CN108178254A - A kind of water purification, removing toxic substances pulvis and its manufacture craft for aquaculture - Google Patents

A kind of water purification, removing toxic substances pulvis and its manufacture craft for aquaculture Download PDF

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Publication number
CN108178254A
CN108178254A CN201711469272.6A CN201711469272A CN108178254A CN 108178254 A CN108178254 A CN 108178254A CN 201711469272 A CN201711469272 A CN 201711469272A CN 108178254 A CN108178254 A CN 108178254A
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CN
China
Prior art keywords
pulvis
aquaculture
water purification
toxic substances
removing toxic
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CN201711469272.6A
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Chinese (zh)
Inventor
郑宝权
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Shenzhen Tian Tian International Bioengineering Technology Co Ltd
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Shenzhen Tian Tian International Bioengineering Technology Co Ltd
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Priority to CN201711469272.6A priority Critical patent/CN108178254A/en
Publication of CN108178254A publication Critical patent/CN108178254A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/101Sulfur compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

The invention discloses a kind of water purification for aquaculture, removing toxic substances pulvis, by weight, including following component:80~99 parts of aluminium polychloride, 0.01~1 part of SODIUM PERCARBONATE, 0.1~2.5 part of calcium chloride, 0.01~2.5 part of selenium soil.The present invention's has the function of quickly to solidify suspended matter, precipitation, organic dirt of degrading for the water purification of aquaculture, removing toxic substances pulvis;The particle and organic debris of suspension can be precipitated after muddy water body use rapidly, makes water body as clear as crystal, has the function of to purify water, improve water quality, removing toxic substances deodorization.Further, the invention also discloses above-mentioned water purification for aquaculture, the manufacture crafts for the pulvis that detoxifies.

Description

A kind of water purification, removing toxic substances pulvis and its manufacture craft for aquaculture
Technical field
The present invention relates to green agriculture, animal husbandry and fishery cultural technique field is particularly a kind of for the net of aquaculture Water, removing toxic substances pulvis and its manufacture craft.
Background technology
The density of aquaculture at present is increasing with the raising of aquaculture cost, and the yield of per unit area yield constantly refreshes, and adds The big load of cultivating pool water body self-purification ability, being also easy to cause dissolved oxygen content in water body reduces, hydrogen sulfide, ammonia nitrogen, Asia The content of nitrate rises, and it is dead due to the deterioration of water quality to be easy to cause aquaculture organism.Thus the water eutrophication brought The consequences such as change, water quality deterioration, illness outbreak are just destroying the benign sustainable development of culture fishery health.High bait throwing in, height are applied The development of fertile formula aquaculture, the organic matters such as residual bait, excrement, entity in water body already exceed water body environment peak load energy Power, substance Cycle-decomposition process are obstructed.In addition, the outburst and die by visitation of God of cyanobacteria and Euglena can all cause aquatic biological One of the poisoning of algae toxin and the factor that causes the large quantities of death of aquatic livestock.And in practical breeding process, due to supporting The educational level for growing family is not generally high, often misapplies heavy metal insecticide, increases Heavy Metals in Waters ion concentration, in water The phenomenon that being enriched in production animal body, aquatic livestock is caused to be poisoned is also to happen occasionally;It is not utilized by effective and reasonable largely Organic matter becomes water body the largest source of pollution, and when oxygenolysis largely consumes dissolved oxygen, and oxygen debt is caused to occur and increase in advance, and into One step inhibits organic matter complete oxidation, so as to generate incomplete oxidation product such as ammonia nitrogen, nitrite and hydrogen sulfide etc., these Substance harm of surviving and grow on aquatic livestock influences very big, aquatic livestock can be caused chronic or acute poisoning;Pond water source Pollution also result in breeding water body pollution after cultivated animals disease generation;Dissolved oxygen is low to cause acid-base value amplitude of diurnal variation big, carefully Bacterium, microorganism, parasite are in active state, and fish body faces the more of low dissolved oxygen, high ammonia nitrogen, high nitrite and bacteriosis It remises sharp, in Immunoresistance is most weak, inferior health and high emergency rating, is very easy to that disease occurs.The above phenomenon is all The phenomenon that being common in aquaculture process, is handled less than often leading to that cultivation object is large quantities of dead and whole death that arrive, cultivation It can't regain one's original capital at family.
At present, it is mainly handled in cultural technique using single means, is such as directed to aquatic livestock heavy metal poisoning feelings Condition, production generally splash EDTA to chelate heavy metal ion, but effect is unstable, there is also the raised side effects of pH.Therefore Lack effective ways or removing toxic substances product in production, quickly and effectively to release the toxicity of noxious material, reduce the aquatic products after raw poisoning Fisherman's loss is saved in the large quantities of death of animal.
Invention content
The present invention is solves more than technical problem, it is desirable to provide a kind of quick-acting Water body antidote, it can be quickly and effectively Improve water quality.The present invention adopts the following technical scheme that realization:
A kind of water purification for aquaculture, removing toxic substances pulvis, by weight, including following component:Aluminium polychloride 80 ~99 parts, 0.01~1 part of SODIUM PERCARBONATE, 0.1~2.5 part of calcium chloride, 0.01~2.5 part of selenium soil.
Preferably, the water purification for aquaculture, removing toxic substances pulvis further include 0.1~2 part of trace element.
It is highly preferred that the trace element includes:Magnesium, ferro element.
Preferably, the water purification for aquaculture, removing toxic substances pulvis further include 0.002~0.09 part of sodium selenite.
Preferably, the content of SODIUM PERCARBONATE and calcium chloride ratio is 1:1~20.
It is any of the above-described described for the water purification of aquaculture, removing toxic substances pulvis and its manufacture craft, it is stirred including raw material is poured into It mixes in machine and is uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made.
The present invention for the water purification of aquaculture, removing toxic substances pulvis have quick solidification suspended matter, precipitation, degrade it is organic The effect of dirt;The particle and organic debris of suspension can be precipitated after muddy water body use rapidly, makes water body as clear as crystal, is had It purifies water, improve water quality, removing toxic substances deodorization.
The present invention for the water purification of aquaculture, pulvis and its manufacture craft of detoxifying can eliminate nitrite, ammonia nitrogen, Vulcanize Hydrogen Energy harmful substance.
The present invention for aquaculture water purification, removing toxic substances pulvis can only kill an Euglena retain other algae simultaneously, favorably It is bred in beneficial algaes such as green alga, diatom, chlorellas.Lower public attention half pond if the excessive pond of Euglena will splash.
The present invention have also been devised above-mentioned water purification for aquaculture, the pulvis that detoxifies manufacture craft, technique includes will be former Material, which is poured into blender, to be uniformly mixed, and the water purification for aquaculture, removing toxic substances pulvis is then made.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to this hair It is bright to be further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not For limiting the present invention.
A kind of water purification for aquaculture, removing toxic substances pulvis, by weight, including following component:
Further, 0.1~2 part of trace element is further included for the water purification of aquaculture, removing toxic substances pulvis.
Wherein, the trace element includes magnesium, ferro element.
Further, the water purification for aquaculture, removing toxic substances pulvis further include 0.002~0.09 part of sodium selenite.
Further, the content of SODIUM PERCARBONATE and calcium chloride ratio is 1:1~10.
Said program for aquaculture water purification, detoxify pulvis component in, aluminium polychloride is between aluminium chloride Intermediate hydrolysate between aluminium hydroxide, the inorganic macromolecule compound can precipitate the organic matter in water body, adjust water Matter.It has the following advantages:One, floccule body is formed soon, and settling velocity is high, reaction sedimentation time section;Two, under equal dosage Hardness in water is consumed during aluminium chloride coagulation and is less than various inorganic coagulants, the pH value variation of water body is small after processing;Three, When handling water, especially handle high concentration who, can be not added with or less plus alkaline assistant or flocculation aid;Four, decoloring ability is better than other Inorganic water purifier, higher in temperature, the big pond of cultivation density is more excellent using aluminium polychloride effect.It and can be with its homicide Worm disinfectant can play a multiplier effect when mixed.
Said program for aquaculture water purification, detoxify pulvis component in, SODIUM PERCARBONATE generated after being dissolved in water Hydrogen oxide and sodium carbonate, and the peroxy in hydrogen peroxide has oxidation and reproducibility simultaneously, and though alkaline condition or Acid condition can be spontaneous decomposition generation water and oxygen, increase the dissolved oxygen in water, and can pass through oxygen in reaction Change organic matter improvement water quality, degradation of ammonia nitrogen, cultured water and organic-inorganic sulfide, chlorine system disinfectant, insecticide residual Object further, can cooperate with the drug of aquiculture animal to play synergistic effect.SODIUM PERCARBONATE decomposes the sodium carbonate of generation An alkaline environment is provided to hydrogen peroxide, hydrogen peroxide decomposition rate in the environment of alkalinity is assisted to accelerate, Ke Yiqi To quick-acting effects.
Said program for aquaculture water purification, detoxify pulvis component in, calcium chloride is made when water body pH is excessively high For acid-base modifier, the pH value of water body is reduced, the colloid being formed simultaneously can be slowed down with some phytoplankton Euglenas of flocculation sediment Euglena consumes amount of carbon dioxide, further reduces pH value.
Said program for aquaculture water purification, detoxify pulvis component in, selenium soil have suppression worm bacteria resistance function, It can inhibit the proliferation of insects bacterium etc., reduce the usage amount of insecticide, and the usage amount of worm medicine excessively will also result in water quality Deteriorate, this situation can be improved by being cooperateed with using selenium soil with aluminium polychloride.
Any of the above-described water purification for being used for aquaculture, the manufacture craft for the pulvis that detoxifies, including raw material is poured into stirring It is uniformly mixed in machine, the water purification for aquaculture, removing toxic substances pulvis is then made.
Embodiment 1
Polymerizable raw material aluminium chloride 990kg, SODIUM PERCARBONATE 2kg, calcium chloride 4kg is weighed, selenium soil 4kg pours into four kinds of raw materials It is uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs in blender.
Embodiment 2
Polymerizable raw material aluminium chloride 950kg, SODIUM PERCARBONATE 8kg, calcium chloride 20kg is weighed, selenium soil 22kg falls four kinds of raw materials Enter in blender and be uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
Embodiment 3
Polymerizable raw material aluminium chloride 950kg, SODIUM PERCARBONATE 5kg, calcium chloride 30kg is weighed, selenium soil 15kg falls four kinds of raw materials Enter in blender and be uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
Embodiment 4
Weigh polymerizable raw material aluminium chloride 900kg, SODIUM PERCARBONATE 10kg, calcium chloride, 80kg, selenium soil 10kg, by four kinds of raw materials It pours into blender and is uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
The water purification obtained for being used for aquaculture of above-described embodiment 1~4, removing toxic substances pulvis are according to 200g. mus of meters of water per acre Deep dosage is directly used in water splashing, the improvement situation before and after body sample analysis water body medication of fetching water, as a result such as table one:
Table one
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Before this product
Ammonia-nitrogen content 0.18 0.17 0.16 0.18 1.2
Content of nitrite 0.1 0.11 0.18 0.15 0.8
Hydrogen sulfide content 0 0 0 0 0.02
Water transparency cm 80 84 82 83 3
It is shown in table one, the water purification for aquaculture, removing toxic substances pulvis is made to reducing ammonia nitrogen in water body in Examples 1 to 4 Content, content of nitrite, hydrogen sulfide content substantially increase the transparency of water body.
Embodiment 5
Polymerizable raw material aluminium chloride 850kg, SODIUM PERCARBONATE 50kg, calcium chloride 55kg is weighed, selenium soil 45kg says four kinds of raw materials It pours into blender and is uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
Embodiment 6
Polymerizable raw material aluminium chloride 880kg, SODIUM PERCARBONATE 15kg, calcium chloride 75kg is weighed, selenium soil 30kg says four kinds of raw materials It pours into blender and is uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
Embodiment 7
Polymerizable raw material aluminium chloride 800kg, SODIUM PERCARBONATE 15kg, calcium chloride 150kg is weighed, selenium soil 35kg says four kinds of raw materials It pours into blender and is uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
Embodiment 8
Polymerizable raw material aluminium chloride 900kg, SODIUM PERCARBONATE 15kg, calcium chloride 80kg is weighed, selenium soil 5kg falls four kinds of raw materials Enter in blender and be uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
The water purification obtained for being used for aquaculture of above-described embodiment 5~8, removing toxic substances pulvis are according to 200g. mus of meters of water per acre Deep dosage is directly used in water splashing, the improvement situation before and after body sample analysis water body medication of fetching water, as a result such as table two:
Table two
By observing the water purification for aquaculture in Examples 1 to 8, function and effect of the pulvis to water body of detoxifying, hair Existing, the content ratio of SODIUM PERCARBONATE and calcium chloride is 1:Between 1~10 range, the improvement of water body is notable, it was demonstrated that crosses carbon Sour sodium has synergistic effect with calcium chloride in the function of improving water body.Ammonia-nitrogen content can be reduced after use, nitrite contains It measures, hydrogen sulfide content, substantially increases the transparency of water body.
Embodiment 9
The present embodiment adds trace element on the basis of embodiment 1, specifically, weighing polymerizable raw material aluminium chloride Above-mentioned raw materials are poured into blender by 990kg, SODIUM PERCARBONATE 2kg, calcium chloride 4kg, selenium soil 4kg, magnesium chloride 3kg, iron chloride 3kg In be uniformly mixed, the water purification for aquaculture is then made, removing toxic substances and is packed pulvis.
Embodiment 10
The present embodiment adds trace element on the basis of embodiment 5, specifically, weighing polymerizable raw material aluminium chloride Four kinds of raw materials are poured into and stirred by 850kg, SODIUM PERCARBONATE 50kg, calcium chloride 55kg, selenium soil 45kg, magnesium chloride 3kg, iron chloride 3kg It mixes in machine and is uniformly mixed, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
Above-described embodiment 9 and the water purification obtained for being used for aquaculture of embodiment 10, removing toxic substances pulvis are according to 200g. per acre The dosage of the meters of depth of waters of mu, is directly used in water splashing, the improvement situation before and after body sample analysis water body medication of fetching water, as a result Such as table three:
Table three
Embodiment 9 Embodiment 10 Before this product
Ammonia-nitrogen content 0.16 0.17 1.0
Content of nitrite 0.13 0.11 0.8
Hydrogen sulfide content 0 0 0.01
Water transparency cm 80 82 2
It can be obtained from table three, in for the water purification of aquaculture, removing toxic substances pulvis, add in a small amount of trace element magnesium Element and ferro element can increase beneficial algae quantity.It can reduce ammonia-nitrogen content after use, content of nitrite, hydrogen sulfide content, Substantially increase the transparency of water body.
Embodiment 11
The present embodiment adds sodium selenite on the basis of embodiment 1, specifically, weighing polymerizable raw material aluminium chloride Five kinds of raw materials are poured into stir in blender and be mixed by 990kg, SODIUM PERCARBONATE 2kg, calcium chloride 4kg, selenium soil 4kg, sodium selenite 1kg It closes uniformly, the water purification for aquaculture, removing toxic substances pulvis is then made and packs.
Embodiment 12
The present embodiment adds sodium selenite on the basis of embodiment 5, specifically, weighing polymerizable raw material aluminium chloride Five kinds of raw materials are poured into blender and stirred by 850kg, SODIUM PERCARBONATE 50kg, calcium chloride 55kg, selenium soil 45kg, sodium selenite 9kg It mixes uniformly mixed, the water purification for aquaculture is then made, removing toxic substances and is packed pulvis.
Above-described embodiment 11 and the water purification obtained for being used for aquaculture of embodiment 12, removing toxic substances pulvis are according to 200g. per acre The dosage of the meters of depth of waters of mu, is directly used in water splashing, the improvement situation before and after body sample analysis water body medication of fetching water, as a result Such as table four:
Table four
Embodiment 11 Embodiment 12 Before this product
Ammonia-nitrogen content 0.18 0.19 1.2
Content of nitrite 0.1 0.11 0.9
Hydrogen sulfide content 0 0 0.022
Water transparency cm 80 81 3
It can be obtained from table four, in for the water purification of aquaculture, removing toxic substances pulvis, add in a small amount of sodium selenite energy Promote the breeding of beneficial algae.Ammonia-nitrogen content, content of nitrite can be reduced after use, hydrogen sulfide content substantially increases water The transparency of body.
Embodiment 13
The present embodiment adds trace element and sodium selenite simultaneously on the basis of embodiment 1, specifically, weighing original Expect aluminium polychloride 990kg, SODIUM PERCARBONATE 1kg, calcium chloride 6kg, selenium soil 4kg, magnesium chloride 3kg, iron chloride 3kg, sodium selenite Four kinds of raw materials are poured into blender and are uniformly mixed by 1kg, and the water purification for aquaculture, removing toxic substances pulvis is then made simultaneously Packaging.
Embodiment 14
Add trace element adds sodium selenite to the present embodiment simultaneously on the basis of embodiment 5, specifically, claiming Polymerizable raw material aluminium chloride 850kg, SODIUM PERCARBONATE 50kg, calcium chloride 55kg, selenium soil 45kg, magnesium chloride 3kg, iron chloride 3kg are taken, Sodium selenite 9kg, above-mentioned raw materials are poured into blender and are uniformly mixed, and the water purification for aquaculture, solution is then made Malicious pulvis is simultaneously packed.
Above-described embodiment 13 and the water purification obtained for being used for aquaculture of embodiment 14, removing toxic substances pulvis are according to 200g. per acre The dosage of the meters of depth of waters of mu, is directly used in water splashing, the improvement situation before and after body sample analysis water body medication of fetching water, as a result Such as table five:
Table five
Embodiment 13 Embodiment 14 Before dosing
Ammonia-nitrogen content 0.18 0.19 1.2
Content of nitrite 0.1 0.11 0.8
Hydrogen sulfide content 0 0 0.002
Water transparency cm 80 82 3.5
It can be obtained from table five, in for the water purification of aquaculture, removing toxic substances pulvis, while add in a small amount of trace element It can promote the breeding of beneficial algae with sodium selenite.It can reduce ammonia-nitrogen content after use, content of nitrite, hydrogen sulfide content, Substantially increase the transparency of water body.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality Example is applied the present invention is described in detail, it for those skilled in the art, still can be to aforementioned each implementation Technical solution recorded in example modifies or carries out equivalent replacement to which part technical characteristic.All essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (6)

1. a kind of water purification for aquaculture, removing toxic substances pulvis, which is characterized in that by weight, raw material includes following component: 80~99 parts of aluminium polychloride, 0.01~1 part of SODIUM PERCARBONATE, 0.1~2.5 part of calcium chloride, 0.01~2.5 part of selenium soil.
2. water purification according to claim 1 for aquaculture, removing toxic substances pulvis, which is characterized in that described to be used for aquatic products The water purification of cultivation, removing toxic substances pulvis further include 0.1~2 part of trace element.
3. water purification according to claim 2 for aquaculture, removing toxic substances pulvis, which is characterized in that the trace element Including magnesium, ferro element.
4. water purification according to claim 1 for aquaculture, removing toxic substances pulvis, which is characterized in that described to be used for aquatic products The water purification of cultivation, removing toxic substances pulvis further include 0.002~0.09 part of sodium selenite.
5. water purification according to claim 1 for aquaculture, removing toxic substances pulvis, which is characterized in that SODIUM PERCARBONATE and chlorine The content ratio for changing calcium is 1:1~10.
6. for the water purification of aquaculture, the manufacture craft for the pulvis that detoxifies according to Claims 1 to 5 is any, including will be former Material, which is poured into blender, to be uniformly mixed, and the water purification for aquaculture, removing toxic substances pulvis is then made.
CN201711469272.6A 2017-12-29 2017-12-29 A kind of water purification, removing toxic substances pulvis and its manufacture craft for aquaculture Pending CN108178254A (en)

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CN112390387A (en) * 2020-11-13 2021-02-23 程佳霖 Water quality modifier, detergent containing water quality modifier and preparation method of water quality modifier
CN114573056A (en) * 2020-11-30 2022-06-03 刘耀红 Sewage ammonia nitrogen remover and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112390387A (en) * 2020-11-13 2021-02-23 程佳霖 Water quality modifier, detergent containing water quality modifier and preparation method of water quality modifier
CN114573056A (en) * 2020-11-30 2022-06-03 刘耀红 Sewage ammonia nitrogen remover and preparation method thereof

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Application publication date: 20180619