CN108198910A - The electric leakage processing method of crystal-silicon solar cell - Google Patents

The electric leakage processing method of crystal-silicon solar cell Download PDF

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Publication number
CN108198910A
CN108198910A CN201810040765.6A CN201810040765A CN108198910A CN 108198910 A CN108198910 A CN 108198910A CN 201810040765 A CN201810040765 A CN 201810040765A CN 108198910 A CN108198910 A CN 108198910A
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CN
China
Prior art keywords
crystal
solar cell
silicon solar
electric leakage
processing method
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Pending
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CN201810040765.6A
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Chinese (zh)
Inventor
夏世伟
张为国
张松
韩向超
杨崇文
陈寒
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Shanghai New Energy Technology Co Ltd Of Big Nation
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Shanghai New Energy Technology Co Ltd Of Big Nation
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Priority to CN201810040765.6A priority Critical patent/CN108198910A/en
Publication of CN108198910A publication Critical patent/CN108198910A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention relates to a kind of electric leakage processing methods of crystal-silicon solar cell.The electric leakage processing method includes the following steps:The positive and negative electrode of crystal-silicon solar cell is connected on to the positive and negative anodes of power supply respectively, is powered;After energization, on the silicon chip front surface of the crystal silicon solar energy battery, acquisition is located at the physical features data at edge different location;According to the physical features data at the different location, the position where the PN junction in the crystal-silicon solar cell is determined;The PN junction is separated using laser.The electric leakage processing method of above-mentioned crystal-silicon solar cell, can not only avoid crystal-silicon solar cell from leaking electricity, additionally it is possible to maximally utilise limited light-emitting area, while can choose the problem of mistake causes yield rate low to avoid insulating regions.

Description

The electric leakage processing method of crystal-silicon solar cell
Technical field
The present invention relates to technical field of solar cells, more particularly to a kind of electric leakage processing side of crystal-silicon solar cell Method.
Background technology
Crystal-silicon solar cell is a kind of semiconductor devices for converting light energy into electric energy.Under the irradiation of light, crystalline silicon Photo-generated carrier is generated inside solar cell, these photo-generated carriers are under the action of PN junction built in field to the positive and negative anodes of battery Migration, and drawn through electrode, it is converted into electric energy.
In solar cell preparation process, PN junction is typically to be prepared using the method for High temperature diffusion or ion implanting.This two Kind method all can generate diffusion layer in the position by proximal edge, be connected so as to cause positive and negative anodes short circuit, form electric leakage.
Invention content
Based on this, it is necessary to for how to avoid the problem that crystal-silicon solar cell leaks electricity, provide a kind of crystalline silicon sun The electric leakage processing method of battery.
A kind of electric leakage processing method of crystal-silicon solar cell, includes the following steps:
The positive and negative electrode of crystal-silicon solar cell is connected on to the positive and negative anodes of power supply respectively, is powered;
After energization, on the silicon chip front surface of the crystal silicon solar energy battery, acquisition is located at edge different location Physical features data;
According to the physical features data at the different location, where determining the PN junction in the crystal-silicon solar cell Position;
The PN junction is separated using laser.
The electric leakage processing method of above-mentioned crystal-silicon solar cell, by the way that the positive and negative electrode of crystal-silicon solar cell is connect respectively In the positive and negative anodes of power supply, so that crystal-silicon solar cell is powered, the silicon chip of the crystal-silicon solar cell after acquisition energization The physical features data of the different location at the edge of front surface, so as to determine crystalline substance according to the physical features data of the different location The position where PN junction in body silicon solar cell recycles laser to separate PN junction, so as to remove electric leakage region, to the region It insulate, this method determines the position where the PN junction in crystal-silicon solar cell by way of acquiring physical features data It puts, additionally it is possible to greatly improve insulation yield rate.
The voltage of the power supply is 10V-15V in one of the embodiments,.
Light intensity of the physical features data for the edge of the crystal-silicon solar cell in one of the embodiments, And/or temperature.
Light intensity is measured using photosensitive probe in one of the embodiments,;Temperature is measured using temp probe.
In one of the embodiments, determine the PN junction where position the step of include by the crystalline silicon sun electricity The position coordinates of every bit on the edge of the front surface of the silicon chip in pond and the physical features data corresponding to it are fitted, and are obtained Obtain matched curve;Obtain the corresponding position coordinates of wave crest in the matched curve, the seat of the position where as described PN junction Mark.
The matched curve is sent to mark galvanometer in one of the embodiments, the mark galvanometer is according to Matched curve carries out laser scanning, and the PN junction is separated, and groove is formed in the position where the PN junction.
The laser is infrared light that wavelength is 700nm-1064nm in one of the embodiments, or wavelength is The green fluorescence of 488nm-532nm.
The pattern of the laser is pulse mode or quasi-continuous pattern in one of the embodiments,;Spot diameter is 1- 500μm。
The depth of the groove is 5 μm -50 μm in one of the embodiments,;The width of the groove is 10 μm of -200 μ m。
The crystal-silicon solar cell is p-n-n types solar cell or the n-n-p type sun in one of the embodiments, Battery.
Description of the drawings
Fig. 1 is the flow diagram of the electric leakage processing method of the crystal-silicon solar cell of an embodiment;
Fig. 2 is the structure diagram of the crystalline silicon Double side diffusion solar cell of an embodiment;
Fig. 3 is the structure diagram after PN junction shown in Fig. 2 partition.
Specific embodiment
It is understandable for the above objects, features and advantages of the present invention is enable to become apparent, below in conjunction with the accompanying drawings to the present invention Specific embodiment be described in detail.
As shown in Figure 1, the electric leakage processing method of the crystal-silicon solar cell of an embodiment, includes the following steps:
S10:The positive and negative electrode of crystal-silicon solar cell is connected on to the positive and negative anodes of power supply respectively, is powered.
Specifically, the voltage of power supply is 10V-15V, the positive and negative electrode of crystal-silicon solar cell respectively with the high potential of power supply End is connected with cold end, so that crystal-silicon solar cell is powered.That is, using the voltage of 10V-15V to crystal Silicon solar cell is powered.Wherein, crystal-silicon solar cell can be p-n-n types crystal-silicon solar cell or n-n-p types Crystal-silicon solar cell.Silicon chip can also be p-type or N-type used by crystal-silicon solar cell, at this to the crystalline silicon sun The type of battery does not limit.Power-on voltage is 12V in one of the embodiments, so as to be carried for crystal-silicon solar cell For stable voltage.In the present embodiment, crystal-silicon solar cell is crystal silicon double-side solar cell.
As shown in Fig. 2, crystal-silicon solar cell 100 include N-type silicon chip 110 and N-type silicon chip 110 back surface successively The p+ emitter layers 120 of stacking, the first silicon nitride passivation 130 and silver-colored aluminum honeycomb 140 and the positive table in N-type silicon chip 110 N+ surface fields layer 150, the second silicon nitride passivation 160 and the silver positive electrode 170 that face stacks gradually.
S20:After energization, on the silicon chip front surface of crystal silicon solar energy battery, acquisition is located at edge different location Physical features data.
Specifically, in one of the embodiments, physical features data for crystal-silicon solar cell edge light intensity or Temperature.In other embodiments, physical features data may be light intensity and temperature.Further, it is measured using photosensitive probe Light intensity measures temperature using temp probe.That is, using photosensitive probe along the side of the front surface of crystal-silicon solar cell Edge one encloses, so as to capture the light intensity of each position at its edge, this is because preparation of the PN junction in crystal-silicon solar cell Cheng Zhonghui is formed at the edge of crystal-silicon solar cell or by the position of proximal edge, and has the light intensity of PN junction where will It is stronger, so as to the light at this want it is bright very much.It should be noted that physical features data may be intensity of reflected light etc..
If physical features data are temperature, using temperature probe along the edge one of the front surface of crystal-silicon solar cell The temperature difference of each position at its edge is enclosed and captures, this is because the temperature of position existing for PN junction can be higher.Wherein, it surveys Temperature probe can be thermocouple etc..
S30:According to the physical features data at different location, the position where the PN junction in crystal-silicon solar cell is determined It puts.
Specifically, by the position of the every bit on the edge of the front surface of crystal-silicon solar cell collected in step S20 It puts coordinate and the physical features data corresponding to it is fitted, obtain matched curve.Wherein it is possible to using modes such as excel It is fitted.That is, can be using coordinate position as abscissa, light intensity or the temperature difference are ordinate, corresponding so as to fit Curve.After matched curve is obtained, the corresponding position coordinates of wave crest in matched curve, the as position where PN junction are obtained Coordinate.It can be seen from the above, the light intensity maximum or maximum temperature of position existing for PN junction, so as to which light intensity is most strong in matched curve Or the position of temperature difference maximum is exactly the position where PN junction 180, as shown in Figure 2.
S40:PN junction is separated using laser.
Specifically, the matched curve obtained in step S30 is sent to mark galvanometer in one of the embodiments, beaten It marks galvanometer and laser scanning is carried out according to the matched curve, and PN junction is separated, form groove 181 in the position where PN junction, such as Shown in Fig. 3.That is, matched curve is sent to mark galvanometer, mark galvanometer presets laser beam scan path, is swept in laser During retouching, laser scanning is carried out to the position where PN junction, so as to separate PN junction, and then formed in the position where PN junction Groove 181.So as to insulate to it, crystal-silicon solar cell is avoided to leak electricity.By the position where first determining PN junction, then use Laser separates the position, so as to maximally utilise limited light-emitting area, while can be to avoid insulation layer The problem of mistake causes yield rate low, is chosen in domain, simple for process, can extensive use.
Laser is infrared light that wavelength is 700nm-1064nm in one of the embodiments, or wavelength is 488nm- The green fluorescence of 532nm.Zlasing mode is pulse mode or quasi-continuous pattern;Spot diameter is 1-500 μm.Spot diameter etc. can To be selected according to the size of actually required groove to be formed.In the present embodiment, it is the infrared of 850nm that laser, which is wavelength, Light, zlasing mode are pulse mode, and spot diameter is 10 μm.
The depth of groove 181 is 5 μm -50 μm in one of the embodiments,;The width of groove 181 is 10 μm -200 μm.
The electric leakage processing method of above-mentioned crystal-silicon solar cell, by the way that the positive and negative electrode of crystal-silicon solar cell is connect respectively In the positive and negative anodes of power supply, so that crystal-silicon solar cell is powered, the silicon chip of the crystal-silicon solar cell after acquisition energization The physical features data of the different location at the edge of front surface, so as to determine crystalline substance according to the physical features data of the different location The position where PN junction in body silicon solar cell recycles laser to separate PN junction, so as to remove electric leakage region, to the region It insulate, this method determines the position where the PN junction in crystal-silicon solar cell by way of acquiring physical features data It puts, additionally it is possible to greatly improve insulation yield rate.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, it is all considered to be the range of this specification record.
Embodiment described above only expresses the several embodiments of the present invention, and description is more specific and detailed, but simultaneously It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that those of ordinary skill in the art are come It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (10)

1. the electric leakage processing method of a kind of crystal-silicon solar cell, which is characterized in that include the following steps:
The positive and negative electrode of crystal-silicon solar cell is connected on to the positive and negative anodes of power supply respectively, is powered;
After energization, on the silicon chip front surface of the crystal silicon solar energy battery, acquisition is located at the physics at edge different location Characteristic;
According to the physical features data at the different location, the position where the PN junction in the crystal-silicon solar cell is determined It puts;
The PN junction is separated using laser.
2. the electric leakage processing method of crystal-silicon solar cell according to claim 1, which is characterized in that the electricity of the power supply It presses as 10V-15V.
3. the electric leakage processing method of crystal-silicon solar cell according to claim 1, which is characterized in that the physical features Light intensity and/or temperature of the data for the edge of the crystal-silicon solar cell.
4. the electric leakage processing method of crystal-silicon solar cell according to claim 3, which is characterized in that using photosensitive probe Measure light intensity;Temperature is measured using temp probe.
5. the electric leakage processing method of the crystal-silicon solar cell according to any one of claim 1-4, which is characterized in that really The step of position where the fixed PN junction, includes:It will be every on the edge of the front surface of the silicon chip of the crystal-silicon solar cell The position coordinates of any and the physical features data corresponding to it are fitted, and obtain matched curve;Obtain the matched curve In the corresponding position coordinates of wave crest, the coordinate of the position where as described PN junction.
6. the electric leakage processing method of crystal-silicon solar cell according to claim 5, which is characterized in that the fitting is bent Line is sent to mark galvanometer, and the mark galvanometer carries out laser scanning according to the matched curve, and the PN junction is separated, Position where the PN junction forms groove.
7. the electric leakage processing method of crystal-silicon solar cell according to claim 6, which is characterized in that the laser is wave The infrared light or wavelength of a length of 700nm-1064nm is the green fluorescence of 488nm-532nm.
8. the electric leakage processing method of crystal-silicon solar cell according to claim 7, which is characterized in that the mould of the laser Formula is pulse mode or quasi-continuous pattern;Spot diameter is 1-500 μm.
9. the electric leakage processing method of crystal-silicon solar cell according to claim 6, which is characterized in that the depth of the groove Spend is 5 μm -50 μm;The width of the groove is 10 μm -200 μm.
10. the electric leakage processing method of the crystal-silicon solar cell according to any one of claim 1-4, which is characterized in that The crystal-silicon solar cell is p-n-n types solar cell or n-n-p type solar cells.
CN201810040765.6A 2018-01-16 2018-01-16 The electric leakage processing method of crystal-silicon solar cell Pending CN108198910A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112103373A (en) * 2020-11-12 2020-12-18 常州捷佳创精密机械有限公司 Edge processing system and method for solar cell

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CN101789465A (en) * 2010-01-08 2010-07-28 中山大学 Defect remedying method of crystalline silicon solar cell
CN102197311A (en) * 2008-08-29 2011-09-21 奥德森公司 System and method for localizing and passivating defects in a photovoltaic element
CN103280494A (en) * 2013-06-14 2013-09-04 奥特斯维能源(太仓)有限公司 Method for repairing crystalline silicon solar cell with leaky edges
CN103746028A (en) * 2013-12-24 2014-04-23 宁夏银星能源股份有限公司 Crystalline silicon solar cells edge local electric leakage processing method
CN104835875A (en) * 2015-04-20 2015-08-12 上海大族新能源科技有限公司 Preparation method and side edge laser isolation method for crystalline silicon solar cell

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102197311A (en) * 2008-08-29 2011-09-21 奥德森公司 System and method for localizing and passivating defects in a photovoltaic element
CN101710601A (en) * 2009-10-30 2010-05-19 浙江正泰太阳能科技有限公司 Method and equipment for repairing thin film solar cell
CN101789465A (en) * 2010-01-08 2010-07-28 中山大学 Defect remedying method of crystalline silicon solar cell
CN103280494A (en) * 2013-06-14 2013-09-04 奥特斯维能源(太仓)有限公司 Method for repairing crystalline silicon solar cell with leaky edges
CN103746028A (en) * 2013-12-24 2014-04-23 宁夏银星能源股份有限公司 Crystalline silicon solar cells edge local electric leakage processing method
CN104835875A (en) * 2015-04-20 2015-08-12 上海大族新能源科技有限公司 Preparation method and side edge laser isolation method for crystalline silicon solar cell

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112103373A (en) * 2020-11-12 2020-12-18 常州捷佳创精密机械有限公司 Edge processing system and method for solar cell
CN112103373B (en) * 2020-11-12 2021-08-13 常州捷佳创精密机械有限公司 Edge processing system and method for solar cell

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