CN108192326A - A kind of non-maintaining tire filler and its application method - Google Patents
A kind of non-maintaining tire filler and its application method Download PDFInfo
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- CN108192326A CN108192326A CN201711498489.XA CN201711498489A CN108192326A CN 108192326 A CN108192326 A CN 108192326A CN 201711498489 A CN201711498489 A CN 201711498489A CN 108192326 A CN108192326 A CN 108192326A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/104—Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof
- C08J9/105—Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Tires In General (AREA)
- Polyurethanes Or Polyureas (AREA)
- Tyre Moulding (AREA)
Abstract
The present invention relates to a kind of non-maintaining tire filler and its application methods, the non-maintaining tire filler, for raw material and appropriate weight proportion is carried out by using polyurethane slurry, foaming agent, catalyst, elasticity after the non-maintaining tire filler foaming finally prepared is big, make the ride effects of tire that can compare favourably with pneumatic tire effect after filling tire, foamed still supports the inner tube of a tyre after tire is punctured, car is travelled without influence, it can effectively avoid the deflation risk of pneumatic tire, Maintenance free.In addition, non-maintaining tire filler of the present invention can be suitable for any air tyre, it is at low cost.
Description
Technical field
The invention belongs to tire filler technical fields, and in particular to a kind of non-maintaining tire filler and its user
Method.
Background technology
It is all inflated wheel that most tires, which include bike tire, in the market, motorcycle tire, automobile tire use
Tire.Pneumatic tire has the advantages that light-weight and provides soft and comfortably take, because these filling tires have gas or sky
Gas.However the major defect of pneumatic tire is deflation risk caused by piercing through, cover tire is detached with wheel rim or cover tire or wheel rim
Other failures.
There is partially self vehicle to use the solid tyre for exempting from inflation in the market.Solid tyre due to be it is solid, can it is non-aerating and
It is anti-tie, but such tire has the following problems：It is of high cost, it is not wear-resisting, shockproof properties are poor, the shortcomings of carcass weight.
Filling tire contains solid or semisolid material rather than compressed air, this eliminates deflation risk, because cover tire
It pierces through or other failures will not cause gas to leak.
Filling tires material should meet several requirements mutually to be competed with the good dynamic characteristic of pneumatic tire.For example, tire
Packing material should make tire absorb concussion and provide good tractive force.Therefore, filling tires material should be soft and flexible.This
Outside, filling tires material should make tire not gather excessive heat in use, because these heats can damage filling material
Therefore material or cover tire simultaneously reduce Life of Tyre.It is considered in addition, cost is very important.
Invention content
In order to solve the above problem of the existing technology, the present invention provides a kind of non-maintaining tire filler and its make
Use method.Elasticity after being foamed using filling tires agent of the present invention is big, and filling makes after tire the ride effects of tire can be with
Pneumatic tire effect compares favourably, while effectively avoids the deflation risk of pneumatic tire, Maintenance free.
The technical solution adopted in the present invention is：
A kind of non-maintaining tire filler, raw material components include：
Polyurethane slurry, 100-300 parts by weight；
Foaming agent, 100-300 parts by weight；
Catalyst, 1-5 parts by weight.
The raw material components of the further preferred non-maintaining tire filler include：
Polyurethane slurry, 200 parts by weight；
Foaming agent, 200 parts by weight；
Catalyst, 2 parts by weight.
The polyurethane slurry is made for they in toluene.
The solid content of the polyurethane slurry is 30-35wt%.
The weight ratio of the polyurethane and toluene is 70:30-80:20.
The foaming agent is one or more of azodicarbonamide, dicyandiamide, azo isobutyronitrile, unifor
Mixture.
The catalyst is that double dimethylaminoethyl ethers are scattered in dihydric alcohol and are made, double dimethylaminoethyl ethers with
The weight ratio of dihydric alcohol is 70:30-80:20.
The dihydric alcohol is the mixture of one or more of methylene glycol, ethylene glycol, propylene glycol, butanediol.
The application method of the non-maintaining tire filler, step are as follows：
(1) catalyst is added in the polyurethane slurry, be sufficiently mixed uniformly, obtain mixed material；
(2) step (1) mixed material is subjected to high-pressure atomization, obtains the first atomization mass；
(3) foaming agent is subjected to high-pressure atomization, obtains the second atomization mass；
(4) first atomization mass and the second atomization mass are injected separately into tire, the injection of first atomization mass
The ratio between volume and tire inner volume are 0.8:100-3:100, the ratio between the injected slurry volume of second atomization mass and tire inner volume
It is 0.8:100-3:100, uniform rotation tire makes uniform in foaming in tire, foams and complete after 10-15min.
In step (2), the pressure of the high-pressure atomization is 0.8-2.5KPa；
In step (3), the pressure of the high-pressure atomization is 0.8-2.5KPa.
Beneficial effects of the present invention are：
Non-maintaining tire filler of the present invention, by using polyurethane slurry, foaming agent, catalyst for raw material simultaneously
Appropriate weight proportion is carried out, the elasticity after the non-maintaining tire filler foaming finally prepared is big, makes tire after filling tire
Ride effects can compare favourably with pneumatic tire effect, foamed still supports the inner tube of a tyre after tire is punctured, to car row
No influence is sailed, can effectively avoid the deflation risk of pneumatic tire, Maintenance free.In addition, non-maintaining tire of the present invention is filled out
Any air tyre can be suitable for by filling agent, at low cost, only injected material 100g or so, cost need to only need 3-5 first in tire.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical scheme of the present invention will be carried out below
Detailed description.Obviously, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art are obtained all under the premise of creative work is not made
Other embodiment belongs to the range that the present invention is protected.
In example below 1g is represented with 1 parts by weight.
Embodiment 1
The present embodiment provides a kind of non-maintaining tire filler, raw material components include：
Polyurethane slurry, 100 parts by weight；
ADC foaming agents (chemical name azodicarbonamide), 300 parts by weight；
Catalyst, 1 parts by weight.
Wherein, the polyurethane slurry is made for they in toluene, and the solid content of the polyurethane slurry is
The weight ratio of 30wt%, polyurethane and toluene is 70:30；The catalyst is that double dimethylaminoethyl ethers are scattered in methylene glycol
In be made, the weight ratio of double dimethylaminoethyl ethers and methylene glycol is 70:30.
Further, the present embodiment also provides the application method of the non-maintaining tire filler, and step is as follows：
(1) catalyst is added in the polyurethane slurry, be sufficiently mixed uniformly, obtain mixed material；
(2) step (1) described mixed material under 0.8KPa pressure conditions is subjected to high-pressure atomization, obtains the first atomization
Body；
(3) foaming agent under 0.8KPa pressure conditions is subjected to high-pressure atomization, obtains the second atomization mass；
(4) first atomization mass and the second atomization mass are injected separately into tire, the injection of first atomization mass
The ratio between volume and tire inner volume are 0.8:100, the ratio between the injected slurry volume of second atomization mass and tire inner volume are 0.8:
100, uniform rotation tire makes uniform in foaming in tire, foams and complete after 10min.
Embodiment 2
The present embodiment provides a kind of non-maintaining tire filler, raw material components include：
Polyurethane slurry, 300 parts by weight；
Azodicarbonamide, dicyandiamide, azo isobutyronitrile, unifor are according to mass ratio 1:1:1:1 composition mixes
Close foaming agent, 100 parts by weight；
Catalyst, 5 parts by weight.
Wherein, the polyurethane slurry is made for they in toluene, and the solid content of the polyurethane slurry is
The weight ratio of 35wt%, polyurethane and toluene is 80:20；The catalyst is that double dimethylaminoethyl ethers are scattered in ethylene glycol
In be made, the weight ratio of double dimethylaminoethyl ethers and ethylene glycol is 80:20.
Further, the present embodiment also provides the application method of the non-maintaining tire filler, and step is as follows：
(1) catalyst is added in the polyurethane slurry, be sufficiently mixed uniformly, obtain mixed material；
(2) step (1) described mixed material under 2.5KPa pressure conditions is subjected to high-pressure atomization, obtains the first atomization
Body；
(3) foaming agent under 2.5KPa pressure conditions is subjected to high-pressure atomization, obtains the second atomization mass；
(4) first atomization mass and the second atomization mass are injected separately into tire, the injection of first atomization mass
The ratio between volume and tire inner volume are 3:100, the ratio between the injected slurry volume of second atomization mass and tire inner volume are 3:100,
Uniform rotation tire makes uniform in foaming in tire, foams and complete after 15min.
Embodiment 3
The present embodiment provides a kind of non-maintaining tire filler, raw material components include：
Polyurethane slurry, 200 parts by weight；
Dicyandiamide foaming agent, 200 parts by weight；
Catalyst, 2 parts by weight.
Wherein, the polyurethane slurry is made for they in toluene, and the solid content of the polyurethane slurry is
The weight ratio of 32wt%, polyurethane and toluene is 75:25；The catalyst is that double dimethylaminoethyl ethers are scattered in propylene glycol
In be made, the weight ratio of double dimethylaminoethyl ethers and propylene glycol is 75:25.
Further, the present embodiment also provides the application method of the non-maintaining tire filler, and step is as follows：
(1) catalyst is added in the polyurethane slurry, be sufficiently mixed uniformly, obtain mixed material；
(2) step (1) described mixed material under 1.5KPa pressure conditions is subjected to high-pressure atomization, obtains the first atomization
Body；
(3) foaming agent under 1.5KPa pressure conditions is subjected to high-pressure atomization, obtains the second atomization mass；
(4) first atomization mass and the second atomization mass are injected separately into tire, the injection of first atomization mass
The ratio between volume and tire inner volume are 2:100, the ratio between the injected slurry volume of second atomization mass and tire inner volume are 2:100,
Uniform rotation tire makes uniform in foaming in tire, foams and complete after 12min.
Embodiment 4
The present embodiment provides a kind of non-maintaining tire filler, raw material components include：
Polyurethane slurry, 200 parts by weight；
Azo isobutyronitrile foaming agent, 200 parts by weight；
Catalyst, 2 parts by weight.
Wherein, the polyurethane slurry is made for they in toluene, and the solid content of the polyurethane slurry is
The weight ratio of 32wt%, polyurethane and toluene is 75:25；The catalyst is that double dimethylaminoethyl ethers are scattered in butanediol
In be made, the weight ratio of double dimethylaminoethyl ethers and butanediol is 75:25.
Further, the present embodiment also provides the application method of the non-maintaining tire filler, and step is as follows：
(1) catalyst is added in the polyurethane slurry, be sufficiently mixed uniformly, obtain mixed material；
(2) step (1) described mixed material under 1.2KPa pressure conditions is subjected to high-pressure atomization, obtains the first atomization
Body；
(3) foaming agent under 1.2KPa pressure conditions is subjected to high-pressure atomization, obtains the second atomization mass；
(4) first atomization mass and the second atomization mass are injected separately into tire, the injection of first atomization mass
The ratio between volume and tire inner volume are 2:100, the ratio between the injected slurry volume of second atomization mass and tire inner volume are 2:100,
Uniform rotation tire makes uniform in foaming in tire, foams and complete after 12min.
Embodiment 5
The present embodiment provides a kind of non-maintaining tire filler, raw material components include：
Polyurethane slurry, 200 parts by weight；
Unifor foaming agent, 200 parts by weight；
Catalyst, 2 parts by weight.
Wherein, the polyurethane slurry is made for they in toluene, and the solid content of the polyurethane slurry is
The weight ratio of 32wt%, polyurethane and toluene is 75:25；The catalyst is that double dimethylaminoethyl ethers are scattered in butanediol
In be made, the weight ratio of double dimethylaminoethyl ethers and butanediol is 75:25.
Further, the present embodiment also provides the application method of the non-maintaining tire filler, and step is as follows：
(1) catalyst is added in the polyurethane slurry, be sufficiently mixed uniformly, obtain mixed material；
(2) step (1) described mixed material under 2KPa pressure conditions is subjected to high-pressure atomization, obtains the first atomization mass；
(3) foaming agent under 2KPa pressure conditions is subjected to high-pressure atomization, obtains the second atomization mass；
(4) first atomization mass and the second atomization mass are injected separately into tire, the injection of first atomization mass
The ratio between volume and tire inner volume are 2:100, the ratio between the injected slurry volume of second atomization mass and tire inner volume are 2:100,
Uniform rotation tire makes uniform in foaming in tire, foams and complete after 12min.
The above description is merely a specific embodiment, but protection scope of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can readily occur in change or replacement, should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. a kind of non-maintaining tire filler, which is characterized in that raw material components include：
Polyurethane slurry, 100-300 parts by weight；
Foaming agent, 100-300 parts by weight；
Catalyst, 1-5 parts by weight.
2. non-maintaining tire filler according to claim 1, which is characterized in that raw material components include：
Polyurethane slurry, 200 parts by weight；
Foaming agent, 200 parts by weight；
Catalyst, 2 parts by weight.
3. non-maintaining tire filler according to claim 1, which is characterized in that the polyurethane slurry is polyurethane point
It dissipates and is made in toluene.
4. non-maintaining tire filler according to claim 3, which is characterized in that the solid content of the polyurethane slurry is
30-35wt%.
5. non-maintaining tire filler according to claim 4, which is characterized in that the weight of the polyurethane and toluene it
Than being 70:30-80:20.
6. non-maintaining tire filler according to claim 1, which is characterized in that the foaming agent is two formyl of azo
The mixture of one or more of amine, dicyandiamide, azo isobutyronitrile, unifor.
7. non-maintaining tire filler according to claim 1, which is characterized in that the catalyst is double dimethylamino second
Base ether, which is scattered in dihydric alcohol, to be made, and the weight ratio of double dimethylaminoethyl ethers and dihydric alcohol is 70:30-80:20.
8. non-maintaining tire filler according to claim 1, which is characterized in that the dihydric alcohol is methylene glycol, second two
The mixture of one or more of alcohol, propylene glycol, butanediol.
9. according to the application method of the non-maintaining tire filler of claim 1-8 any one of them, which is characterized in that step is such as
Under：
(1) catalyst is added in the polyurethane slurry, be sufficiently mixed uniformly, obtain mixed material；
(2) step (1) mixed material is subjected to high-pressure atomization, obtains the first atomization mass；
(3) foaming agent is subjected to high-pressure atomization, obtains the second atomization mass；
(4) first atomization mass and the second atomization mass are injected separately into tire, the injected slurry volume of first atomization mass
It is 0.8 with the ratio between tire inner volume:100-3:100, the ratio between the injected slurry volume of second atomization mass and tire inner volume are
0.8:100-3:100, uniform rotation tire makes uniform in foaming in tire, foams and complete after 10-15min.
10. the application method of non-maintaining tire filler according to claim 9, which is characterized in that in step (2), institute
The pressure for stating high-pressure atomization is 0.8-2.5KPa；
In step (3), the pressure of the high-pressure atomization is 0.8-2.5KPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711498489.XA CN108192326A (en) | 2017-12-29 | 2017-12-29 | A kind of non-maintaining tire filler and its application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711498489.XA CN108192326A (en) | 2017-12-29 | 2017-12-29 | A kind of non-maintaining tire filler and its application method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108192326A true CN108192326A (en) | 2018-06-22 |
Family
ID=62587768
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711498489.XA Pending CN108192326A (en) | 2017-12-29 | 2017-12-29 | A kind of non-maintaining tire filler and its application method |
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| Country | Link |
|---|---|
| CN (1) | CN108192326A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102906214A (en) * | 2010-05-27 | 2013-01-30 | 横滨橡胶株式会社 | Liquid coagulant and tire puncture sealing material set |
| CN103386863A (en) * | 2013-07-16 | 2013-11-13 | 杭州顺源轮胎制造有限公司 | Production technique of run-flat tire resistant to deflation caused by puncturing |
-
2017
- 2017-12-29 CN CN201711498489.XA patent/CN108192326A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102906214A (en) * | 2010-05-27 | 2013-01-30 | 横滨橡胶株式会社 | Liquid coagulant and tire puncture sealing material set |
| CN103386863A (en) * | 2013-07-16 | 2013-11-13 | 杭州顺源轮胎制造有限公司 | Production technique of run-flat tire resistant to deflation caused by puncturing |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20180622 |