CN105647600B - A kind of high cleaning fuel oil compound additive and preparation method thereof - Google Patents

A kind of high cleaning fuel oil compound additive and preparation method thereof Download PDF

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Publication number
CN105647600B
CN105647600B CN201610067900.7A CN201610067900A CN105647600B CN 105647600 B CN105647600 B CN 105647600B CN 201610067900 A CN201610067900 A CN 201610067900A CN 105647600 B CN105647600 B CN 105647600B
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oil
fuel oil
high cleaning
compound additive
antioxidant
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CN105647600A (en
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唐琛
王珉
赵贞
王小婷
王小莉
王敏
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Shaanxi Yanchang Petroleum Energy Technology Co Ltd
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Shaanxi Yanchang Petroleum Energy Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/08Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/232Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/236Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/238Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C10L1/2387Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2300/00Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/20Mixture of two components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)
  • Fuel-Injection Apparatus (AREA)

Abstract

A kind of high cleaning fuel oil compound additive and preparation method thereof, is related to oil dope field, more particularly to a kind of high cleaning fuel oil compound additive.Purpose is to provide a kind of raising fuel power, detergency, high cleaning fuel oil compound additive of anti-rotten wear resistence and preparation method thereof.The high cleaning fuel oil compound additive is made up of the composition of following mass fraction:Detersive host 10~60%, antiwear additive 0~10%, corrosion inhibitor 0~10%, antioxidant 0~5%, carrier oil 15~40%, surplus is diluent;Detersive host is the one or more in polyisobutene phenol Mannich base, PEA polyetheramines, polyisobutene acid amides.There is good detergency using the fuel oil of the compound additive, it can obviously reduce colloid and the carbon distribution coking at the positions such as automobile nozzle, air throttle, combustion chamber, the abrasion of each part of fuel system is reduced, suppresses the oxidation deterioration of fuel oil and additive, harmful substance in engine exhaust emission is reduced.

Description

A kind of high cleaning fuel oil compound additive and preparation method thereof
Technical field
The present invention relates to oil dope field, more particularly to a kind of high cleaning vapour, diesel fuel complex additive.
Background technology
Carbon distribution is a kind of engine inevitable phenomenon in operation process, because unsaturated hydrocarbons is deposited in fuel oil for vehicles In addition to exhaust emissions is directly affected, the site deposition thing generation such as engine nozzle, air throttle, combustion chamber is more being easily caused, especially It is advanced direct fuel-injection engine and engine with supercharger, and the structure of fuel direct injection system can aggravate the generation of carbon distribution, the inlet valve back of the body The carbon distribution in portion is more difficult to remove, so that cause engine power to decline, the problems such as oil consumption is raised, the fuel oil compound additive of high cleaning It is most important to extension engine life, reduction oil consumption.
Vapour, diesel oil detergent in the market typically uses solvent naphtha for solvent, adds aminated compounds and mixes, Peace and quiet effect is undesirable, and does not have wear-resistant, anti-oxidant, erosion-resisting effect, fuel spray effect for state V low-sulfurs vapour, diesel oil Difference.Therefore how effectively to suppress potential deposit in vapour, diesel oil and be attached to engine key position, and will be established heavy Product thing is stripped down from metal surface, promotes vapour, diesel oil fully to burn, and is reduction emission from vehicles pollution, is improved fuel oil combustion Burn the key of efficiency.
The content of the invention
It is an object of the invention to provide it is a kind of can improve fuel power, detergency, anti-rotten wear resistence high cleaning Fuel oil compound additive and preparation method thereof.
The present invention provides a kind of high cleaning fuel oil compound additive, is made up of the composition of following mass fraction:Detersive master Agent 10~60%, antiwear additive 0~10%, corrosion inhibitor 0~10%, antioxidant 0~5%, carrier oil 15~40%, surplus is dilution Agent;
The detersive host be polyisobutene phenol Mannich base, PEA polyetheramines, one kind in polyisobutene acid amides or It is a variety of.
The antiwear additive be it is a kind of in capric acid, capric acid butyl ester, dodecylic acid, ethyl laurate, glycerol trioleate or It is a variety of.
The antioxidant is one or more in antioxidant T551, antioxidant T502, antioxidant T502A.
The carrier oil is at least one of poly alpha olefine synthetic oil, polyethers artificial oil.
The diluent is No. 200 solvent naphthas.
The present invention also provides above-mentioned high cleaning fuel oil compound additive preparation method, comprises the following steps:
(1)By antiwear additive, corrosion inhibitor, antioxidant by mass fraction than adding in a certain amount of carrier oil, this is a certain amount of Carrier oil can be such that antiwear additive, corrosion inhibitor and antioxidant fully dissolves, and the addition of the carrier oil can be excessive, but minimum Limit is antiwear additive, corrosion inhibitor and antioxidant is fully dissolved wherein, forms mixing oil solution;
(2)Under agitation, detersive host and mixing oil solution are separately added into remaining carrier oil, are eventually adding Diluent, stirs to form clear solution, that is, obtains high cleaning fuel oil compound additive.
The present invention has the advantages that:
The compound additive of the present invention, can be added directly into national standard vapour, diesel oil and use, and addition is 100 in gasoline Addition is 100~500ppm in~300ppm, diesel oil.After national standard vapour, diesel oil are using the compound additive of the invention obtained, tool There is good detergency, can obviously reduce colloid and the carbon distribution coking at the positions such as automobile nozzle, air throttle, combustion chamber, subtract simultaneously The abrasion of each part of few fuel system, suppresses the oxidation deterioration of fuel oil and additive, reduces nuisance in engine exhaust emission Matter.
Embodiment
Below by the specific embodiment provided, the present invention will be further described, but not as a limitation of the invention.
Embodiment 1:
A kind of high cleaning fuel oil compound additive, is made up of the composition of following mass fraction:Detersive host 60%, it is wear-resistant Agent 5%, corrosion inhibitor 3%, antioxidant 3%, carrier oil 15%, diluent 14%.
Mass percent of the polyisobutene phenol Mannich base in detersive host is poly- for 60%, PEA in detersive host Mass percent of the ether amines in detersive host is 20%, and mass percent of the polyisobutene acid amides in detersive host is 20%。
Capric acid mass percent in antiwear additive is 20% in antiwear additive, and capric acid butyl ester mass percent in antiwear additive is 20%, dodecylic acid mass percent in antiwear additive is 50%, and glycerol trioleate mass percent in antiwear additive is 10%.
Mass percent of the heptadecyl hydroxyethyl imidazole quinoline in corrosion inhibitor is 50%, oleic acid base miaow in corrosion inhibitor Mass percent of the oxazoline in corrosion inhibitor is 50%.
Mass percents of the T551 in antioxidant is quality hundred of 60%, the T502 in antioxidant in antioxidant Divide than being 40%.
Mass percent of the poly alpha olefine synthetic oil in carrier oil is 60% in carrier oil, and polyethers artificial oil is in carrier oil In mass percent be 40%.
Described diluent is 200# solvent naphthas.
Its preparation method is as follows:
Antiwear additive, corrosion inhibitor, antioxidant are dissolved in a certain amount of carrier oil according to mass ratio first, addition Carrier oil can make antiwear additive, corrosion inhibitor, antioxidant dissolving form mixed solution wherein and be advisable, and then at normal temperatures will Balance carriers are oily to be added in the blending kettle with agitating device, and detersive host is added while stirring and each component is dissolved in advance Carrier oil mixture, is eventually adding diluent, stirs into transparency liquid, that is, obtains the high definition of the embodiment of the present invention 1 Clean fuel oil compound additive.
The addition of the product of the present embodiment in the oil is 120ppm, and the addition in diesel oil is 200ppm, through special Industry testing department is examined, the physico-chemical analysis data fit GB 17930-2013 of oil product《Motor petrol》、GB19147-2013《Car Use diesel oil(Ⅴ)》It is required that.
Embodiment 2:
A kind of high cleaning fuel oil compound additive, is made up of the composition of following mass fraction:Detersive host 50%, it is wear-resistant Agent 6%, corrosion inhibitor 3%, antioxidant 4%, carrier oil 25%, diluent 12%.
Mass percent of the polyisobutene phenol Mannich base in detersive host is poly- for 40%, PEA in detersive host Mass percent of the ether amines in detersive host is 40%, and mass percent of the polyisobutene acid amides in detersive host is 20%。
Capric acid butyl ester mass percent in antiwear additive is 20%, ethyl laurate quality in antiwear additive in antiwear additive Percentage is 40%, and dodecylic acid mass percent in antiwear additive is 30%, glycerol trioleate quality percentage in antiwear additive Than for 10%.
Mass percent of the oily acid based imidazolines in corrosion inhibitor is 100% in corrosion inhibitor.
Mass percents of the T551 in antioxidant is quality hundred of 40%, the T502 in antioxidant in antioxidant Divide than being 60%.
Mass percent of the poly alpha olefine synthetic oil in carrier oil is 60% in carrier oil, and polyethers artificial oil is in carrier oil In mass percent be 40%.
Diluent is 200# solvent naphthas.
The high cleaning fuel oil compound additive, its preparation method such as embodiment 1.
The addition of the product of the present embodiment in the oil is 150ppm, and the addition in diesel oil is 250ppm, through special Industry testing department is examined, the physico-chemical analysis data fit GB 17930-2013 of oil product《Motor petrol》、GB19147-2013《Car Use diesel oil(Ⅴ)》It is required that.
Embodiment 3:
A kind of high cleaning fuel oil compound additive, is made up of the composition of following mass fraction:Detersive host 45%, it is wear-resistant Agent 4%, corrosion inhibitor 7%, antioxidant 4%, carrier oil 30%, diluent 10%.
Mass percent of the polyisobutene phenol Mannich base in detersive host is poly- for 40%, PEA in detersive host Mass percent of the ether amines in detersive host is 60%.
Capric acid mass percent in antiwear additive is 20% in antiwear additive, and capric acid butyl ester mass percent in antiwear additive is 10%, dodecylic acid mass percent in antiwear additive is 20%, and ethyl laurate mass percent in antiwear additive is 30%, Glycerol trioleate mass percent in antiwear additive is 20%.
Mass percent of the heptadecyl hydroxyethyl imidazole quinoline in corrosion inhibitor is 30% in corrosion inhibitor;17 alkenyls Mass percent of the amine ethyl imidazol(e) quinoline in corrosion inhibitor is 30%, quality percentage of the oily acid based imidazolines in corrosion inhibitor Than for 40%.
Mass percents of the T551 in antioxidant is quality hundred of 40%, the T502 in antioxidant in antioxidant It is that mass percents of 30%, the T502A in antioxidant is 30% to divide ratio.
Mass percent of the poly alpha olefine synthetic oil in carrier oil is 30% in carrier oil, and polyethers artificial oil is in carrier oil In mass percent be 70%.
Diluent is 200# solvent naphthas.
The high cleaning fuel oil compound additive, its preparation method such as embodiment 1.
The addition of the product of the present embodiment in the oil is 200ppm, and the addition in diesel oil is 300ppm, through special Industry testing department is examined, the physico-chemical analysis data fit GB 17930-2013 of oil product《Motor petrol》、GB19147-2013《Car Use diesel oil(Ⅴ)》It is required that.
Embodiment 4:
A kind of high cleaning fuel oil compound additive, is made up of the composition of following mass fraction:Detersive host 40%, it is wear-resistant Agent 8%, corrosion inhibitor 7%, antioxidant 5%, carrier oil 25%, diluent 15%.
Mass percent of the polyisobutene phenol Mannich base in detersive host is poly- for 50%, PEA in detersive host Mass percent of the ether amines in detersive host is 30%, and mass percent of the polyisobutene acid amides in detersive host is 20%。
Capric acid butyl ester mass percent in antiwear additive is 50%, dodecylic acid quality percentage in antiwear additive in antiwear additive Than for 30%, glycerol trioleate mass percent in antiwear additive is 20%.
Mass percent of the 17 alkenyl amine ethyl imidazol(e) quinolines in corrosion inhibitor is 60%, oleic acid base miaow in corrosion inhibitor Mass percent of the oxazoline in corrosion inhibitor is 40%.
Mass percents of the T551 in antioxidant is quality hundred of 40%, the T502A in antioxidant in antioxidant Divide than being 60%.
Mass percent of the poly alpha olefine synthetic oil in carrier oil is 70% in carrier oil, and polyethers artificial oil is in carrier oil In mass percent be 30%.
Diluent is 200# solvent naphthas.
The high cleaning fuel oil compound additive, its preparation method such as embodiment 1.
The addition of the product of the present embodiment in the oil is 200ppm, and the addition in diesel oil is 300ppm, through special Industry testing department is examined, the physico-chemical analysis data fit GB 17930-2013 of oil product《Motor petrol》、GB19147-2013《Car Use diesel oil(Ⅴ)》It is required that.
Embodiment 5
The high cleaning fuel oil compound additive that embodiment 1-4 is prepared is separately added into gasoline and bavin with commercially available additive Simulation deposit test, bench test are carried out in oil, result as shown in Table 1 and Table 2 is respectively obtained.
Table 1
Table 2
In summary, the compound additive that the present invention is obtained is added in vapour, diesel oil, heavy to automobile engine fuel oil system Product thing has obvious peace and quiet effect, can improve petrol and diesel oil exhaust emissions, is conducive to pollution treatment to drop haze, energy-saving and emission-reduction.Use this Vapour, the diesel oil of invention high cleaning fuel oil additive, burn more fully, effectively lift rate of economizing gasoline within the engine, while reducing combustion The abrasion of each part of oil system, suppresses the oxidation deterioration of fuel oil and additive, increasing service life of engine.
Above content is to combine the further description that specific embodiment is done to the present invention, it is impossible to assert this hair Bright specific implementation is confined to these explanations.For general technical staff of the technical field of the invention, do not taking off On the premise of from present inventive concept, some simple deduction or replace can also be made, the protection of the present invention should be all considered as belonging to Scope.

Claims (6)

1. a kind of high cleaning fuel oil compound additive, it is characterised in that be made up of the composition of following mass fraction:Detersive host 10~60%, antiwear additive 0~10%, corrosion inhibitor 0~10%, antioxidant 0~5%, carrier oil 15~40%, surplus is diluent;
The detersive host is polyisobutene phenol Mannich base, PEA polyetheramines, one kind in polyisobutene acid amides or many Kind.
2. high cleaning fuel oil compound additive according to claim 1, it is characterised in that:The antiwear additive is capric acid, the last of the ten Heavenly stems It is one or more in acid butyl ester, dodecylic acid, ethyl laurate, glycerol trioleate.
3. high cleaning fuel oil compound additive according to claim 1 or 2, it is characterised in that:The antioxidant is anti- It is one or more in oxygen agent T551, antioxidant T502, antioxidant T502A.
4. high cleaning fuel oil compound additive according to claim 3, it is characterised in that:The carrier oil is poly alpha olefin At least one of artificial oil, polyethers artificial oil.
5. high cleaning fuel oil compound additive according to claim 4, it is characterised in that:The diluent is No. 200 molten Agent oil.
6. a kind of high cleaning fuel oil compound additive preparation method according to claim 1-5, it is characterised in that including such as Lower step:
(1)By antiwear additive, corrosion inhibitor, antioxidant by mass fraction than adding in a certain amount of carrier oil, a certain amount of carrier Oil can be such that antiwear additive, corrosion inhibitor and antioxidant fully dissolves, and form mixing oil solution;
(2)Under agitation, detersive host and mixing oil solution are separately added into remaining carrier oil, are eventually adding dilution Agent, stirs to form clear solution, that is, obtains high cleaning fuel oil compound additive.
CN201610067900.7A 2016-02-01 2016-02-01 A kind of high cleaning fuel oil compound additive and preparation method thereof Active CN105647600B (en)

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CN106010692A (en) * 2016-06-21 2016-10-12 西安卓求新材料有限公司 Composite diesel additive
CN106118767B (en) * 2016-07-03 2017-12-29 宁夏大生生物科技有限公司 A kind of preparation method of biodesel fuel lubrication anti-wear agent
CN106432710B (en) * 2016-08-31 2018-06-29 天津悦泰石化科技有限公司 Polyethers gucosamine and preparation method and the purposes as gasoline cleaning agent host agent
CN106433816B (en) * 2016-09-28 2017-11-03 咸阳东庆石油化工有限公司 A kind of composite additive for gasoline with energy-saving and emission-reduction function
CN107653011A (en) * 2017-10-18 2018-02-02 王天石 A kind of automobile specified gasolene cleaner and preparation method thereof
CN107653008A (en) * 2017-10-27 2018-02-02 苏阳 Energy-saving and environment-protecting diesel fuel
CN108117899A (en) * 2017-12-23 2018-06-05 洛阳名力科技开发有限公司 A kind of fuel oil additive for increasing substantially fuel combustion efficiency
CN108998108A (en) * 2018-07-13 2018-12-14 潍坊天晨物流有限公司 A kind of modified gasoline additive
CN109554202B (en) * 2018-11-29 2020-09-18 云南聚中能源科技有限公司 Ethanol gasoline additive and ethanol gasoline prepared from same
CN110157505B (en) * 2019-05-31 2021-09-03 钟幸华 High-cleaning fuel carbon deposition detergent and preparation method thereof

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CN103374443B (en) * 2012-04-26 2015-09-23 中国石油化工股份有限公司 Composition oil of gasoline engine and manufacture method thereof
CN103450955B (en) * 2013-07-30 2015-03-11 英杰惠能(北京)能源新技术有限公司 Low-sulfur diesel oil additive composition, and preparation method and application of same
CN103642547B (en) * 2013-12-24 2016-06-08 济南开发区星火科学技术研究院 A kind of compound diesel additive and preparation method thereof

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