CN108192445A - One kind is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects - Google Patents
One kind is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects Download PDFInfo
- Publication number
- CN108192445A CN108192445A CN201711174594.8A CN201711174594A CN108192445A CN 108192445 A CN108192445 A CN 108192445A CN 201711174594 A CN201711174594 A CN 201711174594A CN 108192445 A CN108192445 A CN 108192445A
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- China
- Prior art keywords
- parts
- moisture absorption
- sustained release
- expelling parasite
- odor type
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses one kind with moisture absorption, expelling parasite, and the aqueous weather-resistant coating of sustained release odor type of calming effects belongs to technical field of coatings.The water paint of the present invention includes following raw material：Organic-silicon-modified pure-acrylic emulsion, waterborne polyurethane resin, expanded vermiculite, curing agent, function additive, PH conditioning agents, deionized water.Compared with existing water paint, water paint of the invention have the advantages that weatherability it is high, can moisture absorption, can itself is fragrant, available for indoor and outdoor.
Description
Technical field
The present invention relates to one kind with moisture absorption, expelling parasite, and the aqueous weather-resistant coating of sustained release odor type of calming effects belongs to coating
Technical field.
Background technology
It has excellent processing performance, mechanical performance and physical property to acrylic resin paint, and application is very extensive.But at present
Most acrylic resin paints are solvent based coating, mostly sticky liquid or solid, not soluble in water, and are dissolved in aromatic hydrocarbons
The organic solvents such as class, ketone, and organic solvent is volatile and inflammable and explosive, it is toxic, very big danger is caused to environment and human body
Evil as requirement of the people to environmental protection is increasingly urgent and stringent, is grown to even greater heights using the requirement of water paint, acrylic acid tree
Grease coating material Water-borne modification is just applied and is given birth to.It is main film forming substance, but in its building-up process that acrylic emulsion is commonly used in water paint
Because of such as methyl acrylate, ethyl acrylate etc. containing other monomers, cause the peculiar smell after coating use big, do not connect by consumer
By by selecting aqueous pure-acrylic emulsion that can solve the problems, such as this；In addition, the weatherability of existing acrylic acid aqueous coating also has
It waits to improve.The Publication No. CN102786625A as disclosed in State Intellectual Property Office 21 days November in 2012, title
For the patent of invention of " a kind of for emulsion acrylic resin of water paint and preparation method thereof ", which disclose acrylic acid
Resin emulsion mainly by：Deionized water, methacrylic acid, butyl acrylate, methyl methacrylate, nonionic emulsifier,
Anionic emulsifier, single hydroxyl ethyl ester phosphate, N, the compositions such as N- dimethylethanolamines, 10% Ammonium Persulfate 98.5 aqueous solution.This is specially
Profit still has the problem of peculiar smell is big and weatherability is not high enough.
Invention content
Present invention seek to address that in the prior art, when water-based acrylic resin does film forming matter, peculiar smell is big, and weatherability is not high
The problem of, proposition is a kind of using organic-silicon-modified pure-acrylic emulsion as the water paint of main film forming substance, has peculiar smell small, to ring
The advantages of border is friendly, and weatherability is high.
The technical solution that the present invention takes is：One kind is with moisture absorption, expelling parasite, and the sustained release odor type of calming effects is aqueous weather-proof
Coating, the parts by weight of raw material are as follows
Organic-silicon-modified 15~35 parts of pure-acrylic emulsion
15~35 parts of waterborne polyurethane resin
1~8 part of expanded vermiculite
3~12 parts of curing agent
1.5~3 parts of function additive
0.5~3 part of PH conditioning agents
40~55 parts of deionized water.
As a kind of perferred technical scheme：The curing agent is one kind in triethylene tetramine and N- hydroxy acrylic acid amides
Or two kinds.As a kind of perferred technical scheme：The function additive is ultra-violet absorber, in coalescents, antifoaming agent
It is at least one.As a kind of perferred technical scheme：The pH conditioning agents are sodium hydroxide.
The beneficial effects of the invention are as follows：（1）The present invention selects organic-silicon-modified pure-acrylic emulsion to do main film forming substance, removes
Have the characteristics that outside the free from extraneous odour of pure-acrylic emulsion in itself, it is organic-silicon-modified after the water paint that is made into of pure-acrylic emulsion it is sun-proof
Performance is more preferable, after shining long, it is not easy to change colour, after long-time use, appearance still keeps certain flatness, and durability is good, and table
Face is bright and clean, and dirt retention is low.The water paint of the present invention also added function additive, further improve the performance of water paint；
（2）The expanded vermiculite of special ratios is added in the present invention, vermiculite contains a pore more than 12,000, and each pore has
The effect of standby strong hygroscopicity, coating can play clearing damp for interior；In addition, vermiculite can also slowly release perfume (or spice) in itself
Taste, the effect of reaching moisture absorption, deodorization, fragrant expelling parasite, have both coating and allay excitement, foster the spirit of nobility and the effect of health care；（3）It is of the invention preferred
PH conditioning agents for sodium hydroxide, other than cheap, sodium hydroxide does not have the peculiar smell of amine pH adjusting agent, can avoid
Coating material production environment and use environment it is severe.
Specific embodiment
One kind is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, and the parts by weight of raw material are as follows
Organic-silicon-modified 15~35 parts of pure-acrylic emulsion
15~35 parts of waterborne polyurethane resin
1~8 part of expanded vermiculite
3~12 parts of curing agent
1.5~3 parts of function additive
0.5~3 part of PH conditioning agents
40~55 parts of deionized water.
As a kind of perferred technical scheme：The curing agent is one kind in triethylene tetramine and N- hydroxy acrylic acid amides
Or two kinds.As a kind of perferred technical scheme：The function additive is ultra-violet absorber, in coalescents, antifoaming agent
It is at least one.As a kind of perferred technical scheme：The pH conditioning agents are sodium hydroxide.
1 one kind of embodiment is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, including following
Raw material by weight：Organic-silicon-modified 40 parts of pure-acrylic emulsion, 30 parts of waterborne polyurethane resin, 3 parts of expanded vermiculite,
12 parts of curing agent, 3 parts of function additive, 3 parts of PH conditioning agents, 60 parts of deionized water.
2 one kind of embodiment is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, including following
Raw material by weight：Organic-silicon-modified 25 parts of pure-acrylic emulsion, waterborne polyurethane resin 15,1 part of expanded vermiculite, Gu
4 parts of agent, 0.5 part of function additive, 0.5 part of PH conditioning agents, 30 parts of deionized water.
3 one kind of embodiment is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, including pressing below
The raw material of parts by weight meter：Organic-silicon-modified 30 parts of pure-acrylic emulsion, 20 parts of waterborne polyurethane resin, 2 parts of expanded vermiculite, Gu
5 parts of agent, 1.5 parts of function additive, 2 parts of PH conditioning agents, 40 parts of deionized water.
4 one kind of embodiment is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, including following
Raw material by weight：Organic-silicon-modified 28 parts of pure-acrylic emulsion, 18 parts of waterborne polyurethane resin, expanded vermiculite 1.5
Part, 10 parts of curing agent, 2 parts of function additive, 2.5 parts of PH conditioning agents, 55 parts of deionized water；The curing agent is three second
Alkene tetramine.
5 one kind of embodiment is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, including pressing below
The raw material of parts by weight meter：Organic-silicon-modified 40 parts of pure-acrylic emulsion, 30 parts of waterborne polyurethane resin, 1 part of expanded vermiculite, Gu
4 parts of agent, 1 part of function additive, 0.5 part of PH conditioning agents, 35 parts of deionized water；The curing agent is N- hydroxyls third
Olefin(e) acid acyl；The function additive is ultra-violet absorber.
6 one kind of embodiment is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, including pressing below
The raw material of parts by weight meter：Organic-silicon-modified 35 parts of pure-acrylic emulsion, 28 parts of waterborne polyurethane resin, 1.2 parts of expanded vermiculite,
6 parts of curing agent, 0.8 part of function additive, 1.5 parts of PH conditioning agents, 35 parts of deionized water；It is described solid in the present embodiment
Agent is triethylene tetramine；The function additive is ultra-violet absorber, coalescents and antifoaming agent；The pH conditioning agents are
Sodium hydroxide.
6 the present embodiment of embodiment and embodiment 5 difference lies in：Curing agent be N- hydroxy acrylic acid amides, function
Auxiliary agent is coalescents and antifoaming agent.
Claims (4)
1. one kind is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects, it is characterised in that：The weight of raw material
It is as follows to measure number
Organic-silicon-modified 15~35 parts of pure-acrylic emulsion
15~35 parts of waterborne polyurethane resin
1~8 part of expanded vermiculite
3~12 parts of curing agent
1.5~3 parts of function additive
0.5~3 part of PH conditioning agents
40~55 parts of deionized water.
2. one kind according to claim 1 is with moisture absorption, expelling parasite, the aqueous weather-proof painting of sustained release odor type of calming effects
Material, it is characterised in that：The curing agent is one or both of triethylene tetramine and N- hydroxy acrylic acid amides.
3. one kind according to claim 1 is with moisture absorption, expelling parasite, the aqueous weather-proof painting of sustained release odor type of calming effects
Material, it is characterised in that：The function additive is at least one of ultra-violet absorber, coalescents, antifoaming agent.
4. one kind according to claim 1 is with moisture absorption, expelling parasite, the aqueous weather-proof painting of sustained release odor type of calming effects
Material, it is characterised in that：The pH conditioning agents are sodium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711174594.8A CN108192445A (en) | 2017-11-22 | 2017-11-22 | One kind is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711174594.8A CN108192445A (en) | 2017-11-22 | 2017-11-22 | One kind is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108192445A true CN108192445A (en) | 2018-06-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711174594.8A Pending CN108192445A (en) | 2017-11-22 | 2017-11-22 | One kind is with moisture absorption, expelling parasite, the aqueous weather-resistant coating of sustained release odor type of calming effects |
Country Status (1)
| Country | Link |
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| CN (1) | CN108192445A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109721838A (en) * | 2018-12-27 | 2019-05-07 | 会通新材料股份有限公司 | A kind of PP composite material and its preparation method and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952443A (en) * | 2011-08-30 | 2013-03-06 | 湖南晟通科技集团有限公司 | Waterborne coating |
| CN105017917A (en) * | 2015-08-03 | 2015-11-04 | 蓝星（成都）新材料有限公司 | High-weather-resistance waterborne coating |
| CN105017918A (en) * | 2015-08-03 | 2015-11-04 | 蓝星（成都）新材料有限公司 | Waterborne coating |
-
2017
- 2017-11-22 CN CN201711174594.8A patent/CN108192445A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952443A (en) * | 2011-08-30 | 2013-03-06 | 湖南晟通科技集团有限公司 | Waterborne coating |
| CN105017917A (en) * | 2015-08-03 | 2015-11-04 | 蓝星（成都）新材料有限公司 | High-weather-resistance waterborne coating |
| CN105017918A (en) * | 2015-08-03 | 2015-11-04 | 蓝星（成都）新材料有限公司 | Waterborne coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109721838A (en) * | 2018-12-27 | 2019-05-07 | 会通新材料股份有限公司 | A kind of PP composite material and its preparation method and application |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180622 |