CN108190974A - A kind of dechlorination removing heavy metals ceramics powdery water purification agent - Google Patents

A kind of dechlorination removing heavy metals ceramics powdery water purification agent Download PDF

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Publication number
CN108190974A
CN108190974A CN201711308432.9A CN201711308432A CN108190974A CN 108190974 A CN108190974 A CN 108190974A CN 201711308432 A CN201711308432 A CN 201711308432A CN 108190974 A CN108190974 A CN 108190974A
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CN
China
Prior art keywords
parts
water purification
heavy metals
removing heavy
purification agent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711308432.9A
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Chinese (zh)
Inventor
刘宇祥
刘卫东
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Hunan Zhen Yu Energy Ltd
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Hunan Zhen Yu Energy Ltd
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Priority to CN201711308432.9A priority Critical patent/CN108190974A/en
Publication of CN108190974A publication Critical patent/CN108190974A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/481Treatment of water, waste water, or sewage with magnetic or electric fields using permanent magnets
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/12Halogens or halogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

A kind of dechlorination removing heavy metals ceramics powdery water purification agent, it mainly solves the technical problems such as existing water purification means are of high cost, energy consumption is big, function is single, effect unobvious.Its key points of the technical solution are that:It is made of the raw material of following weight proportioning:10 20 parts of sodium bentonite, 8 15 parts of silica flour, 5 10 parts of clay, 10 20 parts of diatomite, 25 parts of sawdust, 8 12 parts of zeolite, 8 10 parts of manganese of electric discharge, 12 parts of magnet powder, 15 20 parts of activated carbon, 35 parts of sepiolite, 46 parts of medical stone.It is mainly used for purification of water quality and sea water desalination.

Description

A kind of dechlorination removing heavy metals ceramics powdery water purification agent
Technical field
The present invention relates to a kind of dechlorination removing heavy metals ceramics powdery water purification agents.
Background technology
As the improvement of people's living standards, increasingly drawing attention to health, water is the important composition substance of body, water The quality of matter directly affects people's health, however seawater and brackish water, river, tap water etc. all contain certain chlorion And heavy metal ion, it is detrimental to health, especially freshwater resources are fewer and fewer, and sea water desalination is particularly important, at present sea water desalination Mainly using electrodialytic method, large scale equipment is needed, using area is big, and electric energy consumption is high, this water purification agent can pass through physics hand Chlorine and heavy metal ion in Duan Gaoxiao removal seawater, make sea water desalination, purification, reach the level of drinking, energy-efficient, function is complete Face.Pure physical means, it is without side-effects, absorption reach can clean after saturation after reuse, service life is long.
Invention content
The object of the present invention is to provide it is a kind of by physical means rapidly and efficiently go water removal in chlorine and heavy metal dechlorination Removing heavy metals ceramics powdery water purification agent.
The technical solution adopted by the present invention to solve the technical problems is:The raw material matched by following weight is made:Sodium 10-20 parts of matter bentonite, 8-15 parts of silica flour, 5-10 parts of clay, 10-20 parts of diatomite, 2-5 parts of sawdust, 8-12 parts of zeolite, Discharge 8-10 parts of manganese, 1-2 parts of magnet powder, 15-20 parts of activated carbon, 3-5 parts of sepiolite, 4-6 parts of medical stone.
The electric discharge manganese is using drawing manganese ore.
The activated carbon select containing carboxyl, phenolic hydroxyl group, quinoid carbonyl, plain edition lactone, fluorescein-type lactone, carboxylic acid anhydrides and The abundant activated carbon of cyclic peroxide class functional group.
First sodium bentonite, silica flour, clay, diatomite, sawdust are mixed with water molding in proportion, are sintered into Ceramics will be uniformly mixed after ceramics, zeolite, electric discharge manganese, magnet powder, sepiolite crushed into powder;Above-mentioned powder is laid on wheat Meal stone upper strata.
The powder particle fineness can be 200~1400 mesh.
Sawdust is a kind of ceramic pore former, brings up the loose porous structure of ceramic monolith.
Zeolite has rack-like structure, is a kind of natural molecule sieve, in their crystal, molecule is connected in as building a framework Together, it is intermediate to form many cavitys, there is adsorptivity, ion exchangeable.
Discharge manganese, main component for electric discharge manganese dioxide, belong to special crystal structure, in water naturally discharge and with activity The materials such as charcoal ceramic monolith form countless electrodes, and under the cooperation in the magnetic field generated in magnet powder, in automatical and efficient absorption water Chlorion and heavy metal ion.
Magnet powder is oxide-based mineral spinelle race magnetic iron ore, main (Fe3O4) containing ferroso-ferric oxide, from carrying magnetic, Magnetic field is generated in water, charge can be promoted to move.
Medical stone is a kind of half igneous rock of neutral alkali, and close to volcanic rock, the natural mineral matter included in medical stone is easy to Oxygen is released in release aperture countless from medical stone, by absorbing bleaching powder and other noxious material purified waters, medical stone In the minerals such as the calcium, iron, the sodium that give out can improve drinking water, become the minerals containing needed by human body trace element Water.
The beneficial effects of the invention are as follows:The present invention uses ceramic powder as carrier, can with loose porous mealy structure Directly to filter sundries, can pre- anti-clogging, increase purification distance, discharge the shapes such as manganese energy automatic discharging and activated carbon, ceramic monolith Into countless electrodes, and under the cooperation in the magnetic field generated in magnet powder, cathode Liquidity limit, anode adsorpting anion makes it certainly Dynamic absorption, so as to rapidly and efficiently remove zwitterion in water removal by physical method, reaches dechlorination on porous dust carrier And heavy-metal ion removal, desalination and the effect of purifying sea water, river water and tap water.Finally, can also be increased by adding medical stone Add the trace element in water body, remove removing heavy metals and chlorion and noxious material, make the water for purifying, desalinating by this cleanser can To directly reach drinking water standard, and supplement the trace element of needed by human body.
Specific embodiment
The present invention is described in further details with reference to embodiment.
Embodiment 1, the present invention are made of the raw material of following weight proportioning:10-20 parts of sodium bentonite, silica flour 8-15 Part, 5-10 parts of clay, 10-20 parts of diatomite, 2-5 parts of sawdust, 8-12 parts of zeolite, electric discharge 8-10 parts of manganese, 1-2 parts of magnet powder, 15-20 parts of activated carbon, 3-5 parts of sepiolite, 4-6 parts of medical stone.Sodium bentonite, silica flour, clay, diatomite and sawdust 2- 5 parts can make ceramic monolith, using the porous ceramic monolith of conveying, it is ensured that the receiving degree of cleanser, while ceramics belong to It is strong to environmental suitability in inactive substance;Zeolite has rack-like structure, and in their crystal, molecule connects as building a framework Together, it is intermediate to form many cavitys, there is adsorptivity, ion exchangeable;Discharge manganese, natural charged, in water with water Solution is electrolyte, can automatically generate electronics movement, and electrode is formed with activated carbon, ceramic monolith;The magnetic field that magnet powder is formed Charge can be promoted to move, strengthen the suction-operated to zwitterion.The cleanser is to utilize the natural physical characteristic shape of substance It is interacted into electrode and zwitterion, does not need to artificial excitation, greatly reduce energy consumption cost and secondary pollution.By being spread in bottom If medical stone, while removing old heavy metal and chlorion, moreover it is possible to be water body microelement-supplementing.The cleanser is not only applied It, can in sea water desalination using upper effect it is also obvious that the seawater purified through cleanser of the present invention in the purified treatment of fresh water To directly reach drinking water standard.
Embodiment 2, the electric discharge manganese is using drawing manganese ore.Remaining is the same as embodiment 1.
Embodiment 3, the activated carbon are selected containing in carboxyl, phenolic hydroxyl group, quinoid carbonyl, plain edition lactone, fluorescein-type Ester, the abundant activated carbon of carboxylic acid anhydrides and cyclic peroxide class functional group, assist adsorption function.Remaining same above-described embodiment.
Sodium bentonite, silica flour, clay, diatomite, sawdust are first mixed with water by embodiment 4 in proportion Type is sintered into ceramics, will be uniformly mixed after ceramics, zeolite, electric discharge manganese, magnet powder, sepiolite crushed into powder;By above-mentioned powder It is laid on medical stone upper strata.Remaining same above-described embodiment.
Embodiment 5, the powder particle fineness can be 200~1400 mesh.Remaining same above-described embodiment.

Claims (5)

1. a kind of dechlorination removing heavy metals ceramics powdery water purification agent, it is characterised in that it is made of the raw material that following weight matches: 10-20 parts of sodium bentonite, 8-15 parts of silica flour, 5-10 parts of clay, 10-20 parts of diatomite, 2-5 parts of sawdust, zeolite 8-12 Part, 8-10 parts of manganese of electric discharge, 1-2 parts of magnet powder, 15-20 parts of activated carbon, 3-5 parts of sepiolite, 4-6 parts of medical stone.
2. dechlorination removing heavy metals ceramics powdery water purification agent according to claim 1, it is characterized in that:The electric discharge manganese is using drawing Manganese ore.
3. dechlorination removing heavy metals ceramics powdery water purification agent according to claim 1, it is characterized in that:The activated carbon selection contains Carboxyl, phenolic hydroxyl group, quinoid carbonyl, plain edition lactone, fluorescein-type lactone, carboxylic acid anhydrides and cyclic peroxide class functional group enrich Activated carbon.
4. the dechlorination removing heavy metals ceramics powdery water purification agent according to claims 1 or 2 or 3, it is characterized in that:It is first that sodium matter is swollen Profit soil, silica flour, clay, diatomite, sawdust are mixed with water molding in proportion, are sintered into ceramics, by ceramics, zeolite, Activated carbon is added in after electric discharge manganese, magnet powder, sepiolite crushed into powder to be uniformly mixed;Above-mentioned powder is laid on medical stone upper strata .
5. dechlorination removing heavy metals ceramics powdery water purification agent according to claim 4, it is characterized in that:The powder particle fineness For 200~1400 mesh.
CN201711308432.9A 2017-12-11 2017-12-11 A kind of dechlorination removing heavy metals ceramics powdery water purification agent Pending CN108190974A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711308432.9A CN108190974A (en) 2017-12-11 2017-12-11 A kind of dechlorination removing heavy metals ceramics powdery water purification agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109126734A (en) * 2018-10-11 2019-01-04 成都其其小数科技有限公司 A kind of high efficiency, low cost adsorbent and preparation method for heavy metal containing wastewater treatment
CN109289765A (en) * 2018-09-30 2019-02-01 江苏斯沃得环保科技有限公司 A kind of active carbon waste water treating agent and preparation method thereof
CN112321104A (en) * 2020-11-27 2021-02-05 北京嘉盛天合气体科技有限公司 River and lake bottom mud curing repairing agent and preparation method thereof

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JP2009254932A (en) * 2008-04-14 2009-11-05 Tosoh Corp Heavy metal treating agent and method of treating heavy metal-contaminated matter using the agent
CN103936116A (en) * 2014-04-22 2014-07-23 中国科学院生态环境研究中心 Manganese dioxide/carbon combined electrode and electric adsorption method for electrically adsorbing heavy metal ions from water
CN105396553A (en) * 2015-12-24 2016-03-16 淄博永辰环境影响评价有限公司 Composite adsorption material of heavy metal ions in industrial wastewater

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109289765A (en) * 2018-09-30 2019-02-01 江苏斯沃得环保科技有限公司 A kind of active carbon waste water treating agent and preparation method thereof
CN109126734A (en) * 2018-10-11 2019-01-04 成都其其小数科技有限公司 A kind of high efficiency, low cost adsorbent and preparation method for heavy metal containing wastewater treatment
CN112321104A (en) * 2020-11-27 2021-02-05 北京嘉盛天合气体科技有限公司 River and lake bottom mud curing repairing agent and preparation method thereof

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Application publication date: 20180622

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