the lower end of the steel pipe and is used for fixing a wiring rod in cooperation with a screw cap, the interior of the steel pipe is hollow, the wiring rod is arranged in the steel pipe, two ends of the wiring rod extend out of the steel pipe, an upper sleeve is arranged at the position extending out of the steel pipe above the wiring rod, a lower sleeve is arranged at the position extending out of the steel pipe below the wiring rod, the upper sleeve and the lower sleeve are clamped between the wiring rod and the steel pipe and are used for fixing and sealing, the whole part of the wiring rod, which is positioned in the steel pipe, is wrapped by a layer of insulating cloth, a first screw cap is arranged at the upper end of the upper screw structure of the steel pipe and is sleeved on the wiring rod and is in threaded connection with the upper screw structure, a clamp and a second screw cap are, the lower end of the lower screw structure is provided with a third screw cap, the lower end of the third screw cap is provided with a conical groove, the part of the wiring rod extending out of the third screw cap is connected with a working electrode sample, and a conical sleeve is arranged at the joint of the working electrode sample and the third screw cap;
in the technical scheme, the steel pipe of the working electrode device is 316L stainless steel, the inner diameter of the steel pipe is 2.5-3.5mm, the outer diameter of the steel pipe is 6-8mm, and the length of the steel pipe is 150-250 mm.
In the technical scheme, the wire connecting rod is 316L stainless steel, the diameter is 2-5mm, and the length is 250-350 mm.
In the technical scheme, the insulating cloth is glass fiber insulating cloth.
The outer layer of the reference-counter electrode device is a steel pipe, the inside of the steel pipe is hollow, a reference electrode and a counter electrode are arranged inside the steel pipe, the reference electrode is connected with a reference electrode connecting lead, the upper end of the reference electrode extends out of the upper edge of the steel pipe, the lower end of the reference electrode connecting lead extends out of the lower edge of the steel pipe, the counter electrode is connected with a counter electrode connecting lead, the upper end of the counter electrode extends out of the upper edge of the steel pipe, the lower end of the counter electrode connecting lead extends out of the lower edge of the steel pipe, the reference electrode and the connecting lead thereof, the counter electrode and the connecting lead thereof are arranged in parallel with the outer wall of the steel pipe and are not contacted with each other, an upper insulating layer, an upper sealing layer, a double-hole ceramic plate;
in the above technical solution, the steel tube of the reference-counter electrode device is a 316L stainless steel tube, the inner diameter of the steel tube is 8-10mm, the outer diameter is 12-14mm, and the length is 350-450 mm.
In the technical scheme, the number of the double-hole ceramic plates is 8-15, and the thickness of the double-hole ceramic plates is 1-2 cm.
In the technical scheme, the reference electrode is a silver chloride wire, and the counter electrode is a platinum sheet.
In the above technical scheme, the upper insulating layer is a polytetrafluoroethylene layer, and the lower insulating layer is a polytetrafluoroethylene layer.
In the above technical scheme, the upper sealing layer is a ceramic powder colloid layer, and the lower sealing layer is a ceramic powder colloid layer.
A preparation method of an electrode system for detecting the corrosion resistance of 304 stainless steel comprises the following steps:
step 1: assembling the working electrode according to the structure of the working electrode device;
step 2: putting the reference electrode and the connecting lead thereof, the counter electrode and the connecting lead thereof into the steel pipe, and keeping the reference electrode and the connecting lead thereof not in contact with each other;
and step 3: sleeving 8-15 double-hole ceramic plates on the reference electrode and the counter electrode and clamping the double-hole ceramic plates on the inner wall of the steel pipe to enable the double-hole ceramic plates to be positioned in the middle of the steel pipe body;
and 4, step 4: mixing ceramic powder and water according to the mass ratio (3-5): 1, uniformly mixing and stirring, and pouring the mixture into a steel pipe from the upper part and the lower part of the steel pipe to form a ceramic powder colloid layer with a certain thickness;
and 5: filling polytetrafluoroethylene columns into gaps among the reference electrode, the counter electrode and the inner wall of the steel pipe from the upper part and the lower part of the steel pipe, pressing the ceramic powder colloid layer and keeping sealing;
step 6: and screwing up the fastening nut at the upper end of the steel pipe, screwing down the fastening nut at the lower end of the steel pipe, and standing the whole device at room temperature (20-25 ℃) for 20-30 hours to solidify the ceramic powder colloid.
Compared with the prior art, the invention has the beneficial effects that: the device is suitable for laboratories, can simulate the environment of electrochemical measurement of a nuclear power station under the conditions of high temperature and high pressure, has the highest temperature range of 160-250 ℃ and the highest pressure range of 6-10 MPa in the working environment, has better sealing property, can meet the insulation requirement, and is simple to prepare, good in stability and convenient to use.
Drawings
FIG. 1 is a schematic diagram of the working electrode assembly of the present invention (shown with the left side being the top side).
FIG. 2 is a schematic diagram of the construction of a reference-counter electrode assembly according to the present invention.
FIG. 3 is a diagram of FIG. 1 according to an embodiment.
FIG. 4 is a diagram illustrating FIG. 2 according to an embodiment.
FIG. 5 is a diagram illustrating FIG. 3 according to an embodiment.
The device comprises a shell, a connector, a working electrode sample, a reference electrode, a counter electrode, a reference electrode, a counter electrode, an upper fastening nut, an upper insulating layer, an upper sealing layer, a reference electrode connecting lead, a counter electrode connecting lead, a double-hole ceramic chip, a lower sealing layer, a lower insulating layer, a lower sealing layer, a lower insulating layer and a lower fastening nut, wherein 1 is the upper sleeve, 2 is a first nut, 3 is an upper screw structure, 4 is a steel pipe, 5 is a connector rod, 6 is a second nut, 7 is a hoop, 8 is a lower screw structure, 9 is a lower sleeve, 10 is a third nut, 11.
Detailed Description
The invention is described in further detail below with reference to specific embodiments and with reference to the following figures:
an electrode system for corrosion resistance detection of 304 stainless steel comprises a working electrode device and a reference-counter electrode device;
the working electrode device is characterized in that the main body of the working electrode device is a steel pipe, an upper screw structure is arranged at the upper end of the steel pipe, a lower screw structure is arranged at the lower end of the steel pipe and is used for fixing a wiring rod in cooperation with a screw cap, the interior of the steel pipe is hollow, the wiring rod is arranged in the steel pipe, two ends of the wiring rod extend out of the steel pipe, an upper sleeve is arranged at the position extending out of the steel pipe above the wiring rod, a lower sleeve is arranged at the position extending out of the steel pipe below the wiring rod, the upper sleeve and the lower sleeve are clamped between the wiring rod and the steel pipe and are used for fixing and sealing, the whole part of the wiring rod, which is positioned in the steel pipe, is wrapped by a layer of insulating cloth, a first screw cap is arranged at the upper end of the upper screw structure of the steel pipe and is sleeved on the wiring rod and is in threaded connection with the upper screw structure, a clamp and a second screw cap are, the lower end of the lower screw structure is provided with a third screw cap, the lower end of the third screw cap is provided with a conical groove, the part of the wiring rod extending out of the third screw cap is connected with a working electrode sample, and a conical sleeve is arranged at the joint of the working electrode sample and the third screw cap;
in the technical scheme, the steel pipe of the working electrode device is 316L stainless steel, the inner diameter of the steel pipe is 2.5-3.5mm, the outer diameter of the steel pipe is 6-8mm, and the length of the steel pipe is 150-250 mm.
In the technical scheme, the wire connecting rod is 316L stainless steel, the diameter is 2-5mm, and the length is 250-350 mm.
In the technical scheme, the insulating cloth is glass fiber insulating cloth.
The outer layer of the reference-counter electrode device is a steel pipe, the inside of the steel pipe is hollow, a reference electrode and a counter electrode are arranged inside the steel pipe, the reference electrode is connected with a reference electrode connecting lead, the upper end of the reference electrode extends out of the upper edge of the steel pipe, the lower end of the reference electrode connecting lead extends out of the lower edge of the steel pipe, the counter electrode is connected with a counter electrode connecting lead, the upper end of the counter electrode extends out of the upper edge of the steel pipe, the lower end of the counter electrode connecting lead extends out of the lower edge of the steel pipe, the reference electrode and the connecting lead thereof, the counter electrode and the connecting lead thereof are arranged in parallel with the outer wall of the steel pipe and are not contacted with each other, an upper insulating layer, an upper sealing layer, a double-hole ceramic plate;
in the above technical solution, the steel tube of the reference-counter electrode device is a 316L stainless steel tube, the inner diameter of the steel tube is 8-10mm, the outer diameter is 12-14mm, and the length is 350-450 mm.
In the technical scheme, the number of the double-hole ceramic plates is 8-15, and the thickness of the double-hole ceramic plates is 1-2 cm.
In the technical scheme, the reference electrode is a silver chloride wire, and the counter electrode is a platinum sheet.
In the above technical scheme, the upper insulating layer is a polytetrafluoroethylene layer, and the lower insulating layer is a polytetrafluoroethylene layer.
In the technical scheme, a ceramic powder colloid layer is arranged in the upper sealing layer, and a ceramic powder colloid layer is arranged in the lower sealing layer.
The preparation method of the reference-counter electrode device comprises the following steps of selecting Duropot809 series developed by Cotronics in America, selecting silver chloride wires and platinum sheets from products of Tianjin Elastang Cheng scientific and technological development Limited, and preparing the reference-counter electrode device by the following steps:
step 1: assembling the working electrode according to the structure of the working electrode device;
step 2: putting the reference electrode and the connecting lead thereof, the counter electrode and the connecting lead thereof into the steel pipe, and keeping the reference electrode and the connecting lead thereof not in contact with each other;
and step 3: sleeving 8-15 double-hole ceramic plates on the reference electrode and the counter electrode and clamping the double-hole ceramic plates on the inner wall of the steel pipe to enable the double-hole ceramic plates to be positioned in the middle of the steel pipe body;
and 4, step 4: mixing ceramic powder and water according to the mass ratio (3-5): 1, uniformly mixing and stirring, and pouring the mixture into a steel pipe from the upper part and the lower part of the steel pipe to form a ceramic powder colloid layer with a certain thickness;
and 5: filling polytetrafluoroethylene columns into gaps among the reference electrode, the counter electrode and the inner wall of the steel pipe from the upper part and the lower part of the steel pipe, pressing the ceramic powder colloid layer and keeping sealing;
step 6: and screwing up the fastening nut at the upper end of the steel pipe, screwing down the fastening nut at the lower end of the steel pipe, and standing the whole device at room temperature (20-25 ℃) for 20-30 hours to solidify the ceramic powder colloid.
The following is illustrated by specific test examples:
the developed electrode measuring system is arranged in a high-temperature high-pressure reaction kettle (the design temperature is 350 ℃ and the design pressure is 25MPa), and the conditions of the 304 stainless steel at 1500ppmH under different temperatures and different soaking times are measured by using an Autolab302N electrochemical workstation3BO3Electrochemical noise spectra in aqueous solution of +2.3ppm LiOH. FIG. 3 is a graph of the stainless steel composition at 1500ppm H for 304 stainless steel3BO3In the normal-temperature soaking experiment of the aqueous solution of +2.3ppm LiOH, the noise resistance changes along with the time, and the noise resistance value tends to decrease along with the prolonging of the soaking time; the noise resistance tends to increase after the next day because uniform corrosion occurs at the initial stage of soaking and the noise resistance gradually increases as an oxide film is formed on the surface with the lapse of the soaking time. FIG. 4 shows the temperature of 304 stainless steel at 1500ppm H3BO3The noise resistance of +2.3ppm LiOH in aqueous solution as a function of time, it can be seen that the corrosion resistance of 304 stainless steel is decreasing with increasing temperature from 25-250 ℃.
As shown in FIG. 5, the developed electrode measuring system was installed in a high-temperature high-pressure reaction kettle (design temperature 350 ℃ C., design pressure 25MPa), and polarization curves of X65 pipeline steel in 3.5% wt. NaCl aqueous solution were measured at different pressures by using an Autolab302N electrochemical workstation. The calculated corrosion current density is 2.323 multiplied by 10 respectively when the pressure is 5MPa, 10MPa and 17MPa respectively-5A·cm-2、3.407×10-5A·cm-2And 8.723 × 10-5A·cm-2. The corrosion current density increased with increasing pressure, indicating that the corrosion rate of the X65 pipeline steel increased with increasing pressure.
The electrode system of the invention actually reflects the electrochemical performance change according to the above embodiment, which shows that the device has application prospect in high temperature (25-250 ℃ for 304 stainless steel) and high pressure (5-20 MPa for X65 pipeline steel).
The present invention has been described in detail, but the above description is only a preferred embodiment of the present invention, and is not to be construed as limiting the scope of the present invention. All equivalent changes and modifications made within the scope of the present invention shall fall within the scope of the present invention.
Claims (7)
1.304 stainless steel corrosion resistance's detection method, its characterized in that: the electrode system is arranged in a high-temperature high-pressure reaction kettle, and the 1500ppmH of the 304 stainless steel is measured by using an Autolab302N electrochemical workstation at the temperature of 25-250 DEG C3BO3+2.3ppm lioh of electrochemical noise spectrum in aqueous solution;
the electrode system comprises a working electrode arrangement and a reference-counter electrode arrangement;
the working electrode device is characterized in that the main body of the working electrode device is a steel pipe, an upper screw structure is arranged at the upper end of the steel pipe, a lower screw structure is arranged at the lower end of the steel pipe and is used for fixing a wiring rod in cooperation with a screw cap, the interior of the steel pipe is hollow, the wiring rod is arranged in the steel pipe, two ends of the wiring rod extend out of the steel pipe, an upper sleeve is arranged at the position extending out of the steel pipe above the wiring rod, a lower sleeve is arranged at the position extending out of the steel pipe below the wiring rod, the upper sleeve and the lower sleeve are clamped between the wiring rod and the steel pipe and are used for fixing and sealing, the whole part of the wiring rod, which is positioned in the steel pipe, is wrapped by a layer of insulating cloth, a first screw cap is arranged at the upper end of the upper screw structure of the steel pipe and is sleeved on the wiring rod and is in threaded connection with the upper screw structure, a clamp and a second screw cap are, the lower end of the lower screw structure is provided with a third screw cap, the lower end of the third screw cap is provided with a conical groove, the part of the wiring rod extending out of the third screw cap is connected with a working electrode sample, and a conical sleeve is arranged at the joint of the working electrode sample and the third screw cap;
the outer layer of the reference-counter electrode device is a steel pipe, the inside of the steel pipe is hollow, a reference electrode and a counter electrode are arranged inside the steel pipe, the reference electrode is connected with a reference electrode connecting lead, the upper end of the reference electrode extends out of the upper edge of the steel pipe, the lower end of the reference electrode connecting lead extends out of the lower edge of the steel pipe, the counter electrode is connected with a counter electrode connecting lead, the upper end of the counter electrode extends out of the upper edge of the steel pipe, the lower end of the counter electrode connecting lead extends out of the lower edge of the steel pipe, the reference electrode and the connecting lead thereof, the counter electrode and the connecting lead thereof are arranged in parallel with the outer wall of the steel pipe and are not in contact with each other, an upper insulating layer, an upper sealing layer, a double-hole ceramic.
2. The method for detecting the corrosion resistance of the 304 stainless steel according to claim 1, wherein the method comprises the following steps: the steel pipe of the working electrode device is 316L stainless steel, the inner diameter of the steel pipe is 2.5-3.5mm, the outer diameter is 6-8mm, the length is 150-350 mm, the wiring rod is 316L stainless steel, the diameter is 2-5mm, and the length is 250-350 mm.
3. The method for detecting the corrosion resistance of the 304 stainless steel according to claim 1, wherein the method comprises the following steps: the insulating cloth is glass fiber insulating cloth.
4. The method for detecting the corrosion resistance of the 304 stainless steel according to claim 1, wherein the method comprises the following steps: the steel pipe of the reference-counter electrode device is a 316L stainless steel pipe, the inner diameter of the steel pipe is 8-10mm, the outer diameter of the steel pipe is 12-14mm, the length of the steel pipe is 350-450mm, the number of the double-hole ceramic pieces is 8-15, and the thickness of the double-hole ceramic pieces is 1-2 cm.
5. The method for detecting the corrosion resistance of the 304 stainless steel according to claim 1, wherein the method comprises the following steps: the reference electrode is silver chloride wire, and the counter electrode is platinum sheet.
6. The method for detecting the corrosion resistance of the 304 stainless steel according to claim 1, wherein the method comprises the following steps: the upper insulating layer is a polytetrafluoroethylene layer, and the lower insulating layer is a polytetrafluoroethylene layer; the upper sealing layer is a ceramic powder colloid layer, and the lower sealing layer is a ceramic powder colloid layer.
7. The method for detecting the corrosion resistance of the 304 stainless steel according to claim 1, wherein the method comprises the following steps: the method is characterized in that: the design temperature of the high-temperature high-pressure reaction kettle is 350 ℃, and the design pressure is 25 MPa.
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| CN201810046391.9A CN108226245B (en) | 2016-07-22 | 2016-07-22 | Method for detecting corrosion resistance of 304 stainless steel under high temperature condition |
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| CN201810046391.9A CN108226245B (en) | 2016-07-22 | 2016-07-22 | Method for detecting corrosion resistance of 304 stainless steel under high temperature condition |
| CN201610599336.3A CN106018520B (en) | 2016-07-22 | 2016-07-22 | A kind of electrode system and its application for electrochemical measurement in high temperature and pressure water environment |
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| CN201810045901.0A Expired - Fee Related CN108387623B (en) | 2016-07-22 | 2016-07-22 | Method for detecting corrosion resistance of X65 pipeline steel |
| CN201810046391.9A Expired - Fee Related CN108226245B (en) | 2016-07-22 | 2016-07-22 | Method for detecting corrosion resistance of 304 stainless steel under high temperature condition |
| CN201610599336.3A Expired - Fee Related CN106018520B (en) | 2016-07-22 | 2016-07-22 | A kind of electrode system and its application for electrochemical measurement in high temperature and pressure water environment |
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| CN107462616A (en) * | 2017-07-13 | 2017-12-12 | 天津大学 | Suitable for the sensor of nuclear power high ambient temperature water under high pressure environment electrochemistry noise measurement |
| CN108956728A (en) * | 2018-07-04 | 2018-12-07 | 东南大学 | A kind of high temperature and pressure working electrode |
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2016
- 2016-07-22 CN CN201810045901.0A patent/CN108387623B/en not_active Expired - Fee Related
- 2016-07-22 CN CN201810046391.9A patent/CN108226245B/en not_active Expired - Fee Related
- 2016-07-22 CN CN201610599336.3A patent/CN106018520B/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| CN108226245A (en) | 2018-06-29 |
| CN108387623B (en) | 2020-02-18 |
| CN106018520B (en) | 2018-06-15 |
| CN106018520A (en) | 2016-10-12 |
| CN108387623A (en) | 2018-08-10 |
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