CN108179038A - The automobile-used high cleaning additive of ethyl alcohol ether amines - Google Patents

The automobile-used high cleaning additive of ethyl alcohol ether amines Download PDF

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Publication number
CN108179038A
CN108179038A CN201810018046.4A CN201810018046A CN108179038A CN 108179038 A CN108179038 A CN 108179038A CN 201810018046 A CN201810018046 A CN 201810018046A CN 108179038 A CN108179038 A CN 108179038A
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parts
ethyl alcohol
methyl
fuel
automobile
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常胜
常涛
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
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    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/189Carboxylic acids; metal salts thereof having at least one carboxyl group bound to an aromatic carbon atom
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1983Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyesters
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
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    • C10L1/14Organic compounds
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/28Organic compounds containing silicon

Abstract

The invention discloses a kind of automobile-used high cleaning additives of ethyl alcohol ether amines, it is related to field of fuel additives, including ethyl alcohol, polybutene, dehydrogenation butadiene, 2 methyl, 2 methyl acrylate, ethylene polyethenoxy ether, triethanolamine, dimethyl ring body siloxanes, 3,4 diaminotoluenes, methylphenol, 4 t-octyl phenol, poly fatty acid methyl ester, methyl acetate and nitromethane.The advantage of the invention is that; after additive and vehicle fuel are used in mixed way; the CO2 emission in tail gas, discharged nitrous oxides can be reduced, the valve carbon distribution plug cylinder cylinder carbon deposit for removing the generation in fuel combustion process deposits; protective film is formed in cylinder barrel and piston face; exhaust emissions is reduced, protection engine extends vehicle combustion system service life, and can reach reduction fuel consumption; power is improved, improves the effect of fuel oil label.

Description

The automobile-used high cleaning additive of ethyl alcohol ether amines
Technical field
The present invention relates to field of fuel additives, more particularly, to a kind of automobile-used high cleaning additive of ethyl alcohol ether amines.
Background technology
As petroleum-based energy is increasingly deficient, fuel cost is constantly soaring, and traditional energy causes great pollution to us, Carbon dioxide, which continues largely to discharge, causes greenhouse effects, and discharged nitrous oxides are the main arch-criminals for causing haze, combustion on the market Oily treasured class additive, since additive amount is smaller, can effectively solve the problem that carbon distribution, increases power, but is reducing CO2 emission With reduce nitrogen oxides use it is very little, and fuel oil treasured on the market increase in use fuel into This, develops a kind of New-type fuel of large scale addition or additive reduces and alleviate fuel cost, reduction disposal of pollutants is compeled The eyebrows and eyelashes, ethyl alcohol are obtained extensive use as clean energy resource of new generation, and national multi-section committee in 2017, which combines, to be issued in the whole country Interior popularization ethanol petrol is also a verification well, and patent of the present invention is relied on based on ethyl alcohol, adds various additives product, It is processed by synthesis technology, obtains ethyl alcohol ether amines fuel high cleaning additive product.
Invention content
In order to solve the above-mentioned technical problem the present invention, provides a kind of ethyl alcohol ether amines automobile-used high cleaning additive, can reduce With alleviation fuel cost, reduction disposal of pollutants.
To achieve these goals, the present invention adopts the following technical scheme that:A kind of automobile-used high cleaning additive of ethyl alcohol ether amines, Its component includes:Ethyl alcohol, polybutene, dehydrogenation butadiene, 2- methyl -2- methyl acrylates, ethylene polyethenoxy ether, three second Hydramine, dimethyl ring body siloxanes, 3,4 diaminotoluenes, methylphenol, 4- t-octyls phenol, poly fatty acid methyl ester, acetic acid first Ester, nitromethane, benzoic acid and silicone oil.
Preferably, the composition by weight is:51 parts of ethyl alcohol, 2 parts of polybutene, 2 parts of dehydrogenation butadiene, 2.7 Part 2- methyl -2- methyl acrylates, 3 parts of ethylene polyethenoxy ethers, 0.3 part of triethanolamine, 11 parts of dimethyl ring body silica Alkane, 5 part 3,4 diaminotoluenes, 2.6 parts of methylphenols, 1.4 parts of 4- t-octyls phenol, 1 part of poly fatty acid methyl ester, 7.5 parts of acetic acid Methyl esters, 7.5 parts of nitromethanes, 1 part of benzoic acid and 2 parts of silicone oil.
A kind of production method of the automobile-used high cleaning additive of ethyl alcohol ether amines, which is characterized in that include the following steps:
Step a:Component described in claim 2 is mixed, carries out dispersion stirring;
Step b:The mixture that step a is obtained at pressure 0.4MPa, 76-78 DEG C of temperature is reacted and is cooled to after forty minutes 40℃;
Step c:Above-mentioned silicone oil is added in after pressure release, in 60-62 DEG C of stirring a period of time of pressure 0.3Mpa temperature;
Step d:Finished product is obtained after pressure release to room temperature.
It is an advantage of the current invention that after additive and vehicle fuel are used in mixed way, the titanium dioxide in tail gas can be reduced Carbon emission, discharged nitrous oxides remove the valve carbon distribution plug cylinder cylinder carbon deposit deposition of the generation in fuel combustion process, in cylinder barrel and Piston face forms protective film, reduces exhaust emissions, and protection engine extends vehicle combustion system service life, and can reach Fuel consumption is reduced, improves power, improves the effect of fuel oil label.
Specific embodiment
Below by embodiment, the invention will be further described.
A kind of automobile-used high cleaning additive of ethyl alcohol ether amines, raw material are calculated by weight to:51 parts of ethyl alcohol, 2 parts of polybutene, 2 Part dehydrogenation butadiene, 2.7 parts of 2- methyl -2- methyl acrylates, 3 parts of ethylene polyethenoxy ethers, 0.3 part of triethanolamine, 11 Part dimethyl ring body siloxanes, 5 part 3,4 diaminotoluenes, 2.6 parts of methylphenols, 1.4 parts of 4- t-octyls phenol, 1 part of poly fat Fatty acid methyl esters, 7.5 parts of methyl acetates and 7.5 parts of nitromethanes, 1 part of benzoic acid and 2 parts of silicone oil.Wherein:Polybutene and dehydrogenation system Butadiene main function passes through dissolving to remove inlet valve carbon distribution and exhaust valve carbon distribution, polybutene and the mixing of dehydrogenation butadiene Valve carbon distribution, causing carbon distribution, just face is loosened, and is slowly discharged with air intake-exhaust.2- methyl -2- methyl acrylates, ethylene glycol polyoxy The carbon distribution removed in cylinder barrel is can aid in after vinethene and triethanolamine mixing, combustion chamber in combustion can be with smaller The interior surface that deposits to cylinder barrel carbon deposit of molecule infiltration generate microexplosion, leading to carbon distribution, just face is detached from layer by layer, then unburned to fill The carbon distribution divided can generate carbon dioxide with fuel mixing after-combustion, be discharged with tail gas.After methyl acetate and nitromethane mixing Burning is participated in fuel combustion process, the explosive force released is 5-6 times of vehicle fuel, increases the explosive force of fuel. 3,4 diaminotoluenes can form protective film in rubber surface, prevent swelling of the organic solution to rubber.Dimethyl ring body silica Alkane, main function are that above-mentioned various components are coupled together, and obtain new ethyl alcohol ether amines class and add chelating body, are avoided between additive It mutually destroys and reduces application effect.After poly fatty acid methyl ester and ethyl alcohol mixing, ethyl alcohol passes through dimethyl as polar molecule Poly fatty acid methyl ester can be evenly distributed in metal surface and played to the protection inside piston and cylinder barrel by ring body siloxanes. Methylphenol and the mixing of 4- t-octyls phenol, main function are the octane number and Cetane number for improving fuel, improve fuel combustion Integral combustion effect in journey, it is whole to improve burning by not atomization and imperfect combustion burning secondary-atomizing and burning completely Performance reduces residual fuel and carbon residue in tail gas.Benzoic acid, major function are to accelerate the fusion of various additives, make various add Agent is added to reduce agglomerate reaction, reduces the residual in reaction, improves dissolving and the rate of dispersion of fuel and additive.The effect of silicone oil Predominantly reduce mixture viscosity.
A kind of automobile-used high cleaning Additive Production technological process of ethyl alcohol ether amines:In blending tank add in 51 parts of ethyl alcohol, 2 parts Polybutene, 2 parts of dehydrogenation butadiene, 2.7 parts of 2- methyl -2- methyl acrylates, 3 parts of ethylene polyethenoxy ethers, 0.3 part of three second Hydramine, 11 parts of dimethyl ring body siloxanes, 5 part 3,4 diaminotoluenes, 2.6 parts of methylphenols, 1.4 parts of 4- t-octyls phenol, 1 part Poly fatty acid methyl ester, 7.5 parts of methyl acetates and 7.5 parts of nitromethanes, 1 part of benzoic acid, the high force dispersion carried out 45 minutes stir It mixes, synthesis reaction vessel is then input to by explosion-proof liquid pump, synthesis reaction vessel needs to close before heating left and right valve to anti- Kettle internal pressurization is answered, reaction kettle internal pressure controls in 0.4MPa, carries out temperature reaction in a kettle, protect during the reaction The rotating speed of blender is demonstrate,proved at 12 turns per minute, temperature is controlled between 76-78 DEG C, and temperature keeps both constant-pressure temperature after reaching Then degree 40 minutes stops heating, continues to stir, natural cooling is cooled within 40 DEG C, opens exhaust apparatus, will be in reaction kettle Pressure pressure release reach normal pressure, open additive filler on reaction kettle, add in 2 parts of silicone oil, then boost to 0.3MPa, continue 60-62 DEG C is warming up to, is stirred to react 25 minutes, is stirred for 15 minutes after stopping heating, then naturally cools to 25 DEG C hereinafter, letting out Finished product additive is obtained after being depressed into room temperature.
Following table is to add the contrast test data of additive of the present invention:
Serial number Comparison project Before gasoline addition After gasoline addition
01 Ash % 0.151 0.092
02 Carbon residue % 0.02 0.015
03 Sulphur emissions (ppm) 1.7 0.55
04 Discharged nitrous oxides (ppm) 0.2 0.12
05 Colloid content % 0.37 0.24
06 Explosive force (space pressure) Mpa 1.4 1.55
As can be known from the above table, after the additive of the addition present invention, the various indexs of gasoline, which have, to be obviously improved.
Although the above-mentioned specific embodiment to the present invention is described, not to the limit of the scope of the present invention System, for some technology contents well known to those of ordinary skill in the art, details are not described herein again, and one of ordinary skill in the art should This understands that based on the technical solutions of the present invention, those skilled in the art do not need to make the creative labor and can make Various modifications or changes still within protection scope of the present invention.

Claims (3)

1. a kind of automobile-used high cleaning additive of ethyl alcohol ether amines, which is characterized in that component includes:Ethyl alcohol, polybutene, dehydrogenation fourth two Alkene, 2- methyl -2- methyl acrylates, ethylene polyethenoxy ether, triethanolamine, dimethyl ring body siloxanes, 3,4 diamino first Benzene, methylphenol, 4- t-octyls phenol, poly fatty acid methyl ester, methyl acetate, nitromethane, benzoic acid and silicone oil.
2. the automobile-used high cleaning additive of ethyl alcohol ether amines according to claim 1, which is characterized in that the component is by weight It is calculated as:51 parts of ethyl alcohol, 2 parts of polybutene, 2 parts of dehydrogenation butadiene, 2.7 parts of 2- methyl -2- methyl acrylates, 3 parts of ethylene glycol Polyoxyethylene ether, 0.3 part of triethanolamine, 11 parts of dimethyl ring body siloxanes, 5 part 3,4 diaminotoluenes, 2.6 parts of methylphenols, 1.4 parts of 4- t-octyls phenol, 1 part of poly fatty acid methyl ester, 7.5 parts of methyl acetates, 7.5 parts of nitromethanes, 1 part of benzoic acid and 2 parts Silicone oil.
3. a kind of production method of the automobile-used high cleaning additive of ethyl alcohol ether amines, which is characterized in that include the following steps:
Step a:Component described in claim 2 is mixed, carries out dispersion stirring;
Step b:The mixture that step a is obtained at pressure 0.4MPa, 76-78 DEG C of temperature is reacted and is cooled to 40 after forty minutes ℃;
Step c:The silicone oil is added in after pressure release, in 60-62 DEG C of stirring a period of time of pressure 0.3Mpa temperature;
Step d:Finished product is obtained after pressure release to room temperature.
CN201810018046.4A 2018-01-09 2018-01-09 The automobile-used high cleaning additive of ethyl alcohol ether amines Pending CN108179038A (en)

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Cited By (1)

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CN109135851A (en) * 2018-10-08 2019-01-04 张文涛 A kind of additive for automobile exhaust detergent

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CN109135851A (en) * 2018-10-08 2019-01-04 张文涛 A kind of additive for automobile exhaust detergent

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