CN108178950A - A kind of highlight water-based gloss oil - Google Patents

A kind of highlight water-based gloss oil Download PDF

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Publication number
CN108178950A
CN108178950A CN201711361010.8A CN201711361010A CN108178950A CN 108178950 A CN108178950 A CN 108178950A CN 201711361010 A CN201711361010 A CN 201711361010A CN 108178950 A CN108178950 A CN 108178950A
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CN
China
Prior art keywords
parts
water
gloss oil
based gloss
highlight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711361010.8A
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Chinese (zh)
Inventor
张彪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STARLITE PRINTING (SUZHOU) Co Ltd
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STARLITE PRINTING (SUZHOU) Co Ltd
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Priority to CN201711361010.8A priority Critical patent/CN108178950A/en
Publication of CN108178950A publication Critical patent/CN108178950A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention is print field, and in particular to a kind of highlight water-based gloss oil, by the component of following parts by weight meter:35~37 parts of styrene-acrylic emulsion, 18~20 parts of water-soluble acrylic epoxy resin, 15~17 parts of poly adipate succinic acid ester, 6~8 parts of wax emulsion, 2 4~4.6 parts of aminoethylamino ethanesulfonic acid sodium, 4.5~5 parts of isophorone diisocyanate, 2.8~3 parts of diethanol amine, 2~2.2 parts of auxiliary agent are configured;The water-soluble acrylic epoxy resin is copolymerized by the component of following parts by weight meter:25 parts of epoxy resin, 8 parts of acrylic acid, 8 parts of maleic anhydride, 5 parts of ethylenediamine.The present invention has the advantages that glossiness is high, cost is relatively low, product is stablized.

Description

A kind of highlight water-based gloss oil
Technical field
The present invention is print field, and in particular to a kind of highlight water-based gloss oil.
Technical background
In recent years, environmental requirement is higher and higher on packaging material, and the process of surface treatment requirement of product packaging is very high, especially It is the glazing process after print, both coated (or spray, print) one layer of water white transparency coating in printed matter surface, protection and increasing are played after dry Add the effect of printed matter gloss.The coating of (or spray, print) last layer water white transparency is applied in printed matter surface, through levelling, drying, pressure A kind of thin and even transparent bright layer is formed in printed matter surface after light, curing, plays enhancing carrier surface smoothness, protection print The technique of the finish machining function of map brushing text.
Mainly there are two kinds of glazing modes of the aqueous glazing of line and off line UV glazings, traditional off line UV glazings currently on the market It is most commonly used, although off line UV gloss oil brightness can reach 85 degree, since UV gloss oil is comprising many harmful Solvent, and pollute the environment seriously, such production technology has not met the development trend of society;More environmentally friendly company at present The aqueous glazing process of line also obtains the use of more and more enterprises, but since such technique is using water as the solvent of aqueous glazing Also there is shortcoming, such as volatilizing, bad, rate of drying is slower, and it is unstable to be easy to cause product, and the brightness of line water-based gloss oil is only 70 degree or so can be reached.
In consideration of it, the highlight water-based gloss oil that a kind of cost of present invention offer is relatively low, product is stablized.
Invention content
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, a kind of highlight water-based gloss oil is provided.
Purpose to realize the present invention, the technical solution adopted by the present invention are:
A kind of highlight water-based gloss oil, by the component of following parts by weight meter:35~37 parts of styrene-acrylic emulsion, water-soluble acrylic ring 18~20 parts of oxygen resin, 15~17 parts of poly adipate succinic acid ester, 6~8 parts of wax emulsion, 2- aminoethylamino ethanesulfonic acids sodium 4 ~4.6 parts, 4.5~5 parts of isophorone diisocyanate, 2.8~3 parts of diethanol amine, 2~2.2 parts of auxiliary agent be configured.
The water-soluble acrylic epoxy resin is copolymerized by the component of following parts by weight meter:25 parts of epoxy resin, 8 parts of acrylic acid, 8 parts of maleic anhydride, 5 parts of ethylenediamine.
Preferably, the wax emulsion is babassu wax emulsion.
Preferably, the auxiliary agent includes levelling agent, dispersant, optical brightener, antifoaming agent and plasticizer.
Preferably, the levelling agent is carboxymethyl cellulose.
Preferably, the dispersant is polyacrylic acid sodium salt.
Preferably, the optical brightener is organosiloxane.
Preferably, the antifoaming agent is dimethyl silicone polymer.
Preferably, the plasticizer is ditridecyl phthalate.
Relative to the prior art, the application achieves following advantageous effect:
Highlight water-based gloss oil wearability of the present invention is good, and adhesion is strong, cracking resistance, and there is good printing to adapt to Property.
Specific embodiment
Embodiment 1
A kind of highlight water-based gloss oil, by the component of following parts by weight meter:35 parts of styrene-acrylic emulsion, water-soluble acrylic asphalt mixtures modified by epoxy resin 20 parts of fat, 17 parts of poly adipate succinic acid ester, 8 parts of wax emulsion, 4.2 parts of 2- aminoethylamino ethanesulfonic acids sodium, isophorone two 5 parts of isocyanates, 2.8 parts of diethanol amine, 2 parts of auxiliary agent are configured.
The water-soluble acrylic epoxy resin is copolymerized by the component of following parts by weight meter:25 parts of epoxy resin, 8 parts of acrylic acid, 8 parts of maleic anhydride, 5 parts of ethylenediamine.
The wax emulsion is babassu wax emulsion.
The auxiliary agent includes levelling agent, dispersant, optical brightener, antifoaming agent and plasticizer.
The levelling agent is carboxymethyl cellulose.
The dispersant is polyacrylic acid sodium salt.
The optical brightener is organosiloxane.
The antifoaming agent is dimethyl silicone polymer.
The plasticizer is ditridecyl phthalate.
Embodiment 2
A kind of highlight water-based gloss oil, by the component of following parts by weight meter:37 parts of styrene-acrylic emulsion, water-soluble acrylic asphalt mixtures modified by epoxy resin 18 parts of fat, 16 parts of poly adipate succinic acid ester, 7 parts of wax emulsion, 4.6 parts of 2- aminoethylamino ethanesulfonic acids sodium, isophorone two 4.5 parts of isocyanates, 3 parts of diethanol amine, 2.1 parts of auxiliary agent are configured.
The water-soluble acrylic epoxy resin is copolymerized by the component of following parts by weight meter:25 parts of epoxy resin, 8 parts of acrylic acid, 8 parts of maleic anhydride, 5 parts of ethylenediamine.
The wax emulsion is babassu wax emulsion.
The auxiliary agent includes levelling agent, dispersant, optical brightener, antifoaming agent and plasticizer.
The levelling agent is carboxymethyl cellulose.
The dispersant is polyacrylic acid sodium salt.
The optical brightener is organosiloxane.
The antifoaming agent is dimethyl silicone polymer.
The plasticizer is ditridecyl phthalate.
Embodiment 3
A kind of highlight water-based gloss oil, by the component of following parts by weight meter:36 parts of styrene-acrylic emulsion, water-soluble acrylic asphalt mixtures modified by epoxy resin 20 parts of fat, 15 parts of poly adipate succinic acid ester, 6 parts of wax emulsion, 4 parts of 2- aminoethylamino ethanesulfonic acids sodium, isophorone two are different 4.7 parts of cyanate, 2.8 parts of diethanol amine, 2.2 parts of auxiliary agent are configured.
The water-soluble acrylic epoxy resin is copolymerized by the component of following parts by weight meter:25 parts of epoxy resin, 8 parts of acrylic acid, 8 parts of maleic anhydride, 5 parts of ethylenediamine.
The wax emulsion is babassu wax emulsion.
The auxiliary agent includes levelling agent, dispersant, optical brightener, antifoaming agent and plasticizer.
The levelling agent is carboxymethyl cellulose.
The dispersant is polyacrylic acid sodium salt.
The optical brightener is organosiloxane.
The antifoaming agent is dimethyl silicone polymer.
The plasticizer is ditridecyl phthalate.
Embodiment 4
Highlight water-based gloss oil performance test
The water-based gloss oil for buying comparative example at random with Examples 1 to 3 and on the market respectively is tested for the property, acquired results As shown in table 1.
Table 1
Glossiness:It is measured by the regulation of GB/T9754, incidence angle is 60 °.
Wearability:It is tested using friction machine, under 4 pounds of load, example edition is cut into wide 50mm* long 220mm, and with pressure Paper device is fixed in rubbing table, and 80 grams of A4 copy papers are cut into wide 50mm* long 220mm, and be fixed on and rubbed with eccentric pinch roller On rub body, 80 grams of A4 copy papers smooth surfaces wear number when exposing ink to represent to example edition coated surface with film.
Scratch resistance:Apply middle pressure with thumbnail, scraped back and forth on water oil dry film, observe the serious of scratch Degree;Evaluation result is divided into 1~5 grade, and 1 grade worst, and 5 grades best.
From the above results, highlight water-based gloss oil of the present invention has preferable glossiness, wearability and anti-scratch Wound property.

Claims (8)

1. a kind of highlight water-based gloss oil, by the component of following parts by weight meter:35~37 parts of styrene-acrylic emulsion, water-soluble acrylic epoxy 18~20 parts of resin, 15~17 parts of poly adipate succinic acid ester, 6~8 parts of wax emulsion, 2- aminoethylamino ethanesulfonic acids sodium 4~ 4.6 parts, 4.5~5 parts of isophorone diisocyanate, 2.8~3 parts of diethanol amine, 2~2.2 parts of auxiliary agent be configured;The water Soluble acrylic epoxy resin is copolymerized by the component of following parts by weight meter:25 parts of epoxy resin, 8 parts of acrylic acid, suitable fourth 8 parts of enedioic acid acid anhydride, 5 parts of ethylenediamine.
2. highlight water-based gloss oil according to claim 1, which is characterized in that the wax emulsion is babassu wax emulsion.
3. highlight water-based gloss oil according to claim 1, which is characterized in that the auxiliary agent includes levelling agent, dispersant, increasing Photo etching, antifoaming agent and plasticizer.
4. highlight water-based gloss oil according to claim 1, which is characterized in that the levelling agent is carboxymethyl cellulose.
5. highlight water-based gloss oil according to claim 4, which is characterized in that the dispersant is polyacrylic acid sodium salt.
6. highlight water-based gloss oil according to claim 4, which is characterized in that the optical brightener is organosiloxane.
7. highlight water-based gloss oil according to claim 4, which is characterized in that the antifoaming agent is dimethyl silicone polymer.
8. highlight water-based gloss oil according to claim 4, which is characterized in that the plasticizer is ditridecyl phthalate.
CN201711361010.8A 2017-12-18 2017-12-18 A kind of highlight water-based gloss oil Pending CN108178950A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711361010.8A CN108178950A (en) 2017-12-18 2017-12-18 A kind of highlight water-based gloss oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711361010.8A CN108178950A (en) 2017-12-18 2017-12-18 A kind of highlight water-based gloss oil

Publications (1)

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CN108178950A true CN108178950A (en) 2018-06-19

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157254A (en) * 2019-04-24 2019-08-23 杭州天龙油墨有限公司 A kind of highlight water-based gloss oil
CN110406287A (en) * 2019-08-28 2019-11-05 蚌埠市比优特包装印务有限责任公司 The highlighted color face oil glazing process of one kind
CN113882191A (en) * 2021-10-27 2022-01-04 上海昶法新材料有限公司 Preparation method of paper-based insect-attracting board barrier layer

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104845500A (en) * 2015-05-05 2015-08-19 齐鲁工业大学 Novel printed product gloss oil
CN105386365A (en) * 2015-10-10 2016-03-09 洋紫荆油墨(中山)有限公司 High-gloss anti-scratch waterborne glazing oil and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104845500A (en) * 2015-05-05 2015-08-19 齐鲁工业大学 Novel printed product gloss oil
CN105386365A (en) * 2015-10-10 2016-03-09 洋紫荆油墨(中山)有限公司 High-gloss anti-scratch waterborne glazing oil and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157254A (en) * 2019-04-24 2019-08-23 杭州天龙油墨有限公司 A kind of highlight water-based gloss oil
CN110406287A (en) * 2019-08-28 2019-11-05 蚌埠市比优特包装印务有限责任公司 The highlighted color face oil glazing process of one kind
CN113882191A (en) * 2021-10-27 2022-01-04 上海昶法新材料有限公司 Preparation method of paper-based insect-attracting board barrier layer

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Application publication date: 20180619