CN108374217A - The Preparation method and use of graphene-superhigh molecular weight polyethylene fibers coating cotton thread - Google Patents
The Preparation method and use of graphene-superhigh molecular weight polyethylene fibers coating cotton thread Download PDFInfo
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- CN108374217A CN108374217A CN201810037240.7A CN201810037240A CN108374217A CN 108374217 A CN108374217 A CN 108374217A CN 201810037240 A CN201810037240 A CN 201810037240A CN 108374217 A CN108374217 A CN 108374217A
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- graphene
- molecular weight
- weight polyethylene
- polyethylene fibers
- superhigh molecular
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/08—Arm or hand
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/32—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
- D02G3/328—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic containing elastane
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/442—Cut or abrasion resistant yarns or threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
- D04B1/28—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel gloves
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0025—Rubber threads; Elastomeric fibres; Stretchable, bulked or crimped fibres; Retractable, crimpable fibres; Shrinking or stretching of fibres during manufacture; Obliquely threaded fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0038—Polyolefin fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
- D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
Abstract
The present invention provides a kind of preparation methods of graphene superhigh molecular weight polyethylene fibers coating cotton thread comprising following steps:Using spandex thread as core wire, with a graphene superhigh molecular weight polyethylene fibers and a nylon yarn or dacron thread to the core wire coated to get.Compared with prior art, the present invention has following advantageous effect:1, the dipped gloves prepared using the anti-cutting coating cotton thread obtained by the present invention, meeting 4 grades of European Union EN388 standards wear-resisting property, 5 grades of anti-cutting performance, 4 grades of tear resistance, penetration-resistant can be 4 grade, meet 2 grades of European Union EN407 standard heat exposures performance simultaneously, meets 4 grades of ANSI anti-cuttings performance;Oversleeve meets 6 grades of ANSI anti-cuttings performance.
Description
Technical field
The present invention relates to a kind of Preparation method and uses of graphene-superhigh molecular weight polyethylene fibers coating cotton thread, belong to
In fibrous material technical field.
Background technology
Safety protection glove is frequently used in complicated work situation or in dangerous sports, can
Play the role of protecting labourer or sportsman's hand.Therefore, safety protection glove has been requested to preferable resistance to when in use
Grind performance and anti-cutting performance, but in the prior art, influenced by thread material and weaving method, safety protection glove it is wear-resisting
Property, anti-cutting, tear resistance and penetration-resistant are insufficient.
Invention content
For the defects in the prior art, it is fine that the object of the present invention is to provide a kind of graphene-ultra-high molecular weight polyethylenes
Tie up the Preparation method and use of coating cotton thread.
The present invention is achieved by the following technical solutions:
The present invention provides a kind of preparation method of graphene-superhigh molecular weight polyethylene fibers coating cotton thread comprising such as
Lower step:
Using spandex thread as core wire, with a graphene-superhigh molecular weight polyethylene fibers and a nylon yarn or dacron thread
To the core wire coated to get.
Preferably, the spandex thread, graphene-superhigh molecular weight polyethylene fibers and nylon yarn or dacron thread
Weight percent is respectively:5~15%, 55~70%, 15~30%.
Preferably, the graphene-superhigh molecular weight polyethylene fibers, nylon yarn or dacron thread, spandex thread
Line density is respectively 380~420D, 130~160D, 130~150D.
Preferably, the twist of the graphene-superhigh molecular weight polyethylene fibers is 180~220 twirls, twist direction
It is twisted for Z, the twist of nylon yarn or dacron thread is 360~540 twirls, and twist direction is twisted for S.
Preferably, in the graphene-superhigh molecular weight polyethylene fibers graphene content be 0.5~
10wt%.
Preferably, also contain filler in the graphene-superhigh molecular weight polyethylene fibers, the filler contains
Amount is 5~20wt%, and the filler includes silicon carbide, diamond, glass microballoon, ceramic fibre, glass fibre, basalt fibre
At least one of dimension, metallic fiber.
Preferably, include graphene that content is 0.1~5wt% in the nylon yarn or dacron thread, it is described
The Lapie of spandex thread is 1.6~2, includes the graphene that content is 0.1~5wt% in the spandex thread.
A kind of Anti-cutting covered yarn line prepared by aforementioned preparation process.
Preferably, the curling coefficient of the Anti-cutting covered yarn line is 96~99.
A kind of purposes of Anti-cutting covered yarn line as the aforementioned in gloves or oversleeve.
A kind of preparation method of gloves as the aforementioned comprising following steps:
Gloves base is made using Anti-cutting covered yarn line, after the gloves base is impregnated in slurry, carries out being solidified into coating,
Obtain gloves;
Wherein, the slurry includes at least one of PU, butyronitrile, natural emulsion, PVC or neoprene;
The preparation method of the gloves base is:The Anti-cutting covered yarn line is inputted to the braider of 7 needles, 10 needles or 13 needles
In, braided parameter is set, is woven;
The braided parameter is specially:It is with technical parameter of the braider of 13 needle when weaving 9 yards of gloves:
Determine that grammes per square metre is 710~730g, lower captain's degree is 24~25cm;
The convolution number for controlling little finger of toe is 56, and nameless convolution number is 76, and the convolution number of middle finger is 82, the convolution number of index finger
It is 72, the convolution number of thumb is 56, and the convolution number of four fingers and palms is 32, and the convolution number of five fingers and palms is 44, the convolution number of threaded portion
It is 66.
Preferably, the oversleeve is the small tubular knitting of 260~320 needles, using 6 anti-cuttings claddings when knitting
Yarn manufactures.
Compared with prior art, the present invention has following advantageous effect:
1, the dipped gloves prepared using the anti-cutting coating cotton thread obtained by the present invention, it is wear-resisting to meet European Union's EN388 standards
4 grades of performance, 5 grades of anti-cutting performance, 4 grades of tear resistance, penetration-resistant can be 4 grades, while meeting European Union EN407 standard heat exposures
2 grades of performance meets 4 grades of ANSI anti-cuttings performance;Oversleeve meets 6 grades of ANSI anti-cuttings performance;
2, the Comprehensive Characteristics and performance that the anti-cutting of high-performance and heat resistanceheat resistant gloves are made in the application have been more than that other are main in the world
Gloves brand;Gloves or oversleeve as made of Du Pont's Kevlar yarns, heat resistance is remarkable, but anti-cutting is insufficient;Royal DSM
Gloves made of Dyneema yarns, anti-cutting can reach 5 grades of standards of Europe superscript, but only 3 grades of American Standard cutting, heat resistanceheat resistant are also less
It is good;Yarn of the present invention and manufactured dipped gloves or oversleeve, not only solar heat protection contact performance is close to Kevlar yarn gloves, anti-cutting
Also it is combine above-mentioned two famous brand excellent to have reached 5 grades of Europe superscript, 6 grades of standards of American Standard or even oversleeve and reached 9 grades of American Standard
Point;
3, meet particular market demand, it is suitable for large-scale promotion.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
In the present invention:" twist " refers to possessed number of twists in every meter of long filament.
" braiders of 10 needles ", practical is circular knitting machine, and glove knitting machine is also one kind of circular knitting machine.
" convolution number ", refers to the a-circle-by-a-circle quantity of braider in knitted glove base.
Embodiment 1
A kind of preparation method of graphene-superhigh molecular weight polyethylene fibers coating cotton thread is present embodiments provided, is wrapped
Include following steps:
Using spandex thread as core wire, with a graphene-superhigh molecular weight polyethylene fibers and a nylon yarn or dacron thread
To the core wire coated to get.
Preferably, the spandex thread, graphene-superhigh molecular weight polyethylene fibers and nylon yarn or dacron thread
Weight percent is respectively:5~15%, 55~70%, 15~30%.
Preferably, the graphene-superhigh molecular weight polyethylene fibers, nylon yarn or dacron thread, spandex thread
Line density is respectively 380~420D, 130~160D, 130~150D.
Preferably, the twist of the graphene-superhigh molecular weight polyethylene fibers is 180~220 twirls, twist direction
It is twisted for Z, the twist of nylon yarn or dacron thread is 360~540 twirls, and twist direction is twisted for S.
Preferably, in the graphene-superhigh molecular weight polyethylene fibers graphene content be 0.5~
10wt%.
Preferably, also contain filler in the graphene-superhigh molecular weight polyethylene fibers, the filler contains
Amount is 5~18wt%, and the filler includes silicon carbide, diamond, ceramic fibre, glass fibre, basalt fibre, metallic fiber
At least one of.
Preferably, include graphene that content is 0.1~5wt% in the nylon yarn or dacron thread, it is described
The Lapie of spandex thread is 1.6~2, includes the graphene that content is 0.1~5wt% in the spandex thread.
The curling coefficient of cutting-resisting yarn manufactured in the present embodiment is 96~99.
Embodiment 2
A kind of method that the Anti-cutting covered yarn line prepared by 1 method of embodiment prepares gloves is present embodiments provided, specifically
Include the following steps:
Gloves base is made using Anti-cutting covered yarn line, after the gloves base is impregnated in slurry, carries out being solidified into coating,
Obtain gloves;
Wherein, the slurry includes at least one of PU, butyronitrile, natural emulsion, PVC or neoprene;
The preparation method of the gloves base is:The Anti-cutting covered yarn line is inputted to the braider of 7 needles, 10 needles or 13 needles
In, braided parameter is set, is woven;
The braided parameter is specially:It is with technical parameter of the braider of 13 needle when weaving 9 yards of gloves:
Determine that grammes per square metre is 710~730g, lower captain's degree is 24~25cm;
The convolution number for controlling little finger of toe is 56, and nameless convolution number is 76, and the convolution number of middle finger is 82, the convolution number of index finger
It is 72, the convolution number of thumb is 56, and the convolution number of four fingers and palms is 32, and the convolution number of five fingers and palms is 44, the convolution number of threaded portion
It is 66.
Embodiment 3
A kind of method that the Anti-cutting covered yarn line prepared by 1 method of embodiment prepares oversleeve is present embodiments provided, it is described
Oversleeve is the small tubular knitting of 260~320 needles, using 6 Anti-cutting covered yarn lines manufactures when knitting.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (12)
1. a kind of preparation method of graphene-superhigh molecular weight polyethylene fibers coating cotton thread, which is characterized in that including walking as follows
Suddenly:
Using spandex thread as core wire, with a graphene-superhigh molecular weight polyethylene fibers and a nylon yarn or dacron thread to institute
State core wire coated to get.
2. the preparation method of graphene as described in claim 1-superhigh molecular weight polyethylene fibers coating cotton thread, feature exist
In the spandex thread, graphene-superhigh molecular weight polyethylene fibers and the weight percent of nylon yarn or dacron thread are respectively:5
~15%, 55~70%, 15~30%.
3. the preparation method of graphene as described in claim 1-superhigh molecular weight polyethylene fibers coating cotton thread, feature exist
In, the line density of the graphene-superhigh molecular weight polyethylene fibers, nylon yarn or dacron thread, spandex thread be respectively 380~
420D, 130~160D, 130~150D.
4. the preparation method of graphene as described in claim 1-superhigh molecular weight polyethylene fibers coating cotton thread, feature exist
In the twist of the graphene-superhigh molecular weight polyethylene fibers is 180~220 twirls, and twist direction is twisted for Z, nylon yarn or terylene
The twist of silk is 360~540 twirls, and twist direction is twisted for S.
5. the preparation method of graphene as described in claim 1-superhigh molecular weight polyethylene fibers coating cotton thread, feature exist
In the content of graphene is 0.5~10wt% in the graphene-superhigh molecular weight polyethylene fibers.
6. the preparation method of graphene as claimed in claim 5-superhigh molecular weight polyethylene fibers coating cotton thread, feature exist
In also containing filler in the graphene-superhigh molecular weight polyethylene fibers, the content of the filler is 5~20wt%, described
Filler include in silicon carbide, diamond, glass microballoon, ceramic fibre, glass fibre, basalt fibre, metallic fiber at least
It is a kind of.
7. the preparation method of graphene as described in claim 1-superhigh molecular weight polyethylene fibers coating cotton thread, feature exist
In, include the graphene that content is 0.1~5wt% in the nylon yarn or dacron thread, the Lapie of the spandex thread is 1.6~
2, include the graphene that content is 0.1~5wt% in the spandex thread.
8. a kind of Anti-cutting covered yarn line prepared by any one of claim 1~7 preparation method.
9. Anti-cutting covered yarn line as described in claim 8, which is characterized in that curling coefficient is 96~99.
10. a kind of purposes of Anti-cutting covered yarn line as claimed in claim 8 in gloves, oversleeve or clothes.
11. a kind of preparation method of gloves as claimed in claim 10, which is characterized in that include the following steps:
Gloves base is made using Anti-cutting covered yarn line, after the gloves base is impregnated in slurry, carries out being solidified into coating, obtain
Gloves;
Wherein, the slurry includes at least one of PU, butyronitrile, natural emulsion, PVC or neoprene;
The preparation method of the gloves base is:The Anti-cutting covered yarn line is inputted in the braider of 7 needles, 10 needles or 13 needles, if
Determine braided parameter, is woven;
The braided parameter is specially:It is with technical parameter of the braider of 13 needle when weaving 9 yards of gloves:
Determine that grammes per square metre is 710~730g, lower captain's degree is 24~25cm;
The convolution number for controlling little finger of toe is 56, and nameless convolution number is 76, and the convolution number of middle finger is 82, and the convolution number of index finger is
72, the convolution number of thumb is 56, and the convolution number of four fingers and palms is 32, and the convolution number of five fingers and palms is 44, and the convolution number of threaded portion is
66。
12. a kind of preparation method of oversleeve as claimed in claim 10, which is characterized in that the oversleeve is that 260-320 needles are small
Tubular knitting, using 6 Anti-cutting covered yarn lines manufactures when knitting.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109629028A (en) * | 2018-11-15 | 2019-04-16 | 南通强生安全防护科技股份有限公司 | A kind of graphene ultra-high molecular weight polyethylene composite fibre and preparation method thereof |
CN109944081A (en) * | 2019-03-31 | 2019-06-28 | 任国峰 | A kind of anti-cutting fabric of graphene and preparation method thereof |
CN110236687A (en) * | 2019-06-13 | 2019-09-17 | 南通强生安全防护科技股份有限公司 | A kind of operation anti-cutting gloves and preparation method thereof |
CN110284251A (en) * | 2019-07-01 | 2019-09-27 | 福建长源纺织有限公司 | A kind of environmental protection knitting fabric and its storing unit |
CN111155334A (en) * | 2020-01-11 | 2020-05-15 | 长江纺织(浙江)有限公司 | Dyeing process of spandex/terylene/denim composite high-strength covered yarn |
CN113026163A (en) * | 2021-02-23 | 2021-06-25 | 山东星宇手套有限公司 | Anti-cutting yarn and preparation method thereof |
WO2023173800A1 (en) * | 2022-03-17 | 2023-09-21 | 南通强生新材料科技股份有限公司 | Cutting-resistant protective gloves and preparation method therefor |
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