CN108183140A - It is a kind of for metal electrode of flexible thin-film solar cell and preparation method thereof - Google Patents

It is a kind of for metal electrode of flexible thin-film solar cell and preparation method thereof Download PDF

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Publication number
CN108183140A
CN108183140A CN201810058143.6A CN201810058143A CN108183140A CN 108183140 A CN108183140 A CN 108183140A CN 201810058143 A CN201810058143 A CN 201810058143A CN 108183140 A CN108183140 A CN 108183140A
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China
Prior art keywords
layer
adhesive linkage
solar cell
metal electrode
film solar
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CN201810058143.6A
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Chinese (zh)
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卢泰
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Xiamen Innov Electronic Technology Co., Ltd.
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卢泰
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/022433Particular geometry of the grid contacts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/0445PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention discloses a kind of for metal electrode of flexible thin-film solar cell and preparation method thereof, the metal electrode includes the substrate layer, adhesive linkage and the electrode layer that are cascading, the material of the substrate layer and adhesive linkage is translucent material, and the material of the adhesive linkage is thermoplastic material.Substrate layer and adhesive linkage are respectively provided with translucency, sunlight can be directed through substrate layer and adhesive linkage reaches electrode layer, adhesive linkage has cementability repeatedly, it is fusible under high-temperature and high-pressure conditions, then it is fitted closely together with the chip of solar cell, bonding strength is high, and web-like or sheet can be made in the metal electrode, suitable for flexible thin-film solar cell.

Description

It is a kind of for metal electrode of flexible thin-film solar cell and preparation method thereof
Technical field
The present invention relates to technical field of solar batteries more particularly to a kind of metals for flexible thin-film solar cell Electrode and preparation method thereof.
Background technology
Electric slurry is generally printed on by the electrode of traditional flexible thin-film solar cell using the method for silk-screen printing On base material, since electric slurry stability in process of production and consistency are poor, the electrode pattern electricity after printing can be caused Resistance is higher, resistance to deflection is general and environment resistant difference.
Invention content
The technical problems to be solved by the invention are:There is provided a kind of metal electrode for flexible thin-film solar cell and Its production method, the resistance of metal electrode is low and the connective stability of chip with solar cell is good.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is:
A kind of metal electrode for flexible thin-film solar cell, including substrate layer, the adhesive linkage being cascading And electrode layer, the material of the substrate layer and adhesive linkage is translucent material, and the material of the adhesive linkage is thermoplastic material.
Another technical solution that the present invention uses for:
The production method of a kind of metal electrode for flexible thin-film solar cell, on the substrate layer with translucency Setting has translucency and thermoplastic adhesive linkage, metal layer is set in one side of the adhesive linkage far from substrate layer, in institute State metal layer far from adhesive linkage one side setting photosensitive layer, the photosensitive layer is exposed successively processing, development treatment and Etching process obtains electrode layer, carries out film process to the electrode layer, obtains the metal electrode.
The beneficial effects of the present invention are:Substrate layer and adhesive linkage are respectively provided with translucency, and sunlight can be directed through base material Layer and adhesive linkage reach the solar chip being mounted on electrode layer, and adhesive linkage has cementability repeatedly, in high temperature and pressure item It is fusible under part, it is then fitted closely together with the chip of solar cell, bonding strength is high, and the metal electrode can be made Into web-like or sheet, suitable for flexible thin-film solar cell;Using covering what then photosensitive layer was exposed, and developed and etches Method makes electrode layer, can make the grid line figure of below 0.05mm, reduces electrode layer on the chip of solar cell Area occupied.
Description of the drawings
Fig. 1 is the sectional view of the metal electrode of the embodiment of the present invention one;
Fig. 2 is the sectional view of the metal electrode of the embodiment of the present invention two;
Fig. 3 is structure diagram of the metal electrode of the embodiment of the present invention two in application;
Fig. 4 is the sectional view of the metal electrode of the embodiment of the present invention three.
Label declaration:
1st, substrate layer;2nd, adhesive linkage;3rd, electrode layer;4th, silver layer;5th, protective layer;6th, chip;
7th, substrate layer;71st, welding section.
Specific embodiment
For the technology contents that the present invention will be described in detail, the objects and the effects, below in conjunction with embodiment and coordinate attached Figure is explained.
The design of most critical of the present invention is:The material of substrate layer and adhesive linkage is translucent material, and the material of adhesive linkage Matter is thermoplastic material, has adhesive property repeatedly, and adhesive strength is high.
Please refer to Fig. 1 to Fig. 3, a kind of metal electrode for flexible thin-film solar cell, including being cascading Substrate layer, adhesive linkage and electrode layer, the material of the substrate layer and adhesive linkage is translucent material, and the material of the adhesive linkage Matter is thermoplastic material.
As can be seen from the above description, the beneficial effects of the present invention are:Substrate layer and adhesive linkage are respectively provided with translucency, and sunlight can The solar chip being mounted on electrode layer is reached to be directed through substrate layer and adhesive linkage, adhesive linkage has bonding repeatedly Property, it is fusible under high-temperature and high-pressure conditions, it is then fitted closely together with the chip of solar cell, bonding strength is high, institute It can be web-like or sheet to state metal electrode, and the material of electrode layer can be metallic copper or metallic aluminium.
Further, one side of the electrode layer far from adhesive linkage is additionally provided with silver layer.
Seen from the above description, setting silver layer can reduce surface contacted resistance, can also improve the weldability with chip Energy.
Further, one side of the substrate layer far from adhesive linkage is additionally provided with protective layer, and the material of the protective layer is Translucent material and for anti-ultraviolet ageing material.
Seen from the above description, protective layer has the performance of anti-ultraviolet aging, and substrate layer can be protected, and extends The service life of metal electrode.
Further, the shape of the protective layer is zigzag or waveform.
Seen from the above description, zigzag or corrugated protective layer can increase the contact area with sunlight, improve sun The transmitance of light.
Further, the material of the substrate layer is PET, PEN, PI or PEEK.
Seen from the above description, substrate layer can be transparent plastics, can select the material of substrate layer according to actual needs Matter.
Further, the material of the adhesive linkage is at least one of thermoplastic polyolefin and thermoplastic polyurethane.
Further, the material of the adhesive linkage in ethylene-vinyl acetate copolymer and polyvinyl butyral extremely Few one kind.
Seen from the above description, adhesive linkage can be any one or a few with thermoplastic resin, such as thermoplasticity In polyolefin (TPO), thermoplastic polyurethane (TPU), ethylene-vinyl acetate copolymer (EVA) and polyvinyl butyral (PVB) One or more, visiing for E.I.Du Pont Company's product commercially may be used and lash row binder resin or DOW Chemical ENLIGHTTM series.
Another technical solution that the present invention uses for:
The production method of a kind of metal electrode for flexible thin-film solar cell, on the substrate layer with translucency Setting has translucency and thermoplastic adhesive linkage, metal layer is set in one side of the adhesive linkage far from substrate layer, in institute State metal layer far from adhesive linkage one side setting photosensitive layer, the photosensitive layer is exposed successively processing, development treatment and Etching process obtains electrode layer, carries out film process to the electrode layer, obtains the metal electrode.
Seen from the above description, the method making electrode layer for being then exposed, developing and etching using photosensitive layer is covered, can To make the grid line figure of below 0.05mm, area occupied of the electrode layer on the chip of solar cell is reduced, and make The stability and uniformity of obtained electrode layer are good.
Further, it is silver-colored in being set on one side of the electrode layer far from adhesive linkage using the method for plating or chemical plating Layer.
Seen from the above description, the thickness of silver layer can be configured as needed.
Further, in setting on one side of the substrate layer far from adhesive linkage with translucency and anti-ultraviolet ageing Protective layer.
Seen from the above description, protective layer has the function of anti-ultraviolet aging, and substrate layer can be protected, and extends The service life of metal electrode.
Embodiment one
Fig. 1 is please referred to, the embodiment of the present invention one is:
A kind of metal electrode for flexible thin-film solar cell, low with resistance and with solar chip connection are steady The advantages of qualitative good.
As shown in Figure 1, the metal electrode includes the substrate layer 1, adhesive linkage 2 and the electrode layer 3 that are cascading, it is described The material of substrate layer 1 and adhesive linkage 2 is translucent material, and the substrate layer 1 and adhesive linkage 2 are in 400-1100nm wave-length coverages Light transmittance be more than 80%, and the material of the adhesive linkage 2 is thermoplastic material, adhesive linkage 2 can be under high-temperature and high-pressure conditions Melting, then bonds together with the chip of solar cell 6.Preferably, the material of the substrate layer 1 is PET, PEN, transparent PI or clear PE EK.In the present embodiment, the material of the adhesive linkage 2 is thermoplastic polyolefin (TPO), thermoplastic polyurethane (TPU), at least one of ethylene-vinyl acetate copolymer (EVA) and polyvinyl butyral (PVB), adhesive linkage 2 can also The ENLIGHTTM series of firm (Bynel) binder resin or DOW Chemical is visitd using Du Pont.The material of the electrode layer 3 is metal Copper or metallic aluminium.
Embodiment two
Fig. 2 is please referred to, the embodiment of the present invention two is further expanded for embodiment one, and something in common repeats no more, no It is with part:The one side of the electrode layer 3 far from adhesive linkage 2 is additionally provided with silver layer 4, and plating or chemistry may be used in silver layer 4 The mode of plating is deposited on electrode layer 3, and the thickness of silver layer 4 can be configured as needed.The substrate layer 1 is far from adhesive linkage 2 one side is additionally provided with protective layer 5, and the material of the protective layer 5 is translucent material and is anti-ultraviolet ageing material, protective layer 5 Light transmittance in 400-1100nm wave-length coverages is more than 80%, and the shape of preferably described protective layer 5 is zigzag or waveform, The transmitance of sunlight can be increased, the protective layer 5 also has the function of waterproof.
As shown in figure 3, when the metal electrode of the present embodiment is applied to solar cell, by silver layer 4 and solar cell Chip 6 welds together, and melts adhesive linkage 2 under high-temperature and high-pressure conditions, is then fitted closely together with chip 6, The number of chip 6 can be configured as needed, be serially connected (not shown) by bus between multiple chips 6, One side of the chip 6 far from silver layer 4 is equipped with substrate layer 7, and substrate layer 7 has certain flexibility, and the material of substrate layer 7 can be poly- When for metal substrate, Titanium, molybdenum, stainless steel, copper and aluminium may be used at least one of acid imide, polyester and metal Metal foil materials are waited, during using metal substrate, welding section 71 can reserve on substrate layer 7 and electrode circuit welds together reality Now it is electrically connected.
Embodiment three
Fig. 4 is please referred to, the embodiment of the present invention three is a kind of metal electrode, is set gradually in the two sides of substrate layer 1 Adhesive linkage 2, electrode layer 3 and silver layer 4, can be by flexible substrate layer when the metal electrode is applied to solar cell The substrate layer of glass material is changed to, can be realized from back side entering light, but to lose overall structure soft for the substrate layer of glass material Property, that is, thin-film solar cells can only be just by changing glass into, it is impossible to be flexible thin-film solar cell, but also have on the market at present Flexible flexible glass is developed, this flexible glass can also be used to substitute substrate layer, make overall structure that there is flexibility.
Example IV
The embodiment of the present invention four is a kind of production method of metal electrode for flexible thin-film solar cell, including Following steps:In setting on the substrate layer with translucency with translucency and thermoplastic adhesive linkage, the material of the substrate layer Matter is PET, PEN, transparent PI or clear PE EK, and the material of the adhesive linkage is thermoplastic polyolefin (TPO), ethyl vinyl acetate second At least one of alkene copolymer (EVA), thermoplastic polyurethane (TPU) and polyvinyl butyral (PVB), adhesive linkage can also The ENLIGHTTM series of firm (Bynel) binder resin or DOW Chemical is visitd using Du Pont.In the adhesive linkage far from substrate layer One side sets metal layer, and the material of metal layer is copper or aluminium.It is photosensitive in one side setting of the metal layer far from adhesive linkage Layer, photosensitive layer can be photosensitive-ink or dry film, and electrode pattern as needed is exposed place successively to the photosensitive layer Reason, development treatment and etching process, obtain electrode layer, and during etching process, ferric trichloride, hydrochloric acid and dioxygen may be used in liquid medicine Water.To treated the moment, electrode layer carries out film process, obtains the metal electrode, can be prepared using this method The superfine gate electrode line figure of below 0.05mm, reduces the occupancy to the chip area of solar cell.Obtain metal electrode It can also use the method for plating or chemical plating that can be dropped in setting silver layer on one side of the electrode layer far from adhesive linkage afterwards Low surface contacted resistance, improving welding property improve the conversion ratio of solar cell.Exposed adhesive linkage can be with after etching It is fitted closely together with solar chip under the conditions of temperature-pressure, there is viscosity repeatedly.In the present embodiment, also in described Protective layer of the setting with translucency and anti-ultraviolet ageing on one side of the substrate layer far from adhesive linkage, protective layer can play anti- Ultraviolet and waterproof effect, the surface of protective layer is zigzag or waveform.
In above-mentioned implementation, the electrode layer can also using the modes such as intaglio printing, letterpress and flexographic printing come It prepares, directly can etch to form electrode pattern after printing, but compared to the photosensitive technique used in above example, print The minimum widith for the electrode pattern that dataller's artistic skill is produced is more than photosensitive technique.
In conclusion a kind of metal electrode and its making side for flexible thin-film solar cell provided by the invention Method, the resistance of the metal electrode is low and the connective stability of chip with solar cell is good, can produce as needed Superfine gate electrode line figure, manufacturing process is simple, at low cost.
The foregoing is merely the embodiment of the present invention, are not intended to limit the scope of the invention, every to utilize this hair The equivalents that bright specification and accompanying drawing content are made directly or indirectly are used in relevant technical field, similarly include In the scope of patent protection of the present invention.

Claims (10)

1. a kind of metal electrode for flexible thin-film solar cell, which is characterized in that including the base material being cascading The material of layer, adhesive linkage and electrode layer, the substrate layer and adhesive linkage is translucent material, and the material of the adhesive linkage is heat Plastic material.
2. the metal electrode according to claim 1 for flexible thin-film solar cell, which is characterized in that the electrode One side of the layer far from adhesive linkage is additionally provided with silver layer.
3. the metal electrode according to claim 1 for flexible thin-film solar cell, which is characterized in that the base material One side of the layer far from adhesive linkage is additionally provided with protective layer, and the material of the protective layer is translucent material and is anti-ultraviolet ageing material Material.
4. the metal electrode according to claim 3 for flexible thin-film solar cell, which is characterized in that the protection The shape of layer is zigzag or waveform.
5. the metal electrode according to claim 1 for flexible thin-film solar cell, which is characterized in that the base material The material of layer is PET, PEN, PI or PEEK.
6. the metal electrode according to claim 1 for flexible thin-film solar cell, which is characterized in that the bonding The material of layer is at least one of thermoplastic polyolefin and thermoplastic polyurethane.
7. the metal electrode according to claim 1 for flexible thin-film solar cell, which is characterized in that the bonding The material of layer is at least one of ethylene-vinyl acetate copolymer and polyvinyl butyral.
8. the production method of a kind of metal electrode for flexible thin-film solar cell, which is characterized in that in translucency Substrate layer on setting there is translucency and thermoplastic adhesive linkage, in one side of the adhesive linkage far from substrate layer, gold is set Belong to layer, photosensitive layer is set in one side of the metal layer far from adhesive linkage, processing is exposed successively to the photosensitive layer, shows Shadow processing and etching process, obtain electrode layer, carry out film process to the electrode layer, obtain the metal electrode.
9. the production method of the metal electrode according to claim 8 for flexible thin-film solar cell, feature exist In using the method for plating or chemical plating in setting silver layer on one side of the electrode layer far from adhesive linkage.
10. the production method of the metal electrode for flexible thin-film solar cell according to claim 8 or claim 9, special Sign is, in protective layer of the setting on one side of the substrate layer far from adhesive linkage with translucency and anti-ultraviolet ageing.
CN201810058143.6A 2018-01-22 2018-01-22 It is a kind of for metal electrode of flexible thin-film solar cell and preparation method thereof Pending CN108183140A (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN110112232A (en) * 2019-04-30 2019-08-09 北京铂阳顶荣光伏科技有限公司 Thin-film solar cells foreboard and preparation method thereof
CN112114499A (en) * 2019-06-19 2020-12-22 上海微电子装备(集团)股份有限公司 Exposure device, photoetching equipment and preparation method of solar cell electrode
CN113284960A (en) * 2021-05-13 2021-08-20 浙江理工大学 Flexible nanofiber membrane light-transmitting electrode with light conversion function and preparation method and application thereof
CN114267744A (en) * 2021-12-29 2022-04-01 明冠新材料股份有限公司 Double-glass photovoltaic cell, preparation method and photovoltaic module
CN114300549A (en) * 2021-12-29 2022-04-08 明冠新材料股份有限公司 Single-glass photovoltaic cell, preparation method and photovoltaic module

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Publication number Priority date Publication date Assignee Title
CN110112232A (en) * 2019-04-30 2019-08-09 北京铂阳顶荣光伏科技有限公司 Thin-film solar cells foreboard and preparation method thereof
CN112114499A (en) * 2019-06-19 2020-12-22 上海微电子装备(集团)股份有限公司 Exposure device, photoetching equipment and preparation method of solar cell electrode
CN112114499B (en) * 2019-06-19 2022-02-11 上海微电子装备(集团)股份有限公司 Exposure device, photoetching equipment and preparation method of solar cell electrode
CN113284960A (en) * 2021-05-13 2021-08-20 浙江理工大学 Flexible nanofiber membrane light-transmitting electrode with light conversion function and preparation method and application thereof
CN113284960B (en) * 2021-05-13 2023-03-10 浙江理工大学 Flexible nanofiber membrane light-transmitting electrode with light conversion function and preparation method and application thereof
CN114267744A (en) * 2021-12-29 2022-04-01 明冠新材料股份有限公司 Double-glass photovoltaic cell, preparation method and photovoltaic module
CN114300549A (en) * 2021-12-29 2022-04-08 明冠新材料股份有限公司 Single-glass photovoltaic cell, preparation method and photovoltaic module
CN114300549B (en) * 2021-12-29 2023-09-08 明冠新材料股份有限公司 Single-glass photovoltaic cell, preparation method and photovoltaic module
CN114267744B (en) * 2021-12-29 2023-09-08 明冠新材料股份有限公司 Double-glass photovoltaic cell, preparation method and photovoltaic module

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