CN108226210A - A kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon - Google Patents

A kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon Download PDF

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CN108226210A
CN108226210A CN201810036010.9A CN201810036010A CN108226210A CN 108226210 A CN108226210 A CN 108226210A CN 201810036010 A CN201810036010 A CN 201810036010A CN 108226210 A CN108226210 A CN 108226210A
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carbon
stainless steel
experiment
compound
steel
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CN108226210B (en
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冯莹莹
余焕
骆宗安
吴庆林
张宏阁
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Northeastern University China
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N3/00Investigating strength properties of solid materials by application of mechanical stress
    • G01N3/08Investigating strength properties of solid materials by application of mechanical stress by applying steady tensile or compressive forces
    • G01N3/18Performing tests at high or low temperatures
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N3/00Investigating strength properties of solid materials by application of mechanical stress
    • G01N3/40Investigating hardness or rebound hardness
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2203/00Investigating strength properties of solid materials by application of mechanical stress
    • G01N2203/0014Type of force applied
    • G01N2203/0016Tensile or compressive
    • G01N2203/0019Compressive
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2203/00Investigating strength properties of solid materials by application of mechanical stress
    • G01N2203/0058Kind of property studied
    • G01N2203/0076Hardness, compressibility or resistance to crushing
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2203/00Investigating strength properties of solid materials by application of mechanical stress
    • G01N2203/02Details not specific for a particular testing method
    • G01N2203/022Environment of the test
    • G01N2203/0222Temperature
    • G01N2203/0226High temperature; Heating means

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Abstract

The present invention provides a kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon.The method of the present invention includes the following steps:Close nested combination after stainless-steel pipe is surface-treated with carbon steel rod;Thermocouple is welded in stainless steel tube outer surface;Bimetallic sample is placed between the collet in thermodynamic simulated experiment machine control box;Carry out high temperature compression and heat treatment experiment;Structure property analysis is carried out to the sample after experiment.The present invention, by changing thermal simulation experiment process program, completes the rolling mill practice simulation process of the compound Ribbed Bar of stainless steel/carbon using thermodynamic simulated experiment machine;And cooperation vacuum system, the problem of oxidation of bimetallic combination interface in experimentation is reduced, so as to ensure that the compound Ribbed Bar interfacial bonding property of stainless steel/carbon is good, organization and performance are met the requirements.The present invention has that preparation method is simple, of low cost, saves material, and repeatability is strong, and experiment purpose easily reaches, the advantages of comparatively fast more accurately finding related law.

Description

A kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon
Technical field
The invention belongs to metal material technical study technology and thermal simulation technical field more particularly to it is a kind of prepare it is stainless The heat simulation of the compound Ribbed Bar of steel/carbon steel.
Background technology
The construction of infrastructure and Important Project all be unable to do without a large amount of uses of reinforced concrete structure, and as coagulation The performance of the reinforcing bar of soil skeleton is increasingly concerned with quality.Especially as the quickening of national Urbanization Construction paces and the "Oceanic" strategy Proposition energetically, the demand of high strength anti-corrosion building bar will be increasing, and commonly used traditional reinforcing bar corrosion resistance Difference, easy-to-rust expansion, causes the easy premature failure of reinforced concrete structure, can not meet the requirement of building life, so as to society Cause huge economic loss.And in order to improve the solid stainless steel of steel bars corrosion problem research and development, because of noble metals such as chromium, nickel It is a large amount of to use, production cost is caused to greatly increase, application range is significantly limited, therefore has both saved money there is an urgent need to research and develop one kind Source reduces cost, and the reinforcing bar with good comprehensive performance.Then, the Research Thinking and technique of stainless steel/carbon composite reinforcing steel bar It comes into being.
Stainless steel/carbon composite reinforcing steel bar is a kind of new material, uses stainless steel to cover material, and carbon steel is core material, the two warp It crosses certain forming technology and obtains, this material combines the excellent corrosion resisting property of stainless steel and the good mechanicalness of carbon steel Can, requirement of the people to capital construction installation security and service life can be met significantly.In addition, stainless steel/carbon composite reinforcing steel bar exists Reduce the consumption of the noble metals such as chromium, nickel to a certain extent, production cost is greatly lowered, realize inexpensive and high performance Perfect adaptation as a kind of product for the type that economizes on resources, will possess good social benefit and economic benefit.
The high performance key factor of stainless steel/carbon composite reinforcing steel bar is interface cohesion situation, this is also that restriction is stainless An important factor for steel composite reinforcing steel bar industrialized production.Therefore, it is most important for the research of compound interface.At present to stainless steel double The research of reinforcing bar is closed, is limited primarily to laboratory research.Correlation seminar of University On The Mountain Of Swallows is by using stainless steel tube inner sleeve carbon steel rod It through drawing process, then will be rolled after the sealing of both ends, obtain compacting carbon steel bits in stainless steel composite muscle and stainless steel tube, then pass through Heating rolling is crossed into stainless steel composite muscle, finally carries out structure property analysis, find generally all to be unevenly distributed there are coating and The shortcomings that bond strength easily fluctuates by continuous adjusting process parameter, repeats hot rolling experiment, and then control structure property. Not only preparation process is complicated, but also wastes experiment material for this method, is not easy to reach experiment purpose;University of Science & Technology, Beijing is efficient Rolling National Engineering Research Centre researcher is welded into pipe, inner sleeve carbon steel rod, after its both ends is welded using stainless steel band Rolling, the shortcomings that obtaining stainless steel composite muscle, then carry out structure property analysis, easily fluctuated there is also above-mentioned interface performance;Its The performance that also all generally existing coating thickness is unevenly distributed and combination interface intensity is not high in his stainless steel composite muscle report lacks Fall into the objective deficiency with preparation process complexity.As it can be seen that there are some problems for composite reinforcing steel bar research, rolling mill practice is still in theory Stage lacks a kind of easy, low cost experimental study means, leads to the new material still without more mature industrial production Technique.
Invention content
According to set forth above for stainless steel composite muscle preparation process is complicated, the period is long, the technical problems such as of high cost, And provide a kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon.It is of the invention mainly to be rolled using Northeastern University Technology and the MMS series of heat simulated experiment machine (patent names of tandem rolling automation National Key Laboratory independent research:Multi-functional heat Power simulated experiment machine, the patent No.:ZL 201110100302.2), by the special-carrier for being specially threaded reinforcing rib slot, High temperature deformation and heat treatment are carried out to the bimetallic composite blank of different specification size, simulate stainless steel/carbon composite band rib steel The deformation process of muscle, and by the way that sample tissue performance evaluation after experimental data and experiment, hot-working is carried out according to experiment purpose Process optimization is adjusted with specimen size, so that it is determined that most suitable process program.
The technological means that the present invention uses is as follows:
A kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon, which is characterized in that include the following steps:
S1, raw material prepare:Prepare the stainless-steel pipe and carbon steel rod of pre-set dimension;Raw material described above be it is common not Steel material of becoming rusty or carbon steel material, needing not move through special working process can obtain;
S2, feedstock processing and assembly:Selected stainless steel inside pipe wall and carbon steel rod outer surface are subjected to cleaning treatment, ensured It is to be combined to show out clean metal, after drying process, it is compound that carbon steel rod is closely nested in formation bimetallic in stainless-steel pipe Blank;
S3, thermocouple setting:Thermocouple is welded in stainless-steel pipe outer surface center;Preferably, a pair of of heat of welding Galvanic couple is for experiment;
S4, clamping sample:The bimetallic composite blank clamping of thermocouple will be welded in thermodynamic simulated experiment machine control box Arranged on left and right sides fixture collet on, it is to be detected;
S5, single pass compression experiment is carried out:Thermodynamic simulated experiment machine control box is vacuumized after dress sample, fills guarantor Protect gas, such as nitrogen, argon gas;Bimetallic composite blank is made to be maintained in certain vacuum state, carries out high temperature compression later And heat treatment experiment;
S6, structure property analysis:Composite reinforcing steel bar sample after experiment is circumferentially subjected to wire cutting sampling with axial, through pre- After processing, metallographic, hardness, Scanning Detction are carried out, the final experimental data for obtaining required organization and performance is analyzed.In order to It realizes the purpose of the good metallurgical binding of compound interface, ensures the preferable comprehensive mechanical property of composite reinforcing steel bar, need to continue to optimize Size of sample and heat processing technique route, finally successfully prepare stainless steel compound belt rib reinforcement.
Further, it is ultrasonic cleaning, mechanical grinding and pickling to the surface treatment mode of raw material in the step S2 Rusty stain, greasy dirt and the high-pressure wash on processing removal surface and drying process.
Further, in the step S4, the collet is equipped with the rib slot of simulation spiral deformation, the rib groove depth Degree is required according to the deflection of bimetallic composite blank and is changed.
Further, each technological parameter can be according to specific reality in the step S5 high temperatures compressive deformation and heat treatment experiment It tests purpose to adjust, and can related data be obtained by data collecting system and be analyzed.
The invention also discloses the compound Ribbed Bars of stainless steel/carbon prepared by above-mentioned heat simulation.
Compared with the prior art, in order to determine appropriate heat processing technique system and technological parameter, the application uses MMS systems Row thermodynamic simulated experiment machine has the function of comprehensive thermo dynamic analogy, the ginsengs such as energy analog temperature, displacement, power, speed, ess-strain Number and passes through experimental machine number, it can be achieved that the multiple functions such as stretching experiment, single multi- passage compression experiment, Plane Strain Compression experiment Temperature-time curve, displacement-time curve, load-deformation curve for being obtained according to acquisition system etc. are analyzed, while to reality It tests sample and carries out organization and performance detection and analysis;And related experiment is concentrated in an equipment and is completed, it is flexibly convenient;It is universal For the research of the Thermal-mechanical Coupling deformational behavior of metal material.And thermomechanical treatment is carried out to stainless steel/carbon composite blank Mode conforms exactly to the single pass compression experiment technique of thermodynamic simulated experiment machine, i.e., by being threaded the special of reinforcing rib slot Collet can realize the deformation and heat treatment of bimetallic blank using single pass compression process route, eventually by optimization hot-working Technological parameter prepares the compound Ribbed Bar of stainless steel/carbon.
For being tested compared to hot rolling, the heat simulation of the compound Ribbed Bar rolling of stainless steel/carbon can solve The problems such as link is more, the period is long, control is unstable, experimental repeatability is poor are prepared present in hot rolling experiment, can be stainless steel/carbon The compound Ribbed Bar hot rolling technology of steel provides a kind of easily research means, has feasibility.
The present invention has the following advantages:
1st, using MMS series hot modeling test machines, and be aided with its vacuum system can utmostly reduce in experimentation it is double The problem of oxidation of metal combination interface, so as to ensure that the compound Ribbed Bar tissue of stainless steel/carbon prepared and performance satisfaction will It asks.
2nd, by designing special-carrier, the compound Ribbed Bar of stainless steel/carbon can be successfully completed (including cross rib and longitudinal rib) Heat simulating.
3rd, the collet of special designing is machined with the rib slot of simulation spiral deformation, and the form and pattern of rib slot can be according to realities Purpose flexible design is tested, rib groove depth can be required according to the compound deflection of bimetallic and be changed.
4th, by the organization and performance of the analysis to acquisition system data and experimental sample detect, can for hot-rolled stainless steel/ The compound Ribbed Bar of carbon steel provides a large amount of comparative study data, is the industry of the compound Ribbed Bar rolling mill practice of stainless steel/carbon Using offer theoretical foundation and easily research means.
5th, relative to actual production and other simulated experiments, thermal simulation test sample size is smaller, and deformation is relatively uniform, leads to It crosses and the parameters such as temperature, deformation is carried out with accurate simulation control, can guarantee the accuracy of result of study.
6th, material preparation is simple in entire experiment flow, and operating procedure is convenient, of low cost, saves material, experimental period Shorter, repeatability is stronger, can comparatively fast calibrate and find related law.
For the foregoing reasons, the present invention can the compound Ribbed Bar laboratory hot rolling experimental study of stainless steel/carbon it It is promoted outside, theoretical direction is provided for stainless steel/carbon composite reinforcing steel bar industrialized production.
Description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, to embodiment or will show below There is attached drawing needed in technology description to do simply to introduce, it should be apparent that, the accompanying drawings in the following description is this hair Some bright embodiments, for those of ordinary skill in the art, without having to pay creative labor, can be with Other attached drawings are obtained according to these attached drawings.
Fig. 1 is the collet (simulation Ribbed Bar longitudinal rib) that the present invention processes.
Fig. 2 is the collet (simulation Ribbed Bar cross rib) that the present invention processes.
Fig. 3 is blank (stainless steel tube and carbon steel rod) combination diagram of the present invention.
The blank (stainless steel tube and carbon steel rod) that Fig. 4 is the present invention is welded with thermocouple sample schematic diagram.
Fig. 5 is the Ribbed Bar photo after the completion of thermal simulation experiment of the present invention-single pass compression experiment.
Fig. 6 is thermal simulation experiment finished product Ribbed Bar axial and circumferential metallograph of the present invention.
In figure:1st, longitudinal rib groove;2nd, cross rib groove;3rd, stainless-steel pipe;4th, carbon steel rod;5th, thermocouple thermo wires;6th, it is welded with The sample of thermocouple thermo wires;7th, Ribbed Bar sample.
Specific embodiment
Purpose, technical scheme and advantage to make the embodiment of the present invention are clearer, below in conjunction with the embodiment of the present invention In attached drawing, the technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is Part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art All other embodiments obtained without making creative work shall fall within the protection scope of the present invention.
As shown in figs 1 to 6, a kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon, including walking as follows Suddenly:
S1, raw material prepare:Prepare the stainless-steel pipe 3 of pre-set dimension and carbon steel rod 4;
S2, feedstock processing and assembly:By selected 3 inner wall of stainless-steel pipe and carbon steel rod 4 since size is smaller, first alcohol Ultrasonic cleaning for some period after submergence, polished after drying with the sand paper inner wall of stainless-steel pipe 3 and the outer surface of carbon steel rod 4, It is wiped with acetone again to carry out cleaning treatment, guarantee is to be combined to show out clean metal, after drying process that carbon steel rod 4 is close embedding It is sleeved in stainless-steel pipe 3 and forms bimetallic composite blank.
S3, thermocouple setting:It is welded in the 3 outer surface center of stainless-steel pipe for being nested with carbon steel rod 4 using thermocouple It picks, a pair of of thermocouple thermo wires 5 is firmly welded on specimen surface by way of percussion welding.During welding, it is desirable that thermocouple is even Silk 5 roots and the perpendicular shape of specimen surface, spacing is appropriate between thermocouple thermo wires 5.
S4, clamping sample:To be welded with a left side of 6 clamping of sample of thermocouple thermo wires in thermodynamic simulated experiment machine control box, It is to be detected on the collet of right both sides fixture;The collet be equipped with simulation spiral deformation rib slot (i.e. longitudinal rib groove 1 or/ With cross rib groove 2), the rib groove depth is required according to the deflection of bimetallic composite blank and is changed.Thermoelectricity will be then welded with A pair of of thermocouple thermo wires 5 on the sample 6 of thermo wires is connected respectively on the anode and cathode of control box internal wiring terminal.
S5, single pass compression experiment is carried out:Thermodynamic simulated experiment machine control box is vacuumized and filled after dress sample Gas is protected, sample is made to be maintained in certain vacuum state, carries out single pass compression experiment according to heat processing technique route later.Examination After sample 6 is kept the temperature more than austenitizing temperature, thermodynamic simulated experiment machine main hydraulic cylinder tup is pressed under position control mode According to given deflection and strain rate to sample carry out compressive deformation, practical distortion amount can by measure two collets between away from It is compared to obtain from initial distance.Ribbed Bar sample 7 after compression can pass through tune according to given cooling technique Current size changes various ways guarantee cooling procedure and temperature change and the coolings such as cooling medium (water, air and heat conduction etc.) Technique initialization curve is consistent.
S6, structure property analysis:The compressed Ribbed Bar sample 7 of single pass is circumferentially taken with axial progress wire cutting Sample is polished by sand paper, is processed by shot blasting after fine grinding polishing, is treated surface no marking, after clean and bright, carried out at corrosion Reason finally carries out the analysis of structure property according to experiment purpose.
Embodiment
The present embodiment is core material to cover material, 20MnSi carbon steel rods 4 with seamless 304 austenitic stainless steel steel pipe 3, and size is distinguished For(outer diameter × wall thickness × length, mm) and(outer diameter × length, mm), Therebetween it combines closely, single pass compression experiment is carried out on MMS-300 thermodynamic simulated experiment machines with this blank, deflection is 75%.
Ultrasonic wave is carried out after above-mentioned seamless 304 austenitic stainless steel steel pipe 3 and 20MnSi carbon steel rods 4 are submerged with alcohol Cleaning 30 minutes, with the outer surface of inner wall and the carbon steel rod 4 of sand paper polishing stainless-steel pipe 3 after drying, then with acetone wipe with Cleaning treatment is carried out, guarantee is to be combined to show out clean metal, and carbon steel rod 4 is closely nested in stainless-steel pipe after drying process In 3;
Then a certain position utilizes thermocouple welding machine in the middle part of 3 sample of stainless-steel pipe for being cased with carbon steel rod 4, passes through punching A pair of of thermocouple thermo wires 5 is firmly welded on specimen surface by the mode for hitting weldering;
Then the one of reinforcing rib slot (longitudinal rib groove 1 or/and cross rib groove 2, rib groove depth are 0.8mm) will be threaded Collet is separately fixed on the arranged on left and right sides fixture in thermodynamic simulated experiment machine control box;Thermocouple thermo wires will be welded with again Sample 6 is fixed in thermodynamic simulated experiment machine control box between a pair of collet on fixture, then by a pair of heat on sample Galvanic couple thermo wires 5 is connected respectively on the anode and cathode of control box internal wiring terminal;
Thermodynamic simulated experiment machine control box is vacuumized after dress sample and fills protection gas, sample is made to be maintained at certain In vacuum state, single pass compression experiment is carried out according to heat processing technique route later:Sample is with the speed of 10 DEG C/s from room temperature 1200 DEG C are heated to, then keeps the temperature 5min, then 1050 DEG C are cooled to the cooling rate of 10 DEG C/s, progress deflection is after keeping the temperature 30s 75% single pass compression experiment, carries out air-cooled processing later, finally obtains the compound Ribbed Bar sample 7 of stainless steel/carbon;
Ribbed Bar sample 7 after experiment is circumferentially subjected to wire cutting sampling with axial, is polished by coarse sandpaper, fine sand Be processed by shot blasting after paper polishing, treat surface no marking, after clean and bright, then with 4% nital to core carbon steel Corrosion treatment is carried out, finally carries out Metallographic Analysis, electron probing analysis and hardness measurement.
As shown in Figure 5, Figure 6, by being obtained to the analysis of experimental phenomena and conclusion, above-mentioned heat simulation is prepared stainless The combination interface of the compound Ribbed Bar of steel/carbon steel realizes good metallurgical binding, and organization and performance meet certain requirement, Theoretical direction is provided for hot rolling experiment.
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Pipe is described in detail the present invention with reference to foregoing embodiments, it will be understood by those of ordinary skill in the art that:Its according to Can so modify to the technical solution recorded in foregoing embodiments either to which part or all technical features into Row equivalent replacement;And these modifications or replacement, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution The range of scheme.

Claims (5)

1. a kind of heat simulation for preparing the compound Ribbed Bar of stainless steel/carbon, which is characterized in that include the following steps:
S1, raw material prepare:Prepare the stainless-steel pipe and carbon steel rod of pre-set dimension;
S2, feedstock processing and assembly:Will be dry after selected stainless steel inside pipe wall and carbon steel rod outer surface progress cleaning treatment, it will Carbon steel rod, which is closely nested in stainless-steel pipe, forms bimetallic composite blank;
S3, thermocouple setting:Thermocouple is welded in stainless-steel pipe outer surface center;
S4, clamping sample:To be welded with a left side of the bimetallic composite blank clamping of thermocouple in thermodynamic simulated experiment machine control box, It is to be detected on the collet of right both sides fixture;
S5, single pass compression experiment is carried out:Thermodynamic simulated experiment machine control box is vacuumized after dress sample, fills protection Gas makes bimetallic composite blank be maintained in certain vacuum state, carries out high temperature compression and heat treatment experiment later;
S6, structure property analysis:It is preprocessed by the composite reinforcing steel bar sample after experiment circumferentially with axial progress wire cutting sampling Afterwards, metallographic, hardness, Scanning Detction are carried out, the final experimental data for obtaining required organization and performance is analyzed.
2. the heat simulation according to claim 1 for preparing the compound Ribbed Bar of stainless steel/carbon, which is characterized in that It is the rust that ultrasonic cleaning, mechanical grinding and pickling processes remove surface to the surface treatment mode of raw material in the step S2 Mark, greasy dirt and high-pressure wash and drying process.
3. the heat simulation according to claim 1 for preparing the compound Ribbed Bar of stainless steel/carbon, which is characterized in that In the step S4, the collet is equipped with the rib slot of simulation spiral deformation, and the rib groove depth is compound according to bimetallic The deflection of blank is required and is changed.
4. the heat simulation according to claim 1 for preparing the compound Ribbed Bar of stainless steel/carbon, which is characterized in that Each technological parameter can be adjusted according to specific experiment purpose in the step S5 high temperatures compressive deformation and heat treatment experiment, and Related data can be obtained by data collecting system to be analyzed.
5. stainless steel/carbon prepared by a kind of heat simulation as described in the arbitrary claim of Claims 1-4 is compound with ribbing Reinforcing bar.
CN201810036010.9A 2018-01-15 2018-01-15 Thermal simulation method for preparing stainless steel/carbon steel composite ribbed steel bar Expired - Fee Related CN108226210B (en)

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