CN108149358A - The Preparation method and use of graphene-superhigh molecular weight polyethylene fibers coating cotton thread - Google Patents
The Preparation method and use of graphene-superhigh molecular weight polyethylene fibers coating cotton thread Download PDFInfo
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- CN108149358A CN108149358A CN201810037243.0A CN201810037243A CN108149358A CN 108149358 A CN108149358 A CN 108149358A CN 201810037243 A CN201810037243 A CN 201810037243A CN 108149358 A CN108149358 A CN 108149358A
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- graphene
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01529—Protective gloves with thermal or fire protection
- A41D19/01535—Heated gloves
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/32—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
- D02G3/328—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic containing elastane
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/442—Cut or abrasion resistant yarns or threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
- D04B1/28—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel gloves
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
- D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Gloves (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
The present invention provides a kind of preparation methods of graphene superhigh molecular weight polyethylene fibers coating cotton thread, include the following steps：Using spandex thread as core wire, with inorganic coating yarn and graphene superhigh molecular weight polyethylene fibers the core wire is coated to get.Compared with prior art, the present invention has following advantageous effect：The dipped gloves prepared using the anti-cutting coating cotton thread obtained by the present invention, meeting 4 grades of European Union EN388 standards wear-resisting property, 5 grades of anti-cutting performance, 4 grades of tear resistance, penetration-resistant can be 4 grade, meet 2 grades of European Union EN407 standard heat exposures performance simultaneously, meet 6 grades of ANSI anti-cuttings performance；Oversleeve meets 9 grades of ANSI anti-cuttings performance.
Description
Technical field
The present invention relates to a kind of Preparation method and uses of graphene-superhigh molecular weight polyethylene fibers coating cotton thread, belong to
In fibrous material technical field.
Background technology
Safety protection glove is frequently used in complicated work situation or in dangerous sports, can
Play the role of protecting labourer or sportsman's hand.Therefore, safety protection glove has been requested to preferable resistance to when in use
Grind performance and anti-cutting performance, but in the prior art, influenced by thread material and weaving method, safety protection glove it is wear-resisting
Property, anti-cutting, tear resistance and penetration-resistant are insufficient.
Invention content
For the defects in the prior art, it is fine the object of the present invention is to provide a kind of graphene-ultra-high molecular weight polyethylene
Tie up the Preparation method and use of coating cotton thread.
The present invention is achieved by the following technical solutions：
The present invention provides a kind of preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread, including such as
Lower step：
Using spandex thread as core wire, with inorganic coating yarn and graphene superhigh molecular weight polyethylene fibers to the core wire into
Row cladding to get.
Preferably, the weight of the spandex thread, inorganic coating yarn and graphene-superhigh molecular weight polyethylene fibers
Measuring percentage is respectively：5~15%, 30~40%, 50~60%.
Preferably, the graphene-superhigh molecular weight polyethylene fibers, spandex thread line density be respectively 380
~420D, 130~150D.
Preferably, the twist of the graphene-superhigh molecular weight polyethylene fibers is twisted with the fingers for 170~190, twist direction
It is twisted with the fingers for S, the twist of inorganic coating yarn is 470~530 sth. made by twisting, and twist direction is twisted with the fingers for Z.
Preferably, in the graphene-superhigh molecular weight polyethylene fibers content of graphene for 0.5~
10wt%.
Preferably, also contain filler in the graphene-superhigh molecular weight polyethylene fibers, the filler contains
It measures as 5~20wt%, the filler includes silicon carbide, diamond, ceramic fibre, glass fibre, basalt fibre, metallic fiber
At least one of.
Preferably, the Lapie of the spandex thread is 1.6~2, include in the spandex thread content for 0.1~
The graphene of 5wt%.
Preferably, the preparation method of the inorganic coating yarn is：
Using inorfil as core wire, the core wire is coated with two nylon yarns to get.
Preferably, the twist of a nylon yarn is 640~720 sth. made by twisting, and twist direction is twisted with the fingers for Z, described in another
The twist of nylon yarn is 660~740 sth. made by twisting, and twist direction is twisted with the fingers for S.
Preferably, the weight percent of the inorfil is 30~40%, the weight percent of two nylon yarns
Number is 30~40%.
Preferably, the line density of the inorfil is 65~75D, the line densities of two nylon yarns is 65~
75D。
Preferably, the graphene that content is 0.1~5wt%, the inorfil are included in the nylon yarn
For one or more of ceramic fibre, glass fibre, basalt fibre or metallic fiber.
A kind of graphene superhigh molecular weight polyethylene fibers coating cotton thread prepared by preparation method as the aforementioned gloves,
Purposes in oversleeve, clothes.
A kind of preparation method of gloves as the aforementioned, includes the following steps：
Gloves base is made using graphene superhigh molecular weight polyethylene fibers coating cotton thread, the gloves base is impregnated in slurry
After in material, carry out being solidified into coating, obtain gloves；
Wherein, the slurry includes at least one of PU, butyronitrile, natural emulsion, PVC or neoprene；
The preparation method of the gloves base is：The Anti-cutting covered yarn line is inputted to the braider of 7 needles, 10 needles or 13 needles
In, braided parameter is set, is woven；
The braided parameter is specially：It is with technical parameter of the braider of 13 needle when weaving 10 yards of gloves：
Grammes per square metre is determined as 570~630g, lower captain's degree is 24~26cm；
The convolution number for controlling little finger of toe is 62, and nameless convolution number is 82, and the convolution number of middle finger is 90, the convolution number of forefinger
It is 80, the convolution number of thumb is 42, and the convolution number of four fingers and palms is 68, and the convolution number of five fingers and palms is 50, the convolution number in rib-loop portion
It is 76.
Preferably, the oversleeve is the small tubular knitting of 260~320 needles, and when knitting is surpassed using 6 graphenes
High molecular weight polyethylene fiber coating cotton thread manufactures.
Compared with prior art, the present invention has following advantageous effect：
1st, the dipped gloves prepared using the anti-cutting coating cotton thread obtained by the present invention, it is wear-resisting to meet European Union's EN388 standards
4 grades of performance, 5 grades of anti-cutting performance, 4 grades of tear resistance, penetration-resistant can be 4 grades, while meet European Union EN407 standard heat exposures
2 grades of performance meets 6 grades of ANSI anti-cuttings performance；Oversleeve meets 9 grades of ANSI anti-cuttings performance.
2nd, the Comprehensive Characteristics and performance that the anti-cutting of high-performance and heat resistanceheat resistant gloves are made in the application have been more than that other are main in the world
Gloves brand；Gloves or oversleeve as made of Du Pont's Kevlar yarns, heat resistance is remarkable, but anti-cutting is insufficient；Royal DSM
Gloves made of Dyneema yarns, anti-cutting can reach 5 grades of standards of Europe superscript, but American Standard cutting can only up to 3 grades, heat resistanceheat resistant also compared with
It is bad；Yarn of the present invention and manufactured dipped gloves, not only solar heat protection contact performance also reached close to Kevlar yarn gloves, anti-cutting
5 grades of standards of Europe superscript, 6 grades of American Standard have been arrived, has been the advantages of combining above-mentioned two famous brand；
3rd, meet particular market demand, it is suitable for large-scale promotion.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill to this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
In the present invention：" twist " refers to possessed number of twists in every meter of long filament.
" braiders of 10 needles ", practical is circular knitting machine, and glove knitting machine is also one kind of circular knitting machine.
" convolution number ", refers in knitted glove base, the a-circle-by-a-circle quantity of braider.
Embodiment 1
A kind of preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread is present embodiments provided, including
Following steps：
Using spandex thread as core wire, with inorganic coating yarn and graphene superhigh molecular weight polyethylene fibers to the core wire into
Row cladding to get.
Preferably, the weight of the spandex thread, inorganic coating yarn and graphene-superhigh molecular weight polyethylene fibers
Measuring percentage is respectively：5~15%, 30~40%, 50~60%.
Preferably, the graphene-superhigh molecular weight polyethylene fibers, spandex thread line density be respectively 380
~420D, 130~150D.
Preferably, the twist of the graphene-superhigh molecular weight polyethylene fibers is twisted with the fingers for 170~190, twist direction
It is twisted with the fingers for S, the twist of inorganic coating yarn is 470~530 sth. made by twisting, and twist direction is twisted with the fingers for Z.
Preferably, in the graphene-superhigh molecular weight polyethylene fibers content of graphene for 0.5~
10wt%.
Preferably, also contain filler in the graphene-superhigh molecular weight polyethylene fibers, the filler contains
It measures as 5~20wt%, the filler includes silicon carbide, diamond, ceramic fibre, glass fibre, basalt fibre, metallic fiber
At least one of.
Preferably, the Lapie of the spandex thread is 1.6~2, include in the spandex thread content for 0.1~
The graphene of 5wt%.
Preferably, the preparation method of the inorganic coating yarn is：
Using inorfil as core wire, the core wire is coated with two nylon yarns to get.
Preferably, the twist of a nylon yarn is 640~720 sth. made by twisting, and twist direction is twisted with the fingers for Z, described in another
The twist of nylon yarn is 660~740 sth. made by twisting, and twist direction is twisted with the fingers for S.
Preferably, the weight percent of the inorfil is 30~40%, the weight percent of two nylon yarns
Number is 30~40%.
Preferably, the line density of the inorfil is 65~75D, the line densities of two nylon yarns is 65~
75D。
Preferably, the graphene that content is 0.1~5wt%, the inorfil are included in the nylon yarn
For ceramic fibre, glass fibre, basalt fibre or metallic fiber.
The curling coefficient of cutting-resisting yarn manufactured in the present embodiment is 96~99.
Embodiment 2
Present embodiments provide a kind of graphene superhigh molecular weight polyethylene fibers wrap yarn prepared by 1 method of embodiment
The method that line prepares gloves, specifically comprises the following steps：
Gloves base is made using graphene superhigh molecular weight polyethylene fibers coating cotton thread, the gloves base is impregnated in slurry
After in material, carry out being solidified into coating, obtain gloves；
Wherein, the slurry includes at least one of PU, butyronitrile, natural emulsion, PVC or neoprene；
The preparation method of the gloves base is：The Anti-cutting covered yarn line is inputted to the braider of 7 needles, 10 needles or 13 needles
In, braided parameter is set, is woven；
The braided parameter is specially：It is with technical parameter of the braider of 13 needle when weaving 10 yards of gloves：
Grammes per square metre is determined as 570~630g, lower captain's degree is 24~26cm；
The convolution number for controlling little finger of toe is 62, and nameless convolution number is 82, and the convolution number of middle finger is 90, the convolution number of forefinger
It is 80, the convolution number of thumb is 42, and the convolution number of four fingers and palms is 68, and the convolution number of five fingers and palms is 50, the convolution number in rib-loop portion
It is 76.
Embodiment 3
Present embodiments provide a kind of graphene superhigh molecular weight polyethylene fibers wrap yarn prepared by 1 method of embodiment
The method that line prepares oversleeve, the oversleeve are the small tubular knitting of 260~320 needles, and 6 Anti-cutting covered yarn lines are used during knitting
Manufacture.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (15)
1. a kind of preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread, which is characterized in that including walking as follows
Suddenly：
Using spandex thread as core wire, the core wire is wrapped with inorganic coating yarn and graphene superhigh molecular weight polyethylene fibers
Cover to get.
2. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as described in claim 1, feature exist
In the weight percent of the spandex thread, inorganic coating yarn and graphene-superhigh molecular weight polyethylene fibers is respectively：5~
15%th, 30~40%, 50~60%.
3. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as described in claim 1, feature exist
In the line density of, graphene-superhigh molecular weight polyethylene fibers, spandex thread be respectively 380~420D, 130~150D.
4. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as described in claim 1, feature exist
In the twist of the graphene-superhigh molecular weight polyethylene fibers is 170~190 sth. made by twisting, and twist direction is twisted with the fingers for S, inorganic coating yarn
The twist for 470~530 sth. made by twisting, twist direction for Z sth. made by twisting.
5. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as described in claim 1, feature exist
In the content of graphene is 0.5~10wt% in the graphene-superhigh molecular weight polyethylene fibers.
6. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as claimed in claim 5, feature exist
In also containing filler in the graphene-superhigh molecular weight polyethylene fibers, the content of the filler is 5~20wt%, described
Filler is included in silicon carbide, diamond, glass microballoon, ceramic fibre, glass fibre, basalt fibre, metallic fiber at least
It is a kind of.
7. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as described in claim 1, feature exist
In the Lapie of the spandex thread is 1.6~2, and the graphene that content is 0.1~5wt% is included in the spandex thread.
8. the preparation of the graphene superhigh molecular weight polyethylene fibers coating cotton thread as described in any one in claim 1~7
Method, which is characterized in that the preparation method of the inorganic coating yarn is：
Using inorfil as core wire, the core wire is coated with two nylon yarns to get.
9. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as claimed in claim 8, feature exist
It is 640~720 sth. made by twisting in the twist of a, nylon yarn, twist direction is twisted with the fingers for Z, and the twist of another nylon yarn is 660~
740 sth. made by twisting, twist direction are twisted with the fingers for S.
10. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as claimed in claim 8, feature exist
In the weight percent of the inorfil is 30~40%, and the weight percent of two nylon yarns is 30~40%.
11. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as claimed in claim 8, feature exist
In the line density of the inorfil is 65~75D, and the line density of two nylon yarns is 65~75D.
12. the preparation method of graphene superhigh molecular weight polyethylene fibers coating cotton thread as claimed in claim 8, feature exist
In, include in the nylon yarn content be 0.1~5wt% graphene, the inorfil for ceramic fibre, glass fibers
One or more of dimension, basalt fibre or metallic fiber.
13. a kind of graphene superhigh molecular weight polyethylene fibers wrap yarn prepared by preparation method as described in claim 1
Purposes of the line in gloves, oversleeve, clothes.
14. a kind of preparation method of gloves as claimed in claim 13, which is characterized in that include the following steps：
Gloves base is made using graphene superhigh molecular weight polyethylene fibers coating cotton thread, the gloves base is impregnated in slurry
Afterwards, it carries out being solidified into coating, obtains gloves；
Wherein, the slurry includes at least one of PU, butyronitrile, natural emulsion, PVC or neoprene；
The preparation method of the gloves base is：The Anti-cutting covered yarn line is inputted in the braider of 7 needles, 10 needles or 13 needles, if
Determine braided parameter, woven；
The braided parameter is specially：It is with technical parameter of the braider of 13 needle when weaving 10 yards of gloves：
Grammes per square metre is determined as 570~630g, lower captain's degree is 24~26cm；
The convolution number for controlling little finger of toe is 62, and nameless convolution number is 82, and the convolution number of middle finger is 90, and the convolution number of forefinger is
80, the convolution number of thumb is 42, and the convolution number of four fingers and palms is 68, and the convolution number of five fingers and palms is 50, and the convolution number in rib-loop portion is
76。
15. a kind of preparation method of oversleeve as claimed in claim 13, which is characterized in that the oversleeve is small for 260~320 needles
Tubular knitting, using 6 graphene superhigh molecular weight polyethylene fibers coating cotton threads manufactures during knitting.
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| CN201810037243.0A CN108149358A (en) | 2018-01-15 | 2018-01-15 | The Preparation method and use of graphene-superhigh molecular weight polyethylene fibers coating cotton thread |
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| CN201810037243.0A CN108149358A (en) | 2018-01-15 | 2018-01-15 | The Preparation method and use of graphene-superhigh molecular weight polyethylene fibers coating cotton thread |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108783680A (en) * | 2018-07-04 | 2018-11-13 | 恒劢安全防护用品（南通）有限公司 | The production method of high-performance anti-cutting gloves core |
| CN108823718A (en) * | 2018-08-06 | 2018-11-16 | 魏桥纺织股份有限公司 | A kind of production method of graphene modified fibre core-spun elastic yarn line and elastic fabric |
| CN109629028A (en) * | 2018-11-15 | 2019-04-16 | 南通强生安全防护科技股份有限公司 | A kind of graphene ultra-high molecular weight polyethylene composite fibre and preparation method thereof |
| CN110236687A (en) * | 2019-06-13 | 2019-09-17 | 南通强生安全防护科技股份有限公司 | A kind of operation anti-cutting gloves and preparation method thereof |
| CN112708979A (en) * | 2020-12-21 | 2021-04-27 | 杭州奥华纺织有限公司 | Electromagnetic shielding core-spun yarn and preparation process thereof |
| WO2023173800A1 (en) * | 2022-03-17 | 2023-09-21 | 南通强生新材料科技股份有限公司 | Cutting-resistant protective gloves and preparation method therefor |
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