CN108149500A - The preparation method of true qualities gold and silver grass fiber water suction lining paper - Google Patents
The preparation method of true qualities gold and silver grass fiber water suction lining paper Download PDFInfo
- Publication number
- CN108149500A CN108149500A CN201711334906.7A CN201711334906A CN108149500A CN 108149500 A CN108149500 A CN 108149500A CN 201711334906 A CN201711334906 A CN 201711334906A CN 108149500 A CN108149500 A CN 108149500A
- Authority
- CN
- China
- Prior art keywords
- gold
- water suction
- true qualities
- lining paper
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/02—Pretreatment of the raw materials by chemical or physical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C1/00—Pretreatment of the finely-divided materials before digesting
- D21C1/06—Pretreatment of the finely-divided materials before digesting with alkaline reacting compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
- D21C3/022—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes in presence of S-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
- D21C9/004—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/02—Washing ; Displacing cooking or pulp-treating liquors contained in the pulp by fluids, e.g. wash water or other pulp-treating agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
- D21D1/00—Methods of beating or refining; Beaters of the Hollander type
- D21D1/20—Methods of refining
- D21D1/30—Disc mills
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/08—Dispersing agents for fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Mechanical Engineering (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of preparation method of true qualities gold and silver grass fiber high water absorption lining paper, more particularly to one kind passes through prepressing using gold and silver grass as raw material, it air-dries, screens dedusting, pre-preg, alkaline cooking, washing, screening, thermokalite are modified, washing, mashing, manufactures paper with pulp, and preparation method using the present invention can prepare that high added value, environmental pollution be small, true qualities gold and silver grass fiber water suction lining paper of satisfactory quality.Can also be used for manufacturing paper with pulp true qualities paper for daily use and with copying true qualities wrapping paper and china picture-character paper etc..
Description
Technical field
The present invention relates to pulp technology for making paper fields, relate in particular to a kind of system of true qualities gold and silver grass fiber water suction lining paper
Preparation Method.
Background technology
Water suction lining paper is wrap up the disposable hygienics nursing materials absorbent core layer such as Time of Fluff Slurry and hydroscopic high-molecular resin one
Class hygienic products.The water suction lining paper of amenities belongs to the speciality paper in paper for daily use.Have in disposable sanitary articles
Not replaceable effect, products characteristics are that have certain physical strength, and soft comfortable, evenness is good, and good water absorption is breathed freely
Property it is good, compared with high bulk, the sanitary indexs such as natural degradable and good bacteriostasis antibiosis antianaphylaxis meet the requirements.It is main at present
Sanltary towel, baby paper diaper are used for, trousers is drawn, is adult incontinence products, pet sanitary belt, Medical hygiene biscuit, compound
Core etc..
Water suction as the production package disposable hygienics nursing materials absorbent core layer such as Time of Fluff Slurry and hydroscopic high-molecular resin
Lining paper, current raw materials for production are mainly timber, for producing true qualities water suction lining paper rarely seen correlation both at home and abroad using gold and silver grass
It reports, and research is very few, exactly necessity of this invention.
With the raising of people's living standard, paper for daily use rapidly becomes most close with people's relationship in the modern life
One of consumer goods.The production of paper for daily use, the level of consumption are not only national people's quality of the life and paper industry technology water
Flat mark, and be the mark of social civilization level.The increase year by year of aging populations quantity has become the world and has been permitted at present
The problem of multinational facing.By taking China as an example, China in 2016 60 years old and above old man are 2.12 hundred million people, account for the total people in China
Mouthful ratio for 15.5%, 65 years old and above old man are 1.37 hundred million people, and the ratio for accounting for China's total population is 10.1%, illustrates China
Aging country is stepped into.Elderly population medical treatment, treatment, nursing, rehabilitation etc. etc. demand rapid growth, to defending
Production-goods source and Service Source all bring huge new challenge, are also brought to the market exploitation of old incontinence health product unlimited latent
Power, and China has put into effect one family can give birth to the family planning policy of two children, also gives absorbency hygiene market
Very big current demand is brought, in addition the excellent hygiene market demand of women increases again and again.Therefore one women of an older man and a youngster
Three big crowds are the main forces of consumption, comparatively his (she) demand is rigid, and the consumption idea of health environment-friendly
It is gradually rooted in the hearts of the people, makes people higher and higher to the quality requirements of disposable sanitary articles, not only want soft comfortable, have the physics strong
Degree, flexible, water absorbing and retaining properties are good, high bacteriostasis antibiosis and antianaphylaxis should also have, in particular time (including infant
Phase, female menstrual period, old man's incontinence phase etc.) it uses, it can effectively reduce or reduce the probability of pathogenic infection and allergic stimulated.Therefore
It develops environmentally protective water suction lining paper product and has a vast market development space.
Since the quality requirement of the water suction lining paper of production is higher, insider thinks the best raw material of lining paper that absorbs water at present
It is bleached softwood wood-fibred.And China's wood raw material is by cultivated area, growth cycle, the ecological balance, production cost and environmental protection
Etc. the constraints of factors lead to its limits throughput so that domestic wood fiber raw material supply is difficult to meet in the future for a long period of time
The raw materials requirement of relevant industries.Existing bleached wood pulp is mostly import, and larger cost of material pressure is brought to domestic relevant industries,
For these reasons, the new type natural of suitable China's national situation, renewable cellulose fibre how to be developed to make up wood raw material
It is insufficient；How by the improvement of preparation flow and technology and equipment etc., the quality for preparing high added value conforms to
The water suction lining paper asked meets the needs of market as important topic urgently to be resolved hurrily.On the one hand increase water suction lining paper production field
Add a kind of new sustainable regenerated raw material, and production cost substantially reduces, alleviate the cost of material pressure of China's relevant industries
Power especially can be alleviated or prevent to have to cause domestic and international speculator to import wood by import due to China's wood raw material scarcity
The monopolization of slurry, to improving the competitive power of export of China's Related product and in face of world's Green Trade Barrier with especially reality
Strategic importance；On the other hand by the differentiation of product, enterprise profit can be not only improved, gold and silver grassland industry can also be pulled to develop,
For agricultural sector structure adjustment, widen Increase Income of Peasant Households channel, drive the vast poor masses participate in plantation gold and silver grass realize it is precisely de-
Poor and continual and steady increase wealth, formed " with careless Dai Mu " slurrying, for grass, slurry paper between good interaction development provide it is a kind of newly
Approach.
Gold and silver grass belongs to perennial grass family tall plants fibrous raw material, belongs to Guizhou expert technical committee of Hua Nong groups and lasts
The independent research of more than 20 years, be the new grass seeds that current domestic graminous pasture kind uniquely obtains national inventing patent mandate, specially
Profit number：ZL201310750244.7；ZL201410406188.X；ZL201510270541.0；ZL201610510574.2；Through more
Year multiple spot cultivation verification shows：Gold and silver grass is the grass fibrous raw material of a kind of drought-enduring, waterlogging, impoverishment tolerant, cold resistant,
It is adaptable it is strong, growth is fast, cut down the phase is short, yield high (average yield per mu is up to 20-40 tons), biodegradable, disposable cultivation,
It can repeatedly fell continuously using 40 years or more, there is good bacteria resistance.Gold and silver grassland industry is in China's gold
Highly important effect is played in the rural economy of silver-colored grass producing region.Chemical composition and fibre morphology analysis knot to gold and silver grassland material
Fruit：Content of cellulose 40%-50% (needlebush 40%-55%), fibre length 1.1-3.2mm (needlebush 3-5mm), length-width ratio
80-120 (needlebush 70-150), fibre morphology and content and needle of the optimum as water suction lining paper raw materials for production of gold and silver grass
Wood is similar, and therefore, gold and silver grass has the genetic prerequisite for preparing water suction lining paper, but gold and silver grass knot is more and section portion is more flourishing,
Section portion surrounding often has hard spinule, and epidermal structure contains more pentose class hemicellulose, fatty wax compared with compacted mass
The non-cellulosic impurities ingredient such as matter, ash content and heteroproteose cell, in addition also containing soft, the stubby parenchyma cell composition in part
Gold and silver grass marrow, in the prior art without the content of report this respect.
Presently commercially available water suction lining paper is almost that bleached pulp produces entirely, and bleaching is mostly floated using efficient chlorine dioxide etc. containing chlorine
Agent is bleached, some businessmans are to meet high whiteness and good visual effect, artificial to add the disabling additive such as fluorescent whitening agent, is caused
Bleach paragraph chemicals dosage and equipment investment increase, and pulping yield declines, and personnel labor intensity increases, and the production cost increases
Problem, and bleaching effluent (containing a large amount of COD and BOD and a large amount of chloroform, chloro phenol compound, Lv Dai bioxin and
The toxic chlorinatedorganic such as furans) intractability up to standard it is big the problem of, thus bring the destructiveness to ecological environment and life
The serious problems such as the harmfulness of object.And bleached pulp since fiber have passed through bleaching process, have to drop by depolymerization by fiber
Solution causes fines content in water suction lining paper more, to its physical strength, water imbibition, bulk, flexibility and gas permeability etc.
Index causes harmful effect, so as to influence the qualification rate of product.
Invention content
The purpose of the present invention is overcoming above-mentioned technological deficiency, replaced using gold and silver grass or part replaces timber to be carried as raw material
For a kind of preparation method with high added value, small, satisfactory quality the true qualities gold and silver grass fiber water suction lining paper of environmental pollution.
Realize the technical scheme is that：A kind of preparation method of true qualities gold and silver grass fiber water suction lining paper, including following
Step：
(1) prepressing：The gold and silver culm for eliminating taper and root and leaf is sent into squeezer squeezing, prepressing pressure 8-
20MPa squeezes time 2-10min, temperature room temperature；
(2) dedusting section is screened：By step (1), treated is sent into oscillatory type roll-type deduster after tablet air-dries and is dusted
Processing；
(3) pre-preg section：The tablet of step (2) is sent into boiling vessel and carries out pre-preg processing, tablet stops impregnation stage
Stay time 10-120min, 20-95 DEG C of temperature, relative to over dry material quality, sodium hydroxide concentration 1-10%, liquor ratio 1：2-6；
(4) alkaline cooking：After pre-preg, add in alkaline matter and carry out alkaline cooking, relative to over dry material quality,
Alkaline matter dosage 8-20% in alkaline cooking, time 80-200min, 130-170 DEG C of temperature, 1 ﹕ 4-8 of liquor ratio, sulphidity
10-18%；
(5) washing concentrating：The slurry that step (4) obtains is washed in spraying pot pulp thickening, screening and washing thickener
Concentration, the mass concentration of slurry is 10-16% after concentration；
(6) thermokalite is modified：The slurry that step (5) obtains first is added in into reducing agent, and be preheated to 60- in steam mixer
70 DEG C, stock pump standpipe is entered after preheating, then sodium hydroxide solution is added in, and lead to and be steam heated to institute in high shear medium-consistency pulp mixer
Need 100-120 DEG C of temperature, into bleaching tower carry out thermokalite modification, tower top pressure 0.1-0.2MPa, time 20-100min, relatively
In over dry material quality, sodium hydroxide concentration 2-8%；
(7) it washs：By the slurry obtained by step (6) through vacuum pulp washing machine washing concentrating, generated scrub raffinate excludes,
The mass concentration of slurry is 8-16% after concentration；
(8) it is beaten：Slurry of the step (7) after concentrated is beaten, beating time 70-100min, after the completion of mashing
Beating degree is 35-450SR；
(9) it manufactures paper with pulp：Slurry after step (8) is beaten is manufactured paper with pulp, and obtains the water suction lining paper of true qualities.
The water suction lining paper of high added value is prepared using gold and silver grass as raw material, prepressing processing is carried out to gold and silver grass first, is made
It obtains raw material to be crushed, flattened, then warp air-dries, screening dust removal process, is uniformly impregnated with conducive to follow-up liquid, improves cooking homogeneities,
Drug consumption is reduced, mitigates gold and silver grass from source since epidermal structure is close, knot is more and the prosperity of section portion causes to be impregnated with difficulty
The problems such as uniformity, quality instability and the gold and silver grass of boiling not easy to control are containing itself weakness more than non-cellulosic impurity；Medicine
Liquid adds in two times, respectively in pre-preg section and alkaline cooking section, it is therefore an objective to：Logical peralkaline pre-preg liquid is removed in gold and silver grass
Alkali-soluble inorganic matter and organic species substance destroy the fatty wax of gold and silver grass exocuticle, increase gap on cell wall, become
It is soft, the diffusion dissolution for follow-up steaming stage medicinal liquid osmosis and reaction product establishes channel, while it is fine to increase gold and silver grass
Dimension and the contact area of lye conducive to delignification is increased, reduce thick slag rate, in addition, alkaline pre-preg liquid can neutralize tablet
Some internal acidic-groups are conducive to mitigate the fluctuation of active alkali effect in the boiling stage, improve slurry uniformity, it is ensured that into
Starch the stability of quality.
Preferably, step (2) the apoplexy siccative piece is 10-40min in the oscillatory type roll-type deduster residence time；Tablet
The air-dried time is 2-12 months.
Dry storage cause raw material moisture gradually with environmental balance and reduce and uniformly, simultaneously because what fresh feed contained
The ingredients such as sugar, protein, fat, wax and fresh feed containing microorganism, enzyme isoreactivity substance by weathering, solarization, fermentation,
The operation of nature such as oxidative deformation and reduce, make intercellular layer and cell wall tissue by different degrees of destruction, conducive to oozing for liquid
Saturating and lignin removing and reduction boiling dosage, can also reduce the slurry probability to go mouldy；In addition, the purpose of dedusting be in order to
The impurity such as the end for the light specific gravity carried secretly in tablet, marrow, leaf, flying dust and larger knot, the sandstone of proportion are removed, so as to effectively subtract
Less or boiling alkali charge that these impurity bands is avoided increases, the shortcomings of yield is low, and pulp quality is not high, and silicon obstacle is big.
Preferably, alkaline matter described in the step (4) is sodium hydroxide and vulcanized sodium.
Preferably, reducing agent described in the step (6) is sodium borohydride, sodium dithionite or sodium sulfite；Relatively
In over dry material quality, reducing agent dosage 0.1-3.0%.
Research shows that cellulose can be by alkaline bleach liquor degradation in thermokalite modification, leading into pulp yield and intensity reduces, into
Starching fiber fines increases, and purity reduces, and influences physical strength, water imbibition, bulk, flexibility and the gas permeability etc. of water suction lining paper
Performance indicator adds in reducing agent, and under (60-70 DEG C) effect of certain temperature when thermokalite is modified thus, will be fine using reducing agent
The plain terminal carbonyl of dimension is reduced into primary hydroxyl group, inhibits the alkaline bleach liquor degradation of cellulose, in addition, when thermokalite is modified, the heating of slurry
It is divided into two benches, leads to steam in steam mixer and high shear medium-consistency pulp mixer respectively so that slurry temperature gradually heats up, profit
In the thermal degradation and alkaline bleach liquor degradation that reduce cellulose, cellulose is protected, improves the selectivity that thermokalite is modified, the purpose that thermokalite is modified
It is：Pass through alkaline matter --- OH-1Nucleophillic attack effect so that residual lignin in slurry, coloring matter, hemicellulose and low
The substances such as molecule carbohydrate are dissolved by alkaline bleach liquor degradation, and alkali sodium hydroxide can make fibre swelling, fiber cohesion
Power weakens, and becomes loose, in addition under certain pressure and temperature action, residual lignin, pigment and half fiber in alkaline bleach liquor degradation slurry
Dimension element, low molecular weight carbohydrate, resin, ash grade ingredient effect synergy, improve the purity of slurry, reach the quality for the lining paper that absorbs water
It is required that.
Preferably, mashing is medium consistency refining or high consistency beating in the step (8)；The medium consistency refining refers to beating consistency
10-20%, it is more than 20% that the high consistency beating, which refers to beating consistency,；Beating equipment use in or high concentration plate mill, in or it is highly concentrated
It is beaten in being especially suitable for, short fibered pulp.The present invention use in or high consistency beating, main is to improve refining pulp quality and reduction
Beating energy consumption, the reason for this is that：In or during high consistency beating pulp fiber forms fiber cushion on tip edge and the flank of tooth, so as to increase fibre
Rubbing action between dimension, friction generates heat, and fiber, which absorbs heat, becomes soft plastic, reduces tip edge and fibre cutting is acted on,
Increase the fibrillating of fiber；The rubbing action when reduction of beating energy consumption is mainly due to middle and high consistency pulping between fiber
Increase, the possibility that mill contacts friction between each other is reduced, so as to reduce beating energy consumption.
Preferably, mud pit is additionally included in the step (9) and adds in fungicide and wet strength agent, relative to oven dry stock matter
Amount, fungicide dosage 0.1-0.5%, wet strengthening agent 0.05-2.5%；Fungicide and the mode of wet strength agent addition are respectively：It will
1000 times of dilution agent is sterilized, system is continuously added to by the screw metering pump of calibration；Wet strength agent clear water is diluted 10 times, is passed through
The screw metering pump of calibration is continuously added to system, the use of the reason of clear water dilution wet strength agent is that it is Cationic aid, is made
Whether it is affected in by system pH value and water containing polymer substances such as anion with effect.
It is highly preferred that the fungicide is alkyl imidazoline quaternary ammonium salt.The fungicide may be used also other than with bactericidal property
Softening fibre and the elimination performances such as electrostatic and excellent emulsification, dispersion, and it is biodegradable, and pollution mitigates significantly.This sterilization
Agent is the permeability by changing pathogenic bacteria endochylema film, makes thalline extravasation, it is hindered to be metabolized and makes pathogenic bacteria dead, is killed
Microbial action mechanism is 1. to change the permeability of cell, and moisture, which enters, ruptures volumination；2. has good surface-active
Effect, can high aggregation in phage surface, influence the metabolism of pathogenic bacteria；3. make protein denaturation；4. inactivated bacteria is intracellular
Dehydrogenase, oxidizing ferment and can decomposition glucose, succinate, the enzyme systems such as acetonate.
It is highly preferred that the wet strength agent is polyamide polyamine-epichlorohydrin resins (PAE).It is that more common thermosetting property is wet
Strong resin, and can be combined well with fiber per se with positive electricity, while wet strength is obtained, and page will not be lost
Flexibility and absorbability.It, which is acted on, is to confer to after page is soaked by liquid still have some strength, and integrality is kept conducive to page.
Its mechanism of action is：PAE carries positive electricity, can be adsorbed onto on negatively charged paper pulp fiber, then carries out quickly dividing in
With intermolecular polymerization, curing is stored after machine dried and lower machine, forms the polymer network of entanglement fiber, on the one hand
Interfibrous activity is limited, also the swollen of corresponding lower limit fiber and page stretch the performances such as denaturation, are on the other hand formed
Polymer network can close some fibre and interfibrous hydrogen bond, aquation occurs again for prevention, these Hydrogenbonds
Intensity protected.Thus the addition of PAE improves the wet strength of page.
Preferably, it is additionally included in head box and adds in dispersant, the dispersant feed postition is：It will disperse dilution agent
1000 times, system is continuously added to by the screw metering pump of calibration, relative to oven dry stock quality, dispersant dosage 0.05-
2.5%.
It is highly preferred that the dispersant is fatty alcohol polyoxyethylene ether methyl-monosilane, potassium pyrophosphate, aliphatic alcohol polyethenoxy
Ether sodium sulfate or polyethylene glycol oxide.The action principle of dispersant is：The dynamic electricity for assigning fiber surface charge or changing on fiber is electric
Lotus makes negative electrical charge on fiber increase or adsorb in fiber surface one layer of cunning of formation without viscous hydrated film, has pulp fiber
Good suspension makes fiber mutually slip over without contacting with each other, and reduces the chance adhered to one another between fiber, fleeces gathers,
Entanglement mitigates significantly, is effectively improved into paper tissue evenness.
Compared with prior art the beneficial effects of the invention are as follows：
1st, the physical performance index of obtained true qualities gold and silver grass fiber water suction lining paper is：Longitudinal tensile index 12-16N
M/g, lateral tensile index 3-6Nm/g, longitudinal wet tensile index 3-4Nm/g, laterally wet tensile index 1-2Nm/g, is indulged
To suction range (finished layer) 14-20mm/100s, lateral suction range (finished layer) 40-65mm/100s, quantitative 10-40g/
m2, whiteness 35-50%ISO, pentosan 8% hereinafter, ash content 1.2% hereinafter, bulk 5.4-6.5cm3/ g, pliability (finished layer
It is average in length and breadth) 250mN is antibacterial to Candida albicans hereinafter, to staphylococcus aureus and more than 99% Escherichia coli bacteriostasis rate
More than 98% rate, therefore, true qualities water suction lining paper prepared by the present invention have high bacteriostasis antibiosis antianaphylaxis, biodegradable,
It is environmentally protective, prevent or prevent inflammation.This is used in particular time (including infantile period, female menstrual period, incontinence phase etc.)
The true qualities water suction lining paper product of invention can effectively reduce the probability of pathogen infection and stimulation allergy.
2nd, the present invention is whole without using harmful chemical agents such as bleaching agent, fluorescent powders, from source Stop harm environment and
(such as chloroform, chloro phenol compound, Lv Dai bioxin and furans are toxic for the persistence organic pollutant of organism health
Chlorinatedorganic) generation, be harmless to the Environmental insults free of contamination health-care environment protection type product of a new generation, maintain water suction
Pure, the natural essential characteristic of lining paper adapts to high-endization, the enjoymentization requirement of modern's demand.
3rd, the present invention combines the national conditions in China, using it is adaptable, growth is fast, yield is high, easily biological-degradable gold and silver grass as
Raw material, the processing mode being combined using physics with chemical method by prepressing, are air-dried, dedusting, pre-preg, alkaline cooking,
Washing, screening, thermokalite are modified, and are washed, and mashing is manufactured paper with pulp, prepare high added value, environmental pollution is small, satisfactory quality
True qualities gold and silver grass fiber water suction lining paper.The natural materials such as timber are not only solved by cultivated area, growth cycle, the ecological balance
And the constraint of the factors such as cost leads to its limits throughput problem so that again more a kind of new in the production field for the lining paper that absorbs water
Sustainable regenerated new raw material, and production cost substantially reduces so that and product is more economical, more preferably meets cost sensitive and disappears
The demand of the person of expense, while the cost of material pressure of China's relevant industries is alleviated, especially it can alleviate or prevent due to China's timber
Scarcity of raw material has to import is relied on to cause the monopolization of domestic and international speculator's import pulp.
4th, the present invention is raw material using gold and silver grass, and being combined processing with chemical method through Physical prepares true qualities water suction lining paper,
It is insufficient can to solve existing bleaching water suction lining paper raw materials for production, is mostly bleached due to bleaching using efficient chlorine-containing bleaching, causes to bleach
Section chemicals dosage and equipment investment increase, and pulping yield declines, and raw material availability is relatively low, and personnel labor intensity increases, raw
The problems such as producing cost increase and bleaching water suction lining paper containing more fiber fines, to its physical strength, water imbibition, bulk,
The problems such as indexs such as flexibility and gas permeability cause harmful effect.True qualities water suction lining paper obtained by the present invention has preferable object
Manage the sanitary indexs such as intensity, soft comfortable, affine skin, water imbibition and good permeability and good bacteriostasis antibiosis antianaphylaxis
It meets the requirements.The true qualities water suction lining paper produced is fully able to the requirement for meeting imbibition product, so as to realize that paper industry is held
Supervention exhibition is harmonious with environmental protection, if it is possible to apply in production, good economic interests and ring can be brought to enterprise
Border benefit and social benefit.
5th, the present invention can not only be improved the profit of enterprise, can also related industry be pulled to develop, be promoted by the differentiation of product
Into Increase Income of Peasant Households and employment, the integrated good interaction development of grass-slurry-paper is formed.
Specific embodiment
The technical solution in the embodiment of the present invention is clearly and completely described below.Based on the implementation in the present invention
Example, those skilled in the art's all other embodiments obtained without making creative work, belongs to this hair
The range of bright protection.
Embodiment 1
(1) prepressing：The gold and silver culm for eliminating taper and root and leaf is sent into squeezer squeezing, prepressing pressure
8MPa squeezes time 10min, temperature room temperature.
(2) dedusting section is screened：The gold and silver blade of 2 months will be air-dried and be sent into oscillatory type roll-type deduster, carry out heavy and light
Matter and the separation of qualified tablet.Tablet is air-dried in oscillatory type roll-type deduster residence time 20min.
(3) pre-preg section：Tablet after screening dedusting is sent into boiling vessel and carries out pre-preg processing.Tablet is in impregnation stage
Residence time 90min, 80 DEG C of temperature, relative to over dry material quality, sodium hydroxide concentration 5%, liquor ratio 1：5.
(4) alkaline cooking：After pre-preg, add in alkaline matter and carry out alkaline cooking, relative to over dry material quality, alkali
Alkaline matter dosage 12% in method boiling, time 120min, 130 DEG C of temperature, 1 ﹕ 6.5 of liquor ratio, sulphidity 18%；
(5) washing concentrating：Slurry after alkaline cooking is dense in the washing of spraying pot pulp thickening, screening and washing thickener
Contracting, the mass concentration of slurry is 16% after concentration；
(6) thermokalite is modified：Concentration slurry is added in into reducing agent, and logical steam preheating is passed through to 60 DEG C in steam mixer
Enter high shear medium-consistency pulp mixer after stock pump standpipe, sodium hydroxide solution, and logical steam are added in a mixer, into bleaching tower
Carry out thermokalite modification.Tower top pressure 0.2MPa, 120 DEG C, time 20min of temperature, relative to over dry material quality, sodium hydroxide concentration
6%, sodium borohydride dosage 2.2%；
(7) it washs：By the modified slurry of thermokalite through vacuum pulp washing machine washing concentrating, generated scrub raffinate excludes,
The mass concentration of slurry is 10% after concentration；
(8) it is beaten：Slurry after concentration is beaten.Dense or high consistency beating in being used in the present embodiment.To this coloured gold
Silver-colored straw pulp beating time 100min, beating degree is 45 ° of SR after the completion of mashing.Beating equipment use in or high concentration plate mill, in or
High consistency beating be especially suitable in, short fibered pulp.Beating consistency 10-20% claims medium consistency refining, and more than 20% beating consistency claims highly concentrated
Mashing.
(9) it manufactures paper with pulp：Slurry after mashing is manufactured paper with pulp, obtains the water suction lining paper of true qualities.Fungicide is added in mud pit
And wet strength agent, relative to oven dry stock quality, fungicide alkyl imidazoline quaternary ammonium salt dosage 0.1%, wet strength agent polyamide polyamine-table
Epichlorohydrin resin dosage 0.05%.Dispersant is added in head box, relative to oven dry stock quality, dispersant potassium pyrophosphate dosage
1.5%.
The physical performance index of obtained true qualities water suction lining paper is：Longitudinal tensile index 16Nm/g, lateral anti-tensile refer to
6Nm/g, longitudinal wet tensile index 4Nm/g are counted, laterally wet tensile index 2Nm/g, longitudinal water imbibition (finished layer) 14mm/
100s, lateral water imbibition (finished layer) 40mm/100s, quantitative 34g/m2, whiteness 50%ISO, pentosan 6.8%, ash content
1.0%, bulk 5.4cm3/ g, pliability (finished layer is average in length and breadth) 248mN.
Comparative example 1：Only cancel prepressing section, remaining technique, flow are same as Example 1.
Comparative example 2：Only cancel pre-preg section, remaining technique, flow are same as Example 1.
Comparative example 3：Prepressing section and pre-preg section are cancelled, remaining technique, flow are same as Example 1.
Embodiment 2
(1) prepressing：The gold and silver culm for eliminating taper and root and leaf is sent into squeezer squeezing, prepressing pressure
20MPa squeezes time 2min, temperature room temperature.
(2) dedusting section is screened：The gold and silver blade of 12 months will be air-dried and be sent into oscillatory type roll-type deduster, carry out heavy and light
Matter and the separation of qualified tablet.It is 10min that tablet, which is air-dried, in the oscillatory type roll-type deduster residence time.
(3) pre-preg section：Tablet after screening dedusting is sent into boiling vessel and carries out pre-preg processing.Tablet is in impregnation stage
Residence time 10min, 95 DEG C of temperature, relative to over dry material quality, sodium hydroxide concentration 10%, liquor ratio 1：2.
(4) alkaline cooking：After pre-preg, add in alkaline matter and carry out alkaline cooking, relative to over dry material quality, alkali
Alkaline matter dosage 8% in method boiling, time 200min, 155 DEG C of temperature, 1 ﹕ 4 of liquor ratio, sulphidity 15%；
(5) washing concentrating：Slurry after alkaline cooking is dense in the washing of spraying pot pulp thickening, screening and washing thickener
Contracting, the mass concentration of slurry is 10% after concentration；
(6) thermokalite is modified：Tower top pressure 0.1MPa, 100 DEG C, time 100min of temperature, relative to over dry material quality, hydrogen-oxygen
Change sodium dosage 8%, sodium sulfite dosage 3.0%.
(7) it washs：By the modified slurry of thermokalite through vacuum pulp washing machine washing concentrating, generated scrub raffinate excludes,
The mass concentration of slurry is 16% after concentration.
(8) it is beaten：Slurry after concentration is beaten.The present invention use in or high consistency beating.To true qualities gold and silver straw pulp
Beating time 70min, beating degree is 35 ° of SR after the completion of mashing.
(9) it manufactures paper with pulp：Slurry after mashing is manufactured paper with pulp, obtains the water suction lining paper of true qualities.Fungicide is added in mud pit
And wet strength agent, relative to oven dry stock quality, fungicide alkyl imidazoline quaternary ammonium salt dosage 0.5%, wet strength agent polyamide polyamine-table
Epichlorohydrin resin dosage 2.1%.Dispersant is added in head box, relative to oven dry stock quality, dispersant polyethylene glycol oxide dosage
0.05%.
The physical performance index of obtained true qualities water suction lining paper is：Longitudinal tensile index 12Nm/g, lateral anti-tensile refer to
3Nm/g, longitudinal wet tensile index 3Nm/g are counted, laterally wet tensile index 1Nm/g, longitudinal water imbibition (finished layer) 20mm/
100s, lateral water imbibition (finished layer) 65mm/100s, quantitative 40g/m2, whiteness 35%ISO, pentosan 7.3%, ash content
0.9%, bulk 6.5cm3/ g, pliability (finished layer is average in length and breadth) 211mN.
Embodiment 3
(1) prepressing：The gold and silver culm for eliminating taper and root and leaf is sent into squeezer squeezing, prepressing pressure
16MPa squeezes time 6min, temperature room temperature.
(2) dedusting section is screened：The gold and silver blade of 6 months will be air-dried and be sent into oscillatory type roll-type deduster, carry out heavy and light
Matter and the separation of qualified tablet.Tablet is air-dried in oscillatory type roll-type deduster residence time 40min.
(3) pre-preg section：Tablet after screening dedusting is sent into boiling vessel and carries out pre-preg processing.Tablet is in impregnation stage
Residence time 120min, 20 DEG C of temperature, relative to over dry material quality, sodium hydroxide concentration 1%, liquor ratio 1：6.
(4) alkaline cooking：After pre-preg, add in alkaline matter and carry out alkaline cooking, relative to over dry material quality, alkali
Alkaline matter dosage 20% in method boiling, time 80min, 170 DEG C of temperature, 1 ﹕ 8 of liquor ratio, sulphidity 10%；
(5) washing concentrating：Slurry after alkaline cooking is dense in the washing of spraying pot pulp thickening, screening and washing thickener
Contracting, the mass concentration of slurry is 12% after concentration；
(6) thermokalite is modified：Tower top pressure 0.17MPa, 110 DEG C, time 80min of temperature, relative to over dry material quality, hydrogen-oxygen
Change sodium dosage 2%, sodium dithionite dosage 0.1%.
(7) it washs：By the modified slurry of thermokalite through vacuum pulp washing machine washing concentrating, generated scrub raffinate excludes,
The mass concentration of slurry is 8% after concentration.
(8) it is beaten：Slurry after concentration is beaten.The present invention use in or high consistency beating.To true qualities gold and silver straw pulp
Beating time 70min, beating degree is 40 ° of SR after the completion of mashing.
(9) it manufactures paper with pulp：Slurry after mashing is manufactured paper with pulp, obtains the water suction lining paper of true qualities.Fungicide is added in mud pit
And wet strength agent, relative to oven dry stock quality, fungicide alkyl imidazoline quaternary ammonium salt dosage 0.5%, wet strength agent polyamide polyamine-table
Epichlorohydrin resin dosage 2.5%.Dispersant is added in head box, relative to oven dry stock quality, dispersant polyethylene glycol oxide dosage
2.5%.
The physical performance index of obtained true qualities water suction lining paper is：Longitudinal tensile index 13Nm/g, lateral anti-tensile refer to
4Nm/g, longitudinal wet tensile index 3Nm/g are counted, laterally wet tensile index 1Nm/g, longitudinal water imbibition (finished layer) 18mm/
100s, lateral water imbibition (finished layer) 62mm/100s, quantitative 10g/m2, whiteness 47%ISO, pentosan 7.1%, ash content
1.1%, bulk 6.2cm3/ g, pliability (finished layer is average in length and breadth) 236mN.
Slurry result after 1 to 3 gained alkaline cooking of the embodiment of the present invention and 1 to 3 acquired results of comparative example are done as follows
Comparative test, be shown in Table 1.
Slurry result is compared with 1 to 3 acquired results of comparative example after 1 embodiment of table, 1 to 3 gained alkaline cooking
Screened yield is noted for the acceptable material after screening dedusting, alkali solubility S10 includes hemicellulose and degradation
Short chain cellulose, S18 are mainly known as the typical hemicellulose of gamma cellulose.
It is learnt by table 1, during soda pulping process, when cancellation prepressing section or cancels pre-preg section or prepressing and preimpregnation
Stain is cancelled and (corresponds to comparative example 1, comparative example 2, comparative example 3 respectively), and slurry is more thick and stiff after obtained alkaline cooking, and boiling is equal
Even property declines, and shows the slurry Kappa number of comparative example 1, comparative example 2 and comparative example 3 and thick slag rate ratio embodiment 1, embodiment 2
And embodiment 3 is higher；And slurry purity reduces, and tiny component increases, and viscosity declines, and shows comparative example 1, comparative example 2
And the slurry pentosan of comparative example 3, alkali solubility S10, S18 and ash rate embodiment 1, embodiment 2 and embodiment 3 are higher.
Analyzing reason is：The gold and silver culm of taper and root and leaf is eliminated after squeezer mechanical presses, gold and silver can be made careless
Stalk is crushed, is flattened into gold and silver grass slag (i.e. gold and silver blade), is uniformly impregnated with conducive to follow-up liquid, cooking homogeneities is improved, from source
Mitigate raw material on head since epidermal structure is closer, lead to be impregnated with uniformity, quality instability of difficult boiling not easy to control etc. and ask
Topic；Prepressing can also make spinule hard at gold and silver culm section portion and section portion be driven plain, be crushed, then pass through subsequent screening dedusting
Processing removes end, section, marrow and the surface impurity of conquassation, effectively overcomes from source more containing non-cellulosic impurity in gold and silver grass
Itself weakness, achieve the purpose that purify paper pulp.Tablet after squeezing is handled again through alkaline pre-preg liquid, it is therefore an objective to：Pass through alkali
Property pre-preg liquid remove tablet in alkali-soluble inorganic matter and organic species substance, destroy tablet exocuticle fatty wax,
Increase gap on cell wall, become soft, the diffusion dissolution for follow-up steaming stage medicinal liquid osmosis and reaction product establishes logical
Road, while the contact area of gold and silver grass fiber and lye is increased, conducive to delignification is increased, thick slag rate is reduced, in addition, alkali
Property pre-preg liquid can neutralize some acidic-groups inside tablet, be conducive to mitigate the fluctuation of active alkali effect in the boiling stage, carry
High slurry uniformity, it is ensured that the stability of pulp quality.
Biocidal property is tested：
1st, test object：True qualities gold and silver grass fiber water suction lining paper prepared by embodiment 1-3；
2nd, test index：Escherichia coli, staphylococcus aureus and Candida albicans；
3rd, experimental method：With reference to GB/T 20944.3-2008；
4th, experimental result：It is shown in Table 2.
2 embodiment 1-3 of table prepares true qualities gold and silver grass fiber water suction lining paper biocidal property test result
Note S. aureus L-forms refer to staphylococcus aureus, bacterium (or mould) concentration of Wo standards blank sample " 0 " time of contact
CFU/mL；Bacterium (or mould) concentration C FU/mL after Wt standards blank sample oscillation 18h；Qt antibiotic fabrics sample vibrates 18h
Bacterium (or mould) concentration C FU/mL afterwards.
It is learnt by upper table, true qualities gold and silver grass fiber of the invention absorbs water lining paper to Escherichia coli, staphylococcus aureus
Bacteriostasis rate is up to more than 99%, to the bacteriostasis rate of Candida albicans up to more than 98%, therefore the true qualities water suction lining paper of the present invention
Very strong bacteriostasis antibiosis is respectively provided with to Escherichia coli, staphylococcus aureus and Candida albicans.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (10)
1. a kind of preparation method of true qualities gold and silver grass fiber water suction lining paper, which is characterized in that include the following steps：
(1) prepressing：The gold and silver culm for eliminating taper and root and leaf is sent into squeezer to squeeze, prepressing pressure 8-20MPa,
Squeeze time 2-10min, temperature room temperature；
(2) dedusting section is screened：By step (1), treated is sent into oscillatory type roll-type deduster after tablet air-dries and is dusted place
Reason；
(3) pre-preg section：The tablet of step (2) is sent into boiling vessel and carries out pre-preg processing, tablet is in the stop of impregnation stage
Between 10-120min, 20-95 DEG C of temperature, relative to over dry material quality, sodium hydroxide concentration 1-10%, liquor ratio 1：2-6；
(4) alkaline cooking：After pre-preg, add in alkaline matter and carry out alkaline cooking, relative to over dry material quality, alkaline process
Alkaline matter dosage 8-20% in boiling, time 80-200min, 130-170 DEG C of temperature, liquor ratio 1 ﹕ 4-8, sulphidity 10-
18%；
(5) washing concentrating：By the slurry that step (4) obtains in spraying pot pulp thickening, screening and washing thickener washing concentrating,
The mass concentration of slurry is 10-16% after concentration；
(6) thermokalite is modified：The slurry that step (5) obtains first is added in into reducing agent, and be preheated to 60-70 in steam mixer
DEG C, stock pump standpipe is entered after preheating, then sodium hydroxide solution is added in high shear medium-consistency pulp mixer, and it is logical be steam heated to needed for
100-120 DEG C of temperature, into bleaching tower carry out thermokalite modification, tower top pressure 0.1-0.2MPa, time 20-100min, relative to
Over dry material quality, sodium hydroxide concentration 2-8%；
(7) it washs：By the slurry obtained by step (6) through vacuum pulp washing machine washing concentrating, generated scrub raffinate excludes, concentration
The mass concentration of slurry is 8-16% afterwards；
(8) it is beaten：Slurry of the step (7) after concentrated is beaten, beating time 70-100min, is beaten after the completion of mashing
It spends for 35-45 ° of SR；
(9) it manufactures paper with pulp：Slurry after step (8) is beaten is manufactured paper with pulp, and obtains the water suction lining paper of true qualities.
2. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 1, which is characterized in that the step
(2) apoplexy siccative piece is 10-40min in the oscillatory type roll-type deduster residence time；The time that tablet air-dries is 2-12 months.
3. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 1, which is characterized in that the step
(4) alkaline matter described in is sodium hydroxide and vulcanized sodium.
4. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 1, which is characterized in that the step
(6) reducing agent described in is sodium borohydride, sodium dithionite or sodium sulfite；Relative to over dry material quality, reducing agent is used
Measure 0.1-3.0%.
5. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 1, which is characterized in that the step
(8) mashing is medium consistency refining or high consistency beating in；The medium consistency refining refers to beating consistency 10-20%, and the high consistency beating, which refers to, to be beaten
Starch a concentration of more than 20%.
6. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 1, which is characterized in that the step
(9) mud pit is additionally included in and adds in fungicide and wet strength agent, relative to oven dry stock quality, fungicide dosage 0.1-0.5% is wet
Strong agent dosage 0.05-2.5%；Fungicide and the mode of wet strength agent addition are respectively：1000 times of dilution agent will be sterilized, passes through calibration
Screw metering pump be continuously added to system；Wet strength agent clear water is diluted 10 times, is continuously added to by the screw metering pump of calibration
System.
7. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 6, which is characterized in that the fungicide
For alkyl imidazoline quaternary ammonium salt.
8. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 6, which is characterized in that the wet strength agent
For polyamide polyamine-epichlorohydrin resins (PAE).
9. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 1, which is characterized in that be additionally included in stream
Dispersant is added in slurry case, the dispersant feed postition is：It will disperse 1000 times of dilution agent, and pass through the screw metering pump of calibration
System is continuously added to, relative to oven dry stock quality, dispersant dosage 0.05-2.5%.
10. the preparation method of true qualities gold and silver grass fiber water suction lining paper according to claim 9, which is characterized in that the dispersion
Agent is fatty alcohol polyoxyethylene ether methyl-monosilane, potassium pyrophosphate, sodium sulfate of polyethenoxy ether of fatty alcohol or polyethylene glycol oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711334906.7A CN108149500B (en) | 2017-12-14 | 2017-12-14 | The preparation method of true qualities gold and silver grass fiber water suction lining paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711334906.7A CN108149500B (en) | 2017-12-14 | 2017-12-14 | The preparation method of true qualities gold and silver grass fiber water suction lining paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108149500A true CN108149500A (en) | 2018-06-12 |
| CN108149500B CN108149500B (en) | 2019-05-28 |
Family
ID=62466111
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711334906.7A Active CN108149500B (en) | 2017-12-14 | 2017-12-14 | The preparation method of true qualities gold and silver grass fiber water suction lining paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108149500B (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1782221A (en) * | 2004-11-30 | 2006-06-07 | 王洪宾 | Pulping paper-making method using hybrid chinese pennisetum as raw material |
| CN1827915A (en) * | 2005-03-02 | 2006-09-06 | 王洪宾 | Hybrid penisetum NaOH-AQ method for pulp making, bleaching and paper forming |
| JP2009120988A (en) * | 2007-11-14 | 2009-06-04 | Moruza Kk | Patterned paper and method for producing patterned paper |
| CN102400404A (en) * | 2011-12-09 | 2012-04-04 | 昆明理工大学 | Straw cutting-free method for preparing straw pulp by spherical digester alkali digestion |
| CN103194923A (en) * | 2013-04-25 | 2013-07-10 | 昆明理工大学 | Preparation method of cutting-free rice and wheat straws by alkaline cooking through vertical digester |
| CN103866647A (en) * | 2014-03-27 | 2014-06-18 | 潍坊恒联美林生活用纸有限公司 | Color water-absorbing interleaving paper production process |
| CN106835793A (en) * | 2017-03-22 | 2017-06-13 | 四川理工学院 | A kind of preparation method of the true qualities bamboo fibre high water absorption lining paper for amenities production |
| CN107313299A (en) * | 2016-04-27 | 2017-11-03 | 上海东冠纸业有限公司 | A kind of preparation method of amenities high-air-permeability water suction lining paper |
-
2017
- 2017-12-14 CN CN201711334906.7A patent/CN108149500B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1782221A (en) * | 2004-11-30 | 2006-06-07 | 王洪宾 | Pulping paper-making method using hybrid chinese pennisetum as raw material |
| CN1827915A (en) * | 2005-03-02 | 2006-09-06 | 王洪宾 | Hybrid penisetum NaOH-AQ method for pulp making, bleaching and paper forming |
| JP2009120988A (en) * | 2007-11-14 | 2009-06-04 | Moruza Kk | Patterned paper and method for producing patterned paper |
| CN102400404A (en) * | 2011-12-09 | 2012-04-04 | 昆明理工大学 | Straw cutting-free method for preparing straw pulp by spherical digester alkali digestion |
| CN103194923A (en) * | 2013-04-25 | 2013-07-10 | 昆明理工大学 | Preparation method of cutting-free rice and wheat straws by alkaline cooking through vertical digester |
| CN103866647A (en) * | 2014-03-27 | 2014-06-18 | 潍坊恒联美林生活用纸有限公司 | Color water-absorbing interleaving paper production process |
| CN107313299A (en) * | 2016-04-27 | 2017-11-03 | 上海东冠纸业有限公司 | A kind of preparation method of amenities high-air-permeability water suction lining paper |
| CN106835793A (en) * | 2017-03-22 | 2017-06-13 | 四川理工学院 | A kind of preparation method of the true qualities bamboo fibre high water absorption lining paper for amenities production |
Non-Patent Citations (1)
| Title |
|---|
| 关克忠等: "贵州省贫困山区农民种植金银草脱贫的探索与实践", 《第十一届（2014）中国羊业发展大会论文集》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108149500B (en) | 2019-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106835793B (en) | A kind of preparation method of true qualities bamboo fibre high water absorption lining paper for amenities production | |
| CN102162150B (en) | Towel gourd viscose fiber and preparation method thereof | |
| CN105011391B (en) | A kind of natural antibacterial bamboo fiber socks | |
| CN104141256B (en) | Uncolored bamboo fiber with high antibacterial activity and processing method thereof | |
| CN107268096A (en) | A kind of preparation method of wormwood antibacterial viscose fiber | |
| CN101171389A (en) | Ligno cellulosic materials and the products made therefrom | |
| CN103498338A (en) | Antimicrobial bamboo and cotton blended fabric | |
| CN102191579B (en) | Coffee viscose fiber and preparation method thereof | |
| CN101532195A (en) | Multifunctional blended spun rayon with polycomponent of fruit rind and precious stone and health products thereof | |
| KR20090091082A (en) | High whiteness chemical pulp using corntalk and method for manufacturing paper product therefrom | |
| CN109853297A (en) | Medical dialysis body paper and its production method | |
| CN104195868B (en) | Natural-color fuzzy bamboo pulp with high bacteriostatic activity and preparation method thereof | |
| CN101440535A (en) | Method for preparing chitosan-silver ion anti-bacterial viscose fiber from corps straw | |
| CN110965149A (en) | Water lily protein fiber and preparation process thereof | |
| CN107653752A (en) | A kind of Degradable environment protection antibacterial tableware and preparation method thereof | |
| CN106192542B (en) | A kind of clean method for preparing of the true qualities bamboo Time of Fluff Slurry of high-quality high-purity | |
| CN108103847A (en) | A kind of medical tissue of disinfection | |
| CN101564203A (en) | Method for manufacturing pineapple leaf fiber antibiosis health-protection socks | |
| CN104292868A (en) | X-ray radiation resistant wood fiber and preparation method thereof | |
| CN106012630B (en) | A kind of pulp making process using walnut shell as raw material | |
| CN107227646A (en) | The preparation method and paper for daily use of paper for daily use | |
| CN107858863A (en) | A kind of preparation method of unbleached paper | |
| CN104451928A (en) | Taxus chinensis viscose and fabric prepared from same | |
| Wille et al. | Cellulose pulp produced from bulrush fiber | |
| CN108755241A (en) | A method of improving bamboo pulp paper for daily use body paper water imbibition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |