CN108190842A - The device and method that martian surface generates oxygen - Google Patents

The device and method that martian surface generates oxygen Download PDF

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Publication number
CN108190842A
CN108190842A CN201810172284.0A CN201810172284A CN108190842A CN 108190842 A CN108190842 A CN 108190842A CN 201810172284 A CN201810172284 A CN 201810172284A CN 108190842 A CN108190842 A CN 108190842A
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China
Prior art keywords
oxygen
gas
plasma generator
unit
power supply
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CN201810172284.0A
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Inventor
辛艳青
武中臣
王霄
王家豪
张江
凌宗成
李勃
付晓辉
郭恺琛
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Shandong University
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Shandong University
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0203Preparation of oxygen from inorganic compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The present invention proposes the device and method that a kind of martian surface generates oxygen, belongs to Mars environment utilization of resources field, and this method is converted into electric energy using martian surface solar energy, by discharging carbon dioxide is plasmarized to carbon dioxide and being converted into oxygen;The apparatus structure is simple, and the purpose in the direct oxygen producing of martian surface can be directly realized using areographic solar energy and Air resource.The device includes Mars gas collection unit, oxygen generation unit, power supply unit, gas-monitoring unit, oxygen separation purifier units and oxygen compression storage element.The present invention can be applied in Mars environment development of resources and utilizing works task, can provide necessary breathing gas and power fuel for Mars manned exploration or sample return.

Description

The device and method that martian surface generates oxygen
Technical field
The invention belongs to Mars environment utilization of resources field more particularly to it is a kind of on Mars by the dioxy in martian atmosphere Change the experimental provision and experimental method that carbon conversion is oxygen.
Background technology
Mars is the celestial body for being most possibly suitble to human survival in solar system exterior planets.Mars exploration has become the world Focus of the competition between hot spot and scientific and technological power suffers from significance to human survival and development.Mars surface condition and ground Spherical aberration is different huge, is mainly characterized by:Low temperature, low pressure (carbon dioxide atmosphere), high radiation, low gravitation.The mankind are to log in very To immigrant's Mars, need Mars carrying out geochemical transformation, very crucial precondition seeks to generate largely for people Class breathes and the oxygen as rocket fuel.
O is generated currently for martian surface2Research ability ground zero, the Massachusetts Institute of Technology research and development martian surface O2In place Generation system (MOXIE, Mars Oxygen in situ resource utilization experiment) use nuclear energy for Carbon dioxide conversion in martian atmosphere is O by power, electro-catalysis mode2.But the system is needed in high temperature, catalysis and compression fire It could be worked normally under conditions of the carbon dioxide gas of star catalogue face.System energy consumption is very big compared with, volume and weight.Therefore, one is found The technological means that kind effectively generates oxygen just seems particularly important.
Invention content
The present invention proposes the device and method that a kind of martian surface generates oxygen, and this method is turned using martian surface solar energy Electric energy is turned to, by discharging carbon dioxide is plasmarized to carbon dioxide and being converted into oxygen;The apparatus structure is simple, can The purpose in the direct oxygen producing of martian surface is directly realized using areographic solar energy and Air resource.
In order to achieve the above object, the present invention provides a kind of martian surface generate oxygen device, including:
Mars gas collection unit;
Oxygen generation unit, the oxygen generation unit are connected with the Mars gas collection unit, the oxygen generation Unit includes high voltagehigh frequency power supply and plasma generator, for the martian atmosphere for acquiring the Mars gas collection unit Plasmarized, it is oxygen to make carbon dioxide conversion;
Oxygen separation purifier units, the oxygen separation purifier units are connected with the oxygen generation unit, for detaching The gas that generation is reacted in the oxygen generation unit is purified, obtains pure oxygen;
Oxygen compresses storage element, and the oxygen compression storage element is connected with the oxygen separation purifier units, is used for Compression stores pure oxygen;
Power supply unit, said supply unit detect respectively with the Mars gas collection unit, oxygen generation unit, gas Unit, oxygen separation purifier units, oxygen compression storage element be connected, for the air inlet of the Mars gas collection unit, The oxygen generation unit, the oxygen separation purifier units and energy needed for oxygen compression storage element offer.
Preferably, the plasma generator includes the first plasma generator and the second plasma occurs Device, first plasma generator is for discharge excitation carbon dioxide reaction generation oxygen and carbon monoxide, and described second Plasma generator for excite the part reaction of carbon monoxide generation oxygen that is generated by the first plasma generator and While carbon, the residual carbon dioxide gas reaction production for not participating in reaction in the first plasma generator completely is further ionized Raw oxygen and carbon monoxide.
Preferably, the high voltagehigh frequency power supply includes the first high voltagehigh frequency power supply and the second high voltagehigh frequency power supply, it is described First high voltagehigh frequency power supply is used to provide energy to second plasma generator, and the second high voltagehigh frequency power supply is used for Energy is provided to the first plasma generator.
Preferably, described device further includes gas-monitoring unit, the gas-monitoring unit is used to monitor described first The gas componant that plasma generator reaction generates carries out energy according to its monitoring result to the first high voltagehigh frequency power supply It adjusts, reaches the high discharging condition of oxygen-producing amount.
Preferably, first plasma generator and second plasma generator are two radius differences The good circular cylinder gas chamber of one-in-and-one-out leakproofness that is spliced into of concentric column conductor shell, two cylindrical conductor shells are respectively The outer wall and inner wall of gas chamber, the outer wall and inner wall of the gas chamber connect the anode and cathode of the high-frequency and high-voltage power supply, gas respectively The polytetrafluoroethylene (PTFE) of the upper bottom of room and bottom well cutting replace and use fluid sealant tight seal glue and, first plasma The outer wall of generator is equipped with the hole for connecting the first air induction conduit and the first outtake tube respectively.
Preferably, the Mars gas collection unit includes and first air induction conduit sequentially close-connected gas Pump, screen pipe and flowmeter.
Preferably, the first outtake tube of first plasma generator by ductule and second grade from Second air induction conduit of daughter generator is connected, the second outtake tube and the oxygen of second plasma generator Separating-purifying unit is connected, wherein, the ductule connects simultaneously to be inserted into the gas-monitoring unit.
Preferably, catalysis list is equipped in first plasma generator and the second plasma generator Member, the catalysis unit include the air-permeable layer made of yttrium stable zirconium oxide or cerium oxide.
The present invention also provides the dresses that a kind of martian surface using as described in any of the above-described technical solution generates oxygen The method for generating oxygen is put, is included the following steps:
Electrical energy drive martian atmosphere collecting unit and oxygen generation unit, Mars are converted solar energy into using power supply unit Air collecting unit will be enriched in the martian atmosphere input oxygen generation unit of carbon dioxide, lead in the first plasma generator Overdischarge excitation carbon dioxide generation oxygen and carbon monoxide monitor first plasma using gas-monitoring unit and occur The gas componant of reaction generation in device, and the energy of the first high voltagehigh frequency power supply is adjusted according to its result, it reaches The high discharging condition of oxygen-producing amount;
The part reaction of carbon monoxide generated in second plasma generator in excitation by the first plasma generator While oxygen is generated with carbon, the remaining titanium dioxide for not participating in reaction in the first plasma generator completely is further ionized Carbon gas reaction generates oxygen and carbon monoxide;
The gas that generation is reacted in second plasma generator by oxygen separation purification unit is purified, is removed Harmful side product in reaction obtains pure oxygen, is inputted in oxygen compression storage element, carries out gas compression immediately It is operated with storage.
Preferably, the reaction condition of the method is:Martian atmosphere collecting unit is positioned over air pressure 300pa- 700pa, the carbon dioxide gas containing 95.5%-100% simulation Mars cabin in, and the temperature of conduit is tieed up with controllable refrigerating plant It holds between -60 DEG C-room temperature.
Compared with prior art, the advantages and positive effects of the present invention are:
1st, the apparatus structure of martian surface plasma method generation oxygen provided by the invention is simple, directly utilizes Mars table The purpose in the direct oxygen producing of martian surface can be realized in the solar energy and Air resource in face, and less energy consumption can be that Mars is visited Rope task provides help;
2nd, the device of martian surface plasma method generation oxygen provided by the invention is equipped with catalysis unit, ensures Higher yields.Higher yield also reduces the generation for the gas componant being harmful to human breathing simultaneously, improves the pure of oxygen Degree.
3rd, martian surface plasma method provided by the invention generates oxygen unit and is equipped with gas-monitoring and compression storage Unit has ensured the purity of oxygen and effective storage.Wherein, gas-monitoring unit can be with oxygen yield in real-time monitoring system With the operating status of total system, it ensure that system generates the quality of oxygen.
Description of the drawings
Fig. 1 is generated the apparatus structure schematic diagram of oxygen by the martian surface that the embodiment of the present invention provides.
Specific embodiment
The device and method that the martian surface provided to become apparent from introducing the embodiment of the present invention in detail generates oxygen, The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described embodiment is only this Invention part of the embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art exist All other embodiments obtained under the premise of creative work are not made, shall fall within the protection scope of the present invention.
Embodiment 1
Referring to Fig. 1, the device that a kind of martian surface generates oxygen is present embodiments provided, including power supply unit 1, Mars gas Body collecting unit 4, oxygen generation unit, gas-monitoring unit 6, oxygen separation purifier units 8 and oxygen compression storage element 9, Wherein oxygen generation unit includes two sets, respectively includes the second high voltagehigh frequency power supply 3 and the first plasma generator 5 and the One high voltagehigh frequency power supply 2 and the second plasma generator 7.
The device particularly may be divided into circuit part and air path part, wherein, circuit part is power supply unit 1, can be Mars Gas collection unit 4 and two sets of oxygen generation units provide air inlet and reaction energy respectively.
Solar panel can be selected in power supply unit 1, to obtain the direct energy, solar panel two-stage under the conditions of Mars It is in parallel with the first high frequency voltage source 2, the second high frequency voltage source 3 and martian atmosphere collecting unit 4.First high frequency voltage source 2, second The effect of high frequency voltage source 3 is that the voltage that solar panel provides is converted into high-frequency and high-voltage to export to plasma generator. First plasma generator 5 and the second plasma generator 7 the concentric column conductor shell pole plate different for two radiuses are spelled The good circular cylinder gas chamber of one-in-and-one-out leakproofness being connected into, two cylindrical conductor shells become the inner and outer wall of gas chamber, institute The inner and outer wall for stating gas chamber connects the positive and negative polarities of high-frequency and high-voltage power supply respectively, bottom and poly- the four of bottom well cutting on gas chamber Vinyl fluoride replace and use fluid sealant tight seal glue and, the outer wall of first plasma generator is equipped with and connects first respectively The hole (not shown) of air induction conduit and the first outtake tube.It should be noted that in the first plasma generator and second etc. Catalysis unit is additionally provided in plasma generator, i.e., the air-permeable layer that yttrium stable zirconium oxide or cerium oxide etc. are made can have Effect improves the transformation efficiency of reactive component.
Air path part may include close-connected martian atmosphere collecting unit 4, the first plasma generator 5 and successively Two plasma generators 7, gas-monitoring unit 6, oxygen separation purifier units 8 and oxygen compression storage element 9.
Martian atmosphere collecting unit 4 includes gas pump close-connected with the first air induction conduit, screen pipe, flowmeter (not Show), wherein, gas pump, flowmeter are powered by solar panel and operated, and the effect of gas pump is to be pumped into martian atmosphere simultaneously And filtering sand and dust, the starting point as gas reaction unit;Screen pipe is the improvement drying tube with sieve shape pore structure;Flowmeter is used for Voltage stabilization and current stabilization.Gas is connected by the first air induction conduit with the first plasma generator 5 after flowmeter, the first plasma First outtake tube of generator 5 is connected by a ductule with the second air induction conduit of the second plasma generator 7, small to lead Pipe is inserted into gas-monitoring unit 6 simultaneously, the second outtake tube and the oxygen separation purification unit of the second plasma generator 7 8 are connected, and the latter further compresses with oxygen to be connected with storage element 9.It is understood that oxygen separation purification unit 8 and oxygen Air pressure contracting is equally also required to 1 supplying energy of power supply unit with storage element 9, the considerations of simplification for structure diagram, in Fig. 1 not Its corresponding connection relation is shown.
When martian surface generates oxygen using plasma method, the atmospheric conditions of Mars are fully simulated as far as possible:It will Martian atmosphere collecting unit 4 is positioned over air pressure 300pa-700pa, in the Mars cabin of the carbon dioxide gas containing 95.5%-100%, And using controllable refrigerating plant by the temperature of conduit maintain -60 DEG C of low temperature-room temperature environment under.By martian atmosphere collecting unit 4 input the martian atmosphere for stablizing pressure into gas circuit, and the first high voltagehigh frequency power supply 2 and the second high voltagehigh frequency power supply 3 respectively will be for The voltage that electric unit such as solar panel provides be converted into high-frequency and high-voltage export to the first plasma generator 5 and the second grade from Electronic generator 7 makes its work, and excitation carbon dioxide generates plasma in the first plasma generator 5, and primary product is oxygen Gas and carbon monoxide, air-flow drive product to enter in the second plasma generator 7 with reactant gas, and according to gas-monitoring The energy of the first high voltagehigh frequency power supply is adjusted in gas componant shown in unit 6, reaches the highest voltage model of oxygen-producing amount It encloses.In the second plasma generator 7, a part of reaction of carbon monoxide generation oxygen and carbon, while also to there is residual two Carbon oxide gas (does not i.e. complete the CO of reaction in the first plasma system generator2) continue electric discharge generation oxygen and carbon monoxide Reaction.Then, the gas generated anyway in the second plasma generator 7 is passed through oxygen separation purification unit 8, eliminates two The gases such as carbonoxide, carbon monoxide, ozone obtain pure oxygen (purity>99.9%) gained oxygen finally, is passed through oxygen Compression and storage element 9 so as to achieve the purpose that store oxygen, facilitate utilization.

Claims (10)

1. a kind of martian surface generates the device of oxygen, which is characterized in that including:
Mars gas collection unit;
Oxygen generation unit, the oxygen generation unit are connected with the Mars gas collection unit, the oxygen generation unit Including high voltagehigh frequency power supply and plasma generator, for martian atmosphere for acquiring the Mars gas collection unit etc. from Daughter, it is oxygen to make carbon dioxide conversion;
Oxygen separation purifier units, the oxygen separation purifier units are connected with the oxygen generation unit, for isolating and purifying The gas of generation is reacted in the oxygen generation unit, obtains pure oxygen;
Oxygen compresses storage element, and the oxygen compression storage element is connected with the oxygen separation purifier units, for compressing Store pure oxygen;
Power supply unit, said supply unit are single with the Mars gas collection unit, oxygen generation unit, gas detection respectively Member, oxygen separation purifier units, oxygen compression storage element are connected, for the air inlet of the Mars gas collection unit, oxygen Gas generation unit, oxygen separation purifier units and energy needed for oxygen compression storage element offer.
2. the apparatus according to claim 1, which is characterized in that the plasma generator is sent out including the first plasma Raw device and the second plasma generator, first plasma generator generate oxygen for discharge excitation carbon dioxide reaction Gas and carbon monoxide, second plasma generator is in the part one generated for excitation by the first plasma generator While carbon dioxide reaction generates oxygen with carbon, further ionize and do not participate in the residual of reaction in the first plasma generator completely Carbon dioxide gas precursor reactant is stayed to generate oxygen and carbon monoxide.
3. the apparatus of claim 2, which is characterized in that the high voltagehigh frequency power supply includes the first high voltagehigh frequency power supply With the second high voltagehigh frequency power supply, the first high voltagehigh frequency power supply is used to provide energy to second plasma generator, The second high voltagehigh frequency power supply is used to provide energy to the first plasma generator.
4. device according to claim 3, which is characterized in that described device further includes gas-monitoring unit, the gas Monitoring unit is used to monitor the gas componant that the first plasma generator reaction generates, according to its monitoring result to described First high voltagehigh frequency power supply carries out energy adjustment, reaches the high discharging condition of oxygen-producing amount.
5. the apparatus of claim 2, which is characterized in that first plasma generator and second grade from The good circular cylinder of one-in-and-one-out leakproofness that the daughter generator concentric column conductor shell different for two radiuses is spliced into Gas chamber, two cylindrical conductor shells are respectively the outer wall and inner wall of gas chamber, and the outer wall and inner wall of the gas chamber connect the height respectively The anode and cathode of frequency high voltage power supply, the upper bottom of gas chamber and the polytetrafluoroethylene (PTFE) of bottom well cutting replace and tight with fluid sealant Fluid sealant and, the outer wall of first plasma generator is equipped with and connects the first air induction conduit and the first outtake tube respectively Hole.
6. device according to claim 5, which is characterized in that the Mars gas collection unit include with described first into Airway sequentially close-connected gas pump, screen pipe and flowmeter.
7. device according to claim 5, which is characterized in that the first outtake tube of first plasma generator It is connected by ductule with the second air induction conduit of second plasma generator, second plasma generator The second outtake tube be connected with the oxygen separation purifier units, wherein, the ductule connects simultaneously is inserted into the gas In monitoring unit.
8. the apparatus of claim 2, which is characterized in that first plasma generator and the second plasma Catalysis unit is equipped in generator, the catalysis unit includes breathing freely made of yttrium stable zirconium oxide or cerium oxide Layer.
9. a kind of method for generating oxygen using the device that oxygen is generated such as claim 1-8 any one of them martian surface, It is characterised in that it includes following steps:
Electrical energy drive martian atmosphere collecting unit and oxygen generation unit, martian atmosphere are converted solar energy into using power supply unit Collecting unit will be enriched in the martian atmosphere input oxygen generation unit of carbon dioxide, by putting in the first plasma generator Carbon dioxide generation oxygen and carbon monoxide are electrically excited, is monitored in first plasma generator using gas-monitoring unit The gas componant of generation is reacted, and the energy of the first high voltagehigh frequency power supply is adjusted according to its result, reaches production oxygen Measure high discharging condition;
The part reaction of carbon monoxide generation generated in second plasma generator in excitation by the first plasma generator While oxygen is with carbon, the remaining carbon dioxide gas for not participating in reaction in the first plasma generator completely is further ionized Precursor reactant generates oxygen and carbon monoxide;
The gas that generation is reacted in second plasma generator is purified by oxygen separation purification unit, removal reaction In harmful side product, obtain pure oxygen, be inputted oxygen compression storage element in, immediately carry out gas compression with storage Deposit operation.
10. according to the method described in claim 9, it is characterized in that, the reaction condition of the method is:Martian atmosphere is acquired Unit is positioned in the simulation Mars cabin of air pressure 300pa-700pa, the carbon dioxide gas containing 95.5%-100%, and with controllable Device for cooling maintains the temperature of conduit between -60 DEG C-room temperature.
CN201810172284.0A 2018-03-01 2018-03-01 The device and method that martian surface generates oxygen Pending CN108190842A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60137025A (en) * 1983-12-26 1985-07-20 Seiko Epson Corp Plasma treater
CN2474546Y (en) * 2000-12-25 2002-01-30 陈尉 Multipurpose electrochemical oxygen generator
US20100176085A1 (en) * 2007-08-21 2010-07-15 Panasonic Corporation Plasma processing device and method of monitoring plasma discharge state in plasma processing device
CN101903089A (en) * 2007-10-11 2010-12-01 赵文基 Plasma decomposition apparatus and method for carbon dioxide
CN102730644A (en) * 2011-04-08 2012-10-17 崔锦华 Plasma carbon dioxide oxygen-generator powered by solar energy compensated by wind power
CN105905900A (en) * 2016-04-28 2016-08-31 清华大学 CO2 decomposing method, CO2 decomposing system and application thereof
CN107290296A (en) * 2017-06-23 2017-10-24 山东大学 Mars environment analogue experiment installation and experimental method
CN206960173U (en) * 2017-07-10 2018-02-02 宜昌宜陵环境检测有限公司 A kind of airborne particulate harvester

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60137025A (en) * 1983-12-26 1985-07-20 Seiko Epson Corp Plasma treater
CN2474546Y (en) * 2000-12-25 2002-01-30 陈尉 Multipurpose electrochemical oxygen generator
US20100176085A1 (en) * 2007-08-21 2010-07-15 Panasonic Corporation Plasma processing device and method of monitoring plasma discharge state in plasma processing device
CN101903089A (en) * 2007-10-11 2010-12-01 赵文基 Plasma decomposition apparatus and method for carbon dioxide
US20110162958A1 (en) * 2007-10-11 2011-07-07 Moon-Ki Cho Plasma decomposition apparatus and method for carbon dioxide
CN102730644A (en) * 2011-04-08 2012-10-17 崔锦华 Plasma carbon dioxide oxygen-generator powered by solar energy compensated by wind power
CN105905900A (en) * 2016-04-28 2016-08-31 清华大学 CO2 decomposing method, CO2 decomposing system and application thereof
CN107290296A (en) * 2017-06-23 2017-10-24 山东大学 Mars environment analogue experiment installation and experimental method
CN206960173U (en) * 2017-07-10 2018-02-02 宜昌宜陵环境检测有限公司 A kind of airborne particulate harvester

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