CN108164155A - A kind of dye technology of high-boron-silicon glass and soda-lime glass - Google Patents
A kind of dye technology of high-boron-silicon glass and soda-lime glass Download PDFInfo
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- CN108164155A CN108164155A CN201810042965.5A CN201810042965A CN108164155A CN 108164155 A CN108164155 A CN 108164155A CN 201810042965 A CN201810042965 A CN 201810042965A CN 108164155 A CN108164155 A CN 108164155A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of high-boron-silicon glass and the dye technologies of soda-lime glass, include the following steps：Colorant, debugging spraying equipment, spraying and annealing are prepared, wherein colorant its component by weight includes 18 22 parts of dimethyl fumarate, 18 22 parts of tributyl phosphate, 13 17 parts of methyl methacrylate, 9 10 parts of pure acrylate elastic emulsion, 12 18 parts of red lead, 6 10 parts of polyethylene micropowder wax, 79 parts of triethanolamine, 26 parts of enuatrol, 8 10 parts of N methyl pyrrolidones, 15 parts of coalescents, 10 14 parts of 13 parts of levelling agent, 24 parts of wetting agent and solvent type premetallized dye solution.The dye technology of the high-boron-silicon glass and soda-lime glass, glass article surface after coloring is beautiful in colour, gloss transparency is high, smooth exquisiteness, has good market prospects.
Description
Technical field
The invention belongs to glass working arts fields, and in particular to the coloring skill of a kind of high-boron-silicon glass and soda-lime glass
Art.
Background technology
High-boron-silicon glass (heat resistant glass) feed liquid viscosity is high, and melt temperature is high, and heat loss is high, especially does with coloured
Because the use of various colorants and co-solvent materials, colorant and cosolvent excessive corrosion kiln, subtract significantly during glass frit
Small kiln service life, cost increase considerably, and in addition colorant and cosolvent make feed liquid melt temperature space is small to lead to feed liquid
Unstable, excessive high hardness, viscosity is excessively high, makes compacting, and the handicraft products molding such as blowing and trombone slide is difficult, and bubble, calculus increases, into
Product rate declines.
Present glass coloration technology is all that bed rearrangement melting furnace feeds intake and high temperature after material path coloring process or molding
(less than 400 degree) or low temperature (less than 200 degree) color spray, product is more there are manufacturing procedure after such color spray, and product after processing
Color easily comes off, and harmful substance has no idea completely or largely to remove.
Invention content
The purpose of the present invention is to provide a kind of high-boron-silicon glass and the dye technology of soda-lime glass, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical solution：A kind of coloring of high-boron-silicon glass and soda-lime glass
Technology includes the following steps：
S1, colorant is prepared：Colorant its component by weight is as follows：18-22 parts of dimethyl fumarate, tricresyl phosphate fourth
18-22 parts of ester, 13-17 parts of methyl methacrylate, 9-10 parts of pure acrylate elastic emulsion, 12-18 parts of red lead, polyethylene micropowder wax 6-
10 parts, 7-9 parts of triethanolamine, 2-6 parts of enuatrol, 8-10 parts of N-Methyl pyrrolidone, 1-5 parts of coalescents, levelling agent 1-3
Part, 10-14 parts of 2-4 parts of wetting agent and solvent type premetallized dye solution；Preparation method is first by red lead, fumaric acid diformazan
Ester, tributyl phosphate, methyl methacrylate, pure acrylate elastic emulsion and polyethylene micropowder wax are added to solvent type metal complex dye
It is stirred and evenly mixed in material solution, obtains mixed material A；Triethanolamine, enuatrol and N-Methyl pyrrolidone are added to mixture again
It is stirred evenly in material A, obtains mixed material B；Finally coalescents, levelling agent and wetting agent are added to stir in mixed material B and be mixed
It is even to get to colorant；
S2, debugging spraying equipment：The equipment of spray colouration agent is debugged, and colorant is subjected to constant temperature preservation, spray
Automatic doubler surface glouer is positioned over far from high temperature, low temperature and the larger environment of difference variation, and thermostat is installed on the nozzle of spraying equipment,
The source pressure of spraying equipment is in installing steam-water separator on air compressor machine, air compressor machine；
S3, spraying：After high-boron-silicon glass and the demoulding of soda-lime glass formed product, temperature will in the environment of 400-700 degree
Spraying equipment is opened, and high-boron-silicon glass and soda-lime glass are sprayed, after colorant spraying, according to the reflection temperature of colorant
Degree decides whether secondary heating or carries out fire polishing processing or carried out in high-boron-silicon glass and soda-lime glass control product
After secondary operation aftershaping, sprayed after product is warming up to 400-700 degree；
S4, annealing：After high-boron-silicon glass and soda-lime glass product pyrolytic coating colorant and fire polishing, carry out high temperature and move back
Fire makes colorant have the longer time to carry out molecule exchange.
Preferably, the colorant its component by weight is as follows：20 parts of dimethyl fumarate, tributyl phosphate 20
Part, 15 parts of methyl methacrylate, 10 parts of pure acrylate elastic emulsion, 15 parts of red lead, 8 parts of polyethylene micropowder wax, 8 parts of triethanolamine,
4 parts of enuatrol, 9 parts of N-Methyl pyrrolidone, 3 parts of coalescents, 2 parts of levelling agent, 3 parts of wetting agent and solvent type metal complex contaminate
Expect 12 parts of solution.
Preferably, the coalescents are 2,2,4- trimethyls -1 and the mixture of 3- pentanediol diisobutyrates.
Preferably, the levelling agent is one kind in organosilicon, carboxymethyl cellulose or dimethyl silicone polymer.
Preferably, the wetting agent is alkyl aryl polyether.
The technique effect and advantage of the present invention：The dye technology of the high-boron-silicon glass and soda-lime glass, using transparent or
Nontransparent high-boron-silicon glass and soda-lime glass product, solve coloring must bed rearrangement melting furnace the drawbacks of feeding intake, product from
Melting furnace tear drop and choose material or draw expect out after include colorant and cosolvent are sprayed on production while later stage high temperature process
On product, glass baseplate and colorant and cosolvent is made to carry out molecule exchange under the high temperature conditions, so as to be merged, and incite somebody to action
Harmful substance volatilization in toner and cosolvent, reaches high color fastness and safety in utilization, the glass article surface color after coloring
Color gorgeous, gloss transparency height, smooth exquisiteness, have good market prospects.
Specific embodiment
Technical scheme of the present invention is further elaborated with reference to embodiment：
Embodiment 1
The dye technology of a kind of high-boron-silicon glass and soda-lime glass, includes the following steps：
S1, colorant is prepared：Colorant its component by weight is as follows：18 parts of dimethyl fumarate, tributyl phosphate
18 parts, 13 parts of methyl methacrylate, 9 parts of pure acrylate elastic emulsion, 12- parts of red lead, 6 parts of polyethylene micropowder wax, triethanolamine 7
Part, 2 parts of enuatrol, 8 parts of N-Methyl pyrrolidone, 1 part of coalescents, 1 part of levelling agent, 2 parts of wetting agent and solvent type metal network
Close 10 parts of dye solution；Preparation method is first by red lead, dimethyl fumarate, tributyl phosphate, methyl methacrylate, pure
Acrylate elastic emulsion and polyethylene micropowder wax are added in solvent type premetallized dye solution and stir and evenly mix, and obtain mixed material A；Again
Triethanolamine, enuatrol and N-Methyl pyrrolidone are added in mixed material A and stirred evenly, obtains mixed material B；It finally will be into
Film auxiliary agent, levelling agent and wetting agent, which are added in mixed material B, to be stirred and evenly mixed to get to colorant, and wherein coalescents are 2,
The mixture of 2,4- trimethyls -1 and 3- pentanediol diisobutyrates, levelling agent are organosilicon, carboxymethyl cellulose or poly- diformazan
One kind in radical siloxane, wetting agent are alkyl aryl polyether；
S2, debugging spraying equipment：The equipment of spray colouration agent is debugged, and colorant is subjected to constant temperature preservation, spray
Automatic doubler surface glouer is positioned over far from high temperature, low temperature and the larger environment of difference variation, and thermostat is installed on the nozzle of spraying equipment,
The caused coloring of the reason of solving the problems, such as because of the temperature difference is unstable and color fastness is unstable, and the source pressure of spraying equipment is in sky
Press installs steam-water separator on air compressor machine；
S3, spraying：After high-boron-silicon glass and the demoulding of soda-lime glass formed product, temperature will spraying in the environment of 400 degree
Opening of device sprays high-boron-silicon glass and soda-lime glass, after colorant spraying, is determined according to the reflection temperature of colorant
It is fixed whether to need secondary heating or carry out fire polishing processing or carried out in high-boron-silicon glass and soda-lime glass control product secondary
After processing aftershaping, sprayed after product is warming up to 400 degree；
S4, annealing：After high-boron-silicon glass and soda-lime glass product pyrolytic coating colorant and fire polishing, carry out high temperature and move back
Fire makes colorant have the longer time to carry out molecule exchange, reaches and preferably melts color effect and go de-stress.
Embodiment 2
The dye technology of a kind of high-boron-silicon glass and soda-lime glass, includes the following steps：
S1, colorant is prepared：Colorant its component by weight is as follows：20 parts of dimethyl fumarate, tributyl phosphate
20 parts, 15 parts of methyl methacrylate, 10 parts of pure acrylate elastic emulsion, 15 parts of red lead, 8 parts of polyethylene micropowder wax, triethanolamine 8
Part, 4 parts of enuatrol, 9 parts of N-Methyl pyrrolidone, 3 parts of coalescents, 2 parts of levelling agent, 3 parts of wetting agent and solvent type metal network
Close 12 parts of dye solution；Preparation method is first by red lead, dimethyl fumarate, tributyl phosphate, methyl methacrylate, pure
Acrylate elastic emulsion and polyethylene micropowder wax are added in solvent type premetallized dye solution and stir and evenly mix, and obtain mixed material A；Again
Triethanolamine, enuatrol and N-Methyl pyrrolidone are added in mixed material A and stirred evenly, obtains mixed material B；It finally will be into
Film auxiliary agent, levelling agent and wetting agent, which are added in mixed material B, to be stirred and evenly mixed to get to colorant, and wherein coalescents are 2,
The mixture of 2,4- trimethyls -1 and 3- pentanediol diisobutyrates, levelling agent are organosilicon, carboxymethyl cellulose or poly- diformazan
One kind in radical siloxane, wetting agent are alkyl aryl polyether；
S2, debugging spraying equipment：The equipment of spray colouration agent is debugged, and colorant is subjected to constant temperature preservation, spray
Automatic doubler surface glouer is positioned over far from high temperature, low temperature and the larger environment of difference variation, and thermostat is installed on the nozzle of spraying equipment,
The caused coloring of the reason of solving the problems, such as because of the temperature difference is unstable and color fastness is unstable, and the source pressure of spraying equipment is in sky
Press installs steam-water separator on air compressor machine；
S3, spraying：After high-boron-silicon glass and the demoulding of soda-lime glass formed product, temperature will spraying in the environment of 550 degree
Opening of device sprays high-boron-silicon glass and soda-lime glass, after colorant spraying, is determined according to the reflection temperature of colorant
It is fixed whether to need after cold spray secondary heating after heating or thermal jet or carry out fire polishing processing or in high-boron-silicon glass and sodium calcium glass
After glass control product carries out secondary operation aftershaping, sprayed after product is warming up to 550 degree or more；
S4, annealing：After high-boron-silicon glass and soda-lime glass product pyrolytic coating colorant and fire polishing, carry out high temperature and move back
Fire makes colorant have the longer time to carry out molecule exchange, reaches and preferably melts color effect and go de-stress.
Embodiment 3
The dye technology of a kind of high-boron-silicon glass and soda-lime glass, includes the following steps：
S1, colorant is prepared：Colorant its component by weight is as follows：22 parts of dimethyl fumarate, tributyl phosphate
22 parts, 17 parts of methyl methacrylate, 10 parts of pure acrylate elastic emulsion, 18 parts of red lead, 10 parts of polyethylene micropowder wax, triethanolamine 9
Part, 6 parts of enuatrol, 10 parts of N-Methyl pyrrolidone, 5 parts of coalescents, 3 parts of levelling agent, 4 parts of wetting agent and solvent type metal network
Close 14 parts of dye solution；Preparation method is first by red lead, dimethyl fumarate, tributyl phosphate, methyl methacrylate, pure
Acrylate elastic emulsion and polyethylene micropowder wax are added in solvent type premetallized dye solution and stir and evenly mix, and obtain mixed material A；Again
Triethanolamine, enuatrol and N-Methyl pyrrolidone are added in mixed material A and stirred evenly, obtains mixed material B；It finally will be into
Film auxiliary agent, levelling agent and wetting agent, which are added in mixed material B, to be stirred and evenly mixed to get to colorant, and wherein coalescents are 2,
The mixture of 2,4- trimethyls -1 and 3- pentanediol diisobutyrates, levelling agent are organosilicon, carboxymethyl cellulose or poly- diformazan
One kind in radical siloxane, wetting agent are alkyl aryl polyether；
S2, debugging spraying equipment：The equipment of spray colouration agent is debugged, and colorant is subjected to constant temperature preservation, spray
Automatic doubler surface glouer is positioned over far from high temperature, low temperature and the larger environment of difference variation, and thermostat is installed on the nozzle of spraying equipment,
The caused coloring of the reason of solving the problems, such as because of the temperature difference is unstable and color fastness is unstable, and the source pressure of spraying equipment is in sky
Press installs steam-water separator on air compressor machine；
S3, spraying：After high-boron-silicon glass and the demoulding of soda-lime glass formed product, temperature will spraying in the environment of 700 degree
Opening of device sprays high-boron-silicon glass and soda-lime glass, after colorant spraying, is determined according to the reflection temperature of colorant
It is fixed whether to need secondary heating or carry out fire polishing processing or carried out in high-boron-silicon glass and soda-lime glass control product secondary
After processing aftershaping, sprayed after product is warming up to 700 degree；
S4, annealing：After high-boron-silicon glass and soda-lime glass product pyrolytic coating colorant and fire polishing, carry out high temperature and move back
Fire makes colorant have the longer time to carry out molecule exchange, reaches and preferably melts color effect and go de-stress.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify to the technical solution recorded in foregoing embodiments or carry out equivalent replacement to which part technical characteristic,
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (5)
1. a kind of dye technology of high-boron-silicon glass and soda-lime glass, it is characterised in that：Include the following steps：
S1, colorant is prepared：Colorant its component by weight is as follows：18-22 parts of dimethyl fumarate, tributyl phosphate
18-22 parts, 13-17 parts of methyl methacrylate, 9-10 parts of pure acrylate elastic emulsion, 12-18 parts of red lead, polyethylene micropowder wax 6-10
Part, 7-9 parts of triethanolamine, 2-6 parts of enuatrol, 8-10 parts of N-Methyl pyrrolidone, 1-5 parts of coalescents, 1-3 parts of levelling agent,
10-14 parts of 2-4 parts of wetting agent and solvent type premetallized dye solution；Preparation method be first by red lead, dimethyl fumarate,
Tributyl phosphate, methyl methacrylate, pure acrylate elastic emulsion and polyethylene micropowder wax are added to solvent type premetallized dye
It is stirred and evenly mixed in solution, obtains mixed material A；Triethanolamine, enuatrol and N-Methyl pyrrolidone are added to mixed material A again
In stir evenly, obtain mixed material B；Finally coalescents, levelling agent and wetting agent are added in mixed material B and stirred and evenly mixed,
Obtain colorant；
S2, debugging spraying equipment：The equipment of spray colouration agent is debugged, and colorant is subjected to constant temperature preservation, spraying is set
It is standby to be positioned over far from high temperature, low temperature and the larger environment of difference variation, thermostat on the nozzle of spraying equipment is installed, is sprayed
The source pressure of equipment is in installing steam-water separator on air compressor machine, air compressor machine；
S3, spraying：After high-boron-silicon glass and the demoulding of soda-lime glass formed product, temperature will spraying in the environment of 400-700 degree
Opening of device sprays high-boron-silicon glass and soda-lime glass, after colorant spraying, is determined according to the reflection temperature of colorant
It is fixed whether to need secondary heating or carry out fire polishing processing or carried out in high-boron-silicon glass and soda-lime glass control product secondary
After processing aftershaping, sprayed after product is warming up to 400-700 degree；
S4, annealing：After high-boron-silicon glass and soda-lime glass product pyrolytic coating colorant and fire polishing, high annealing is carried out,
Colorant is made to have the longer time to carry out molecule exchange.
2. the dye technology of a kind of high-boron-silicon glass according to claim 1 and soda-lime glass, it is characterised in that：Described
Toner its component by weight is as follows：20 parts of dimethyl fumarate, 20 parts of tributyl phosphate, 15 parts of methyl methacrylate,
10 parts of pure acrylate elastic emulsion, 15 parts of red lead, 8 parts of polyethylene micropowder wax, 8 parts of triethanolamine, 4 parts of enuatrol, N- crassitudes
12 parts of 9 parts of ketone, 3 parts of coalescents, 2 parts of levelling agent, 3 parts of wetting agent and solvent type premetallized dye solution.
3. the dye technology of a kind of high-boron-silicon glass according to claim 1 and soda-lime glass, it is characterised in that：It is described into
Film auxiliary agent is 2,2,4- trimethyls -1 and the mixture of 3- pentanediol diisobutyrates.
4. the dye technology of a kind of high-boron-silicon glass according to claim 1 and soda-lime glass, it is characterised in that：The stream
Flat agent is one kind in organosilicon, carboxymethyl cellulose or dimethyl silicone polymer.
5. the dye technology of a kind of high-boron-silicon glass according to claim 1 and soda-lime glass, it is characterised in that：The profit
Humectant is alkyl aryl polyether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810042965.5A CN108164155A (en) | 2018-01-17 | 2018-01-17 | A kind of dye technology of high-boron-silicon glass and soda-lime glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810042965.5A CN108164155A (en) | 2018-01-17 | 2018-01-17 | A kind of dye technology of high-boron-silicon glass and soda-lime glass |
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| CN108164155A true CN108164155A (en) | 2018-06-15 |
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| CN201810042965.5A Pending CN108164155A (en) | 2018-01-17 | 2018-01-17 | A kind of dye technology of high-boron-silicon glass and soda-lime glass |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117361894A (en) * | 2023-10-23 | 2024-01-09 | 中国耀华玻璃集团有限公司 | Glass rapid coloring and color changing equipment and process method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103613269A (en) * | 2013-04-22 | 2014-03-05 | 罗海涛 | Manufacturing method for glass hand basin or glass foot basin |
| CN106583088A (en) * | 2016-10-31 | 2017-04-26 | 江苏华航威泰机器人科技有限公司 | High-pressure airless spraying device |
| CN107176795A (en) * | 2017-06-22 | 2017-09-19 | 合肥钢骨玻璃制品有限公司 | A kind of glass article surface coloring process |
-
2018
- 2018-01-17 CN CN201810042965.5A patent/CN108164155A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103613269A (en) * | 2013-04-22 | 2014-03-05 | 罗海涛 | Manufacturing method for glass hand basin or glass foot basin |
| CN106583088A (en) * | 2016-10-31 | 2017-04-26 | 江苏华航威泰机器人科技有限公司 | High-pressure airless spraying device |
| CN107176795A (en) * | 2017-06-22 | 2017-09-19 | 合肥钢骨玻璃制品有限公司 | A kind of glass article surface coloring process |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117361894A (en) * | 2023-10-23 | 2024-01-09 | 中国耀华玻璃集团有限公司 | Glass rapid coloring and color changing equipment and process method |
| CN117361894B (en) * | 2023-10-23 | 2024-03-26 | 中国耀华玻璃集团有限公司 | Glass rapid coloring and color changing equipment and process method |
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Application publication date: 20180615 |