CN108148466A - A kind of high damage resistant aqueous transparent printing ink composition and preparation method thereof - Google Patents
A kind of high damage resistant aqueous transparent printing ink composition and preparation method thereof Download PDFInfo
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- CN108148466A CN108148466A CN201810194436.7A CN201810194436A CN108148466A CN 108148466 A CN108148466 A CN 108148466A CN 201810194436 A CN201810194436 A CN 201810194436A CN 108148466 A CN108148466 A CN 108148466A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
The present invention relates to a kind of high damage resistant aqueous transparent printing ink compositions and preparation method thereof, belong to ink area, are prepared by the following component counted in parts by weight：Multi-functional styrene acrylic copolymer lotion 20 60%, high molecular weight solid acrylic resin 10 60%, aqueous defoamer 0.1 1%, 25% ammonium hydroxide 0.1 3%, dimethylethanolamine 0.1 5%, slipping agent 0.1 2%, wax emulsion 0.5 8%, reactive amines 0.5 6%, calcium carbonate 0.1 2.0%, gas phase nano silica 0.5 2%, coalescents 0.5 5%, deionized water 1 30%, small molecule 0.5% 1%, the small molecule is urea, thiocarbamide, methylurea, dimethyl urea, trimethyl-urea, tetramethylurea, it is one or more in p-nitrophenol；The high molecular weight solid acrylic resin molecular weight is 12500；Ethyl alcohol 0.5 1.5%, mimeograph drying time of the present invention is within 22S.
Description
Technical field
The present invention relates to a kind of high damage resistant aqueous transparent printing ink compositions and preparation method thereof, belong to ink area.
Background technology
Aqueous transparent ink quickly grows as a kind of environmentally protective printing material, is widely used in electronics and disappears in recent years
Take in the fine work packages printings such as product packages printing, pack printing, cosmetic package printing, but due to the film forming of aqueous transparent ink
Density and compactness are not high enough, easily scratch, scratch, mould subsequently gold stamping to fine work packages printing after aqueous transparent ink film forming
It cuts, the shortcomings of bonding etc. is scratched after processes, scuffing, causes product bad.This is also that current aqueous transparent ink is generally deposited
The shortcomings that, annoying press significantly, seriously affected utilization of the aqueous transparent ink in packages printing.
The development of high damage resistant aqueous transparent ink group components composition：Aqueous transparent ink generally uses aqueous third at present
Olefin(e) acid resin is as film-forming resin, and for pure acrylic resin due to less with collateral group, self-crosslinking reaction degree is relatively low, and form a film compactness
Not enough, hardness is inadequate, there is the shortcomings of easily scratching, not wear-resisting after aqueous transparent ink solidification film forming.It exists in the prior art
The scratch resistance of numerous studies ink film forming, the document of scratch resistance, however still it is difficult to meet ink to high scratch resistance, scratch-resistant
The requirement of wound property.
Patent CN1521223A discloses a kind of multifunction green environment protection type nano paint, and main ingredient is：Methyl-prop
Olefin(e) acid, butyl acrylate, styrene and methyl methacrylate quadripolymer latex 20~65%；Nano-titanium dioxide 0.3~
5%；Nano zine oxide 0.2~3%；Nano silicon dioxide 0.3~3%；Nano-calcium carbonate 0.5~5%；Deionized water 3~
12%；Superfine talcum powder 1~3%；Calcium carbonate superfine powder 3~15%；Titanium dioxide 3~25%；Dispersant, wetting agent, rheological agent, increasing
Thick dose, mill base, the auxiliary agents 2~12% such as antifoaming agent.The nano paint of production has nontoxic, pollution-free, washability, damage resistant, resistance to
Ultraviolet light, ageing-resistant, waterproof, it is mould proof the characteristics of, and also have self-cleaning function.
Patent CN102617771A discloses a kind of preparation side of Water-based plastic printing ink binding agent in flexible packaging industry
The glass transition temperature of method, wherein acrylate copolymer with 0~45 DEG C, preferably 5~40 DEG C, which is by acrylic acid
Butyl ester, methyl methacrylate, ethyl acrylate and/or methyl acrylate, styrene and cross-linking monomer as monomer component and
In the case where being with or without molecular weight regulator, in the defoaming without sulfonate groups, moist type surfactant and reaction
In the presence of type surfactant and in water-based acrylic resin of the weight average molecular weight between 4000-12000 and optionally
Free-radical emulsion polymerization reaction is carried out by adding initiator in the presence of anion surfactant containing sulfonate groups, so
The crosslinking agent that addition can be reacted with cross-linking monomer afterwards carries out crosslinking preparation.
The patent CN104177990A of Tianjin Cnpc Boxing Engineering Technology Co., Ltd. discloses a kind of vinyl anti-corrosion and applies
Material and manufacturing method, styrene, the copolymer solution containing acidic-group, silicon are added to by bisphenol-A epoxy type vinyl ester resin
Oil, polyacrylate solution, aminopropyl triethoxysilane dispersing and dissolving after high-speed stirred, add in gas in the case of stirring
With sand mill grinding mixed liquor is made, then added in mixed liquor in aerosil, titanium dioxide, barite, silicon powder, carbon black
Glass flake, high speed dispersion add in modified urea solution in dispersion process in dispersion process；B liquid is by cobalt naphthenate, styrene
Mixed solution forms, and C liquid liquid is by methyl ethyl ketone peroxide, methyl ethyl ketone, phthalic acid ester mixed solution composition, by A liquid during use
It is mixed with B liquid, C liquid；Its coating have excellent adhesive force, impact resistance, wearability, humidity resistance, sea water resistance and salt tolerant
Mist, working life is long, splash zone and underwater anticorrosion available for ocean platform and extra large work steel structure etc..
The patent CN104263062A of Anhui Ya Mei ink Co., Ltd discloses a kind of high absorption abrasion-resistance water environmental protection light
Curing metal decorating ink, the ink are made of the raw material of following parts by weight：The nanometer two of tungsten disulfide 0.1-0.2, solid content 30%
It is 40-50%'s to aoxidize silicon suspension 5-8, sodium styrene sulfonate 1-2, methyl glucose glucoside 0.1-0.2, solid content
Aqueous polyurethane acrylate lotion 20-26, photoinitiator 3-6, deionized water 15-26, ethyl alcohol 8-10, environmental-friendly pigment
8-13, auxiliary agent 1-2.The ink of preparation possesses excellent printing adaptability, and ink exquisiteness is stablized, is not easy to reunite, uniform drying
Quickly, coating tough and hard wear resistant prints quickness and high efficiency.
The patent CN104910712A of Hefei Qi Hua Environmental Protection Technology Co., Ltd discloses a kind of high glaze water lustering oil,
It is characterized in that it is made by the raw material of following weight parts：Modifying cinepazid emulsion 60-80, nano silicon dioxide 0.5-1, poly- sorb
Ester-80 0.5-1, castor oil 2-4, atoleine 1-2, sodium benzoate 0.1-0.2, peanut protein 1-2, polyethylene wax
Lotion 4-8, glycidyl methacrylate 0.5-1, water 10-15.The water lustering oil of preparation have good hardness,
Wearability, impact resistance, water resistance, corrosion resistance are superior, and coating film gloss degree is high, and transparent feel is strong, and appearance is good.
Application No. is high damage resistant aqueous transparent ink a kind of disclosed in 201611149734.1 and preparation method thereof, use
Multi-functional Styrene-acrylic copolymer improves the compactness of film forming as self-crosslinking reaction resin；High molecular weight solid
Resin and solid carbonic acid calcium can improve the hardness of the film forming of aqueous transparent ink；Coalescents lauryl alcohol ester and reactive amines can improve
The self-crosslinking reaction activity of film-forming resin improves the compactness and adhesive force of the film forming of aqueous transparent ink；Spheroidal particle dioxy
SiClx and newborn wax can form a laminated board type densification separation layer on aqueous transparent ink film forming surface layer, be effective against preventing external force or broken
It is bad；Slipping agent can form hydrophobic layer on aqueous transparent ink film forming surface layer, increase the flatness and resistance to marring of film forming, but should
The stamp-pad ink drying time of invention is more than 24s, needs to reduce stamp-pad ink drying time, and do not reduce other indexs.
Invention content
The shortcomings that the purpose of the invention is to overcome the above-mentioned prior art, a kind of high damage resistant of development was aqueous with insufficient
Bright printing ink composition and preparation method thereof, the present invention are realized by following proposal：
In order to improve the easy scuffing of aqueous transparent ink, it is not wear-resisting the shortcomings that, the present invention screens multi-functional benzene second
Alkene-acrylic copolymer can occur as self-crosslinking reaction resin, the Styrene-acrylic copolymer of the more side chains of polyfunctional group
Multi-faceted self-crosslinking reaction greatly improves the compactness of film forming.High molecular weight solid resin and solid carbonic acid calcium can improve aqueous
The hardness of the film forming of transparent ink；Coalescents lauryl alcohol ester and reactive amines can improve the self-crosslinking reaction activity of film-forming resin,
Improve the compactness and adhesive force of the film forming of aqueous transparent ink；Spheroidal particle silica and newborn wax can be in aqueous transparent ink
Form a film one laminated board type densification separation layer of surface layer formation, is effective against preventing external force or destruction；Slipping agent can be in aqueous transparent ink
Form a film surface layer formation hydrophobic layer, increases the flatness and resistance to marring of film forming.
The present invention adopts the following technical scheme that：A kind of preparation method of high damage resistant aqueous transparent printing ink composition, the height
Damage resistant aqueous transparent printing ink composition is prepared by the following component counted in parts by weight：Multi-functional styrene-the third
Olefin(e) acid copolymer emulsion 20-60%, high molecular weight solid acrylic resin 10-60%, preferably 10-40%, aqueous defoamer
0.1-1%, 25% ammonium hydroxide 0.1-3%, dimethylethanolamine 0.1-5%, slipping agent 0.1-2%, wax emulsion 0.5-8%, activity
Amine 0.5-6%, calcium carbonate 0.1-2%, gas phase nano silica 0.5-2%, coalescents 0.5- 5%, deionized water 1-
30%, preferably 1-20%, ethyl alcohol 0.5-1.5%, by the proportioning of above-mentioned each component, first by high molecular weight solid acrylic resin,
Deionized water and antifoaming agent are added in container, are stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, stirred
Ammonium hydroxide is slowly added in journey in three times, every 20 minutes plus primary, stirring 2- 8 hours, until hard resin is completely dissolved, then
Remaining component in addition to ethyl alcohol is added in the hard resin lotion of dissolving, the high-speed stirred of 400-1500 turns/hour of rotating speed
Disperse 1 hour, be finally mixed into ethyl alcohol, obtain a kind of high damage resistant aqueous transparent printing ink composition.
The acrylic solid molecular resin amount for the high molecular weight that the present invention uses is preferably 12500.
The levelling agent is at least one of polysiloxane-polyether copolymer and polyether-modified dimethyl silicone polymer；
The antifoaming agent is at least one of polyether siloxane copolymer and polyether silicones emulsion-type；
The substrate wetting agents are at least one of organic silicon surfactant, nonionic surfactant；
The slipping agent in organic silicon modified by polyether oxygen alkane and super high molecular weight dimethyl silicone polymer dispersion liquid at least
It is a kind of.
The printing ink composition of the present invention can also add in small molecule 0.1%-2% to improve the filming performance of ink, described
Small molecule is urea, one or more in thiocarbamide, methylurea, dimethyl urea, trimethyl-urea, tetramethylurea, p-nitrophenol.
The present invention is had the following advantages and advantageous effect relative to the prior art：
(1) present invention uses multi-functional styrene acrylic copolymer lotion as self-contained film resin, due to benzene second
Alkene acrylic copolymer is with styrene and other side chains, then adds the acrylic resin with high molecular weight, occur it is multi-faceted from
Cross-linking reaction greatly improves the compactness of film forming, improves the film forming compactness and hardness of aqueous transparent ink, enhances resistance to scraping.
The multi-functional styrene acrylic copolymer lotion that the present invention uses is includes styrene, methyl styrene, methyl-prop
The styrene acrylic copolymer lotion of the side chain functionalities such as e pioic acid methyl ester, preparation method are known, patents
CN102617771A discloses the preparation method of lotion, can also use commercially available product, such as brocade is by 1022 and brocade by 1031.
(2) present invention changes the film-forming quality of aqueous transparent ink using surface slipping agent, forms a film in aqueous transparent ink
Surface layer forms hydrophobic layer, enhances the smoothness and feel of film forming, improves the anti-scratch performance of aqueous transparent ink；
(3) present invention can improve the activity of resin reaction, the crosslink density of polyfunctional group acrylic resin using reactive amines
Height, aqueous transparent ink adhesion.
(4) the gas phase nano silica that the present invention uses has following features and effect：1. water imbibition, with aqueous systems parent
With formation is uniformly distributed；2. gas phase nano silica is nanometer particle, surface area can form greatly a laminated board type is isolated firmly
Layer can effectively resist the scuffing or destruction for preventing external force, improve the wearability and resistance to scraping of aqueous transparent ink.
The additive amount of gas phase nano silica is 0.5-2%, preferably 0.5-1%, it should be noted that silica
Addition is too low, cannot effectively play the role of improving the wearability and resistance to scraping of aqueous transparent ink less than 0.5%；Add
Enter that amount is too high, the wearability and resistance to scraping of aqueous transparent ink then cannot be not only further improved higher than 2%, and influence ink
Film forming and ink layer intensity.
(5) high molecular weight solid resin and solid carbonic acid calcium can improve the hardness of the film forming of aqueous transparent ink, macromolecule
The acrylic solid molecular resin amount of amount is preferably 12500.The preferred 0.1-2% of addition of calcium carbonate, the too high influence of usage amount
The film forming of ink.
(6) coefficient of kinetic friction can reach 0.1-0.2 after high damage resistant aqueous transparent printing ink composition of the invention film forming, and 4
Pound does not grind flower 800 times, has smooth, anti-scratch, the performances such as wear-resisting and good printing adaptability.
(7) stamp-pad ink drying time of the invention is controlled within 22S, greatly improves drying time.
Specific embodiment
Following embodiment cannot be used for limiting claimed model for illustrating technical scheme of the present invention
It encloses.
Embodiment 1
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 34.5%, 30% high molecular weight solid propylene
Acid resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 8.0%, reactive amines 6.0%, gas phase nano silica 0.6%, coalescents 1.5%, deionized water
4.0%, ethyl alcohol 0.5%.By the proportioning of above-mentioned each component, first by high molecular weight solid acrylic resin, deionized water and defoaming
Agent is added in container, is stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, in whipping process in three times slowly
Ammonium hydroxide is added in, it is every 20 minutes plus primary, it stirs 2-8 hours, is added in until hard resin is completely dissolved, then by remaining component
In the hard resin lotion of dissolving, the high-speed stirred of 1000 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-scratch essence
Product box prints water-based gloss oil.
Embodiment 2
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 33.2%, 30% high molecular weight solid propylene
Acid resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 8.0%, reactive amines 5.6%, gas phase nano silica 1 %, coalescents 1.5%, deionized water 9%,
Ethyl alcohol 0.8%.By the proportioning of above-mentioned each component, first high molecular weight solid acrylic resin, deionized water and antifoaming agent are added in
In container, stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, be slowly added to ammonia in whipping process in three times
Water, it is every 20 minutes plus primary, it stirs 2-8 hour, adds in what is dissolved until hard resin is completely dissolved, then by remaining component
In hard resin lotion, the high-speed stirred of 1000 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-scratch gift box print
Brush water-based gloss oil.
Embodiment 3
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 25%, Styrene-acrylic copolymer hard emulsion 29.2%, 30% high molecular weight solid propylene
Acid resin 25%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 5.0%, reactive amines 3%, gas phase nano silica 1 .6%, coalescents 1.5%, deionized water
4.0%, ethyl alcohol 0.8%.By the proportioning of above-mentioned each component, first by high molecular weight solid acrylic resin, deionized water and defoaming
Agent is added in container, is stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, in whipping process in three times slowly
Ammonium hydroxide is added in, it is every 20 minutes plus primary, it stirs 2-8 hours, is added in until hard resin is completely dissolved, then by remaining component
In the hard resin lotion of dissolving, the high-speed stirred of 1000 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-scratch essence
Product box prints water-based gloss oil.
Embodiment 4
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 34%, 30% high molecular weight solid acrylic acid
Resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 8.0%, reactive amines 5%, thiocarbamide 1%, gas phase nano silica 0.6%, coalescents 1.5%, go from
Sub- water 4.0%, ethyl alcohol 1.0%.By the proportioning of above-mentioned each component, first by high molecular weight solid acrylic resin, deionized water and
Antifoaming agent is added in container, is stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, in whipping process in three times
Ammonium hydroxide is slowly added to, it is every 20 minutes plus primary, it stirs 2-8 hours, until hard resin is completely dissolved, then by remaining component
It adds in the hard resin lotion of dissolving, the high-speed stirred of 1000 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-
Scrape gift box printing water-based gloss oil.
Embodiment 5
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 34.1%, 30% high molecular weight solid propylene
Acid resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 8.0%, reactive amines 5%, thiocarbamide 0.5%, p-nitrophenol 0.5%, gas phase nano silica 0.6%,
Coalescents 1.5%, deionized water 4.0%, ethyl alcohol 0.9%.By the proportioning of above-mentioned each component, first by high molecular weight solid propylene
Acid resin, deionized water and antifoaming agent are added in container, are stirred in the high-speed stirred dispersion machine of 1500 turns/hours of rotating speed 400-
It mixes, is slowly added to ammonium hydroxide in whipping process in three times, it is every 20 minutes plus primary, it stirs 6 hours, until hard resin is completely molten
Solution, then remaining component is added in the hard resin lotion of dissolving, the high-speed stirred dispersion of 1200 turns/hour of rotating speed is 1 small
When, obtain a kind of smooth anti-scratch gift box printing water-based gloss oil.
Embodiment 6
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 33.8%, 30% high molecular weight solid propylene
Acid resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 2%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 8.0%, reactive amines 6.0%, gas phase nano silica 0.6%, coalescents 1.5%, deionized water
5%, ethyl alcohol 1.2%.By the proportioning of above-mentioned each component, first by high molecular weight solid acrylic resin, deionized water and antifoaming agent
It adds in container, is stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, slowly added in three times in whipping process
Enter ammonium hydroxide, it is every 20 minutes plus primary, it stirs 2-8 hours, until hard resin is completely dissolved, then the addition of remaining component is molten
In the hard resin lotion of solution, the high-speed stirred of 1000 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-scratch fine work
Box prints water-based gloss oil.
Embodiment 7
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 30%, Styrene-acrylic copolymer hard emulsion 23.5%, 30% high molecular weight solid propylene
Acid resin 25%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 1%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 5.0%, reactive amines 6.0%, gas phase nano silica 0.6%, coalescents 1.5%, deionized water
4.0%, ethyl alcohol 1.5%.By the proportioning of above-mentioned each component, first by high molecular weight solid acrylic resin, deionized water and defoaming
Agent is added in container, is stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, in whipping process in three times slowly
Ammonium hydroxide is added in, it is every 20 minutes plus primary, it stirs 2-8 hours, is added in until hard resin is completely dissolved, then by remaining component
In the hard resin lotion of dissolving, the high-speed stirred of 1000 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-scratch essence
Product box prints water-based gloss oil.
Embodiment 8
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 33.5%, 30% high molecular weight solid propylene
Acid resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 6%, reactive amines 5%, gas phase nano silica 0.6%, coalescents 1.5%, deionized water 7%, second
Alcohol 1.5%.By the proportioning of above-mentioned each component, first high molecular weight solid acrylic resin, deionized water and antifoaming agent are added in and held
In device, stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, be slowly added to ammonia in whipping process in three times
Water, it is every 20 minutes plus primary, it stirs 4 hours, until hard resin is completely dissolved, then consolidating the addition dissolving of remaining component
In body resin emulsion, the high-speed stirred of 1500 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-scratch gift box printing
Water-based gloss oil.
Comparative example 1
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 35%, 30% high molecular weight solid acrylic acid
Resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 8.0%, reactive amines 6.0%, gas phase nano silica 3%, coalescents 1.5%, deionized water
4.0%.By the proportioning of above-mentioned each component, high molecular weight solid acrylic resin, deionized water and antifoaming agent are first added in into container
In, it is stirred in the high-speed stirred dispersion machine of 400-1500 turns/hour of rotating speed, is slowly added to ammonium hydroxide in whipping process in three times,
It is every 20 minutes plus primary, it stirs 2-8 hours, until hard resin is completely dissolved, then consolidating the addition dissolving of remaining component
In body resin emulsion, the high-speed stirred of 1000 turns/hour of rotating speed disperses 1 hour, obtains a kind of smooth anti-scratch gift box printing
Water-based gloss oil.
Comparative example 2
The smooth resistance to scraping water-based gloss oil is prepared by the following component counted in parts by weight：Multi-functional styrene
Acrylic copolymer soft emulsion 20%, Styrene-acrylic copolymer hard emulsion 35%, 30% high molecular weight solid acrylic acid
Resin 20%, aqueous defoamer 0.3%, levelling agent 0.3%, 25% ammonium hydroxide 3%, dimethylethanolamine 1.0%, slipping agent
0.3%, wax emulsion 8.0%, reactive amines 6.0%, coalescents 1.5%, deionized water 4.6%.By the proportioning of above-mentioned each component,
First high molecular weight solid acrylic resin, deionized water and antifoaming agent are added in container, in 400-1500 turns/hour of rotating speed
It is stirred in high-speed stirred dispersion machine, is slowly added to ammonium hydroxide in whipping process in three times, every 20 minutes plus primary, stirring 2-8 is small
When, it is added in the hard resin lotion of dissolving until hard resin is completely dissolved, then by remaining component, 1000 turns of rotating speed/small
When high-speed stirred disperse 1 hour, obtain a kind of smooth anti-scratch gift box printing water-based gloss oil.
The test of 1 gloss oil scratch resistant performance of table compares
The high damage resistant aqueous transparent printing ink composition provided above the embodiment of the present invention and preparation method thereof progress
It is discussed in detail.Specific embodiment used herein is expounded the principle of the present invention and embodiment, implements above
The explanation of example is merely used to help understand the method and its core concept of the present invention；Meanwhile for the general technology people of this field
Member, thought according to the present invention, there will be changes in specific embodiments and applications, in conclusion this explanation
Book content should not be construed as limiting the invention, and be made under other any Spirit Essences and principle without departing from the present invention
Change, modification, substitute, combination, simplify, should be equivalent substitute mode, be included within protection scope of the present invention.
Claims (5)
1. a kind of high damage resistant aqueous transparent printing ink composition, which is characterized in that prepared by the following component counted in parts by weight
It forms：Multi-functional Styrene-acrylic copolymer lotion 20-60%, high molecular weight solid acrylic resin 10-60%,
Aqueous defoamer 0.1-1%, 25% ammonium hydroxide 0.1-3%, dimethylethanolamine 0.1-5%, slipping agent 0.1-2%, wax emulsion
0.5-8%, reactive amines 0.5-6%, calcium carbonate 0.1-2.0%, gas phase nano silica 0.5-2%, coalescents 0.5-
5%, deionized water 1-30%, small molecule 0.5%-1%, the small molecule is urea, thiocarbamide, methylurea, dimethyl urea, front three
It is one or more in base urea, tetramethylurea, p-nitrophenol；The high molecular weight solid acrylic resin molecular weight is
12500；Ethyl alcohol 0.5-1.5%.
2. printing ink composition according to claim 1, it is characterised in that：The multi-functional Styrene And Chloroalkyl Acrylates
Copolymer emulsion is Styrene-acrylic copolymer soft emulsion and Styrene-acrylic copolymer hard emulsion.
3. printing ink composition according to claim 1, it is characterised in that：The aqueous defoamer is total to for polyether silicone
At least one of polymers and polyether silicones emulsion-type.
4. printing ink composition according to claim 1, it is characterised in that：The slipping agent is organic silicon modified by polyether oxygen alkane
At least one of with super high molecular weight dimethyl silicone polymer dispersion liquid.
5. the preparation method of claim 1-4 any one of them printing ink compositions, which is characterized in that include the following steps：It presses
According to the proportioning of above-mentioned each component, first high molecular weight solid acrylic resin, deionized water and aqueous defoamer are added in container,
Turn/the high-speed stirred of hour with rotating speed 400-1500 in dispersion machine, ammonium hydroxide is slowly added in three times in whipping process, every 20
Minute plus it is primary, stir 2-8 hour, until high molecular weight solid acrylic resin is completely dissolved, then will be not comprising ethyl alcohol remain
Remaining component is added in the high molecular weight solid emulsion acrylic resin of dissolving, with the high-speed stirring of 400-1500 turns/hour of rotating speed
1 hour of dispersion is mixed, ethyl alcohol is finally added, after mixing, and seals, obtain a kind of high damage resistant aqueous transparent printing ink composition.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109385195A (en) * | 2018-10-12 | 2019-02-26 | 中山市富日印刷材料有限公司 | A kind of environment-friendly water-based bloom gloss oil and preparation method thereof |
| CN117304444A (en) * | 2023-10-31 | 2023-12-29 | 北京中彩印制有限公司 | Water-based polyurethane and preparation method thereof, and water-based scratch-off ink and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519796A (en) * | 2016-12-13 | 2017-03-22 | 永发印务(东莞)有限公司 | Water-borne transparent oil with high scratch resistance and preparing method thereof |
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2018
- 2018-03-09 CN CN201810194436.7A patent/CN108148466A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519796A (en) * | 2016-12-13 | 2017-03-22 | 永发印务(东莞)有限公司 | Water-borne transparent oil with high scratch resistance and preparing method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109385195A (en) * | 2018-10-12 | 2019-02-26 | 中山市富日印刷材料有限公司 | A kind of environment-friendly water-based bloom gloss oil and preparation method thereof |
| CN117304444A (en) * | 2023-10-31 | 2023-12-29 | 北京中彩印制有限公司 | Water-based polyurethane and preparation method thereof, and water-based scratch-off ink and preparation method thereof |
| CN117304444B (en) * | 2023-10-31 | 2024-05-07 | 北京中彩印制有限公司 | Water-based polyurethane and preparation method thereof, and water-based scratch-off ink and preparation method thereof |
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