CN108130177A - A kind of health-caring equipment antioxidant wear-resistant type lubricating oil and preparation method thereof - Google Patents
A kind of health-caring equipment antioxidant wear-resistant type lubricating oil and preparation method thereof Download PDFInfo
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- CN108130177A CN108130177A CN201810066241.4A CN201810066241A CN108130177A CN 108130177 A CN108130177 A CN 108130177A CN 201810066241 A CN201810066241 A CN 201810066241A CN 108130177 A CN108130177 A CN 108130177A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/14—Inorganic compounds or elements as ingredients in lubricant compositions inorganic compounds surface treated with organic compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
Abstract
The invention discloses a kind of health-caring equipment antioxidant wear-resistant type lubricating oil and preparation method thereof, include the raw material of following parts by weight：48 52 parts of base oil, 26 30 parts of organic-molybdenum mixture, 14 16 parts of modified nano graphite, 10 12 parts of modified Nano kaolin, 6 14 parts of antioxidant, 6 10 parts of antiwear additive, 59 parts of corrosion prevention rust preventer, 48 parts of alkylbenzenesulfonate, 24 parts of viscosity modifier, 13 parts of surface modifier.A kind of health-caring equipment antioxidant wear-resistant type lubricating oil of the present invention, the lubricating oil is pollution-free, environmentally protective, efficient, with good antirust, wear-resisting, antioxygen property, material cost is relatively low in addition, raw material is easy to get, and has higher use value and good application prospect.
Description
Technical field
The present invention relates to health-caring equipment technical field of lubricating oil, and in particular to a kind of health-caring equipment antioxidant wear-resistant type moistens
Lubricating oil and preparation method thereof.
Background technology
Lubricating oil is used in automobile, on mechanical equipment to reduce the liquid of friction, protection machinery and workpiece, primarily serve
Lubrication, cooling, anti-rust action, are usually made of base oil and additive two parts, and base oil is the main component of lubricating oil,
Decide the fundamental property of lubricating oil, additive can then make up and improve the deficiency of base oil aspect of performance；Health-caring equipment includes
Fitness equipment, the sports apparatus in cell, various massage apparatus, rehabilitation and the therapeutic equipments of health club, these health-promoting apparatus
Material using when part between phase mutual friction can cause wear phenomenon, therefore, can reduce parts depreciation using lubricating oil, reduce and rub
Wipe economic loss caused by with abrasion.
Containing zinc dialkyl dithiophosphate etc. in traditional lubricating oil family, bearing can be corroded, pollute atmospheric environment, it is existing
Having in technology, under rainwater and sun exposure environment, the wear-resisting of lubricating oil, antioxygen, rustless property reduce, simultaneously health-caring equipment,
The service life of lubricating oil greatly reduces, in addition, cannot use at quite low temperatures, easily influences lubricating oil usability
Energy.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of health-caring equipment antioxidant wear-resistant types to lubricate
Oil, the lubricating oil is pollution-free, environmentally protective, efficient, have good antirust, wear-resisting, antioxygen property, in addition material cost compared with
Low, raw material is easy to get, and has higher use value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention provides a kind of health-caring equipment antioxidant wear-resistant type lubricating oil, include the raw material of following parts by weight：
48-52 parts of base oil, 26-30 parts of organic-molybdenum mixture, 14-16 parts of modified nano graphite, modified Nano kaolin 10-12
Part, 6-14 parts of antioxidant, 6-10 parts of antiwear additive, 5-9 parts of corrosion prevention rust preventer, 4-8 parts of alkylbenzenesulfonate, viscosity modifier 2-4
Part, 1-3 parts of surface modifier.
Preferably, the health-caring equipment includes the raw material of following parts by weight with antioxidant wear-resistant type lubricating oil：
It is 50 parts of base oil, 28 parts of organic-molybdenum, 15 parts of modified nano graphite, 11 parts of modified Nano kaolin, 10 parts of antioxidant, wear-resistant
8 parts of agent, 7 parts of corrosion prevention rust preventer, 6 parts of alkylbenzenesulfonate, 3 parts of viscosity modifier, 2 parts of surface modifier.
Preferably, the base oil is poly alpha olefin (PAO) synthetic oil, and adds two in poly alpha olefin (PAO) synthetic oil
Ester, multi-hydroxy ester.
Preferably, the organic-molybdenum mixture is dialkyl dithiophosphoric acid oxygen molybdenum, in molybdenum naphthenate, alkyl salicylate molybdenum
One or more compositions.
Preferably, the preparation method of the modified nano graphite includes the following steps：
Graphite is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the sodium bicarbonate that mass fraction is 5%
It in solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Dried graphite is put into the ferric chloride solution that mass fraction is 10%, 30-40 DEG C of solution temperature, reaction by step 2
Time 20-30 minute, apply the ultrasonic wave of frequency 30KHz, 12h taking-ups are dried to obtain chlorination modified graphite；
Chlorination modified graphite is put into ball mill by step 3, and temperature is -10-20 DEG C, is ground to grain size as 20-33nm, is obtained
Nano-graphite is put into the olive oil of 5 times of its quality by nano-graphite, and olive oil temperature is 100-110 DEG C, is sufficiently stirred 30-
40 minutes, nano-graphite is filtered out, is drying to obtain modified nano graphite.
Preferably, the modified Nano kleit preparation method includes the following steps：
Kaolin is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the bicarbonate that mass fraction is 5%
It in sodium solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Step 2, by dried kaolin in potcal pot calcination, 1000-1200 DEG C of calcination temperature, calcination time 1-2h takes out
To high temperature modified kaolin；
High temperature modified kaolin is put into ball mill by step 3, and temperature is -10-30 DEG C, is ground to grain size as 20-30nm, is obtained
To nano kaoline, nano kaoline is put into the olive oil of 5 times of its quality, olive oil temperature is 100-110 DEG C, is fully stirred
It mixes 30-40 minutes, filters out nano kaoline, be drying to obtain modified Nano kaolin.
Preferably, the antioxidant is antioxidant BHT；The antiwear additive is alkyl zinc dithiophosphate；The anti-corrosion is prevented
Rust agent is metal sulfonate.
Preferably, the alkylbenzenesulfonate is alkyl benzene calcium sulfonate；The viscosity modifier for polymethacrylates,
One or more combinations in ring-alkylated styrenes；The surface modifier is neopelex, silane coupling agent, ten
One or more combinations in six alkyl trimethyl ammonium bromides.
The present invention also provides a kind of health-caring equipment preparation method of antioxidant wear-resistant type lubricating oil, including following step
Suddenly：
Step 1 weighs each component raw material as required；
Step 2 by base oil, organic-molybdenum mixture, antioxidant, antiwear additive, corrosion prevention rust preventer, is added sequentially to height in order
It is stirred in fast blender, speed of agitator 1000-1200r/min, mixing time 20-30min, obtains mixture A, then by mixture
A is added in reaction kettle, is reacted 1-2h at being 150-160 DEG C in temperature, is obtained mixture B；
Step 3 by alkylbenzenesulfonate, viscosity modifier, surface modifier, is added sequentially in homogenizer in order
Stirring, speed of agitator 1000-1200r/min, mixing time 20-30min obtain mixture C；
Step 4 receives mixture C obtained in mixture B obtained in step 2, step 3, modified nano graphite, modification
Rice kaolin is added in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 600-800r/min,
Mixing time 20-30 minutes, then add mixture in reaction kettle, it is reacted 40-50 minutes at being 170-180 DEG C in temperature,
The health-caring equipment antioxidant wear-resistant type lubricating oil of invention is made.
Preferably, the health-caring equipment is with the preparation process of antioxidant wear-resistant type lubricating oil：
Step 1 weighs each component raw material as required；
Step 2 by base oil, organic-molybdenum mixture, antioxidant, antiwear additive, corrosion prevention rust preventer, is added sequentially to height in order
It is stirred in fast blender, speed of agitator 1100r/min, mixing time 25min, obtains mixture A, then mixture A is added to
In reaction kettle, 1.5h is reacted at being 155 DEG C in temperature, obtains mixture B；
Step 3 by alkylbenzenesulfonate, viscosity modifier, surface modifier, is added sequentially in homogenizer in order
Stirring, speed of agitator 1100r/min, mixing time 25min obtain mixture C；
Step 4 receives mixture C obtained in mixture B obtained in step 2, step 3, modified nano graphite, modification
Rice kaolin is added in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 700r/min is stirred
25 minutes time, then add mixture in reaction kettle, it is reacted 45 minutes at being 175 DEG C in temperature, the health care of invention is made
Equipment antioxidant wear-resistant type lubricating oil.
Compared with prior art, the present invention has following advantageous effect：
（1）A kind of poly alpha olefin (PAO) synthetic oil of health-caring equipment antioxidant wear-resistant type lubricating oil addition of the present invention has
High thermo oxidative stability, health-caring equipment can also work normally under arctic weather, still maintain higher under the high temperature conditions
Viscosity index (VI), though thering is shortcoming and diester, multi-hydroxy ester to allocate, can solve the problems, such as exist.
（2）A kind of health-caring equipment of the present invention adds organic-molybdenum mixture with antioxidant wear-resistant type lubricating oil, antioxidant, resists
Grinding agent, corrosion prevention rust preventer can significantly improve the anti-oxidant, wear-resisting of lubricating oil, rustless property, and alkylbenzenesulfonate has in addition
There is good rust-proof effect, also have both peace and quiet effect, greatly extend the service life of lubricating oil.
（3）A kind of health-caring equipment antioxidant wear-resistant type lubricating oil of the present invention, modified nano graphite are lamellar structure, change
Property nano kaoline be spherical structure, the two is blended, and interacts, cooperation, mitigates the opposite fortune between equipment part
The frictional force of movable property life, while the oxidation activity factor is absorbed, enhance the stability of lubricating oil.
（4）A kind of health-caring equipment antioxidant wear-resistant type lubricating oil of the present invention, the viscosity modifier of addition can improve
The viscosity of lubricating oil improves viscosity index (VI), extends Working Life of Lubricating Oil, the surface modifier added in addition makes raw material can
With preferably compatible.
（5）A kind of health-caring equipment antioxidant wear-resistant type lubricating oil of the present invention includes the raw material of following parts by weight：Basis
48-52 parts oily, 26-30 parts of organic-molybdenum mixture, 14-16 parts of modified nano graphite, 10-12 parts of modified Nano kaolin, antioxygen
6-14 parts of agent, 6-10 parts of antiwear additive, 5-9 parts of corrosion prevention rust preventer, 4-8 parts of alkylbenzenesulfonate, 2-4 parts of viscosity modifier, surface
1-3 parts of modifying agent, the raw material dosage is also no too small both without too big, and is controlled in a suitable range, because only
There is the lubricants performance prepared in the claimed range of the present invention excellent.
（6）The present invention a kind of health-caring equipment antioxidant wear-resistant type lubricating oil, the lubricating oil is pollution-free, it is environmentally protective,
Efficiently, there is good antirust, wear-resisting, antioxygen property, material cost is relatively low in addition, raw material is easy to get, and has and higher uses valency
Value and good application prospect.
Specific embodiment
With reference to specific embodiment, the technical solution in the embodiment of the present invention is clearly and completely described, is shown
So, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based on the reality in the present invention
Apply example, those of ordinary skill in the art's all other embodiments obtained without making creative work all belong to
In the scope of protection of the invention.
Embodiment 1.
A kind of health-caring equipment of the present embodiment antioxidant wear-resistant type lubricating oil includes the raw material of following parts by weight：
48 parts of base oil, 26 parts of organic-molybdenum mixture, 14 parts of modified nano graphite, 10 parts of modified Nano kaolin, antioxidant 6
Part, 6 parts of antiwear additive, 5 parts of corrosion prevention rust preventer, 4 parts of alkylbenzenesulfonate, 2 parts of viscosity modifier, 1 part of surface modifier.
Base oil in the present embodiment is poly alpha olefin (PAO) synthetic oil, and add two in poly alpha olefin (PAO) synthetic oil
Ester, multi-hydroxy ester.
Organic-molybdenum mixture in the present embodiment is dialkyl dithiophosphoric acid oxygen molybdenum.
The preparation method of modified nano graphite in the present embodiment includes the following steps：
Graphite is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the sodium bicarbonate that mass fraction is 5%
It in solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Dried graphite is put into the ferric chloride solution that mass fraction is 10%, 30 DEG C of solution temperature, during reaction by step 2
Between 20 minutes, apply the ultrasonic wave of frequency 30KHz, 12h taking-ups are dried to obtain chlorination modified graphite；
Chlorination modified graphite is put into ball mill by step 3, and temperature is -10 DEG C, is ground to grain size as 20nm, is obtained a nanometer stone
Nano-graphite is put into the olive oil of 5 times of its quality by ink, and olive oil temperature is 100 DEG C, is sufficiently stirred 30 minutes, filters out and receive
Meter Shi Mo is drying to obtain modified nano graphite.
Modified Nano kleit preparation method in the present embodiment includes the following steps：
Kaolin is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the bicarbonate that mass fraction is 5%
It in sodium solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Step 2, by dried kaolin in potcal pot calcination, 1000 DEG C, calcination time 1h of calcination temperature is taken out and obtains high temperature
Modified kaolin；
High temperature modified kaolin is put into ball mill by step 3, and temperature is -10 DEG C, is ground to grain size as 20nm, is obtained nanometer
Nano kaoline is put into the olive oil of 5 times of its quality by kaolin, and olive oil temperature is 100 DEG C, is sufficiently stirred 30 minutes,
Nano kaoline is filtered out, is drying to obtain modified Nano kaolin.
Antioxidant in the present embodiment is antioxidant BHT, and antiwear additive is alkyl zinc dithiophosphate, and corrosion prevention rust preventer is gold
Belong to sulfonate.
Alkylbenzenesulfonate in the present embodiment is alkyl benzene calcium sulfonate, and viscosity modifier is polymethacrylates, table
Face modifying agent is neopelex.
A kind of health-caring equipment preparation method of antioxidant wear-resistant type lubricating oil of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Step 2 by base oil, organic-molybdenum mixture, antioxidant, antiwear additive, corrosion prevention rust preventer, is added sequentially to height in order
It is stirred in fast blender, speed of agitator 1000r/min, mixing time 20min, obtains mixture A, then mixture A is added to
In reaction kettle, 1h is reacted at being 150 DEG C in temperature, obtains mixture B；
Step 3 by alkylbenzenesulfonate, viscosity modifier, surface modifier, is added sequentially in homogenizer in order
Stirring, speed of agitator 1000r/min, mixing time 20min obtain mixture C；
Step 4 receives mixture C obtained in mixture B obtained in step 2, step 3, modified nano graphite, modification
Rice kaolin is added in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 600r/min is stirred
20 minutes time, then add mixture in reaction kettle, it is reacted 40 minutes at being 170 DEG C in temperature, the health care of invention is made
Equipment antioxidant wear-resistant type lubricating oil.
Embodiment 2.
A kind of health-caring equipment of the present embodiment antioxidant wear-resistant type lubricating oil includes the raw material of following parts by weight：
52 parts of base oil, 30 parts of organic-molybdenum mixture, 16 parts of modified nano graphite, 12 parts of modified Nano kaolin, antioxidant 14
Part, 10 parts of antiwear additive, 9 parts of corrosion prevention rust preventer, 8 parts of alkylbenzenesulfonate, 4 parts of viscosity modifier, 3 parts of surface modifier.
Base oil in the present embodiment is poly alpha olefin (PAO) synthetic oil, and add two in poly alpha olefin (PAO) synthetic oil
Ester, multi-hydroxy ester.
Organic-molybdenum mixture in the present embodiment is dialkyl dithiophosphoric acid oxygen molybdenum.
The preparation method of modified nano graphite in the present embodiment includes the following steps：
Graphite is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the sodium bicarbonate that mass fraction is 5%
It in solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Dried graphite is put into the ferric chloride solution that mass fraction is 10%, 40 DEG C of solution temperature, during reaction by step 2
Between 30 minutes, apply the ultrasonic wave of frequency 30KHz, 12h taking-ups are dried to obtain chlorination modified graphite；
Chlorination modified graphite is put into ball mill by step 3, and temperature is 20 DEG C, is ground to grain size as 33nm, is obtained a nanometer stone
Nano-graphite is put into the olive oil of 5 times of its quality by ink, and olive oil temperature is 110 DEG C, is sufficiently stirred 40 minutes, filters out and receive
Meter Shi Mo is drying to obtain modified nano graphite.
Modified Nano kleit preparation method in the present embodiment includes the following steps：
Kaolin is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the bicarbonate that mass fraction is 5%
It in sodium solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Step 2, by dried kaolin in potcal pot calcination, 1200 DEG C, calcination time 2h of calcination temperature is taken out and obtains high temperature
Modified kaolin；
High temperature modified kaolin is put into ball mill by step 3, and temperature is 30 DEG C, is ground to grain size as 30nm, is obtained nanometer
Nano kaoline is put into the olive oil of 5 times of its quality by kaolin, and olive oil temperature is 110 DEG C, is sufficiently stirred 40 minutes,
Nano kaoline is filtered out, is drying to obtain modified Nano kaolin.
Antioxidant in the present embodiment is antioxidant BHT, and antiwear additive is alkyl zinc dithiophosphate, and corrosion prevention rust preventer is gold
Belong to sulfonate.
Alkylbenzenesulfonate in the present embodiment is alkyl benzene calcium sulfonate, and viscosity modifier is polymethacrylates, table
Face modifying agent is neopelex.
A kind of health-caring equipment preparation method of antioxidant wear-resistant type lubricating oil of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Step 2 by base oil, organic-molybdenum mixture, antioxidant, antiwear additive, corrosion prevention rust preventer, is added sequentially to height in order
It is stirred in fast blender, speed of agitator 1200r/min, mixing time 30min, obtains mixture A, then mixture A is added to
In reaction kettle, 2h is reacted at being 160 DEG C in temperature, obtains mixture B；
Step 3 by alkylbenzenesulfonate, viscosity modifier, surface modifier, is added sequentially in homogenizer in order
Stirring, speed of agitator 1200r/min, mixing time 30min obtain mixture C；
Step 4 receives mixture C obtained in mixture B obtained in step 2, step 3, modified nano graphite, modification
Rice kaolin is added in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 800r/min is stirred
30 minutes time, then add mixture in reaction kettle, it is reacted 50 minutes at being 180 DEG C in temperature, the health care of invention is made
Equipment antioxidant wear-resistant type lubricating oil.
Embodiment 3.
A kind of health-caring equipment of the present embodiment antioxidant wear-resistant type lubricating oil includes the raw material of following parts by weight：
It is 50 parts of base oil, 28 parts of organic-molybdenum, 15 parts of modified nano graphite, 11 parts of modified Nano kaolin, 10 parts of antioxidant, wear-resistant
8 parts of agent, 7 parts of corrosion prevention rust preventer, 6 parts of alkylbenzenesulfonate, 3 parts of viscosity modifier, 2 parts of surface modifier.
Base oil in the present embodiment is poly alpha olefin (PAO) synthetic oil, and add two in poly alpha olefin (PAO) synthetic oil
Ester, multi-hydroxy ester.
Organic-molybdenum mixture in the present embodiment is dialkyl dithiophosphoric acid oxygen molybdenum.
The preparation method of modified nano graphite in the present embodiment includes the following steps：
Graphite is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the sodium bicarbonate that mass fraction is 5%
It in solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Dried graphite is put into the ferric chloride solution that mass fraction is 10%, 35 DEG C of solution temperature, during reaction by step 2
Between 25 minutes, apply the ultrasonic wave of frequency 30KHz, 12h taking-ups are dried to obtain chlorination modified graphite；
Chlorination modified graphite is put into ball mill by step 3, and temperature is 10 DEG C, is ground to grain size as 26.5nm, is obtained nanometer
Nano-graphite is put into the olive oil of 5 times of its quality by graphite, and olive oil temperature is 105 DEG C, is sufficiently stirred 30-40 minutes, is filtered
Go out nano-graphite, be drying to obtain modified nano graphite.
Modified Nano kleit preparation method in the present embodiment includes the following steps：
Kaolin is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the bicarbonate that mass fraction is 5%
It in sodium solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Step 2, by dried kaolin in potcal pot calcination, 1100 DEG C, calcination time 1.5h of calcination temperature is taken out and obtains height
Warm modified kaolin；
High temperature modified kaolin is put into ball mill by step 3, and temperature is 10 DEG C, is ground to grain size as 25nm, is obtained nanometer
Nano kaoline is put into the olive oil of 5 times of its quality by kaolin, and olive oil temperature is 105 DEG C, is sufficiently stirred 35 minutes,
Nano kaoline is filtered out, is drying to obtain modified Nano kaolin.
Antioxidant in the present embodiment is antioxidant BHT, and antiwear additive is alkyl zinc dithiophosphate, and corrosion prevention rust preventer is gold
Belong to sulfonate.
Alkylbenzenesulfonate in the present embodiment is alkyl benzene calcium sulfonate, and viscosity modifier is polymethacrylates, table
Face modifying agent is neopelex.
A kind of health-caring equipment preparation method of antioxidant wear-resistant type lubricating oil of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Step 2 by base oil, organic-molybdenum mixture, antioxidant, antiwear additive, corrosion prevention rust preventer, is added sequentially to height in order
It is stirred in fast blender, speed of agitator 1100r/min, mixing time 25min, obtains mixture A, then mixture A is added to
In reaction kettle, 1.5h is reacted at being 155 DEG C in temperature, obtains mixture B；
Step 3 by alkylbenzenesulfonate, viscosity modifier, surface modifier, is added sequentially in homogenizer in order
Stirring, speed of agitator 1100r/min, mixing time 25min obtain mixture C；
Step 4 receives mixture C obtained in mixture B obtained in step 2, step 3, modified nano graphite, modification
Rice kaolin is added in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 700r/min is stirred
25 minutes time, then add mixture in reaction kettle, it is reacted 45 minutes at being 175 DEG C in temperature, the health care of invention is made
Equipment antioxidant wear-resistant type lubricating oil.
Health-caring equipment prepared by embodiment 1 to 3 is as follows with the performance test results of antioxidant wear-resistant type lubricating oil：
| Corrosion degree（%） | Compression strength（MPa） | Antioxygenic property | Anti-friction performance | |
| Embodiment 1 | 36 | 56.8 | It is excellent | It is excellent |
| Embodiment 2 | 35 | 57.6 | It is excellent | It is excellent |
| Embodiment 3 | 38 | 58.6 | It is excellent | It is excellent |
| Technical indicator | 64 | ≥28 | It is qualified | It is qualified |
The object of the present invention is to provide a kind of health-caring equipment antioxidant wear-resistant type lubricating oil, and the lubricating oil is pollution-free, green ring
It protects, efficiently, there is good antirust, wear-resisting, antioxygen property, material cost is relatively low in addition, raw material is easy to get, and has higher use
Value and good application prospect.
It is obvious to a person skilled in the art that the present invention is not limited to the details of above-mentioned exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in each embodiment can also be properly combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (10)
1. a kind of health-caring equipment antioxidant wear-resistant type lubricating oil, which is characterized in that include the raw material of following parts by weight：
48-52 parts of base oil, 26-30 parts of organic-molybdenum mixture, 14-16 parts of modified nano graphite, modified Nano kaolin 10-12
Part, 6-14 parts of antioxidant, 6-10 parts of antiwear additive, 5-9 parts of corrosion prevention rust preventer, 4-8 parts of alkylbenzenesulfonate, viscosity modifier 2-4
Part, 1-3 parts of surface modifier.
A kind of 2. health-caring equipment according to claim 1 antioxidant wear-resistant type lubricating oil, which is characterized in that the health care
Equipment includes the raw material of following parts by weight with antioxidant wear-resistant type lubricating oil：
It is 50 parts of base oil, 28 parts of organic-molybdenum, 15 parts of modified nano graphite, 11 parts of modified Nano kaolin, 10 parts of antioxidant, wear-resistant
8 parts of agent, 7 parts of corrosion prevention rust preventer, 6 parts of alkylbenzenesulfonate, 3 parts of viscosity modifier, 2 parts of surface modifier.
3. a kind of health-caring equipment according to claim 1 or 2 antioxidant wear-resistant type lubricating oil, which is characterized in that described
Base oil is poly alpha olefin (PAO) synthetic oil, and diester, multi-hydroxy ester are added in poly alpha olefin (PAO) synthetic oil.
4. a kind of health-caring equipment according to claim 1 or 2 antioxidant wear-resistant type lubricating oil, which is characterized in that described
Organic-molybdenum mixture is dialkyl dithiophosphoric acid oxygen molybdenum, one or more combinations in molybdenum naphthenate, alkyl salicylate molybdenum
Object.
5. a kind of health-caring equipment according to claim 1 or 2 antioxidant wear-resistant type lubricating oil, which is characterized in that described
The preparation method of modified nano graphite includes the following steps：
Graphite is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the sodium bicarbonate that mass fraction is 5%
It in solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Dried graphite is put into the ferric chloride solution that mass fraction is 10%, 30-40 DEG C of solution temperature, reaction by step 2
Time 20-30 minute, apply the ultrasonic wave of frequency 30KHz, 12h taking-ups are dried to obtain chlorination modified graphite；
Chlorination modified graphite is put into ball mill by step 3, and temperature is -10-20 DEG C, is ground to grain size as 20-33nm, is obtained
Nano-graphite is put into the olive oil of 5 times of its quality by nano-graphite, and olive oil temperature is 100-110 DEG C, is sufficiently stirred 30-
40 minutes, nano-graphite is filtered out, is drying to obtain modified nano graphite.
6. a kind of health-caring equipment according to claim 1 or 2 antioxidant wear-resistant type lubricating oil, which is characterized in that described
Modified Nano kleit preparation method includes the following steps：
Kaolin is put into dilute hydrochloric acid by step 1, and immersion is taken out after twenty minutes, is then placed in the bicarbonate that mass fraction is 5%
It in sodium solution, is taken out after impregnating 15 minutes, drying for standby is rinsed with clear water；
Step 2, by dried kaolin in potcal pot calcination, 1000-1200 DEG C of calcination temperature, calcination time 1-2h takes out
To high temperature modified kaolin；
High temperature modified kaolin is put into ball mill by step 3, and temperature is -10-30 DEG C, is ground to grain size as 20-30nm, is obtained
To nano kaoline, nano kaoline is put into the olive oil of 5 times of its quality, olive oil temperature is 100-110 DEG C, is fully stirred
It mixes 30-40 minutes, filters out nano kaoline, be drying to obtain modified Nano kaolin.
A kind of 7. health-caring equipment according to claim 1 antioxidant wear-resistant type lubricating oil, which is characterized in that the antioxygen
Agent is antioxidant BHT；The antiwear additive is alkyl zinc dithiophosphate；The corrosion prevention rust preventer is metal sulfonate.
A kind of 8. health-caring equipment according to claim 1 antioxidant wear-resistant type lubricating oil, which is characterized in that the alkyl
Benzene sulfonate is alkyl benzene calcium sulfonate；The viscosity modifier is polymethacrylates, one kind in ring-alkylated styrenes or more
The combination of kind；The surface modifier is neopelex, in silane coupling agent, cetyl trimethylammonium bromide
One or more combinations.
9. a kind of prepare such as the method for claim 1-8 any one of them health-caring equipment antioxidant wear-resistant type lubricating oil,
It is characterized in that, includes the following steps：
Step 1 weighs each component raw material as required；
Step 2 by base oil, organic-molybdenum mixture, antioxidant, antiwear additive, corrosion prevention rust preventer, is added sequentially to height in order
It is stirred in fast blender, speed of agitator 1000-1200r/min, mixing time 20-30min, obtains mixture A, then by mixture
A is added in reaction kettle, is reacted 1-2h at being 150-160 DEG C in temperature, is obtained mixture B；
Step 3 by alkylbenzenesulfonate, viscosity modifier, surface modifier, is added sequentially in homogenizer in order
Stirring, speed of agitator 1000-1200r/min, mixing time 20-30min obtain mixture C；
Step 4 receives mixture C obtained in mixture B obtained in step 2, step 3, modified nano graphite, modification
Rice kaolin is added in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 600-800r/min,
Mixing time 20-30 minutes, then add mixture in reaction kettle, it is reacted 40-50 minutes at being 170-180 DEG C in temperature,
The health-caring equipment antioxidant wear-resistant type lubricating oil of invention is made.
10. a kind of preparation method of health-caring equipment antioxidant wear-resistant type lubricating oil according to claim 9, feature exist
In the preparation process is：
Step 1 weighs each component raw material as required；
Step 2 by base oil, organic-molybdenum mixture, antioxidant, antiwear additive, corrosion prevention rust preventer, is added sequentially to height in order
It is stirred in fast blender, speed of agitator 1100r/min, mixing time 25min, obtains mixture A, then mixture A is added to
In reaction kettle, 1.5h is reacted at being 155 DEG C in temperature, obtains mixture B；
Step 3 by alkylbenzenesulfonate, viscosity modifier, surface modifier, is added sequentially in homogenizer in order
Stirring, speed of agitator 1100r/min, mixing time 25min obtain mixture C；
Step 4 receives mixture C obtained in mixture B obtained in step 2, step 3, modified nano graphite, modification
Rice kaolin is added in high-speed mixer, is sufficiently stirred so that all material is uniformly mixed, mixing speed 700r/min is stirred
25 minutes time, then add mixture in reaction kettle, it is reacted 45 minutes at being 175 DEG C in temperature, the health care of invention is made
Equipment antioxidant wear-resistant type lubricating oil.
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| CN116554941A (en) * | 2023-04-23 | 2023-08-08 | 上海奇克氟硅材料有限公司 | Anti-corrosion turbine oil antioxidant, preparation method thereof and lubricating oil |
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