CN108217841A - A kind of reverse osmosis water treatment system method for cleaning - Google Patents

A kind of reverse osmosis water treatment system method for cleaning Download PDF

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Publication number
CN108217841A
CN108217841A CN201711261574.4A CN201711261574A CN108217841A CN 108217841 A CN108217841 A CN 108217841A CN 201711261574 A CN201711261574 A CN 201711261574A CN 108217841 A CN108217841 A CN 108217841A
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Prior art keywords
reverse osmosis
cleaning
treatment system
water treatment
ultrafiltration
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CN201711261574.4A
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CN108217841B (en
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吕新春
徐占锋
于海
郎子国
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Shandong Province Liaocheng City Luxi Nitrocompound Fertilizer Co Ltd
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Shandong Province Liaocheng City Luxi Nitrocompound Fertilizer Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4698Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electro-osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Molecular Biology (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention relates to a kind of reverse osmosis water treatment system method for cleaning, including:1)Waste water in reverse osmosis water treatment system is washed;2)Metal peroxides is added to the water and is configured to heated alkaline solution, the ultrafiltration of reverse osmosis water treatment system and first-stage reverse osmosis film are impregnated in above-mentioned heated alkaline solution, the nitrobacteria being adhered in ultrafiltration and first-stage reverse osmosis film is carried out to impregnate cleaning and air supporting cleaning, ultrafiltration and first-stage reverse osmosis film are taken out after the completion, for use;3)By step 2)In for use ultrafiltration and first-stage reverse osmosis film be placed in progress air quick separating in high-speed air;4)With clear water rinsing step 3)Ultrafiltration and first-stage reverse osmosis film after middle air quick separating, in order to be cleaned to the nitrobacteria separated.The cleaning method of the present invention realizes ultrafiltration, counter-infiltration system cleans the effect that can once meet production requirement in every 23 months.

Description

A kind of reverse osmosis water treatment system method for cleaning
Technical field
The present invention relates to the field of wastewater of nitro-compound fertilizer device processing, more particularly to a kind of reverse osmosis water treatment system is clear Reason method.
Background technology
Reverse osmosis technology can be removed effectively since the membrane aperture of reverse osmosis membrane is very small (being only 10A or so) (removal rate are up to 97%-98%) such as dissolved salts, colloid, microorganism, organic matter in water.Reverse osmosis is that current high purity water is set Most widely used a kind of desalting technology in standby, its separation object are the organic of ion range in solution and molecular weight hundreds of Object;Reverse osmosis (RO), hyperfiltration (UF), micro-pore-film filtration (MF) and electrodialysis (EDI) technology belong to membrane separation technique.
Often containing some impurity in the ammonium nitrate wastewater handled by nitro-compound fertilizer device, these impurity are easy to adhere to On counter-infiltration system, the ultrafiltration of counter-infiltration system and first-stage reverse osmosis film are blocked, and the substance viscosity blocked is big, using routine Acidic cleaner hydrochloric acid, nitric acid, the drugs such as sulfuric acid and alkaline cleaner caustic soda, sodium hypochlorite do not imitate substantially after carrying out foam washing Fruit, even if being rinsed again to blocking substance with water on the basis of drug foam washing, effect still unobvious, it is reverse osmosis that treated System can only maintain 1-2 days, just come back to the state of blocking, and carry out drug foam washing and rinse to handle to need 12- every time 24 hours, not only of high cost, time-consuming and laborious, treatment effect was also bad, seriously affected the production efficiency of factory.Therefore, it is necessary to Restudy a set of practical, and the reverse osmosis water treatment system method for cleaning of high treating effect.
Invention content
For the above-mentioned prior art the problem of, the purpose of the present invention is to provide a kind of reverse osmosis water treatment systems Method for cleaning;The present invention after the characteristic of ammonium nitrate wastewater that nitro-compound fertilizer device is handled is analyzed to having found:Cause The reason of substance is difficult to clean up is blocked to be:Nitrification mushroom in ammonium nitrate wastewater, these nitrifiers are by reverse osmosis water Ultrafiltration and first-stage reverse osmosis film can be adhered to when the ultrafiltration of processing system and first-stage reverse osmosis film, blocks ultrafiltration and first-stage reverse osmosis Film, on this basis, the present invention using cleaning, drug foam washing, air quick separating, clear water flushing method, realize ultrafiltration, Per 2-3, month cleaning can once meet the effect of production requirement to counter-infiltration system.
An object of the present invention is to provide a kind of reverse osmosis water treatment system method for cleaning.
The second object of the present invention is to provide the application of above-mentioned reverse osmosis water treatment system method for cleaning.
For achieving the above object, the invention discloses following technical schemes:
First, the invention discloses a kind of reverse osmosis water treatment system method for cleaning, specifically comprise the following steps:
1) it cleans:Waste water in reverse osmosis water treatment system is washed, the waste water in anti-locking system influences outer draining;
2) drug foam washing:Metal peroxides is added to the water and is configured to heated alkaline solution, by reverse osmosis water treatment system Ultrafiltration and first-stage reverse osmosis film impregnate in above-mentioned heated alkaline solution, it is thin to the nitrification being adhered in ultrafiltration and first-stage reverse osmosis film Bacterium carries out impregnating cleaning and air supporting cleaning, takes out ultrafiltration and first-stage reverse osmosis film after the completion, for use;
3) air quick separating:For use ultrafiltration and first-stage reverse osmosis film, which are placed in high-speed air, in step 2) carries out air Quick separating, in order to remain adhered to nitrobacteria in ultrafiltration and first-stage reverse osmosis film and other impurities carry out it is clear again Reason;
4) it rinses:With clear water rinsing step 3) in ultrafiltration after air quick separating and first-stage reverse osmosis film, in order to right The nitrobacteria separated is cleaned, and the nitrobacteria and its that are adhered in ultrafiltration and first-stage reverse osmosis film are removed with thorough His impurity;
5) step 1) to after 4) 2-3 times, that is, completes the cleaning of reverse osmosis water treatment system repeatedly.
In step 2), the metal peroxides includes sodium peroxide, potassium peroxide.
In step 2), the input amount of the metal peroxides is 80-120g/L.
It is described to impregnate cleaning and the time that air supporting is cleared up for 2-3h in step 2).
In step 3), the air velocity of the high-speed air is:5-8m/s.
In step 3), the time of the air quick separating is 0.5-1h.
Secondly, the invention also discloses above-mentioned reverse osmosis water treatment system method for cleaning in reverse osmosis, hyperfiltration, microporous barrier Application in filtering and the cleaning of electrodialytic water processing system.
It should be noted that the present invention is primarily directed to for handling the super of the reverse osmosis water treatment system of ammonium nitrate wastewater Filter and first-stage reverse osmosis film, since ammonium nitrate is strong acid weak base salt, it is faintly acid to lead to ammonium nitrate wastewater, and pH value is about 5 Left and right, and nitrobacteria is easy to survive under acidic environment, and can be firmly adhered in ultrafiltration and first-stage reverse osmosis film, and This kind of bacterium can largely be bred just using nitrogenous inorganic salts as nutriment, lead to ultrafiltration and first-stage reverse osmosis film Severe blockage, in addition, nitrobacteria is also easy to be grown in weakly alkaline environment, it therefore, be to reverse osmosis water treatment system Ultrafiltration and first-stage reverse osmosis film thoroughly cleared up, it is necessary to destroy weak acid and weak base this ring for being easy to nitrobacteria existence Border (PH about 6.5~8.2), reduces its adhesive capacity.The present invention is found by experiment that:Nitrobacteria is under alkalinity and hot water environment Adhesive capacity can be greatly lowered, but the adherency of nitrobacteria only cannot be destroyed by the immersion of alkaline solution hot water completely Power, therefore, the present invention using it are reacted by the input of metal peroxides and generate alkaline product and gas, and release in water The characteristics of amplification quantity heat, carries out impregnating cleaning and air supporting is cleared up to the nitrobacteria in ultrafiltration and first-stage reverse osmosis film, former Reason is:After sodium peroxide is added to the water, reaction generate this alkaline matter of sodium hydroxide, while released a large amount of oxygen and Heat, as a result, generate the hot solution of strong basicity, and the cell wall of nitrobacteria in this hot alkaline solution by strong Strong destruction, adhesion strength decline to a great extent, meanwhile, a large amount of oxygen of generation float, and accelerate the stream of nitrobacteria surrounding liquid Dynamic rate promotes nitrobacteria coming off from ultrafiltration and first-stage reverse osmosis film, is handled by this step, 90% nitrobacteria quilt Cleaning, then, by the impact of the high-speed air of 5-8m/s, remaining nitrobacteria is also detached, and finally, is rinsed by clear water Afterwards, the nitrobacteria other impurities being adhered in ultrafiltration and first-stage reverse osmosis film are thoroughly removed;It is reverse osmosis by above step The tamper removal rate of water treatment system reaches more than 98%, and reverse osmosis and ultra-filtration flux reaches design discharge, complies fully with life Production needs.
Compared with prior art, the present invention achieves following advantageous effect:The method of the present invention is to anti-penetration wastewater disposal system In tamper cleaning it is thorough, cleaning efficiency is high, and cleaning effect is good, and to ultrafiltration, counter-infiltration system, per 2-3, month cleaning is primary i.e. Production requirement can be met.
Specific embodiment
It is noted that following detailed description is all illustrative, it is intended to provide further instruction to the application.It is unless another It indicates, all technical and scientific terms used herein has usual with the application person of an ordinary skill in the technical field The identical meanings of understanding.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singulative It is also intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, operation, device, component and/or combination thereof.
As background technology is introduced, existing method for cleaning has that time-consuming, cleaning is not thorough, effect difference etc. lacks Point, to solve the above-mentioned problems, the present invention provides a kind of reverse osmosis water treatment system method for cleaning, with reference to specific reality Applying example, the present invention is described further.
Embodiment 1:
A kind of reverse osmosis water treatment system method for cleaning, specifically comprises the following steps:
1) it cleans:Waste water in reverse osmosis water treatment system is washed, the waste water in anti-locking system influences outer draining;
2) drug foam washing:4kg sodium peroxides are slowly added to be configured to hot sodium hydroxide solution in 50L water, it will be reverse osmosis The ultrafiltration of water treatment system and first-stage reverse osmosis film impregnate 2h in above-mentioned hot sodium hydroxide solution, anti-to being adhered to ultrafiltration and level-one Nitrobacteria on permeable membrane carries out impregnating cleaning and air supporting cleaning, takes out ultrafiltration and first-stage reverse osmosis film after the completion, for use;
3) air quick separating:In step 2) for use ultrafiltration and first-stage reverse osmosis film be placed in the high-speed air of 8m/s into Row air quick separating 0.5h, in order to remaining adhered to nitrobacteria and other impurities in ultrafiltration and first-stage reverse osmosis film It is cleared up again;
4) it rinses:With clear water rinsing step 3) in ultrafiltration after air quick separating and first-stage reverse osmosis film, in order to right The nitrobacteria separated is cleaned, and the nitrobacteria and its that are adhered in ultrafiltration and first-stage reverse osmosis film are removed with thorough His impurity;
5) step 1) to after 4) 2 times, that is, completes the cleaning of reverse osmosis water treatment system repeatedly
Tamper in the ultrafiltration and first-stage reverse osmosis film of the reverse osmosis water treatment system that are handled by the present embodiment removes Rate reaches 98%, and the normal use phase is 64 days.
Embodiment 2:
A kind of reverse osmosis water treatment system method for cleaning, specifically comprises the following steps:
1) it cleans:Waste water in reverse osmosis water treatment system is washed, the waste water in anti-locking system influences outer draining;
2) drug foam washing:6kg potassium peroxides are slowly added to be configured to hot potassium hydroxide solution in 50L water, it will be reverse osmosis The ultrafiltration of water treatment system and first-stage reverse osmosis film impregnate 3h in above-mentioned hot potassium hydroxide solution, anti-to being adhered to ultrafiltration and level-one Nitrobacteria on permeable membrane carries out impregnating cleaning and air supporting cleaning, takes out ultrafiltration and first-stage reverse osmosis film after the completion, for use;
3) air quick separating:In step 2) for use ultrafiltration and first-stage reverse osmosis film be placed in the high-speed air of 5m/s into Row air quick separating 1h, in order to remain adhered to nitrobacteria in ultrafiltration and first-stage reverse osmosis film and other impurities into Row is cleared up again;
4) it rinses:With clear water rinsing step 3) in ultrafiltration after air quick separating and first-stage reverse osmosis film, in order to right The nitrobacteria separated is cleaned, and the nitrobacteria and its that are adhered in ultrafiltration and first-stage reverse osmosis film are removed with thorough His impurity;
5) step 1) to after 4) 3 times, that is, completes the cleaning of reverse osmosis water treatment system repeatedly.
Tamper in the ultrafiltration and first-stage reverse osmosis film of the reverse osmosis water treatment system that are handled by the present embodiment removes Rate reaches 99%, and the normal use phase is 88 days.
Embodiment 3:
A kind of reverse osmosis water treatment system method for cleaning, specifically comprises the following steps:
1) it cleans:Waste water in reverse osmosis water treatment system is washed, the waste water in anti-locking system influences outer draining;
2) drug foam washing:6kg sodium peroxides are slowly added to be configured to hot sodium hydroxide solution in 50L water, it will be reverse osmosis The ultrafiltration of water treatment system and first-stage reverse osmosis film impregnate 3h in above-mentioned hot sodium hydroxide solution, anti-to being adhered to ultrafiltration and level-one Nitrobacteria on permeable membrane carries out impregnating cleaning and air supporting cleaning, takes out ultrafiltration and first-stage reverse osmosis film after the completion, for use;
3) air quick separating:In step 2) for use ultrafiltration and first-stage reverse osmosis film be placed in the high-speed air of 7m/s into Row air quick separating 40min, in order to remaining adhered to nitrobacteria in ultrafiltration and first-stage reverse osmosis film and other are miscellaneous Matter is cleared up again;
4) it rinses:With clear water rinsing step 3) in ultrafiltration after air quick separating and first-stage reverse osmosis film, in order to right The nitrobacteria separated is cleaned, and the nitrobacteria and its that are adhered in ultrafiltration and first-stage reverse osmosis film are removed with thorough His impurity;
5) step 1) to after 4) 2 times, that is, completes the cleaning of reverse osmosis water treatment system repeatedly.
Tamper in the ultrafiltration and first-stage reverse osmosis film of the reverse osmosis water treatment system that are handled by the present embodiment removes Rate reaches 98%, and the normal use phase is 75 days.
The foregoing is merely the preferred embodiments of the application, are not limited to the application, for the skill of this field For art personnel, the application can have various modifications and variations.It is all within spirit herein and principle, made any repair Change, equivalent replacement, improvement etc., should be included within the protection domain of the application.

Claims (8)

1. a kind of reverse osmosis water treatment system method for cleaning, feature are:Specifically comprise the following steps:
A kind of reverse osmosis water treatment system method for cleaning, specifically comprises the following steps:
1) it cleans:Waste water in reverse osmosis water treatment system is washed, the waste water in anti-locking system influences outer draining;
2) drug foam washing:Metal peroxides is added to the water and is configured to heated alkaline solution, by the super of reverse osmosis water treatment system Filter and first-stage reverse osmosis film are impregnated in above-mentioned heated alkaline solution, to be adhered to the nitrobacteria in ultrafiltration and first-stage reverse osmosis film into Row impregnates cleaning and air supporting cleaning, takes out ultrafiltration and first-stage reverse osmosis film after the completion, for use;
3) air quick separating:It is quick to be placed in progress air in high-speed air for for use ultrafiltration and first-stage reverse osmosis film in step 2) Separation;
4) it rinses:With clear water rinsing step 3) in ultrafiltration after air quick separating and first-stage reverse osmosis film, that is, complete reverse osmosis The cleaning of water treatment system.
2. reverse osmosis water treatment system method for cleaning as described in claim 1, feature are:In step 2), the metal Peroxide includes sodium peroxide, potassium peroxide.
3. reverse osmosis water treatment system method for cleaning as described in claim 1, feature are:In step 2), the metal The input amount of peroxide is 80-120g/L.
4. reverse osmosis water treatment system method for cleaning as described in claim 1, feature are:In step 2), the immersion The time of cleaning and air supporting cleaning is 2-3h.
5. reverse osmosis water treatment system method for cleaning as described in claim 1, feature are:In step 3), the high speed The air velocity of air is:5-8m/s.
6. reverse osmosis water treatment system method for cleaning as described in claim 1, feature are:In step 3), the air The time of quick separating is 0.5-1h.
7. such as claim 1-6 any one of them reverse osmosis water treatment system method for cleaning, feature is:Repeat step 1) To after 4) 2-3 times, that is, complete the cleaning of reverse osmosis water treatment system.
8. if claim 1-6 any one of them reverse osmosis water treatment system method for cleaning is in reverse osmosis, hyperfiltration, microporous barrier Application in filtering and the cleaning of electrodialytic water processing system.
CN201711261574.4A 2017-12-04 2017-12-04 Reverse osmosis water treatment system cleaning method Active CN108217841B (en)

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CN102210978A (en) * 2011-03-14 2011-10-12 四川科伦药业股份有限公司 Method and reagent for cleaning and repairing discarded reverse osmosis film in offline mode
CN103551044A (en) * 2013-11-20 2014-02-05 哈尔滨理工大学 Method for cleaning polluted membrane by using singlet oxygen produced from peroxymonosulfate under induction of inorganic solid peroxide
CN104548948A (en) * 2014-12-24 2015-04-29 哈尔滨工业大学 Cleaning technology suitable for processing oil recovery waste water polytetrafluoroethylene film

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US4740308A (en) * 1984-04-26 1988-04-26 Champion International Corporation Membrane cleaning process
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CN1816384A (en) * 2003-07-04 2006-08-09 阿克佐诺贝尔股份有限公司 Cleaning of filtration membranes with peroxides
CN102210978A (en) * 2011-03-14 2011-10-12 四川科伦药业股份有限公司 Method and reagent for cleaning and repairing discarded reverse osmosis film in offline mode
CN103551044A (en) * 2013-11-20 2014-02-05 哈尔滨理工大学 Method for cleaning polluted membrane by using singlet oxygen produced from peroxymonosulfate under induction of inorganic solid peroxide
CN104548948A (en) * 2014-12-24 2015-04-29 哈尔滨工业大学 Cleaning technology suitable for processing oil recovery waste water polytetrafluoroethylene film

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