CN108211767A - A kind of biological environmental production preparation for being used to remove formaldehyde - Google Patents
A kind of biological environmental production preparation for being used to remove formaldehyde Download PDFInfo
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- CN108211767A CN108211767A CN201611156169.1A CN201611156169A CN108211767A CN 108211767 A CN108211767 A CN 108211767A CN 201611156169 A CN201611156169 A CN 201611156169A CN 108211767 A CN108211767 A CN 108211767A
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- formaldehyde
- production preparation
- biological environmental
- environmental production
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 153
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 230000007613 environmental effect Effects 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- 239000003610 charcoal Substances 0.000 claims abstract description 25
- 241000196324 Embryophyta Species 0.000 claims abstract description 23
- 239000002028 Biomass Substances 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000000605 extraction Methods 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 12
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 11
- 102000004190 Enzymes Human genes 0.000 claims abstract description 10
- 108090000790 Enzymes Proteins 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000013078 crystal Substances 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 238000003763 carbonization Methods 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 20
- 239000000919 ceramic Substances 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 241000609240 Ambelania acida Species 0.000 claims description 15
- 244000060011 Cocos nucifera Species 0.000 claims description 15
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000010905 bagasse Substances 0.000 claims description 15
- 230000005855 radiation Effects 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 230000003213 activating effect Effects 0.000 claims description 11
- 239000000284 extract Substances 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 10
- 239000011812 mixed powder Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000010903 husk Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 241000219357 Cactaceae Species 0.000 claims description 6
- 244000166124 Eucalyptus globulus Species 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 5
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 5
- 241000195493 Cryptophyta Species 0.000 claims description 5
- 240000005001 Paeonia suffruticosa Species 0.000 claims description 5
- 235000003889 Paeonia suffruticosa Nutrition 0.000 claims description 5
- -1 Peach-pit Substances 0.000 claims description 5
- 244000082204 Phyllostachys viridis Species 0.000 claims description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 5
- 239000011425 bamboo Substances 0.000 claims description 5
- 238000010000 carbonizing Methods 0.000 claims description 5
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 239000011592 zinc chloride Substances 0.000 claims description 5
- 235000005074 zinc chloride Nutrition 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 2
- 244000301850 Cupressus sempervirens Species 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract description 9
- 241000218691 Cupressaceae Species 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 102000004317 Lyases Human genes 0.000 abstract description 3
- 108090000856 Lyases Proteins 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract description 2
- 230000000505 pernicious effect Effects 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 210000002345 respiratory system Anatomy 0.000 description 5
- 230000000638 stimulation Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 210000004400 mucous membrane Anatomy 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Inorganic materials [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- 206010061218 Inflammation Diseases 0.000 description 2
- 208000026935 allergic disease Diseases 0.000 description 2
- 230000007815 allergy Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000004064 dysfunction Effects 0.000 description 2
- 230000004054 inflammatory process Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 2
- 229910001950 potassium oxide Inorganic materials 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 235000013479 Amaranthus retroflexus Nutrition 0.000 description 1
- 240000005674 Ceanothus americanus Species 0.000 description 1
- 235000014224 Ceanothus americanus Nutrition 0.000 description 1
- 235000001904 Ceanothus herbaceus Nutrition 0.000 description 1
- 241000331528 Chlorophytum capense Species 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 240000000411 Sansevieria trifasciata Species 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000003444 anaesthetic effect Effects 0.000 description 1
- 208000022531 anorexia Diseases 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 206010061428 decreased appetite Diseases 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 210000001061 forehead Anatomy 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 231100000405 induce cancer Toxicity 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 210000003928 nasal cavity Anatomy 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000009325 pulmonary function Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000036387 respiratory rate Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/84—Biological processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B01J35/40—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/95—Specific microorganisms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Abstract
The present invention relates to a kind of for removing the biological environmental production preparation of formaldehyde, the biological environmental production preparation is made of the raw material of following parts by weight：80 120 parts of 30 45 parts of enzyme crystal of formaldehyde special efficacy dissolving, 5 10 parts of Japan cypress tree plant bacteriocidin, 30 40 parts of composite biomass charcoal, 15 20 parts of plant extraction liquid, 10 15 parts of auxiliary agent and pure water.The present invention uses environment-friendly type formula, without harmful substance, formaldehyde special efficacy lyase can react under liquid, solid, gaseous state with free formaldehyde in product, the bigger serface of composite biomass charcoal can ensure the absorption of remaining pernicious gas and harmful substance, rapid dissolving removal formaldehyde pollution, effect is lasting, to human body without any harm, suitable for adhesive of the various planks of aldehyde-containing type, furniture and aldehyde-containing type etc..
Description
Technical field
The invention belongs to environmental technology fields, are related to a kind of biological environmental production preparation for removing formaldehyde more particularly to a kind of ring
Protect the biological environmental production preparation for being used to remove formaldehyde pollution-free, that removal formaldehyde is efficient.
Background technology
Formaldehyde is a kind of important Organic Ingredients, be mainly used for plastics industry phenolic resin such as processed, urea-formaldehyde plastics-electricity it is beautiful,
Synthetic fibers such as synthesize vinylon-polyvinyl formal, leather industry, medicine, dyestuff.Formaldehyde printing and dyeing assistant is used at present
More than comparing is pure cotton textile, because pure cotton textile easily wrinkles, the stiffening of cotton can be improved using the auxiliary agent containing formaldehyde
Degree.Textile containing formaldehyde during people's dress and use, can gradually disengage free formaldehyde, pass through human respiratory tract
And skin contact causes respiratory inflammation and scytitis, can also generate stimulation to eyes.Formaldehyde can cause allergy, can also induce
Cancer.Producer to reduce cost, uses high honest and clean of content of formaldehyde using the dyeing assistant containing formaldehyde, particularly some factories
Valency auxiliary agent, it is extremely harmful to human body.
Influence of the formaldehyde to health includes allotriosmia, stimulation, allergy, abnormal pulmonary function, dysfunction of liver, is immunized
The inhereditary material that dysfunction, nervous centralis be impacted, can also be in damaging cells, is suspecious carcinogen.Wherein most sensitive is
Smell and stimulation, therefore its main harm shows as the stimulation to mucous membrane.Formaldehyde is easy to absorb through respiratory tract, but through skin
It absorbs seldom.Formaldehyde through nasal inhalation 93% is trapped in nasal cavity tissue, and high concentration will appear the serious thorn of respiratory tract when sucking
Swash and oedema, resistance of respiratory tract are increased, respiratory rate declines, Eye irritation, headache.Formaldehyde can be with NH in protein2Base junction symphysis
Into formylated albumen, initial stimulation eye mucous membrane, stimulates the upper respiratory tract at low concentrations when concentration is slightly higher, causes cough, uncomfortable in chest, together
When forehead feel there is special constriction, intense stimulus mucous membrane simultaneously makes it fester, and then cause inflammation in lung.After inhaled formaldehyde
Cause anorexia, apocleisis, weight loss, weak, insomnia；If there may be sensitization phenomenons often in contact with if.And it can make
It festers into skin histology.Formaldehyde Central nervous also has anesthetic effect.
In general, removal formaldehyde has many methods, including：(the physical absorption and chemisorbed) method of absorption, plasma skill
The methods of art method, photocatalytic oxidation and non-photocatalytic oxidation.In these methods, absorption method is contour using activated carbon
Specific surface substance carrys out formaldehyde adsorption to achieve the purpose that reduce concentration of formaldehyde.This method is easy to operate, however easily brings secondary pollution,
And it must often replace sorbing material；Plasma technology method is by the formaldehyde in a large amount of plasma oxidation air of generation that discharge
To achieve the purpose that purify air.The method is also easy to produce ozone and secondary pollution is caused to air, and device is complicated；Photochemical catalytic oxidation
Method is the catalysis oxidation formaldehyde under the irradiation of specific light source such as burst of ultraviolel light source using photochemical catalyst.The method device is more multiple
It is miscellaneous, and need to provide additional energy；Plant purification method is to absorb indoor first by the plant such as plants such as bracketplant, sansevieria trifasciata prain
Aldehyde toxic gas, but have little effect；Room ventilation method is that have by indoor flowed with outdoor air to reduce in room air
The content of evil substance, however formaldehyde pollution source generally requires the deenergized period of three to ten five years, deenergized period is too long；Traditional heat is urged
It is to utilize catalyst catalysis oxidation formaldehyde under the action of thermal energy to change oxidizing process, however the method generally requires higher temperature.
Invention content
It is an object of the present invention to long in order to solve the method time of tradition removal formaldehyde, removal formaldehyde is not thorough, easy band
The defects of carrying out secondary pollution and provide a kind of environment friendly and pollution-free, removal formaldehyde it is efficient for removing the biological environmental production system of formaldehyde
Agent.
To achieve these goals, the present invention uses following technical scheme：
A kind of biological environmental production preparation for being used to remove formaldehyde, the biological environmental production preparation are made of the raw material of following parts by weight：First
30-45 parts of enzyme crystal of aldehyde special efficacy dissolving, 5-10 parts of Japan cypress tree plant bacteriocidin, 30-40 parts of composite biomass charcoal, plant extraction liquid
80-120 parts of 15-20 parts, 10-15 parts of auxiliary agent and pure water.
In the technical program, formaldehyde special efficacy dissolving enzyme crystal primary raw material is extracted out of natural plants, molten according to plant
The natural principle of formaldehyde is solved, the active catalytic that enzyme is dissolved in using high-tech technology is acted on, the formaldehyde special efficacy lyase developed, can be high
Effect quickly removes the pollutant of finishing etc.；Strength efficiently, quickly comes into force, long stable effect.Product itself is equal with product
Nonhazardous acts on, and is environment-friendly products.Product has country's CMA examining reports.This product with formaldehyde fast reaction by can form
The material of stable innocuous substance and the material and auxiliary material that clear, colorless air-tightness polymeric membrane can be formed in wood surface
Composition.It is quick and long-acting lasting that it is acted on, and penetration is strong, plays a role immediately after coating.With good sterilizing and antibacterial work(
Effect.This product colorless and odorless, product do not generate secondary pollution.
Preferably, the auxiliary agent is ceramic nano catalysed particulate.
Preferably, the preparation method of the ceramic nano catalysed particulate is：Take 50 parts by weight ceramic powders and 45 weight
The bamboo powder of part is added in the sodium hydroxide solution of a concentration of 20-25wt% of its 15-20 times of quality, after being uniformly dispersed, decompression
145-180 DEG C is heated to, 75-80min is discongested in heat preservation；Mixed-powder is obtained by filtration after discongesting, then mixed-powder is added to it
In the ethanol solution of a concentration of 90-95wt% of 15-20 times of quality, 3-5h is kept the temperature after being heated to 80-90 DEG C, was carried out again
Filter is added in the absolute ethyl alcohol of its 18-22 times of quality after being eluted with water and being evaporated under reduced pressure, obtains mixed liquor；Into mixed liquor
The marine algae extract of 500-600 parts by weight is added, the copper chloride that isometric a concentration of 2-4wt% is added after stirring evenly is molten
Liquid after being crosslinked 1-2h at 80-95 DEG C, freezes 1-2 days in a low temperature of -18 DEG C to -22 DEG C of transfer, then takes out frost object, uses
Flowing water thaws, and gel is made, and after vacuum drying and grinding, ceramic nano catalysed particulate is made.
Preferably, the preparation method of composite biomass charcoal is as follows：
1) it is positioned in carbonizing apparatus after, coconut husk, dewatered bagasse, peach-pit after dehydration are crushed and mixed, in logical air
Under the conditions of be warming up to 300-500 DEG C with the speed of 45-65 DEG C/min and keep 10-30min, after clean, it is dry, obtain pre-
Carbide；
2), by the pre- carbide and activating agent in mass ratio 1：2-3 is mixed and is positioned in microwave radiation device, in indifferent gas
Low-temperature carbonization and high temperature carbonization, wherein 200-300 DEG C of low-temperature carbonization temperature, carbonization time 2-4h are successively carried out under body atmosphere；It is high
Warm carbonization temperature is 1500-1800 DEG C, carbonization time 4-6h；
3), the substance after charing is cleaned, is dried, composite biomass charcoal is made.
In the technical program, microwave radiation heating is selected to carbonize pre- carbide, microwave radiation heating is to pass through
The high-frequency reciprocating movement of heated object internal dipole molecule makes intermolecular mutual collision generate a large amount of frictional heats, then makes object
Expect inside and outside Quick uniform heating simultaneously.Microwave radiation heating have it is easy to operate, heating rate is fast, reaction efficiency is high, heating
The advantages that uniformity is good.Carbonization process is divided into two steps of low-temperature carbonization and high temperature carbonization, during low-temperature carbonization, raw material
In organic compound charcoal and various gases are decomposed under anoxybiotic and hot conditions.Wherein carbon source reaches glass transition temperature
After degree, rigidity reduces, flexible reinforced, and at this temperature, activating agent potassium hydroxide reacts generation potassium carbonate with C, and potassium carbonate is again
Potassium oxide and carbon dioxide are decomposed into, since the flexibility of Carbon Materials at this time is stronger, plasticity is higher, can be when gas generates
A large amount of holes are generated in carbon matrix, are maintained for a long time at this temperature, are conducive to increase the specific surface area of charcoal.In high temperature carbonization
In the process, carbon source generates the stronger charcoal of rigidity again after continuing heating, and the structure of charcoal is substantially stationary at this time, due to rigidity reinforced,
Big hole can not generate.At this moment the boiling point of the metallic potassium of potassium carbonate, potassium oxide and C generations has reached (760 DEG C of potassium boiling point),
Generate potassium steam.The steam of these high temperature can generate the smaller micropore of size on carbon matrix, further increase the ratio table of charcoal
Area.
Preferably, the mass ratio of the coconut husk, peach-pit, bagasse is 1:2-4:1-2；Activating agent is that mass ratio is 1:3
Potassium hydroxide and zinc chloride mixture.
Preferably, during the low-temperature carbonization of step 2), heating rate is 20-25 DEG C/min, microwave power 500-
600W, microwave frequency 2450MHz；During high temperature carbonization, heating rate is 50-55 DEG C/min, microwave power 800-
1000W, microwave frequency 2450MHz；During the high temperature carbonization of step 2), ammonia is passed through into microwave radiation device, relative to
Coconut husk, peach-pit, bagasse gross mass per 100g, the intake of ammonia is 5-7L/min.
Preferably, it is 1 that plant extraction liquid, which is volume ratio,:3:1:5 Folium Artemisiae Argyi extractive liquid, eucalyptus leaf extract, cactus
Extracting solution and tree peony root extracting solution.
Preferably, active ingredient in Folium Artemisiae Argyi extractive liquid, eucalyptus leaf extract, cactus extraction and tree peony root extracting solution
Content is 1.5-3mg/L.
The beneficial effects of the invention are as follows the present invention using environment-friendly type formula, without harmful substance, formaldehyde special efficacy is molten in product
Solution enzyme can react under liquid, solid, gaseous state with free formaldehyde, and the bigger serface of composite biomass charcoal can be with
Ensure the absorption of remaining pernicious gas and harmful substance, rapid dissolving removal formaldehyde pollution, effect is lasting, to human body without any danger
Evil, suitable for adhesive of the various planks of aldehyde-containing type, furniture and aldehyde-containing type etc..
Specific embodiment
Below by specific embodiment, technical scheme of the present invention is described in further detail.It should be appreciated that this hair
Bright implementation is not limited to the following examples, and the accommodation in any form made to the present invention and/or changed will all be fallen
Enter the scope of the present invention.
In the present invention, if not refering in particular to, all parts, percentage are unit of weight, used equipment and raw material etc.
It is commercially available or commonly used in the art.Method in following embodiments is the normal of this field unless otherwise instructed
Rule method.
The preparation method of plant extraction liquid is common extracting method.
Plant extraction liquid is that volume ratio is 1:3:1:5 Folium Artemisiae Argyi extractive liquid, eucalyptus leaf extract, cactus extraction with it is male
Red root extracting solution.Active constituent content is equal in Folium Artemisiae Argyi extractive liquid, eucalyptus leaf extract, cactus extraction and tree peony root extracting solution
For 1.5-3mg/L.
Formaldehyde special efficacy lyase is commercially available.
Embodiment 1
A kind of biological environmental production preparation for being used to remove formaldehyde, the biological environmental production preparation are made of the raw material of following parts by weight：First
30 parts of enzyme crystal of aldehyde special efficacy dissolving, 5 parts of Japan cypress tree plant bacteriocidin, 30 parts of composite biomass charcoal, 15 parts of plant extraction liquid, ceramics
80 parts of 10 parts of catalyzing nano-particles and pure water.
The preparation method of ceramic nano catalysed particulate is：50 parts by weight ceramic powders and the bamboo powder of 45 parts by weight is taken to be added to
In the sodium hydroxide solution of a concentration of 20wt% of its 15 times of quality, after being uniformly dispersed, heating under reduced pressure to 145 DEG C, discongest by heat preservation
75min；It is obtained by filtration mixed-powder after discongesting, then mixed-powder is added to the ethyl alcohol of a concentration of 90wt% of its 15 times of quality
In solution, 3h is kept the temperature after being heated to 80 DEG C, is filtered again, added to its 18 times of quality after being eluted with water and being evaporated under reduced pressure
In absolute ethyl alcohol, mixed liquor is obtained；The marine algae extract of 500 parts by weight is added into mixed liquor, the bodies such as addition after stirring evenly
The copper chloride solution of long-pending a concentration of 2wt% after being crosslinked 1h at 80 DEG C, freezes 1 day, Ran Houqu in a low temperature of -18 DEG C of transfer
Go out to freeze object, be thawed with flowing water, gel is made, after vacuum drying and grinding, ceramic nano catalysed particulate is made.
The preparation method of composite biomass charcoal is as follows：
1) it is positioned in carbonizing apparatus after, coconut husk, dewatered bagasse, peach-pit after dehydration are crushed and mixed, in logical air
Under the conditions of be warming up to 300 DEG C with the speed of 45 DEG C/min and keep 10min, after clean, it is dry, obtain pre- carbide；Coconut palm
Shell, peach-pit, bagasse mass ratio be 1:2:1；
2), by the pre- carbide and activating agent in mass ratio 1：2 mix and are positioned in microwave radiation device, in inert gas
Low-temperature carbonization and high temperature carbonization are successively carried out under atmosphere, wherein 200 DEG C of low-temperature carbonization temperature, carbonization time 2h, heating rate is
20 DEG C/min, microwave power 500W, microwave frequency 2450MHz；；High temperature carbonization temperature is 1500 DEG C, carbonization time 4h, heating speed
Rate is 50 DEG C/min, and microwave power 800W, microwave frequency 2450MHz are passed through ammonia into microwave radiation device, relative to coconut palm
Shell, peach-pit, bagasse gross mass per 100g, the intake of ammonia is 5L/min；Activating agent is that mass ratio is 1:3 hydroxide
The mixture of potassium and zinc chloride；
3), the substance after charing is cleaned, is dried, composite biomass charcoal is made.
Embodiment 2
A kind of biological environmental production preparation for being used to remove formaldehyde, the biological environmental production preparation are made of the raw material of following parts by weight：First
35 parts of enzyme crystal of aldehyde special efficacy dissolving, 7 parts of Japan cypress tree plant bacteriocidin, 36 parts of composite biomass charcoal, 18 parts of plant extraction liquid, ceramics
100 parts of 12 parts of catalyzing nano-particles and pure water.
The preparation method of ceramic nano catalysed particulate is：50 parts by weight ceramic powders and the bamboo powder of 45 parts by weight is taken to be added to
In the sodium hydroxide solution of a concentration of 22wt% of its 18 times of quality, after being uniformly dispersed, heating under reduced pressure to 165 DEG C, discongest by heat preservation
78min；It is obtained by filtration mixed-powder after discongesting, then mixed-powder is added to the ethyl alcohol of a concentration of 93wt% of its 16 times of quality
In solution, 4h is kept the temperature after being heated to 85 DEG C, is filtered again, added to its 20 times of quality after being eluted with water and being evaporated under reduced pressure
In absolute ethyl alcohol, mixed liquor is obtained；The marine algae extract of 550 parts by weight is added into mixed liquor, the bodies such as addition after stirring evenly
The copper chloride solution of long-pending a concentration of 3wt% after being crosslinked 1.5h at 85 DEG C, freezes 2 days, then in a low temperature of -20 DEG C of transfer
Frost object is taken out, is thawed with flowing water, gel is made, after vacuum drying and grinding, ceramic nano catalysed particulate is made.
The preparation method of composite biomass charcoal is as follows：
1) it is positioned in carbonizing apparatus after, coconut husk, dewatered bagasse, peach-pit after dehydration are crushed and mixed, in logical air
Under the conditions of be warming up to 400 DEG C with the speed of 50 DEG C/min and keep 20min, after clean, it is dry, obtain pre- carbide；Coconut palm
Shell, peach-pit, bagasse mass ratio be 1：3:2；
2), by the pre- carbide and activating agent in mass ratio 1：3 mix and are positioned in microwave radiation device, in inert gas
Low-temperature carbonization and high temperature carbonization are successively carried out under atmosphere, wherein 230 DEG C of low-temperature carbonization temperature, carbonization time 3h, heating rate is
22 DEG C/min, microwave power 580W, microwave frequency 2450MHz；；High temperature carbonization temperature is 1700 DEG C, carbonization time 5h, heating speed
Rate is 53 DEG C/min, and microwave power 900W, microwave frequency 2450MHz are passed through ammonia into microwave radiation device, relative to coconut palm
Shell, peach-pit, bagasse gross mass per 100g, the intake of ammonia is 6L/min；Activating agent is that mass ratio is 1:3 hydroxide
The mixture of potassium and zinc chloride；
3), the substance after charing is cleaned, is dried, composite biomass charcoal is made.
Embodiment 3
A kind of biological environmental production preparation for being used to remove formaldehyde, the biological environmental production preparation are made of the raw material of following parts by weight：First
45 parts of enzyme crystal of aldehyde special efficacy dissolving, 10 parts of Japan cypress tree plant bacteriocidin, 40 parts of composite biomass charcoal, 20 parts of plant extraction liquid, pottery
120 parts of 15 parts of porcelain catalyzing nano-particles and pure water.
The preparation method of ceramic nano catalysed particulate is：50 parts by weight ceramic powders and the bamboo powder of 45 parts by weight is taken to be added to
In the sodium hydroxide solution of a concentration of 25wt% of its 20 times of quality, after being uniformly dispersed, heating under reduced pressure to 180 DEG C, discongest by heat preservation
80min；It is obtained by filtration mixed-powder after discongesting, then mixed-powder is added to the ethyl alcohol of a concentration of 95wt% of its 20 times of quality
In solution, 5h is kept the temperature after being heated to 90 DEG C, is filtered again, added to its 22 times of quality after being eluted with water and being evaporated under reduced pressure
In absolute ethyl alcohol, mixed liquor is obtained；The marine algae extract of 600 parts by weight is added into mixed liquor, the bodies such as addition after stirring evenly
The copper chloride solution of long-pending a concentration of 4wt% after being crosslinked 2h at 95 DEG C, freezes 2 days, Ran Houqu in a low temperature of -22 DEG C of transfer
Go out to freeze object, be thawed with flowing water, gel is made, after vacuum drying and grinding, ceramic nano catalysed particulate is made.
The preparation method of composite biomass charcoal is as follows：
1) it is positioned in carbonizing apparatus after, coconut husk, dewatered bagasse, peach-pit after dehydration are crushed and mixed, in logical air
Under the conditions of be warming up to 500 DEG C with the speed of 65 DEG C/min and keep 30min, after clean, it is dry, obtain pre- carbide；Coconut palm
Shell, peach-pit, bagasse mass ratio be 1:4:2；
2), by the pre- carbide and activating agent in mass ratio 1：3 mix and are positioned in microwave radiation device, in inert gas
Low-temperature carbonization and high temperature carbonization are successively carried out under atmosphere, wherein 300 DEG C of low-temperature carbonization temperature, carbonization time 4h, heating rate is
25 DEG C/min, microwave power 600W, microwave frequency 2450MHz；；High temperature carbonization temperature is 1800 DEG C, carbonization time 6h, heating speed
Rate is 55 DEG C/min, and microwave power 1000W, microwave frequency 2450MHz are passed through ammonia into microwave radiation device, relative to coconut palm
Shell, peach-pit, bagasse gross mass per 100g, the intake of ammonia is 7L/min；Activating agent is that mass ratio is 1:3 hydroxide
The mixture of potassium and zinc chloride；
3), the substance after charing is cleaned, is dried, composite biomass charcoal is made.
Under the ultrasonication of 65kw, composite biomass charcoal, Japan cypress tree plant bacteriocidin and plant are added in into pure water
Extracting solution is warming up to 45 DEG C, adds in ceramic nano catalysed particulate after placing 30min, is continuously heating to 65 DEG C, keeps 45min, most
Formaldehyde special efficacy dissolving enzyme crystal is added in after postcooling to room temperature, the biological environmental production preparation of the present invention is made.
The product of embodiment 1-3 is detected according to the regulation of GB/T1881-2008, using food grade active charcoal as comparison
Example, the results are shown in Table 1.
Table 1, testing result
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example | |
| Initial amount concentration (mg/ ㎡) | 0.91 | 0.91 | 0.91 | 0.91 |
| Concentration of formaldehyde (mg/ ㎡) after 30min | 0.64 | 0.66 | 0.67 | 0.89 |
| Concentration of formaldehyde (mg/ ㎡) after 1h | 0.23 | 0.27 | 0.30 | 0.81 |
| Concentration of formaldehyde (mg/ ㎡) after 2h | 0.11 | 0.13 | 0.12 | 0.74 |
| Concentration of formaldehyde (mg/ ㎡) after 3h | 0.03 | 0.02 | 0.01 | 0.67 |
By table 1 as it can be seen that the product of the present invention is environment friendly and pollution-free, it is efficient to remove formaldehyde.
Claims (8)
1. a kind of biological environmental production preparation for being used to remove formaldehyde, which is characterized in that the biological environmental production preparation is by following parts by weight
Raw material be made：30-45 parts of enzyme crystal of formaldehyde special efficacy dissolving, 5-10 parts of Japan cypress tree plant bacteriocidin, composite biomass charcoal 30-40
80-120 parts of part, 15-20 parts of plant extraction liquid, 10-15 parts of auxiliary agent and pure water.
It is 2. according to claim 1 a kind of for removing the biological environmental production preparation of formaldehyde, which is characterized in that the auxiliary agent is
Ceramic nano catalysed particulate.
3. a kind of biological environmental production preparation for being used to remove formaldehyde according to claim 2, which is characterized in that the ceramics are received
Rice catalysed particulate preparation method be：The bamboo powder of 50 parts by weight ceramic powders and 45 parts by weight is taken to be added to its 15-20 times of quality
A concentration of 20-25wt% sodium hydroxide solution in, after being uniformly dispersed, heating under reduced pressure to 145-180 DEG C, heat preservation discongest 75-
80min；Mixed-powder is obtained by filtration after discongesting, then mixed-powder is added to a concentration of 90-95wt% of its 15-20 times of quality
Ethanol solution in, 3-5h is kept the temperature after being heated to 80-90 DEG C, is filtered again, is eluted with water and is added to after being evaporated under reduced pressure
In the absolute ethyl alcohol of its 18-22 times of quality, mixed liquor is obtained；The marine algae extract of 500-600 parts by weight is added into mixed liquor,
The copper chloride solution of isometric a concentration of 2-4wt% is added after stirring evenly, after being crosslinked 1-2h at 80-95 DEG C, transfer -18
DEG C to freeze 1-2 days in a low temperature of -22 DEG C, then take out frost object, thawed with flowing water, gel is made, through vacuum drying with
After grinding, ceramic nano catalysed particulate is made.
A kind of 4. biological environmental production preparation for being used to remove formaldehyde according to claim 1, which is characterized in that composite biomass
The preparation method of charcoal is as follows：
1) it is positioned in carbonizing apparatus after, coconut husk, dewatered bagasse, peach-pit after dehydration are crushed and mixed, in logical air
Under the conditions of be warming up to 300-500 DEG C with the speed of 45-65 DEG C/min and keep 10-30min, after clean, it is dry, obtain pre-
Carbide；
2), by the pre- carbide and activating agent in mass ratio 1：2-3 is mixed and is positioned in microwave radiation device, in indifferent gas
Low-temperature carbonization and high temperature carbonization, wherein 200-300 DEG C of low-temperature carbonization temperature, carbonization time 2-4h are successively carried out under body atmosphere；It is high
Warm carbonization temperature is 1500-1800 DEG C, carbonization time 4-6h；
3), the substance after charing is cleaned, is dried, composite biomass charcoal is made.
5. a kind of biological environmental production preparation for being used to remove formaldehyde according to claim 4, which is characterized in that the coconut husk,
Peach-pit, bagasse mass ratio be 1:2-4:1-2；Activating agent is that mass ratio is 1:3 potassium hydroxide and the mixture of zinc chloride.
6. a kind of biological environmental production preparation for being used to remove formaldehyde according to claim 4, which is characterized in that in step 2)
During low-temperature carbonization, heating rate is 20-25 DEG C/min, microwave power 500-600W, microwave frequency 2450MHz；In high temperature
In carbonization process, heating rate is 50-55 DEG C/min, microwave power 800-1000W, microwave frequency 2450MHz；The height of step 2)
In warm carbonization process, ammonia is passed through into microwave radiation device, relative to coconut husk, peach-pit, bagasse gross mass per 100g, ammonia
The intake of gas is 5-7L/min.
A kind of 7. biological environmental production preparation for being used to remove formaldehyde according to claim 1, which is characterized in that plant extraction liquid
It is 1 for volume ratio:3:1:5 Folium Artemisiae Argyi extractive liquid, eucalyptus leaf extract, cactus extraction and tree peony root extracting solution.
8. a kind of biological environmental production preparation for being used to remove formaldehyde according to claim 7, which is characterized in that folium artemisiae argyi is extracted
Active constituent content is 1.5-3mg/L in liquid, eucalyptus leaf extract, cactus extraction and tree peony root extracting solution.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054236A (en) * | 2018-07-17 | 2018-12-21 | 桐城市钰锦塑料包装有限公司 | It is a kind of can purifying formaldehyde PVC decorative material |
| CN110938890A (en) * | 2019-12-07 | 2020-03-31 | 杭州东南纺织有限公司 | Production method of polyester colored yarn |
-
2016
- 2016-12-14 CN CN201611156169.1A patent/CN108211767A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054236A (en) * | 2018-07-17 | 2018-12-21 | 桐城市钰锦塑料包装有限公司 | It is a kind of can purifying formaldehyde PVC decorative material |
| CN110938890A (en) * | 2019-12-07 | 2020-03-31 | 杭州东南纺织有限公司 | Production method of polyester colored yarn |
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