CN111227433A - Green antibacterial and bactericidal insole - Google Patents

Green antibacterial and bactericidal insole Download PDF

Info

Publication number
CN111227433A
CN111227433A CN202010087657.1A CN202010087657A CN111227433A CN 111227433 A CN111227433 A CN 111227433A CN 202010087657 A CN202010087657 A CN 202010087657A CN 111227433 A CN111227433 A CN 111227433A
Authority
CN
China
Prior art keywords
parts
powder
intermediate product
negative oxygen
oxygen ion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010087657.1A
Other languages
Chinese (zh)
Inventor
何新桥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changde Jizhi Biotechnology Co Ltd
Original Assignee
Changde Jizhi Biotechnology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changde Jizhi Biotechnology Co Ltd filed Critical Changde Jizhi Biotechnology Co Ltd
Priority to CN202010087657.1A priority Critical patent/CN111227433A/en
Publication of CN111227433A publication Critical patent/CN111227433A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B17/00Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
    • A43B17/003Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/14Plasma, i.e. ionised gases

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a green antibacterial insole which is formed by dip-dyeing in modified dye and drying; the modified dye comprises the following components: 94-97 parts of water-based dye and 3-6 parts of negative oxygen ion powder, wherein the negative oxygen ion powder comprises the following components in parts by weight: the coating comprises, by weight, 15-28 parts of chlorophyll, 19-25 parts of catechin, 10-15 parts of tea polyphenol, 20-50 parts of nano zinc oxide powder, 0.6-2.5 parts of selenium dioxide, 3-10 parts of potassium octatitanate, 0.5-4 parts of gallium arsenide, 1-6 parts of vermiculite powder and 5-20 parts of nano aerogel powder. The green antibacterial insole has the antibacterial and bactericidal functions, and can release negative oxygen ions for a long time, so that the practicability is improved.

Description

Green antibacterial and bactericidal insole
Technical Field
The invention relates to the technical field of articles for daily use, in particular to a green antibacterial and bactericidal insole.
Background
The concentration of negative ions in the air is closely related to the health of people, and people need the negative ions at any time, especially in the present day with increasingly serious pollution. According to the research of environmental scientists, people feel tired, dizziness and bloating when the concentration of negative oxygen ions in the air is less than 20 per cubic centimeter; when the number of the negative oxygen ions in each cubic centimeter of air is between 500 and 1000, people can feel calm and calm; when the number of the negative oxygen ions in each cubic centimeter of air is more than 1000, people can feel refreshed, comfortable and pleasant; the negative oxygen ions can also play a role in calming, relieving asthma, eliminating fatigue, regulating nerves and other diseases preventing and treating effects.
Negative oxygen ions are mostly present in clean, natural environments, such as: seaside, forest, waterfall (the content of waterfall is the highest), modern society has many high-tech electronic equipment, make modern people convenient, but electrical equipment can produce the harmful positive ion (known as tired ion) to the human body, we expose under TV, cell-phone, computer and new-type electronic equipment for a long time, the positive ion that they send out constantly permeates into our body and diet is acidified, cause body, heart tired, weaken immune system, reduce blood circulation, accelerate cell aging, can heart, hypertension, skin spot, muscle bone ache or various diseases for a long time.
Therefore, if the insole which can effectively sterilize and release negative oxygen ions in green for a long time can be designed, the insole has great significance and wide application prospect for human health.
Disclosure of Invention
The invention provides a green antibacterial insole, solves the technical problem that the functionality of the insole in the prior art needs to be improved, and achieves the technical effects of providing a negative oxygen ion insole, purifying the plantar environment, releasing negative oxygen ions for a long time and improving the practicability.
The invention provides a green antibacterial insole which is formed by dip-dyeing in modified dye and drying;
the modified dye comprises the following components: 94-97 parts of water-based dye and 3-6 parts of negative oxygen ion powder by weight, wherein,
the negative oxygen ion powder comprises the following components: the coating comprises, by weight, 15-28 parts of chlorophyll, 19-25 parts of catechin, 10-15 parts of tea polyphenol, 20-50 parts of nano zinc oxide powder, 0.6-2.5 parts of selenium dioxide, 3-10 parts of potassium octatitanate, 0.5-4 parts of gallium arsenide, 1-6 parts of vermiculite powder and 5-20 parts of nano aerogel powder.
Preferably, the modified dye comprises the following components: 95.5 parts of water-based dye and 4.5 parts of negative oxygen ion powder.
Preferably, the modified dye is prepared by adding the negative oxygen ion powder into the water-based dye and then uniformly stirring.
Preferably, the negative oxygen ion powder comprises the following components: the coating comprises, by weight, 20 parts of chlorophyll, 20 parts of catechin, 10 parts of tea polyphenol, 30 parts of nano zinc oxide powder, 1 part of selenium dioxide, 5 parts of potassium octatitanate, 1 part of gallium arsenide, 3 parts of vermiculite powder and 10 parts of nano aerogel powder.
Preferably, the preparation process of the negative oxygen ion powder comprises the following steps:
stirring the nano zinc oxide, the selenium dioxide, the potassium octatitanate, the gallium arsenide and the vermiculite powder at a first stage to obtain a first intermediate product;
calcining the first intermediate product to obtain a second intermediate product;
after the second intermediate product is cooled, adding the chlorophyll, the catechin and the tea polyphenol into the second intermediate product for second-stage stirring;
adding the nano aerogel powder into the second intermediate product to carry out third-stage stirring to obtain a third intermediate product;
adding normal saline into the third intermediate product for grinding to obtain a fourth intermediate product;
and drying the fourth intermediate product to obtain the negative oxygen ion powder.
One or more technical solutions provided in the embodiments of the present application have at least the following technical effects or advantages:
the insole is formed by dip-dyeing in modified dye and drying; the modified dye takes the traditional water-based dye and the negative oxygen ion powder as raw materials, and on the basis of dyeing of the traditional water-based dye, the functions of antibiosis, sterilization and negative oxygen ion release are enhanced through the negative oxygen ion powder; the chlorophyll, catechin and tea polyphenol contained in the negative oxygen ion powder are plants which absorb carbon dioxide and release more oxygen, and are more than 10 times of those of common plants. The nano zinc oxide is an antioxidant material, the selenium dioxide is a photosensitive material, the potassium octatitanate is a heat-resistant and heat-insulating material and absorbs light, the gallium arsenide is a superconducting material and can release absorbed ultraviolet rays at night, the vermiculite powder is a material with a higher expansion coefficient, the nano aerogel is a porous nano material, the material is filled in the aerogel, and the ultraviolet rays irradiate the chlorophyll, the tea polyphenol and the catechin by means of expansion of the vermiculite powder during heating, so that the function of releasing negative oxygen ions for a long time is realized. Like this, solved among the prior art technical problem that the shoe-pad functionality remains to be promoted, realized providing a negative oxygen ion shoe-pad, when purifying sole environment, can also release negative oxygen ion for a long time, promote practicality's technical effect.
Drawings
Fig. 1 is a schematic flow chart of a process for preparing a modified dye provided in an embodiment of the present application.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
The invention provides a green antibacterial insole which is formed by dip-dyeing in modified dye and drying; the insole can be made of common fabric or leather.
The modified dye comprises the following components: 94-97 parts of water-based dye and 3-6 parts of negative oxygen ion powder by weight, wherein,
the negative oxygen ion powder comprises the following components: the coating comprises, by weight, 15-28 parts of chlorophyll, 19-25 parts of catechin, 10-15 parts of tea polyphenol, 20-50 parts of nano zinc oxide powder, 0.6-2.5 parts of selenium dioxide, 3-10 parts of potassium octatitanate, 0.5-4 parts of gallium arsenide, 1-6 parts of vermiculite powder and 5-20 parts of nano aerogel powder.
The nano zinc oxide has the double characteristics of nano materials and traditional zinc oxide, has the characteristics of high-efficiency biological activity, high absorption rate, strong oxidation resistance, safety, stability and the like as a nano material, and utilizes the oxidation resistance of the nano zinc oxide.
Selenium dioxide is a photosensitive material; the potassium octatitanate is heat-resistant and heat-insulating material and can be adsorbed by light; the gallium arsenide is a superconducting material and can release absorbed ultraviolet rays at night; the vermiculite powder is a material with a higher expansion coefficient; the nano aerogel is a porous nano material, and the nano aerogel is filled in pores. When the heat is generated, ultraviolet rays are irradiated on chlorophyll, tea polyphenol and catechin by means of expansion of vermiculite powder, so that the function of releasing negative oxygen ions for a long time is realized. Chlorophyll, tea polyphenol and catechin absorb carbon dioxide to release oxygen, the oxygen contains abundant large, medium and small anions (negative oxygen ions), and the small anions have the functions of adsorbing and decomposing formaldehyde, peculiar smell, benzene and tvoc and can kill various viruses.
Further, the modified dye comprises the following components: 95.5 parts of water-based dye and 4.5 parts of negative oxygen ion powder. The modified dye is prepared by adding negative oxygen ion powder into water-based dye and then uniformly stirring.
As a preferred embodiment, the negative oxygen ion powder comprises the following components: the composition comprises, by weight, 20 parts of chlorophyll, 20 parts of catechin, 10 parts of tea polyphenol, 30 parts of nano zinc oxide powder, 1 part of selenium dioxide, 5 parts of potassium octatitanate, 1 part of gallium arsenide, 3 parts of vermiculite powder and 10 parts of nano aerogel powder.
Further, the preparation process of the negative oxygen ion powder comprises the following steps:
s1: stirring nano zinc oxide, selenium dioxide, potassium octatitanate, gallium arsenide and vermiculite powder in a set ratio at a first stage to obtain a first intermediate product;
s2: calcining the first intermediate product to obtain a second intermediate product;
s3: after the second intermediate product is cooled, adding chlorophyll, catechin and tea polyphenol into the second intermediate product for second-stage stirring;
s4: adding the nano aerogel powder into the second intermediate product, and stirring for the third stage to obtain a third intermediate product;
s5: adding normal saline into the third intermediate product for grinding to obtain a fourth intermediate product;
s6: and drying the fourth intermediate product to obtain negative oxygen ion powder.
Further, the stirring time of the first stage is controlled to be 25-60 minutes; the calcination time is controlled to be 7-10 hours; the stirring time of the second stage is controlled to be 25-40 minutes; the stirring time in the third stage is controlled to be 45-100 minutes; the grinding time is controlled to be 10-20 hours. As a preferred example, the time of the first-stage stirring is controlled to 30 minutes; the calcination time is controlled to be 8 hours; the stirring time of the second stage is controlled to be 30 minutes; the stirring time of the third stage is controlled to be 60 minutes; the time for milling was controlled at 12 hours.
In addition, referring to the attached figure 1, the preparation process of the modified dye is as follows: after the preparation of the negative oxygen ion powder is completed, the process proceeds to step S7: adding the negative oxygen ion powder with a set ratio into the water-based dye, and uniformly stirring to obtain the modified dye.
The preparation of the modified dyes is described in detail below by means of specific examples, all raw materials being calculated in parts by weight:
example 1
S1: putting 28 parts of nano zinc oxide powder, 1 part of selenium dioxide, 4 parts of potassium octatitanate, 0.6 part of gallium arsenide and 1.5 parts of vermiculite powder into a stainless steel stirring tank for first-stage stirring to obtain a first intermediate product; the stirring time of the first stage is controlled to be 30 minutes;
s2: calcining the first intermediate product in a high-temperature furnace to obtain a second intermediate product; the calcination time is controlled to be 8 hours;
s3: after the second intermediate product is cooled, placing the second intermediate product in a stainless steel stirring tank, and then adding 19 parts of chlorophyll, 20 parts of catechin and 10 parts of tea polyphenol into the stainless steel stirring tank for second-stage stirring; the stirring time of the second stage is controlled to be 35 minutes;
s4: adding 8 parts of nano aerogel powder into a stainless steel stirring tank for third-stage stirring to obtain a third intermediate product; the stirring time of the third stage is controlled to be 70 minutes;
s5: putting the third intermediate product into a sand mill, adding 12 parts of normal saline, and grinding to obtain a fourth intermediate product; the grinding time is controlled to be 12 hours;
s6: putting the fourth intermediate product into a spray dryer for spray drying to obtain negative oxygen ion powder;
s7: adding 3.5 parts of negative oxygen ion powder into 96.5 parts of water-based dye, and uniformly stirring to obtain the modified dye.
Example 2
S1: placing 30 parts of nano zinc oxide powder, 1 part of selenium dioxide, 5 parts of potassium octatitanate, 1 part of gallium arsenide and 3 parts of vermiculite powder in a stainless steel stirring tank for first-stage stirring to obtain a first intermediate product; the stirring time of the first stage is controlled to be 30 minutes;
s2: calcining the first intermediate product in a high-temperature furnace to obtain a second intermediate product; the calcination time is controlled to be 8 hours;
s3: after the second intermediate product is cooled, placing the second intermediate product in a stainless steel stirring tank, and then adding 20 parts of chlorophyll, 20 parts of catechin and 10 parts of tea polyphenol into the stainless steel stirring tank for second-stage stirring; the stirring time of the second stage is controlled to be 30 minutes;
s4: adding 10 parts of nano aerogel powder into a stainless steel stirring tank for third-stage stirring to obtain a third intermediate product; the stirring time of the third stage is controlled to be 60 minutes;
s5: placing the third intermediate product in a sand mill, adding 15 parts of normal saline, and grinding to obtain a fourth intermediate product; the grinding time is controlled to be 12 hours;
s6: putting the fourth intermediate product into a spray dryer for spray drying to obtain negative oxygen ion powder;
s7: and 4.5 parts of negative oxygen ion powder is added into 95.5 parts of water-based dye, and the modified dye is obtained after uniform stirring.
Example 3
S1: putting 35 parts of nano zinc oxide powder, 1.3 parts of selenium dioxide, 5.5 parts of potassium octatitanate, 1.5 parts of gallium arsenide and 3.5 parts of vermiculite powder into a stainless steel stirring tank for first-stage stirring to obtain a first intermediate product; the stirring time of the first stage is controlled to be 40 minutes;
s2: calcining the first intermediate product in a high-temperature furnace to obtain a second intermediate product; the calcination time is controlled to be 9 hours;
s3: after the second intermediate product is cooled, placing the second intermediate product in a stainless steel stirring tank, and then adding 21 parts of chlorophyll, 22 parts of catechin and 11 parts of tea polyphenol into the stainless steel stirring tank for second-stage stirring; the stirring time of the second stage is controlled to be 35 minutes;
s4: adding 13 parts of nano aerogel powder into a stainless steel stirring tank for third-stage stirring to obtain a third intermediate product; the stirring time of the third stage is controlled to be 80 minutes;
s5: placing the third intermediate product in a sand mill, adding 16 parts of normal saline, and grinding to obtain a fourth intermediate product; the grinding time is controlled to be 15 hours;
s6: putting the fourth intermediate product into a spray dryer for spray drying to obtain negative oxygen ion powder;
s7: and adding 5 parts of negative oxygen ion powder into 95 parts of water-based dye, and uniformly stirring to obtain the modified dye.
The above-mentioned embodiments, objects, technical solutions and advantages of the present invention are further described in detail, it should be understood that the above-mentioned embodiments are only illustrative of the present invention and are not intended to limit the present invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (5)

1. A green antibacterial insole is characterized in that the insole is formed by dip-dyeing in modified dye and drying;
the modified dye comprises the following components: 94-97 parts of water-based dye and 3-6 parts of negative oxygen ion powder by weight, wherein,
the negative oxygen ion powder comprises the following components: the coating comprises, by weight, 15-28 parts of chlorophyll, 19-25 parts of catechin, 10-15 parts of tea polyphenol, 20-50 parts of nano zinc oxide powder, 0.6-2.5 parts of selenium dioxide, 3-10 parts of potassium octatitanate, 0.5-4 parts of gallium arsenide, 1-6 parts of vermiculite powder and 5-20 parts of nano aerogel powder.
2. The green antibacterial and bactericidal insole as claimed in claim 1, wherein the modified dye is composed of: 95.5 parts of water-based dye and 4.5 parts of negative oxygen ion powder.
3. The green antibacterial insole as claimed in claim 1, wherein said modified dye is prepared by adding said negative oxygen ion powder to said aqueous dye and stirring uniformly.
4. The green antibacterial and bactericidal insole as claimed in claim 1, wherein said negative oxygen ion powder comprises the following components: the coating comprises, by weight, 20 parts of chlorophyll, 20 parts of catechin, 10 parts of tea polyphenol, 30 parts of nano zinc oxide powder, 1 part of selenium dioxide, 5 parts of potassium octatitanate, 1 part of gallium arsenide, 3 parts of vermiculite powder and 10 parts of nano aerogel powder.
5. The green antibacterial and bactericidal insole as claimed in claim 1, wherein the preparation process of the negative oxygen ion powder comprises:
stirring the nano zinc oxide, the selenium dioxide, the potassium octatitanate, the gallium arsenide and the vermiculite powder at a first stage to obtain a first intermediate product;
calcining the first intermediate product to obtain a second intermediate product;
after the second intermediate product is cooled, adding the chlorophyll, the catechin and the tea polyphenol into the second intermediate product for second-stage stirring;
adding the nano aerogel powder into the second intermediate product to carry out third-stage stirring to obtain a third intermediate product;
adding normal saline into the third intermediate product for grinding to obtain a fourth intermediate product;
and drying the fourth intermediate product to obtain the negative oxygen ion powder.
CN202010087657.1A 2020-02-12 2020-02-12 Green antibacterial and bactericidal insole Pending CN111227433A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010087657.1A CN111227433A (en) 2020-02-12 2020-02-12 Green antibacterial and bactericidal insole

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010087657.1A CN111227433A (en) 2020-02-12 2020-02-12 Green antibacterial and bactericidal insole

Publications (1)

Publication Number Publication Date
CN111227433A true CN111227433A (en) 2020-06-05

Family

ID=70874981

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010087657.1A Pending CN111227433A (en) 2020-02-12 2020-02-12 Green antibacterial and bactericidal insole

Country Status (1)

Country Link
CN (1) CN111227433A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7320711B1 (en) 2022-12-16 2023-08-04 株式会社データマックス footwear

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000009607U (en) * 1998-11-07 2000-06-05 전주범 Refrigerator Hot Pipe Fixture
CN104117085A (en) * 2014-08-04 2014-10-29 武汉市意朗一品生物环保科技有限公司 Air freshener and preparation method thereof
CN105708046A (en) * 2016-03-15 2016-06-29 崔仕生 Preparation method of sterilization insole
CN106263267A (en) * 2016-08-22 2017-01-04 界首市普惠科技咨询服务有限公司 Efficient deodorizing Antimicrobial sanitation material for sole of shoe
CN106360879A (en) * 2016-08-28 2017-02-01 杭州锴越新材料有限公司 Multifunctional healthy negative-ion insoles and making method thereof
CN108634481A (en) * 2018-06-04 2018-10-12 湖州林品服饰有限公司 A kind of insole
CN108835770A (en) * 2018-07-11 2018-11-20 合肥远科服装设计有限公司 A kind of environmental-protecting insoles and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000009607U (en) * 1998-11-07 2000-06-05 전주범 Refrigerator Hot Pipe Fixture
CN104117085A (en) * 2014-08-04 2014-10-29 武汉市意朗一品生物环保科技有限公司 Air freshener and preparation method thereof
CN105708046A (en) * 2016-03-15 2016-06-29 崔仕生 Preparation method of sterilization insole
CN106263267A (en) * 2016-08-22 2017-01-04 界首市普惠科技咨询服务有限公司 Efficient deodorizing Antimicrobial sanitation material for sole of shoe
CN106360879A (en) * 2016-08-28 2017-02-01 杭州锴越新材料有限公司 Multifunctional healthy negative-ion insoles and making method thereof
CN108634481A (en) * 2018-06-04 2018-10-12 湖州林品服饰有限公司 A kind of insole
CN108835770A (en) * 2018-07-11 2018-11-20 合肥远科服装设计有限公司 A kind of environmental-protecting insoles and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李玉宝 等: "《纳米材料研究与应用》", 31 January 2005, 电子科技大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7320711B1 (en) 2022-12-16 2023-08-04 株式会社データマックス footwear
JP2024086343A (en) * 2022-12-16 2024-06-27 株式会社データマックス footwear

Similar Documents

Publication Publication Date Title
CN111134393A (en) Green antibacterial sterilization negative oxygen ion release mask
CN107468423A (en) Tea Polyphenols sanitary towel chip and sanitary napkin
KR20110000216A (en) Composition for aromatic containing extracts of pine needlesand, artemisia, green tea leaves and the manufacturing method thereof
CN112322386A (en) Negative oxygen ion plant essence for water forest air disinfection and preparation method thereof
CN111227433A (en) Green antibacterial and bactericidal insole
CN101336855A (en) Magnetic far-infrared negative-ion energy eye-mask
CN111282414A (en) Green antibacterial sterilization negative oxygen ion releasing powder and preparation method thereof
CN111172750A (en) Green antibacterial sterilizing negative oxygen ion releasing curtain
CN111287005A (en) Green antibacterial and bactericidal negative oxygen ion releasing garment
CN111264553A (en) Green antibacterial sterilization negative oxygen ion release spray and preparation method thereof
CN111286272A (en) Green antibacterial sterilization negative oxygen ion release air conditioner filter screen and air conditioner
CN111171710A (en) Green antibacterial negative oxygen ion releasing picture
CN111778734A (en) Green antibacterial sterilization negative oxygen ion release automobile lining cloth
CN111206436A (en) Green antibacterial sterilizing negative oxygen ion releasing seat cushion
CN111281839A (en) Green antibacterial and bactericidal mask
CN102090996A (en) Traditional Chinese medicine perfume
CN113047036B (en) Jade-zinc ice health-care fiber and preparation method thereof
CN111172755A (en) Green antibacterial sterilization negative oxygen ion release bed sheet quilt cover
CN111265365A (en) Green antibiotic ventilative diaper that disinfects
CN111206437A (en) Green antibacterial sterilization negative oxygen ion release automobile cushion
CN111206435A (en) Green antibacterial breathable baby mattress
CN111281008A (en) Green antibacterial and bactericidal negative oxygen ion releasing pillow
KR102075753B1 (en) Composition of deodorant for sanitary materials, Deodorant for sanitary materials
CN109364686A (en) A kind of efficient deodorizing oxygen material
KR102075436B1 (en) Sports muscle tape

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20200605

RJ01 Rejection of invention patent application after publication