CN108161279A - A kind of carbon steel A-TIG weldering activating agents and welding method - Google Patents

A kind of carbon steel A-TIG weldering activating agents and welding method Download PDF

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Publication number
CN108161279A
CN108161279A CN201711443277.1A CN201711443277A CN108161279A CN 108161279 A CN108161279 A CN 108161279A CN 201711443277 A CN201711443277 A CN 201711443277A CN 108161279 A CN108161279 A CN 108161279A
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powder
carbon steel
welding
activating agent
agent
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CN201711443277.1A
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CN108161279B (en
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冯英超
查泽火
任丽丽
扈晓刚
侯彦文
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China Nuclear Industry 23 Construction Co Ltd
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China Nuclear Industry 23 Construction Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3602Carbonates, basic oxides or hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/362Selection of compositions of fluxes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/16Arc welding or cutting making use of shielding gas
    • B23K9/167Arc welding or cutting making use of shielding gas and of a non-consumable electrode

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Arc Welding In General (AREA)

Abstract

The invention belongs to carbon steel welding technology fields, and in particular to a kind of carbon steel A TIG weldering activating agents and welding method.The invention discloses a kind of dedicated for carrying out the activating agent of A TIG welderings to carbon steel, carbon steel A TIG weldering activating agents, and including Agent Powder, the Agent Powder is by SiO that mass percent is 30%~50%2Powder, 20%~40% Cr2O3Powder, 10%~30% Al2O3Powder, 5%~10% TiO2Powder, 10%~30% MnO2Powder, 5%~10% Y2O3Powder and 2%~10% B2O3Powder constituent.Activating agent using the present invention carries out the A TIG welderings of carbon steel, can not only realize the single face welding and double face shaping to carbon steel, improve welding efficiency, and can ensure the quality of welding.

Description

A kind of carbon steel A-TIG weldering activating agents and welding method
Technical field
The invention belongs to carbon steel welding technology fields, and in particular to a kind of carbon steel A-TIG weldering activating agents and welding method.
Background technology
Since traditional TIG welderings, i.e. non-melt pole inert gas tungsten electrode protection weldering have welding quality height, welding process The advantages that material of stable, suitable welding is more, highly reliable, welding metal is unlikely to deteriorate, and be widely used.However, with Also there is certain limitation in continuous improvement to welding requirements, the welding method.For example, since the limited electric current of tungsten electrode is held By ability, arc energy density is reduced, limits its power density, causes that its deposition efficiency is low, welding penetration is shallow and raw It is low to produce efficiency.
In recent years, a kind of novel A-TIG welderings cause extensive concern.A-TIG welderings refer to, are coated on the surface of welding plank One layer of very thin surfactant, can cause arc constriction, and molten bath fluidised form is made to change, so as to substantially improve welding Fusion penetration.Welding penetration can be made to reach 2-3 times that traditional TIG is welded with this method, slope need not be opened to the plank of plate thickness 3-12mm Mouthful, it can once weld completion, and one side welding with back formation.Production efficiency is substantially increased, reduces production cost, with prospect It is very extensive.
Invention content
The present invention proposes a kind of carbon steel A-TIG welderings activating agent, for A-TIG of the plate thickness for 3~12mm carbon sheets Welding.Carbon steel A-TIG welds activating agent, and including Agent Powder, which is 30%~50% by mass percent SiO2Powder, 20%~40% Cr2O3Powder, 10%~30% Al2O3Powder, 5%~10% TiO2Powder, 10% ~30% MnO2Powder, 5%~10% Y2O3Powder and 2%~10% B2O3Powder constituent.
Preferably, which is paste or viscous liquid, is mixed by Agent Powder and organic solvent.
It is further preferred that organic solvent uses absolute ethyl alcohol.
It is further preferred that the activating agent by mass percent be 90%~95% Agent Powder and 5%~10% Absolute ethyl alcohol mix.
Preferably, Agent Powder by mass percent be 30% SiO2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 10% TiO2Powder, 10% MnO2Powder, 5% Y2O3Powder and 5% B2O3Powder constituent.
Preferably, Agent Powder by mass percent be 30% SiO2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 8% TiO2Powder, 7% MnO2Powder, 10% Y2O3Powder and 5% B2O3Powder constituent.
A kind of method for carrying out carbon steel A-TIG welding using above-mentioned carbon steel A-TIG weldering activating agents, specifically includes following step Suddenly:
Step S1, prepares activating agent;By mass percentage weigh 90%~95% Agent Powder and 5%~10% Absolute ethyl alcohol is mixed, and obtains into the activating agent of paste or viscous liquid;
Step S2 carries out carbon-steel parts surface treatment;Grinding process is carried out to the face of weld of carbon-steel parts using mechanical means, Until there is metallic luster;
Step S3 coats activating agent;By the activating agent even application prepared in the step S1 carbon-steel parts welding table The coated weight in face, wherein activating agent is subject to covers metallic luster just;
Step S4, is subjected to;After the absolute ethyl alcohol evaporating completely that carbon-steel parts surface is coated in activating agent, along work It is welded in the coated length direction of property agent.
Preferably, in the step S2, after completing carbon-steel parts surface grinding process, using absolute ethyl alcohol to carbon-steel parts Surface starts the cleaning processing.
It is further preferred that the welding method of hand tungsten argon arc welding is used in the step S4.
It is further preferred that welding parameter is:Welding current value is 110A~130A, and welding voltage value is 10V~14V, Speed of welding is 2~5m/h, and welding gun inclination angle is 70 °~80 °, and shield gas flow rate is 10~20L/min.
The invention has the advantages that:
1st, A-TIG welderings are carried out to carbon steel steel plate using the activating agent in the present invention, not only can once completes to weld, realized Single-side welding double-side forming, and the weld seam for being molded good and high-tensile can be obtained, so as to improve to carbon steel steel plate Welding efficiency and welding quality.
2nd, in the present invention by by Y in activating agent2O3The mass percent of powder is controlled between 5%~10%, simultaneously It matches corresponding welding operation and obtains preferable welding bead fusion penetration, ensure that the final Forming Quality for obtaining weld seam and weld seam Tensile strength.
Description of the drawings
Fig. 1 is the full face figure that weld seam is obtained in embodiment 1;
Fig. 2 is the back side photo figure that weld seam is obtained in embodiment 1;
Fig. 3 is the full face figure that weld seam is obtained in embodiment 2;
Fig. 4 is the back side photo figure that weld seam is obtained in embodiment 2;
Fig. 5 is the full face figure that weld seam is obtained in comparative example 1;
Fig. 6 is the back side photo figure that weld seam is obtained in comparative example 1;
Fig. 7 is the full face figure that weld seam is obtained in comparative example 2;
Fig. 8 is the back side photo figure that weld seam is obtained in comparative example 2;
Fig. 9 is the full face figure that weld seam is obtained in comparative example 3;
Figure 10 is the back side photo figure that weld seam is obtained in comparative example 3.
Specific embodiment
It describes in detail with reference to specific embodiment and comparative example to technical scheme of the present invention.
The carbon steel A-TIG weldering activating agents of the present invention are paste or viscous liquid, and by mass percent for 90%~ 95% Agent Powder and 5%~10% absolute ethyl alcohol mix.Equally, other organic solvents can also be used, into The modulation of row activating agent.It is preferable to employ nontoxic absolute ethyl alcohol carries out the modulation of activating agent, in this way can to avoid Modulated process impacts the body of operating personnel due to the volatilization of organic solvent.
Wherein, Agent Powder by mass percent be 30%~50% SiO2Powder, 20%~40% Cr2O3Powder End, 10%~30% Al2O3Powder, 5%~10% TiO2Powder, 10%~30% MnO2Powder, 5%~10% Y2O3Powder and 2%~10% B2O3Powder constituent.
Activating agent using the present invention to thickness be 3~12mm carbon steel sheet carry out A-TIG welderings the specific steps are:
Step S1, prepares activating agent.By mass percentage weigh 90%~95% Agent Powder and 5%~10% Absolute ethyl alcohol is mixed and the two is sufficiently stirred using glass bar, finally obtains into the work of paste or viscous liquid Property agent.
Step S2 carries out carbon steel sheet surface treatment.Grinding process is carried out to the face of weld of carbon steel sheet using mechanical means, Until there is metallic luster.Wherein, in the present embodiment, burnishing part is carried out to the welding position surface of carbon steel sheet using angle grinder Reason removes the impurity and oxidation film on surface.
Step S3 coats activating agent.Using hairbrush by the activating agent even application prepared in step S1 carbon steel sheet weldering Surface is connect, is i.e. the region of grinding process is completed in step S2.Wherein, the coated weight of activating agent can cover polishing region just Metallic luster subject to.
Step S4, is subjected to.After the activating agent of carbon steel plate surface coating dries completely, i.e., the nothing in activating agent After water-ethanol evaporating completely, carbon steel sheet is subjected to along the coated length direction of activating agent.
Embodiment 1
Activating agent using the present invention carries out A-TIG welderings to the Q245R carbon steel sheets that thickness is 6mm.Wherein, Agent Powder By the SiO that mass percent is 30%2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 10% TiO2Powder, 10% MnO2Powder, 5% Y2O3Powder and 5% B2O3Powder constituent.Using WSM-315D type total digital DC pulse argons Arc-welding machine is subjected to, and main welding parameters are:Welding current value be 110A~130A, welding voltage value for 10V~ 14V, speed of welding are 2~5m/h, and welding gun inclination angle is 70 °~80 °, and protective gas uses argon gas, and gas flow is 10~20L/ min。
Weld seam full face figure as shown in Figure 1 and back of weld photo figure as shown in Figure 2 are finally obtained, and to complete Carbon steel sheet into welding carries out mechanics pull test, obtains the result of the test shown in table 1.
Table 1
Embodiment 2
Method same as Example 1 is used to carry out A-TIG welderings for the Q245R carbon steel sheets of 6mm to thickness, difference only exists In, Agent Powder by SiO that mass percent is 30%2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 8% TiO2Powder, 7% MnO2Powder, 10% Y2O3Powder and 5% B2O3Powder constituent.
Weld seam full face figure as shown in Figure 3 and back of weld photo figure as shown in Figure 4 are finally obtained, and to complete Carbon steel sheet into welding carries out mechanics pull test, obtains the result of the test shown in table 2.
Table 2
Comparative example 1
Method same as Example 1 is used to carry out A-TIG welderings for the Q245R carbon steel sheets of 6mm to thickness, difference only exists In, Agent Powder by SiO that mass percent is 30%2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 13% TiO2Powder, 12% MnO2Powder and 5% B2O3Powder constituent.Finally obtain weld seam full face figure as shown in Figure 5 With back of weld photo figure as shown in Figure 6.
Comparative example 2
Method same as Example 1 is used to carry out A-TIG welderings for the Q245R carbon steel sheets of 6mm to thickness, difference only exists In, Agent Powder by SiO that mass percent is 30%2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 10% TiO2Powder, 12% MnO2Powder, 3% Y2O3Powder and 5% B2O3Powder constituent.It is final to obtain as shown in Figure 7 Weld seam full face figure and back of weld photo figure as shown in Figure 8.
Comparative example 3
Method same as Example 1 is used to carry out A-TIG welderings for the Q245R carbon steel sheets of 6mm to thickness, difference only exists In, Agent Powder by SiO that mass percent is 30%2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 6% TiO2Powder, 6% MnO2Powder, 13% Y2O3Powder and 5% B2O3Powder constituent.Finally obtain weldering as shown in Figure 9 Stitch full face figure and back of weld photo figure as shown in Figure 10.
With reference to shown in Fig. 1 to Fig. 4, comparative example 1 and embodiment 2 are it is found that activating agent using the present invention and by Y2O3 The mass percent of powder is controlled between 5%~10%, not only can disposably be completed the welding to carbon steel steel plate and be reached To one side welding with back formation effect.Meanwhile the front and back for obtaining weld seam is the weld seam of continuous uniform, and in the back of the body of weld seam Face forms the reinforcement of high uniformity, and excellent welded seam is molded so as to obtain.With reference to Tables 1 and 2 it is found that in embodiment 1 Very high tensile strength is respectively provided with the weld seam obtained in embodiment 2, tensile strength all reaches more than 450Rm/MPa, and surpasses Go out the tensile strength of base material itself, realize the welding effect of high quality.
With reference to shown in Fig. 1, Fig. 2, Fig. 5 and Fig. 6, comparative example 1 and comparative example 3 are it is found that by the Y in activating agent2O3Powder After removal, the positive sinking effect that weld seam is obtained in comparative example 3 weakens, and intermittent phenomenon occurs in the back side of weld seam, Even regional area is there are the weld defect of incomplete fusion, i.e., there is no the connections really realized to 6mm carbon steel sheets in comparative example 1 Through welding.Therefore, compared with comparative example 1, in embodiment 1 and embodiment 2 by adding Y2O3Powder can be promoted to carbon steel Plate carries out the welding bead fusion penetration effect of A-TIG welderings, ensures molding and the welding quality of weld seam.
With reference to shown in Fig. 1 to Fig. 4 and Fig. 7 to Figure 10, comparative example 1, embodiment 2, comparative example 2 and comparative example 3 it is found that By controlling Y in carbon steel activating agent2O3The mass percent of powder, i.e., by Y2O3The mass percent control of powder 5%~ Between 10%, it is ensured that the fusion penetration effect of welding bead in the continuity and welding process of welding obtains the weld seam of forming.When Y2O3When the mass percent of powder is less than 5%, although the front welding effect of weld seam keeps good, obtain continuous uniform Weld seam, but but there are some hair wastes phenomenons and has stomata generation in the back side of weld seam, i.e., in entire welding process not Ensure the through welding of whole positions, the fusion penetration effect of welding bead declines, and the fusion effect of weld seam is caused to decline;Work as Y2O3The quality of powder When percentage is higher than 10%, the front welding effect of similary weld seam keeps good, obtains continuous uniform weld seam, but weld seam The back side leachy appearance, there are weld defects.

Claims (10)

1. a kind of carbon steel A-TIG welds activating agent, which is characterized in that including Agent Powder, the Agent Powder is by quality percentage Than the SiO for 30%~50%2Powder, 20%~40% Cr2O3Powder, 10%~30% Al2O3Powder, 5%~10% TiO2Powder, 10%~30% MnO2Powder, 5%~10% Y2O3Powder and 2%~10% B2O3Powder constituent.
2. carbon steel A-TIG according to claim 1 welds activating agent, which is characterized in that the activating agent is paste or thick Liquid is mixed by Agent Powder and organic solvent.
3. carbon steel A-TIG according to claim 2 welds activating agent, which is characterized in that organic solvent uses absolute ethyl alcohol.
4. carbon steel A-TIG according to claim 3 welds activating agent, which is characterized in that the activating agent is by mass percent 90%~95% Agent Powder and 5%~10% absolute ethyl alcohol mix.
5. the carbon steel A-TIG weldering activating agents according to any one in claim 1-4, which is characterized in that Agent Powder By the SiO that mass percent is 30%2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 10% TiO2Powder, 10% MnO2Powder, 5% Y2O3Powder and 5% B2O3Powder constituent.
6. the carbon steel A-TIG weldering activating agents according to any one in claim 1-4, which is characterized in that Agent Powder By the SiO that mass percent is 30%2Powder, 30% Cr2O3Powder, 10% Al2O3Powder, 8% TiO2Powder, 7% MnO2Powder, 10% Y2O3Powder and 5% B2O3Powder constituent.
7. carbon steel A-TIG described in any one welds the carbon steel A-TIG welding sides that activating agent carries out in a kind of 1-6 using claim Method, which is characterized in that specifically include following steps:
Step S1, prepares activating agent;Weigh by mass percentage 90%~95% Agent Powder and 5%~10% it is anhydrous Ethyl alcohol is mixed, and obtains into the activating agent of paste or viscous liquid;
Step S2 carries out carbon-steel parts surface treatment;Grinding process is carried out to the face of weld of carbon-steel parts using mechanical means, until There is metallic luster;
Step S3 coats activating agent;By the activating agent even application prepared in the step S1 carbon-steel parts face of weld, The coated weight of middle activating agent is subject to covers metallic luster just;
Step S4, is subjected to;After the absolute ethyl alcohol evaporating completely that carbon-steel parts surface is coated in activating agent, along activating agent Coated length direction welded.
8. carbon steel A-TIG welding methods according to claim 7, which is characterized in that in the step S2, complete carbon steel After the grinding process of part surface, the surface of carbon-steel parts is started the cleaning processing using absolute ethyl alcohol.
9. carbon steel A-TIG welding methods according to claim 7, which is characterized in that using by hand in the step S4 The welding method of argon tungsten-arc welding.
10. carbon steel A-TIG welding methods according to claim 9, which is characterized in that welding parameter is:Welding current value For 110A~130A, welding voltage value is 10V~14V, and speed of welding is 2~5m/h, and welding gun inclination angle is 70 °~80 °, protects gas Body flow is 10~20L/min.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109175787A (en) * 2018-10-19 2019-01-11 昆山华恒焊接股份有限公司 A kind of carbon steel argon tungsten-arc welding activating agent and its application
CN109570710A (en) * 2018-12-11 2019-04-05 南京工程学院 A kind of activating agent and application method for mild steel high speed MAG weldering
CN113927201A (en) * 2020-07-14 2022-01-14 中国核工业二三建设有限公司 Formula and using method of activator for Q245R carbon steel A-TIG welding
CN113927202A (en) * 2020-07-14 2022-01-14 中国核工业二三建设有限公司 Formula and use method of activator for 316 stainless steel A-TIG welding
CN114393285A (en) * 2021-12-30 2022-04-26 河南三建美辰建筑科技有限公司 Welding method for increasing welding penetration
CN114932333A (en) * 2022-06-07 2022-08-23 广东瑞迅精密机械有限公司 Welding process of closed pressure-bearing container
CN118287890A (en) * 2024-05-10 2024-07-05 张家界航空工业职业技术学院 2205-Based duplex stainless steel A-TIG welding active agent

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WO2008056371A1 (en) * 2006-11-08 2008-05-15 The Secretary, Department Of Atomic Energy, Govt. Of India A penetration enhancing flux formulation for tungsten inert gas (tig) welding of austenitic stainless steel and its application
CN103990919A (en) * 2014-04-21 2014-08-20 张家港华宝机械制造有限公司 Dedicated welding active agent for deep penetration TIG welding and using method
US20160167178A1 (en) * 2014-12-16 2016-06-16 National Pingtung University Of Science & Technology Welding activated flux for structural alloy steels
CN106216885A (en) * 2016-08-21 2016-12-14 飞潮(无锡)过滤技术有限公司 A kind of special welding activating agent of rustless steel weldering

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CN1439478A (en) * 2002-03-29 2003-09-03 甘肃工业大学 Active agent for low-carbon steel tungsten argon arc welding
WO2008056371A1 (en) * 2006-11-08 2008-05-15 The Secretary, Department Of Atomic Energy, Govt. Of India A penetration enhancing flux formulation for tungsten inert gas (tig) welding of austenitic stainless steel and its application
CN103990919A (en) * 2014-04-21 2014-08-20 张家港华宝机械制造有限公司 Dedicated welding active agent for deep penetration TIG welding and using method
US20160167178A1 (en) * 2014-12-16 2016-06-16 National Pingtung University Of Science & Technology Welding activated flux for structural alloy steels
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109175787A (en) * 2018-10-19 2019-01-11 昆山华恒焊接股份有限公司 A kind of carbon steel argon tungsten-arc welding activating agent and its application
CN109175787B (en) * 2018-10-19 2020-11-06 昆山华恒焊接股份有限公司 Carbon steel tungsten electrode argon arc welding active agent and application thereof
CN109570710A (en) * 2018-12-11 2019-04-05 南京工程学院 A kind of activating agent and application method for mild steel high speed MAG weldering
CN113927201A (en) * 2020-07-14 2022-01-14 中国核工业二三建设有限公司 Formula and using method of activator for Q245R carbon steel A-TIG welding
CN113927202A (en) * 2020-07-14 2022-01-14 中国核工业二三建设有限公司 Formula and use method of activator for 316 stainless steel A-TIG welding
CN114393285A (en) * 2021-12-30 2022-04-26 河南三建美辰建筑科技有限公司 Welding method for increasing welding penetration
CN114932333A (en) * 2022-06-07 2022-08-23 广东瑞迅精密机械有限公司 Welding process of closed pressure-bearing container
CN114932333B (en) * 2022-06-07 2024-02-23 广东瑞迅精密机械有限公司 Welding process of closed pressure-bearing container
CN118287890A (en) * 2024-05-10 2024-07-05 张家界航空工业职业技术学院 2205-Based duplex stainless steel A-TIG welding active agent
CN118287890B (en) * 2024-05-10 2024-10-15 张家界航空工业职业技术学院 2205-Based duplex stainless steel A-TIG welding active agent

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