CN108218413A - 一种彩色泡沫玄武岩材料及制作方法 - Google Patents

一种彩色泡沫玄武岩材料及制作方法 Download PDF

Info

Publication number
CN108218413A
CN108218413A CN201810040860.6A CN201810040860A CN108218413A CN 108218413 A CN108218413 A CN 108218413A CN 201810040860 A CN201810040860 A CN 201810040860A CN 108218413 A CN108218413 A CN 108218413A
Authority
CN
China
Prior art keywords
basalt
foam
powder
colored
materials according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810040860.6A
Other languages
English (en)
Inventor
刘希辉
刘佐夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HARBIN TIME INNOVATION TECHNOLOGY DEVELOPMENT Co Ltd
Original Assignee
HARBIN TIME INNOVATION TECHNOLOGY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HARBIN TIME INNOVATION TECHNOLOGY DEVELOPMENT Co Ltd filed Critical HARBIN TIME INNOVATION TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN201810040860.6A priority Critical patent/CN108218413A/zh
Publication of CN108218413A publication Critical patent/CN108218413A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C04B2235/321—Dolomites, i.e. mixed calcium magnesium carbonates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3409—Boron oxide, borates, boric acids, or oxide forming salts thereof, e.g. borax
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/36—Glass starting materials for making ceramics, e.g. silica glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562—Heating rate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6565—Cooling rate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/77—Density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9646—Optical properties
    • C04B2235/9661—Colour

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

一种彩色泡沫玄武岩材料及制作方法，属于建筑装饰材料领域。本发明解决了现有技术中无机发泡保温材料抗压强度和抗折强度低的问题，本发明所述的彩色泡沫玄武岩材料主要由以下原料配比制成：玄武岩矿石50％～70％、废玻璃粉4％～7％、氧化铝0.1％～3％、发泡剂5％～15％、助熔剂5％～11％、稳泡剂3.5％～8％、分散剂0.1％～0.4％、辅料0.3％～0.6％和色料2％～12％，上述各原料质量分数之和为100％。将上述原料经处理，球磨粉碎，配比混合，干燥制粉，发泡成品等步骤即可制成彩色泡沫玄武岩材料。本发明可以用于建筑建设或建筑装饰上的基础材料，如建筑用砖或建筑用板等。

Description

一种彩色泡沫玄武岩材料及制作方法
技术领域
本发明涉及一种建筑装饰材料，尤其是涉及一种彩色泡沫玄武岩材料及制作方法。
背景技术
隔热保温材料方面，保温市场上主要采用EPS、XPS苯板材料。这种材料保温性能好、价格低廉，市 场占有率在90％以上。然而，随着这类隔热材料的大规模推广，聚苯保温板的火灾隐患逐渐暴露。近些年 国内各大城市发生的建筑物火灾中，人们发现聚苯保温板燃点低、燃烧速度快、烟雾毒性大、蔓延猛烈并 且在燃烧时候熔融滴落，防火标准只能达到B2级。相对苯板，岩棉的导热系数低，耐火性好，保温性、 隔音性也相当优越，在国内保温市场上也有应用。但是岩棉的性能缺陷也很明显，主要表现为抗拉强度低、 吸水性大、耐久性差等。这些缺陷直接带来岩棉保温工程的工程质量低，使用寿命短等问题。
目前，出现新型的无机发泡保温材料，如：泡沫水泥、泡沫玻璃和发泡陶瓷等，其中发泡水泥容易生 产，但自身较脆，自身膨胀内应力较大，导热系数较高，吸水易发胀；泡沫玻璃有较低的吸水率，但自身 较脆，导热系数高，严冷地区使用较厚；发泡陶瓷各方面效果都比较好，但是抗折强度不够，且生产成本 较贵，不易推广。
发明内容
针对目前无机发泡保温材料抗压强度和抗折强度低的问题，本发明提供了一种彩色泡沫玄武岩材料， 该材料由以下质量分数的原料配比制成：玄武岩矿石50％～70％、废玻璃粉4％～7％、氧化铝0.1％～3％、 发泡剂5％～15％、助熔剂5％～11％、稳泡剂3.5％～8％、分散剂0.1％～0.4％、辅料0.3％～0.6％和色料 2％～12％，上述各原料质量分数之和为100％。
优选地，该材料由以下原料配比制成：玄武岩矿石60％、废玻璃粉7％、氧化铝1.55％、发泡剂10％、 助熔剂8％、稳泡剂5.75％、分散剂0.25％、辅料0.45％和色料7％。
进一步地，所述发泡剂为煤粉、纯碱、石灰石中的一种。
所述助溶剂为白云石、硼砂中的一种。
所述稳泡剂为磷酸钠、滑石粉中的一种。
所述分散剂为多聚乙烯醇、聚磷酸钠、硅酸钠、碳酸钠中的一种。
所述辅料为纳米中空微珠、凹凸棒石粘土尾矿粉、坡缕石中的一种或几种的组合，所述辅料为组合物
时，各辅料之间以任意比混合。
所述色料为Zr-Si-V、Ti-Sb-Cr、Cd-Se-S-Zr-Si中的一种。
本发明还提供了上述彩色泡沫玄武岩材料的制作方法，包括如下步骤：
(1)原料粉碎：将玄武岩矿石块、废玻璃粉、氧化铝和辅料分别粉碎成300目以下的细末；
(2)配比制粉：然后将玄武岩矿石粉、废玻璃粉、氧化铝、发泡剂、助熔剂、稳泡剂、分散剂、色 料和辅料按配比进行混合搅拌，经干燥后制成混合干粉；
(3)发泡成品：将上述制成的混合干粉在900～1000℃融化烧结成型后保温10～15min，然后在530～ 580℃保温30～90min，室温冷却后制得为彩色玄武岩发泡材料。
优选地，步骤(3)所述发泡成品的制备过程中，是以10～20℃/min速率升温至900～1000℃，融化 烧结成型后保温10～15min，然后以30～35℃/min速率降温至530～580℃，然后保温30～90min，室温冷 却后制得为彩色玄武岩发泡材料。
有益效果
本发明制得的彩色玄武岩发泡建筑装饰材料是一种性能优异的无机非金属材料，无毒无辐射；它的导 热系数低，保温性能好；化学性质稳定，PH值为7-8，呈中性或弱碱性，对碳钢、不锈钢、铝等金属材料 均无腐蚀；耐火性好，熔点高于1200℃，防火等级达到A级标准；综合了泡沫玻璃和发泡陶瓷的优点，导 热系数和吸水率都低，抗压强度和抗折强度较大，剪切强度高，与建筑物同寿命等等，完全满足工程质量 要求。
此外，它的耐温、耐火性好，能够在-269～650℃环境中使用，且吸湿能力低(体积吸湿率只有0.2％～ 0.3％)不易氧化，长时间使用不会出现质量问题。产品的主要原料玄武岩作为一种火山岩，在国内矿藏分 布广泛，容易获取并且价格低廉，所得产品的性价比高。
本发明制得的产品，不仅仅可以应用于建筑建设上的基础材料，也可用作建筑装饰上的基础材料，可 制成更多比天然石材色彩更加丰富多彩、装饰效果更突出的产品，尤其可以消除人们普遍担心的某些石材 的放射性威胁，在室内装修中充分满足了人们的追求，获得物廉价美的享受。还可将本产品制成建筑用砖 或建筑用板，可都具有良好的硬度和抗压程度，并且保温性能良好，化学性质稳定，在制作和使用的过程 中具有环保的效果。
具体实施方式
本发明的方法简单，容易操作，制得的彩色发泡玄武岩建筑装饰材料的干体积密度：160～240kg/m3， 抗压强度：0.6～25.0MPa，抗折强度：0.55～1.15MPa，导热系数(35℃)，0.102W/(m*K)，吸音能力：0.09％ ～0.19％，孔隙率：70％～95％，体积吸水率：0.1％～0.2％，脆性系数<0.01，最高使用温度：650℃，最低 使用温度：-269℃。
实施例1.彩色发泡玄武岩材料的制作方法。
(1)原料粉碎：将开采后的玄武岩矿石料输送到颚式粉碎机中，通过颚式粉碎机粉碎成较小的玄武 岩矿石块；将玄武岩矿石块放入球磨机内，通过球磨机磨粉，将玄武岩矿石块磨成300目以下的粉状，备 用；将原料中的废玻璃粉，氧化铝和辅料分别放入磨粉机内，磨成300目以下，备用；
(2)配比制粉：将下述各原料按照质量分数含量进行配比混合，玄武岩矿石粉55％，废玻璃粉7％， 氧化铝3％，纯碱8％、硼砂8％，滑石粉6％，聚磷酸钠0.4％，Zr-Si-V12％、和凹凸棒石粘土尾矿粉0.6％， 获得含有蓝色色料的混合粉，经喷雾干燥塔干燥后制成混合干粉，备用；
(3)发泡成品：将上述制成的混合干粉放入窑炉内，以20℃/min速率升温，在1000℃融化烧结成型 后保温15min，然后以35℃/min速率降温至580℃，然后保温90min后随炉冷却至室温成型，制得蓝色玄 武岩发泡材料。
本实施例制得的彩色发泡玄武岩材料在隧道窑中冷却至50℃以下时，即可用切割机切割成所需形状制 成成品。具有大量的细微闭孔气泡结构，孔径从纳米级到微米级不等，泡孔分布均匀，其主要的技术指标 如表1所示。
实施例2.彩色发泡玄武岩材料的制作方法。
(1)原料粉碎：将开采后的玄武岩矿石料输送到颚式粉碎机中，通过颚式粉碎机粉碎成较小的玄武 岩矿石块；将玄武岩矿石块放入球磨机内，通过球磨机磨粉，将玄武岩矿石块磨成300目以下的粉状，备 用；将原料中的废玻璃粉，氧化铝和辅料分别放入磨粉机内，磨成300目以下，备用；
(2)配比制粉：将下述各原料按照质量分数含量进行配比混合，玄武岩矿石粉60％，废玻璃粉5％， 氧化铝1.5％，石灰石10％，白云石5％，滑石粉8％，硅酸钠0.2％，Ti-Sb-Cr10％、和坡缕石0.3％，获得 含有黄色色料的混合粉，经喷雾干燥塔干燥后制成混合干粉，备用；
(3)发泡成品：将上述制成的混合干粉放入窑炉内，以10℃/min速率升温，在900℃融化烧结成型 后保温10min，然后以30℃/min速率降温至530℃，然后保温30min后随炉冷却至室温成型，制得黄色玄 武岩发泡材料。
本实施例制得的彩色发泡玄武岩材料在隧道窑中冷却至50℃以下时，即可用切割机切割成所需形状制 成成品。具有大量的细微闭孔气泡结构，孔径从纳米级到微米级不等，泡孔分布均匀，其主要的技术指标 如表1所示。
实施例3.彩色发泡玄武岩材料的制作方法。
(1)原料粉碎：将开采后的玄武岩矿石料输送到颚式粉碎机中，通过颚式粉碎机粉碎成较小的玄武 岩矿石块；将玄武岩矿石块放入球磨机内，通过球磨机磨粉，将玄武岩矿石块磨成300目以下的粉状，备 用；将原料中的废玻璃粉，氧化铝和辅料分别放入磨粉机内，磨成300目以下，备用；
(2)配比制粉：将下述各原料按照质量分数含量进行配比混合，玄武岩矿石粉70％，废玻璃粉4％， 氧化铝3％，煤粉12％，硼砂5％，滑石粉3.5％，多聚乙烯醇0.1％，Cd-Se-S-Zr-Si 2％和纳米中空微珠0.4％， 获得含有红色色料的混合粉，经喷雾干燥塔干燥后制成混合干粉，备用；
(3)发泡成品：将上述制成的混合干粉放入窑炉内，以15℃/min速率升温，在950℃融化烧结成型 后保温12min，然后以33℃/min速率降温至560℃，然后保温60min后随炉冷却至室温成型，制得红色玄 武岩发泡材料。
本实施例制得的彩色发泡玄武岩材料在隧道窑中冷却至50℃以下时，即可用切割机切割成所需形状制 成成品。具有大量的细微闭孔气泡结构，孔径从纳米级到微米级不等，泡孔分布均匀，其主要的技术指标 如表1所示。
对比例1：泡沫玻璃，泡沫玻璃又称多孔玻璃，是一种气孔率在90％以上，由均匀的气孔组成的隔热玻 璃。本对比例采用粉末烧结法制备泡沫玻璃，在玻璃微粉中添加发泡剂并混合，与热熔器中加热、膨胀后 退火，制得成品。
对比例2：发泡陶瓷，发泡陶瓷是以陶土尾矿、陶瓷碎片、河道淤泥等作为主要原料，本对比例利用 现有工艺及发泡技术经高温焙烧制备高气孔率的闭孔陶瓷材料。
表1本发明获得的彩色玄武岩发泡材料与现有产品的性能参数对比
由表1可见，本发明制备的彩色泡沫玄武岩综合了泡沫玻璃和发泡陶瓷的优点，导热系数和吸水率都 低，抗压强度和抗折强度较大，剪切强度高，与建筑物同寿命等等，完全满足工程质量要求。

Claims (10)

1.一种彩色泡沫玄武岩材料，其特征在于，该材料由以下质量分数的原料配比制成：玄武岩矿石50％～70％、废玻璃粉4％～7％、氧化铝0.1％～3％、发泡剂5％～15％、助熔剂5％～11％、稳泡剂3.5％～8％、分散剂0.1％～0.4％、辅料0.3％～0.6％和色料2％～12％，上述各原料质量分数之和为100％。
2.根据权利要求1所述的一种彩色泡沫玄武岩材料，其特征在于，该材料由以下原料配比制成：玄武岩矿石60％、废玻璃粉7％、氧化铝1.55％、发泡剂10％、助熔剂8％、稳泡剂5.75％、分散剂0.25％、辅料0.45％和色料7％。
3.根据权利要求1或2所述的一种彩色泡沫玄武岩材料，其特征在于，所述发泡剂为煤粉、纯碱、石灰石中的一种。
4.根据权利要求1或2所述的一种彩色泡沫玄武岩材料，其特征在于，所述助溶剂为白云石、硼砂中的一种。
5.根据权利要求1或2所述的一种彩色泡沫玄武岩材料，其特征在于，所述稳泡剂为磷酸钠、滑石粉中的一种。
6.根据权利要求1或2所述的一种彩色泡沫玄武岩材料，其特征在于，所述分散剂为多聚乙烯醇、聚磷酸钠、硅酸钠、碳酸钠中的一种。
7.根据权利要求1或2所述的一种彩色泡沫玄武岩材料，其特征在于，所述辅料为纳米中空微珠、凹凸棒石粘土尾矿粉、坡缕石中的一种或几种的组合。
8.根据权利要求1或2所述的一种彩色泡沫玄武岩材料，其特征在于，所述色料为Zr-Si-V、Ti-Sb-Cr、Cd-Se-S-Zr-Si中的一种。
9.权利要求1或2所述的一种彩色泡沫玄武岩材料的制作方法，其特征在于，包括如下步骤：
(1)原料粉碎：将玄武岩矿石块、废玻璃粉、氧化铝和辅料分别粉碎成300目以下的细末；
(2)配比制粉：然后将玄武岩矿石粉、废玻璃粉、氧化铝、发泡剂、助熔剂、稳泡剂、分散剂、色料和辅料按配比进行混合搅拌，经干燥后制成混合干粉；
(3)发泡成品：将上述制成的混合干粉在900～1000℃融化烧结成型后保温10～15min，然后在530～580℃保温30～90min，室温冷却后制得为彩色玄武岩发泡材料。
10.根据权利要求9所述的一种彩色泡沫玄武岩材料的制作方法，其特征在于，步骤(3)所述发泡成品的制备过程中，是以10～20℃/min速率升温至900～1000℃，融化烧结成型后保温10～15min，然后以30～35℃/min速率降温至530～580℃，然后保温30～90min，室温冷却后制得为彩色玄武岩发泡材料。
CN201810040860.6A 2018-01-16 2018-01-16 一种彩色泡沫玄武岩材料及制作方法 Pending CN108218413A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810040860.6A CN108218413A (zh) 2018-01-16 2018-01-16 一种彩色泡沫玄武岩材料及制作方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810040860.6A CN108218413A (zh) 2018-01-16 2018-01-16 一种彩色泡沫玄武岩材料及制作方法

Publications (1)

Publication Number Publication Date
CN108218413A true CN108218413A (zh) 2018-06-29

Family

ID=62641235

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810040860.6A Pending CN108218413A (zh) 2018-01-16 2018-01-16 一种彩色泡沫玄武岩材料及制作方法

Country Status (1)

Country Link
CN (1) CN108218413A (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109987962A (zh) * 2019-04-26 2019-07-09 陕西理工大学 钒钛磁铁矿尾矿制备多孔陶瓷材料的方法
CN110713378A (zh) * 2019-11-20 2020-01-21 廖桃元 一种玄武岩一体板及其制作工艺
CN112500128A (zh) * 2020-12-15 2021-03-16 佛山欧神诺陶瓷有限公司 一种彩色装饰发泡陶瓷及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105819890A (zh) * 2016-04-21 2016-08-03 哈尔滨时代创新科技发展有限公司 一种发泡玄武岩环保隔音材料及制作方法
CN105906366A (zh) * 2016-04-21 2016-08-31 哈尔滨时代创新科技发展有限公司 一种发泡玄武岩环保墙板材料及制作方法
CN105924128A (zh) * 2016-04-21 2016-09-07 哈尔滨时代创新科技发展有限公司 一种泡沫玄武岩材料及制作方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105819890A (zh) * 2016-04-21 2016-08-03 哈尔滨时代创新科技发展有限公司 一种发泡玄武岩环保隔音材料及制作方法
CN105906366A (zh) * 2016-04-21 2016-08-31 哈尔滨时代创新科技发展有限公司 一种发泡玄武岩环保墙板材料及制作方法
CN105924128A (zh) * 2016-04-21 2016-09-07 哈尔滨时代创新科技发展有限公司 一种泡沫玄武岩材料及制作方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李青山: "《着色配色技术手册》", 31 January 2016, 中国纺织出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109987962A (zh) * 2019-04-26 2019-07-09 陕西理工大学 钒钛磁铁矿尾矿制备多孔陶瓷材料的方法
CN109987962B (zh) * 2019-04-26 2021-06-22 陕西理工大学 钒钛磁铁矿尾矿制备多孔陶瓷材料的方法
CN110713378A (zh) * 2019-11-20 2020-01-21 廖桃元 一种玄武岩一体板及其制作工艺
CN112500128A (zh) * 2020-12-15 2021-03-16 佛山欧神诺陶瓷有限公司 一种彩色装饰发泡陶瓷及其制备方法和应用

Similar Documents

Publication Publication Date Title
CN108191230A (zh) 一种利用锂尾渣制备彩色泡沫玻璃陶瓷材料的方法
CN104631688B (zh) 利用尾砂生产的微晶发泡墙体砌块及其制造方法
CN102674883B (zh) 泡沫陶瓷保温板及其制备方法
CN104446568B (zh) 一种耐火保温砖及其制备方法
CN102627469B (zh) 高强轻质发泡陶瓷板及其制作方法
CN105924128A (zh) 一种泡沫玄武岩材料及制作方法
CN102086129B (zh) 一种以凝灰岩为主要原料的轻质高强发泡材料及其制备方法
CN102838375A (zh) 一种无机泡沫保温材料及其制备方法
CN101830725B (zh) 一种轻质保温陶瓷砖及其制备方法
CN103553701B (zh) 一种泡沫陶瓷保温材料的制备方法及其产品
CN105399437A (zh) 一种超低温快速烧成的保温装饰陶瓷板及其生产方法
CN101717267B (zh) 以莫来石质辊棒废料为原料的轻质砖及其制备方法
CN108218413A (zh) 一种彩色泡沫玄武岩材料及制作方法
CN107352972A (zh) 一种煤矸石、石墨尾矿制备的泡沫陶瓷轻质内隔墙板及制备方法
CN107602147A (zh) 泡沫玄武岩保温材料及其制备方法
CN105198481A (zh) 一种利用黄河泥沙和赤泥制备发泡陶瓷隔热保温板的方法
CN106542843A (zh) 一种利用固体废弃物制备轻质保温墙体材料的方法
CN105418149A (zh) 一种石材面蜂孔双层再生材料
CN104556954A (zh) 一种磷酸镁水泥基多孔材料及其制备方法
CN105819890B (zh) 一种发泡玄武岩环保隔音材料及制作方法
CN102617180A (zh) 一种多孔泡沫陶瓷及其制备方法
CN105503238A (zh) 一种发泡陶瓷保温板及其制备方法
CN104086214B (zh) 一种泡沫陶瓷保温材料的制备方法
CN112047754A (zh) 一种防火保温板及其制备方法
CN105906366B (zh) 一种发泡玄武岩环保墙板材料及制作方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180629

RJ01 Rejection of invention patent application after publication