CN108191077A - A kind of method using single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water - Google Patents

A kind of method using single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water Download PDF

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Publication number
CN108191077A
CN108191077A CN201810074268.8A CN201810074268A CN108191077A CN 108191077 A CN108191077 A CN 108191077A CN 201810074268 A CN201810074268 A CN 201810074268A CN 108191077 A CN108191077 A CN 108191077A
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China
Prior art keywords
electromagnetic wave
frequency
water
home position
microorganism
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CN201810074268.8A
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Chinese (zh)
Inventor
王兴祖
白渝梅
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Polar Membrane Environment Technology (shanghai) Co Ltd
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Polar Membrane Environment Technology (shanghai) Co Ltd
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Priority to CN201810074268.8A priority Critical patent/CN108191077A/en
Publication of CN108191077A publication Critical patent/CN108191077A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds

Abstract

The invention discloses a kind of methods using single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water, the Anoxygenic photosynthetic bacteria in sewage with efficient dirty removal capacities is activated using the electromagnetic wave irradiation of effective frequency, so as to improve the activity and quantity of choosing microorganism, so as to the dirt in accelerated decomposition sewage.The present invention is a kind of microorganism Activiation method easy to operate, economical and efficient.This method can selectively improve beneficial microorganism quantity and activity in polluted-water, carry out and improve the micro organism purifying effect of polluted-water.

Description

A kind of method using single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water
Technical field
The present invention relates to a kind of waste water control methods, and single-frequency electromagnetic wave home position strengthening microorganism is used more particularly to a kind of The method for repairing polluted-water.
Background technology
City rivers pollution is an environmental problem of generally existing in current world wide, most of countries and regions Urban river exists to be polluted in various degree, and the living environment of aquatile is destroyed, the ecological functions of urban river It receives and seriously affects.In-situ immobilization mode is generally taken in the improvement of polluted river water at present.Removal water pollutant is controlled Reason means are broadly divided into chemical remediation technology, peripheral doses technology and bioremediation technology.Microorganism enhanced technology has investment The features such as saving, good purification, while the clear-cutting forestland of aquatic ecosystem can also be promoted, therefore administering polluted river water During play irreplaceable role.
Microbial technique core is the activity of promotion microorganisms in water, accelerates the degradation and conversion of water pollutant.Mesh Before, for the polluted river channel in-situ immobilization based on microbial augmentation reparation mainly using two kinds of technologies, one kind is directly to be thrown into water body Add the microbial bacterial agent with efficient decontamination function, another kind is that the nutrition that microorganism can be promoted to grow and be metabolized is added to water body The microorganisms activator such as substance, electron acceptor.The former is added by external source is directly realized by carrying for quantity of useful microbe in river It rises, and the latter is substantially the growth of the indigenous functional microorganism in the activation water body by activator selectivity, so as to activate it Ecological functions achieve the effect that water remediation.Although the microbial augmentation recovery technique of polluted-water have the advantages that it is many, The problem of certain is also faced in practical applications.
(1)Effect persistence problem.Microbial augmentation recovery technique is with strong points, quick, but by physics and chemistry, biotic environment Deng influence add rear Black Liquor with Efficient Bacteria quantity and activity is difficult to maintain, strain or growth-promoting agent generally require to add repeatedly, are expensive.
(2)Embodiment problem.Workshop Production, long-distance transport and scene will be undergone by adding microbial inoculum or growth-promoting agent This series of steps is added, increases the difficulty for the treatment of cost and operational administrative, simultaneously because taking longer efficient before adding The quantity and activity of bacterium have declined.
(3)Environmental safety.Because microbial augmentation(Add strain or growth-promoting agent)Belong to invasive recovery technique, at present The focus of dispute concentrates in open water body whether bring Environmental security sex chromosome mosaicism using biological reinforced bioremediation technology.It is multiple Inoculating microbe certainly will be introduced by closing adding for microbial inoculum, and influence of these microorganisms to target water ecological setting is still unknown at present Really.Microorganism activator is launched although there is no the problem of inoculating microbe, as a kind of adding for compound chemical reagent, Its residual components(Such as organic matter or minor metallic element)Environmental risk caused by possible also should not be underestimated.Therefore, there is an urgent need to A kind of microorganism enhanced technology that develop Noninvasive, that environment influence is small, effect is lasting.
Invention content
In view of the drawbacks described above of the prior art, the technical problems to be solved by the invention are to provide a kind of using single-frequency electricity The method of magnetic wave home position strengthening microorganism remediation polluted-water, by setting appropriate frequency, appropriate illumination, appropriate irradiation cycle Deng, selectively to activate a certain kind or certain several beneficial microbe in water body, it is allowed to quantity and activity is significantly promoted, from And accelerate the removal of pollutant in water body.
To achieve the above object, to activate there is height in sewage the present invention provides the electromagnetic wave irradiation using effective frequency Dirty removal capacities, Anoxygenic photosynthetic bacteria containing bacteriochlorophyll b are imitated, so as to improve the activity and quantity of choosing microorganism, So as to the dirt in accelerated decomposition sewage.
As a further improvement on the present invention, the electromagnetic wave(Light)Frequency range between 5THz ~ 380THz, electricity Half-peak breadth≤50nm of magnetic wave, the irradiation intensity of electromagnetic wave is between 0.01mw ~ 10w/m2.
As a further improvement on the present invention, effective electromagnetic wave be single-frequency, frequency range 5THz ~ 380THz it Between.
As a further improvement on the present invention, effective electromagnetic wave is combined for the electromagnetic wave of multi-frequency, each single-frequency electricity The frequency of magnetic wave is between 5THz ~ 380THz.
As a further improvement on the present invention, effective electromagnetic wave is by electromagnetic wave outside electromagnetic wave in effect frequency and effective frequency, I.e. frequency is less than the electromagnetic wave of 5THz or frequency more than 380THz and is composed.
As a further improvement on the present invention, effective electromagnetic wave radiation mode is using Continuous irradiation, discontinuous irradiation, pulse Irradiate a kind of mode therein or its arbitrary combination.
As a further improvement on the present invention, the object that effective electromagnetic wave promotes is the microorganism in water body, including but not It is limited to, the microorganism that the indigenous microorganism and artificial external source in target water body are launched.
As a further improvement on the present invention, electromagnetic wave wave source is therein a kind of or more using artificial light source, lamp Kind combination of light sources obtains, and light source can be placed on the water surface or be irradiated under the water surface.
During using artificial light source, single-frequency electromagnetic wave can be by the electromagnetic wave source of the specific single-frequency electromagnetic wave of generation, such as two pole of laser Pipe, light emitting diode etc. directly generate, and also can indirectly be obtained by the filtered filtration of material of electromagnetic wave source of generation mixed frequency;It adopts During with natural light, the filtered filtration of material of single-frequency electromagnetic wave obtains indirectly.
A kind of intelligent electromagnetic wave producer for generating above-mentioned effective electromagnetic wave, and irradiates target.
As a further improvement on the present invention, including solar energy receiving converter, solar storage battery and electromagnetic wave hair Raw device;
Solar energy receiving converter is connected to solar storage battery and passes through solar power generation to charge for it;Solar energy power accumulating Pond is connected on electromagnetic wave generator and powers for it;Electromagnetic wave generator is used to generate preset electromagnetic wave;
Electromagnetic wave induction device and controller are equipped in electromagnetic wave generator, when the electromagnetic intensity of ambient enviroment is less than the threshold set When being worth range, controller opens electromagnetic wave wave source, and electromagnetic wave starts to irradiate;When the electromagnetic intensity of ambient enviroment is higher than setting During threshold value, controller closes electromagnetic wave wave source, and electromagnetic wave stops irradiation.
The beneficial effects of the invention are as follows:
1st, with traditional throwing bacterium method and compared with adding growth-promoting agent method, the present invention adds microbial bacterial agent or chemical drugs without external source Agent, and device it is simple, without externally fed, can long-time automatic running.
2nd, there are specific photoreceptors, such as photosensitive Huang into the cell for the photosynthetic microorganism of protokaryon and some non-photosynthesizing microorganisms Albumen, bacterial rhodopsin, bacterial typing techniques, blue light experience albumen etc., and the wave frequency that various photoreceptors receive is different, Caused physiological reaction is also different.By the electromagnetic wave irradiation of different frequency, optionally activate different microorganisms intracellular Light receptor, so as to adjust the quantity and activity of specified microorganisms in mixed bacterial.This technology uses except visible region, special Determine the single-frequency electromagnetic wave radiation polluted-water of frequency, activate in water body anaerobism Anoxygenic photosynthetic bacteria specific photoreception into the cell Device so as to a series of signal transduction and gene expression in active cell, makes the water purification bacterium containing bacteriochlorophyll b into the cell Population quantity and activity are significantly promoted, you can achieve the purpose that river training effects of purification quality.
3rd, the present invention is a kind of microorganism Activiation method easy to operate, economical and efficient.This method can be in polluted-water In selectively improve beneficial microorganism quantity and activity, carry out and improve the micro organism purifying effect of polluted-water.This skill Art has the following advantages that compared with current existing biological reinforcing technology:
3.1st, Noninvasive, it is environmental-friendly.Compared with tradition adds microbial inoculum or adds the biological reinforcing technologies such as growth-promoting agent, this technology Without putting into any allogenic material, no Environmental Risk to water body;
3.2nd, being precisely controlled on space-time.This technology by open can activate immediately after light radiation in water body beneficial to micro- life Object, irradiation can stop activating immediately after stopping;
3.3rd, targeted activation.Selected single-frequency wave frequency is green containing bacterium leaf to Chromatiaceae, Rhodospirillaceae, Chlorobacteriaceae etc. The purifying water micrcxDrganism monoid of plain b has activation, and the microorganisms such as harmful blue algae to causing algal tufa are without facilitation;Such as cyanobacteria Activation frequency in more than 400THz, do not include in the frequency range of the present invention, therefore without activation.
3.4th, it is intelligent, modularization.The modularization editor of irradiation frequency and intensity can be carried out according to objective microbe, is allowed Activation is oriented to the microorganism species of photoresponses different in the same area;
3.5th, automation and low cost can be achieved.The equipment that this technology uses is simple, and operation maintenance is convenient, can unattended length Phase runs, more than 50% escapable cost compared with traditional biology adds technology.
Description of the drawings
Fig. 1 is the influence detection figure that electromagnetic wave radiation removes water body COD in embodiment two.
Fig. 2 is influence detection figure of the electromagnetic wave radiation to water body ammonia nitrogen removal in embodiment two.
Fig. 3 is the influence detection figure that electromagnetic wave radiation removes water body TN in embodiment two.
Fig. 4 is influence detection figure of the electromagnetic wave radiation to water body DO in embodiment two.
Fig. 5 is the influence detection figure that electromagnetic wave radiation removes water body COD in embodiment three.
Fig. 6 is influence detection figure of the electromagnetic wave radiation to water body DO in embodiment three.
Specific embodiment
With reference to embodiment, the invention will be further described:
Embodiment one
A kind of method for strengthening water course in situ restoration of the ecosystem using specific electromagnetic wave spectrum sets solar-electricity magnetic wave on river bank Generating means(Utilize the electromagnetic wave generating device of photovoltaic power supply)River overlying water is irradiated.Electromagnetic wave generator has Automatic decision environment electromagnetics intensity of wave and automatic switching system automatically turn on electromagnetism when environment electromagnetics intensity of wave is less than setting value Electromagnetic wave wave source is automatically closed when environment natural electric magnetic wave intensity is higher than setting value in wave wave source.
Daytime, electromagnetic wave generator are automatically closed, and solar energy receiving converter charges for solar storage battery;Night, Electromagnetic wave generator is opened, and the frequency that electromagnetic wave generator generates electromagnetic wave wave source is 5THz ~ 380THz, and carries out spoke to river According to intensity(In terms of target water surface)For the irradiation of 0.01mw ~ 10w/m2, so as to activate the beneficial microbe in river, improve Its quantity and activity, and then improve the removal rate of pollutant in water body.
Embodiment two
Quality of river water COD is tested as 50mg/L, ammonia nitrogen 7.5mg/L, dissolved oxygen 1.1mg/L, 8 g/L of bed mud concentration.Equivalent is divided into Two groups, be respectively A1 and A2, and wherein A2 is control group, and two groups are positioned under same environment, wherein:
A1:Use laser diode wave source of the frequency for 345 THz, half-peak breadth≤5nm, average illumination 0.1w/m2.With the sun Energy system power supply, when ambient light illumination is less than 10 lux, wave source automatically turns on.
A2:Any means are not used, are blank control group.
Experiment starts 7d(My god)Afterwards, compared with blank, the electromagnetic wave radiation of 345THz puies forward the concentration of Chromatiaceae bacterium It is about 1000 times high, cyanobacteria and green alga concentration indifference.For water quality situation referring to Fig. 1~Fig. 4, testing result shows 345 THz's After electromagnetic wave radiation 7d, water body COD, ammonia nitrogen, TN removal rate respectively reach 69%, 94% and 80%, non-irradiated blank at this time COD, ammonia nitrogen, TN removal rate be only 38%, 53% and 44%.Using reaching after the system dissolved oxygen 7d of 345 THz electromagnetic wave radiations 5.4mg/L, blank control group are only 3.1mg/L.
Embodiment three
Quality of river water COD is tested as 60mg/L, ammonia nitrogen 12.5mg/L, dissolved oxygen 0.8mg/L, 10 g/L of bed mud concentration.Equivalent point It is two groups, is respectively B1 and B2, wherein B2 is control group, and two groups are positioned under same environment, wherein:
B1:Use monochromatic sources of the frequency for 295THz, half-peak breadth≤50nm, average illumination 0.01w/m2, with 220V alternating currents Driving, takes the mode of Continuous irradiation to be irradiated.
B2:Any means are not used, are blank control group.
After experiment starts 7d, compared with blank, the electromagnetic wave radiation of 295THz improves the concentration of bud life Chlorobacterium bacterium About 400 times, cyanobacteria and green alga concentration indifference.Water quality situation is referring to Fig. 5-Fig. 6 it is found that using electromagnetism of the frequency for 295THz Amplitude is according to the removal effect that can significantly improve experiment water body COD, and the removal rate of COD has reached 83% in 7d, and do not irradiated Blank COD removal rates are only 47%.The wave source irradiation that frequency is 295THz can be obviously promoted Dissolved Oxygen in Water rising, and when 7d is reachable To 2.25mg/L, the blank control group of irradiation is not added to only have 0.83 mg/L at this time.
Part is not described in detail by the present invention, is the known technology of those skilled in the art.
The preferred embodiment of the present invention described in detail above.It should be appreciated that those of ordinary skill in the art without Creative work is needed according to the present invention can to conceive and makes many modifications and variations.Therefore, all technologies in the art Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea Technical solution, all should be in the protection domain being defined in the patent claims.

Claims (10)

  1. A kind of 1. method using single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water, which is characterized in that using effective In sewage with efficient dirty removal capacities, the non-oxygen-production containing bacteriochlorophyll b is photosynthetic thin to activate for the electromagnetic wave irradiation of frequency Bacterium, so as to improve the activity and quantity of choosing microorganism, so as to the dirt in accelerated decomposition sewage.
  2. 2. the method for single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water, feature are used as described in claim 1 It is, the frequency range of the electromagnetic wave is between 5THz ~ 380THz, half-peak breadth≤50nm of electromagnetic wave, the spoke of electromagnetic wave According to intensity between 0.01mw ~ 10w/m2.
  3. 3. the method for single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water is used as claimed in claim 1 or 2, it is special Sign is that effective electromagnetic wave is single-frequency, and frequency range is between 5THz ~ 380THz.
  4. 4. the method for single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water is used as claimed in claim 1 or 2, it is special Sign is that effective electromagnetic wave is combined for the electromagnetic wave of multi-frequency, and the frequency of each single-frequency electromagnetic wave is in 5THz ~ 380THz Between.
  5. 5. the method for single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water is used as claimed in claim 1 or 2, it is special Sign is that effective electromagnetic wave is by electromagnetic wave outside electromagnetic wave in effect frequency and effective frequency, i.e., frequency is less than 5THz or frequency is more than The electromagnetic wave of 380THz is composed.
  6. 6. the method for single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water, feature are used as described in claim 1 It is, effective electromagnetic wave radiation mode is using Continuous irradiation, discontinuous irradiation, a kind of pulse irradiation mode therein or it is arbitrary Combination.
  7. 7. the method for single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water, feature are used as described in claim 1 It is, the object that effective electromagnetic wave promotes is the microorganism in water body, including but not limited to, the indigenous microorganism in target water body And the microorganism that artificial external source is launched.
  8. 8. the method for single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water, feature are used as described in claim 1 It is, electromagnetic wave wave source is obtained using artificial light source, lamp one or more combination of light sources therein, and light source can be placed in water It is irradiated on face or under the water surface.
  9. 9. a kind of intelligent electromagnetic wave producer, which is characterized in that for generating any effective electromagnetism of claim 1-8 Wave, and target is irradiated.
  10. 10. intelligent electromagnetic wave producer as described in claim 1, which is characterized in that including, solar energy receiving converter, Solar storage battery and electromagnetic wave generator;
    Solar energy receiving converter is connected to solar storage battery and passes through solar power generation to charge for it;Solar energy power accumulating Pond is connected on electromagnetic wave generator and powers for it;Electromagnetic wave generator is used to generate preset electromagnetic wave;
    Electromagnetic wave induction device and controller are equipped in electromagnetic wave generator, when the electromagnetic intensity of ambient enviroment is less than the threshold set When being worth range, controller opens electromagnetic wave wave source, and electromagnetic wave starts to irradiate;When the electromagnetic intensity of ambient enviroment is higher than setting During threshold value, controller closes electromagnetic wave wave source, and electromagnetic wave stops irradiation.
CN201810074268.8A 2018-01-25 2018-01-25 A kind of method using single-frequency electromagnetic wave home position strengthening microorganism remediation polluted-water Pending CN108191077A (en)

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CN113000595A (en) * 2021-03-05 2021-06-22 广东工业大学 Composition for degrading pollutants, preparation method thereof and application of composition in degrading soil pollutants
CN115947451A (en) * 2022-12-30 2023-04-11 山东大学 Method for reinforcing nitrate dissimilation reduction to ammonium process by utilizing nanoscale zero-valent iron coupled low-frequency infrared electromagnetic waves

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CN109607784A (en) * 2018-12-18 2019-04-12 武汉理工大学 A kind of method of electromagnetic wave load returned sludge regulator control system biological community structure
CN109607784B (en) * 2018-12-18 2021-03-30 武汉理工大学 Method for electromagnetic wave loading backflow sludge regulation and control system microbial community structure
CN113000595A (en) * 2021-03-05 2021-06-22 广东工业大学 Composition for degrading pollutants, preparation method thereof and application of composition in degrading soil pollutants
CN115947451A (en) * 2022-12-30 2023-04-11 山东大学 Method for reinforcing nitrate dissimilation reduction to ammonium process by utilizing nanoscale zero-valent iron coupled low-frequency infrared electromagnetic waves

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