CN108217733A - 一种碳-二氧化锰复合材料的制备方法 - Google Patents
一种碳-二氧化锰复合材料的制备方法 Download PDFInfo
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- CN108217733A CN108217733A CN201711391426.4A CN201711391426A CN108217733A CN 108217733 A CN108217733 A CN 108217733A CN 201711391426 A CN201711391426 A CN 201711391426A CN 108217733 A CN108217733 A CN 108217733A
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- graphite
- manganese dioxide
- carbon
- acid
- composite material
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- 239000002131 composite material Substances 0.000 title claims abstract description 49
- FFGXGLUAKPOPEJ-UHFFFAOYSA-N [O-2].[O-2].[Mn+2].[C+4] Chemical compound [O-2].[O-2].[Mn+2].[C+4] FFGXGLUAKPOPEJ-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 166
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 101
- 239000010439 graphite Substances 0.000 claims abstract description 100
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 68
- 238000006243 chemical reaction Methods 0.000 claims abstract description 57
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 46
- 238000005406 washing Methods 0.000 claims abstract description 34
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 27
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002253 acid Substances 0.000 claims abstract description 19
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000007800 oxidant agent Substances 0.000 claims abstract description 14
- 230000001590 oxidative effect Effects 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 13
- 230000008961 swelling Effects 0.000 claims abstract description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 12
- 239000000138 intercalating agent Substances 0.000 claims abstract description 12
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims abstract description 9
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims abstract description 8
- 238000009830 intercalation Methods 0.000 claims abstract description 6
- 230000002687 intercalation Effects 0.000 claims abstract description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 5
- 230000003068 static effect Effects 0.000 claims abstract description 5
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 4
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims abstract description 3
- UMPKMCDVBZFQOK-UHFFFAOYSA-N potassium;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[K+].[Fe+3] UMPKMCDVBZFQOK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000001875 compounds Chemical class 0.000 claims description 37
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 16
- 229910052700 potassium Inorganic materials 0.000 claims description 16
- 239000011591 potassium Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 12
- 239000004575 stone Substances 0.000 claims description 6
- 239000002023 wood Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229910021383 artificial graphite Inorganic materials 0.000 claims description 2
- 229910021382 natural graphite Inorganic materials 0.000 claims description 2
- 238000009288 screen filtration Methods 0.000 claims description 2
- 238000003828 vacuum filtration Methods 0.000 claims description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract description 50
- 229910052799 carbon Inorganic materials 0.000 abstract description 17
- 239000002135 nanosheet Substances 0.000 abstract description 11
- 239000003575 carbonaceous material Substances 0.000 abstract description 8
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract description 3
- 235000019394 potassium persulphate Nutrition 0.000 abstract description 3
- 239000000446 fuel Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 48
- 239000000047 product Substances 0.000 description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 14
- 229910052698 phosphorus Inorganic materials 0.000 description 14
- 239000011574 phosphorus Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 14
- 239000002245 particle Substances 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 238000001291 vacuum drying Methods 0.000 description 9
- 239000005457 ice water Substances 0.000 description 8
- 230000009467 reduction Effects 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 5
- 238000006396 nitration reaction Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007772 electrode material Substances 0.000 description 4
- 238000004108 freeze drying Methods 0.000 description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007770 graphite material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- GCNLQHANGFOQKY-UHFFFAOYSA-N [C+4].[O-2].[O-2].[Ti+4] Chemical compound [C+4].[O-2].[O-2].[Ti+4] GCNLQHANGFOQKY-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002057 nanoflower Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002055 nanoplate Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000002096 quantum dot Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides; Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (6)
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109192529A (zh) * | 2018-09-13 | 2019-01-11 | 复旦大学 | 一种二氧化锰-还原氧化石墨烯复合材料的制备方法与应用 |
CN109244354A (zh) * | 2018-07-14 | 2019-01-18 | 哈尔滨工业大学 | 一种自支撑复合电极 |
CN109616668A (zh) * | 2018-12-06 | 2019-04-12 | 中国科学院兰州化学物理研究所 | 锂电负极材料氧化锰-小尺寸微扩层天然石墨的制备方法 |
CN110048130A (zh) * | 2019-04-09 | 2019-07-23 | 广东工业大学 | 一种二氧化锰/炭黑复合材料及其制备方法和应用 |
CN110342580A (zh) * | 2019-06-20 | 2019-10-18 | 昆明理工大学 | 一种微波辅助制备活性炭-二氧化锰纳米复合材料的方法 |
CN112374552A (zh) * | 2020-11-12 | 2021-02-19 | 昆明云大新能源有限公司 | 一种复合改性石墨负极材料及其制备方法 |
CN115433475A (zh) * | 2021-06-03 | 2022-12-06 | 中国科学院上海硅酸盐研究所 | 光电响应型氧化锰-碳复合涂层及其制备方法和在神经和骨组织修复中的应用 |
CN116081617A (zh) * | 2023-01-16 | 2023-05-09 | 中国石油大学(华东) | 超深层油气藏湿相可膨胀改性石墨控水体系及其制备方法和应用 |
Citations (3)
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CN102275903A (zh) * | 2011-05-24 | 2011-12-14 | 东华大学 | 一种石墨烯和二氧化锰纳米复合材料的制备方法 |
CN105405677A (zh) * | 2015-11-23 | 2016-03-16 | 复旦大学 | 一种由石墨直接制备石墨烯-二氧化锰复合材料的方法及其应用 |
CN107104002A (zh) * | 2017-05-19 | 2017-08-29 | 齐鲁工业大学 | 一种还原态氧化石墨烯/锰氧化物复合物及其制备方法 |
-
2017
- 2017-12-21 CN CN201711391426.4A patent/CN108217733B/zh active Active
Patent Citations (3)
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CN102275903A (zh) * | 2011-05-24 | 2011-12-14 | 东华大学 | 一种石墨烯和二氧化锰纳米复合材料的制备方法 |
CN105405677A (zh) * | 2015-11-23 | 2016-03-16 | 复旦大学 | 一种由石墨直接制备石墨烯-二氧化锰复合材料的方法及其应用 |
CN107104002A (zh) * | 2017-05-19 | 2017-08-29 | 齐鲁工业大学 | 一种还原态氧化石墨烯/锰氧化物复合物及其制备方法 |
Non-Patent Citations (5)
Title |
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WENCONG ZENG ET AL.: "Fast pseudocapacitive reactions of threedimensional manganese dioxide structures synthesized via self-limited redox deposition on microwave-expanded graphite oxide", 《RSC ADV》 * |
张达威: "新型无卤可膨胀石墨的制备及其阻燃材料的开发", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
徐德芳等: "纳米MnO2/膨胀石墨复合材料的制备及其电化学性能", 《新型炭材料》 * |
田艳红等: "由碳还原KMnO4制备氧化锰/碳超级电容材料", 《北京化工大学学报》 * |
赵纪金等: "分步插层法制备高倍膨胀石墨及其微观结构", 《光学精密工程》 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109244354A (zh) * | 2018-07-14 | 2019-01-18 | 哈尔滨工业大学 | 一种自支撑复合电极 |
CN109244354B (zh) * | 2018-07-14 | 2021-03-02 | 哈尔滨工业大学 | 一种自支撑复合电极 |
CN109192529A (zh) * | 2018-09-13 | 2019-01-11 | 复旦大学 | 一种二氧化锰-还原氧化石墨烯复合材料的制备方法与应用 |
CN109616668A (zh) * | 2018-12-06 | 2019-04-12 | 中国科学院兰州化学物理研究所 | 锂电负极材料氧化锰-小尺寸微扩层天然石墨的制备方法 |
CN110048130A (zh) * | 2019-04-09 | 2019-07-23 | 广东工业大学 | 一种二氧化锰/炭黑复合材料及其制备方法和应用 |
CN110048130B (zh) * | 2019-04-09 | 2022-05-06 | 广东工业大学 | 一种二氧化锰/炭黑复合材料及其制备方法和应用 |
CN110342580A (zh) * | 2019-06-20 | 2019-10-18 | 昆明理工大学 | 一种微波辅助制备活性炭-二氧化锰纳米复合材料的方法 |
CN110342580B (zh) * | 2019-06-20 | 2022-04-05 | 昆明理工大学 | 一种微波辅助制备活性炭-二氧化锰纳米复合材料的方法 |
CN112374552A (zh) * | 2020-11-12 | 2021-02-19 | 昆明云大新能源有限公司 | 一种复合改性石墨负极材料及其制备方法 |
CN115433475A (zh) * | 2021-06-03 | 2022-12-06 | 中国科学院上海硅酸盐研究所 | 光电响应型氧化锰-碳复合涂层及其制备方法和在神经和骨组织修复中的应用 |
CN115433475B (zh) * | 2021-06-03 | 2023-04-07 | 中国科学院上海硅酸盐研究所 | 光电响应型氧化锰-碳复合涂层及其制备方法和在神经和骨组织修复中的应用 |
CN116081617A (zh) * | 2023-01-16 | 2023-05-09 | 中国石油大学(华东) | 超深层油气藏湿相可膨胀改性石墨控水体系及其制备方法和应用 |
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