CN108130164A - A kind of novel lubricating ointment - Google Patents

A kind of novel lubricating ointment Download PDF

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Publication number
CN108130164A
CN108130164A CN201711415377.3A CN201711415377A CN108130164A CN 108130164 A CN108130164 A CN 108130164A CN 201711415377 A CN201711415377 A CN 201711415377A CN 108130164 A CN108130164 A CN 108130164A
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parts
base number
sulphur phosphorus
calcium
novel lubricating
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陈兴进
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Jiangsu Kanazawa Heavy Machinery Co Ltd
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Jiangsu Kanazawa Heavy Machinery Co Ltd
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Priority to CN201711415377.3A priority Critical patent/CN108130164A/en
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M167/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/105Silica
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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    • C10M2207/08Aldehydes; Ketones
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/28Amides; Imides
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/061Metal salts
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/36Seal compatibility, e.g. with rubber
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention relates to a kind of novel lubricating ointment, score proportioning by weight is made of following components:23 28 parts of detergent-dispersant additive, 10 20 parts of hydroxyphenylmethyl aldehyde, 13 17 parts of oxidation and corrosion inhibitor, 7 16 parts of polyethylene, 3 11 parts of extreme pressure anti-wear additives, 3 10 parts of silica, 21 25 parts of tackifier, 10 16 parts of diisocyanate, 23 parts of iron oxygroup magnetic fluid, 3 10 parts of polyalkyl methacrylate, 35 67 parts of base oil, 5 10 parts of sorbierite, 23 parts of di-iso-octyldiphenylamine, 28 parts of glyceryl monostearate.The advantage of the invention is that:This kind of lubricating cream stable structure, raw material is cheap and easy to get, and production cost is relatively low, has good high-temperature behavior and wear-resisting property, resistance to frost, viscosity are preferable, and service life is long.

Description

A kind of novel lubricating ointment
Technical field
The present invention relates to field of textile machinery, more particularly to a kind of novel lubricating ointment.
Background technology
Lubricating oil, that is, lubricating grease oiling cream is mainly used for the secondary lubrication of friction and protection, application range:Heavy duty, low speed, Oscillating motion, it is outdoor, work intermittently and adverse circumstances under.Kollag plays primary lubricant in ointment, this and lubrication Base oil plays primary lubricant difference in fat.Soft metal powder in ointment is other than playing lubrication, antifriction function, also It can play the role of heat absorption, a large amount of heat be absorbed under the high temperature conditions, when soft metal is melted, so being capable of high temperature resistant.
Invention content
The technical problem to be solved in the present invention is to provide a kind of novel lubricating ointment, have good adhesiveness high heat stability Property;Good leakproofness;High-voltage load, while there is good high heat stability performance;Excellent greasy property.
In order to solve the above technical problems, the technical scheme is that:A kind of novel lubricating ointment, innovative point are: Score proportioning by weight is made of following components:
23-28 parts of detergent-dispersant additive, 10-20 parts of hydroxyphenylmethyl aldehyde, 13-17 parts of oxidation and corrosion inhibitor, 7-16 parts of polyethylene, pole Press 3-11 parts of antiwear additive, 3-10 parts of silica, 21-25 parts of tackifier, 10-16 parts of diisocyanate, iron oxygroup magnetic fluid 2-3 Part, 3-10 parts of polyalkyl methacrylate, 35-67 parts of base oil, 5-10 parts of sorbierite, 2-3 parts of di-iso-octyldiphenylamine, firmly 2-8 parts of resin acid monoglyceride.
Further, the detergent-dispersant additive is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene synthesizes Sulfoacid calcium, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene High base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutenyl succinyl Imines, high molecular weight polyisobutylene base succimide, one kind in boronation high molecular weight polyisobutylene base succimide or More than one mixing of person.
Further, the oxidation and corrosion inhibitor is the pungent primary alkyl zinc salt of sulphur phosphorus fourth, sulphur phosphorus double pungent primary alkyl zinc salt, alkali formula sulphur It is one or more than one kinds of in phosphorus double pungent primary alkyl zinc salt, the pungent secondary primary alkyl zinc salt of sulphur phosphorus third, sulphur phosphorus brothers alkyl zinc salts Mixing.
Further, the extreme pressure anti-wear additives are olefine sulfide, phosphate or nitride.
Further, the tackifier be polyvinyl n-butyl ether, it is polymethacrylates, polyacrylate, poly- different One or more kinds of mixing in butylene, random polypropylene, ethylene-propylene copolymer, butadiene rubber.
The advantage of the invention is that:This kind of lubricating cream stable structure, raw material is cheap and easy to get, and production cost is relatively low, has Good high-temperature behavior and wear-resisting property, resistance to frost, viscosity are preferable, and service life is long.
Lubricating oil of the present invention is arranged in pairs or groups by multiple additives common combination, substantially improves the performance of lubricating oil various aspects, is increased Add lubrication oil-proofness, enhance lubricant effect, extend the service life of lubricating oil, this lubricating oil can be widely applied to mechanical profit It is sliding, machinery, and energy-saving consumption-reducing can be protected well, therefore are with a wide range of applications.
Specific embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this It is bright to be limited among the embodiment described range.
Embodiment 1
The novel lubricating ointment parts by weights number proportioning of the present invention is made of following components:
Score proportioning by weight is made of following components:
23 parts of detergent-dispersant additive, 10 parts of hydroxyphenylmethyl aldehyde, 13 parts of oxidation and corrosion inhibitor, 7 parts of polyethylene, 3 parts of extreme pressure anti-wear additives, 3 parts of silica, 21 parts of tackifier, 10 parts of diisocyanate, 2 parts of iron oxygroup magnetic fluid, 3 parts of polyalkyl methacrylate, 35 parts of base oil, 5 parts of sorbierite, 2 parts of di-iso-octyldiphenylamine, 2 parts of glyceryl monostearate.
In above-mentioned formula, detergent-dispersant additive is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene synthesizes Sulfoacid calcium, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene High base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutenyl succinyl Imines, high molecular weight polyisobutylene base succimide, one kind in boronation high molecular weight polyisobutylene base succimide or More than one mixing of person;Oxidation and corrosion inhibitor is the pungent primary alkyl zinc salt of sulphur phosphorus fourth, the double pungent primary alkyl zinc salts of sulphur phosphorus, alkali formula sulphur phosphorus pair One or more than one kinds of mixing in the pungent secondary primary alkyl zinc salt of pungent primary alkyl zinc salt, sulphur phosphorus third, sulphur phosphorus brothers alkyl zinc salt; Extreme pressure anti-wear additives are olefine sulfide, phosphate or nitride;Tackifier for polyvinyl n-butyl ether, polymethacrylates, One or more kinds of mixing in polyacrylate, polyisobutene, random polypropylene, ethylene-propylene copolymer, butadiene rubber.
Embodiment 2
The novel lubricating ointment parts by weights number proportioning of the present invention is made of following components:
Score proportioning by weight is made of following components:
28 parts of detergent-dispersant additive, 20 parts of hydroxyphenylmethyl aldehyde, 17 parts of oxidation and corrosion inhibitor, 16 parts of polyethylene, extreme pressure anti-wear additives 11 Part, 0 part of silica 1,25 parts of tackifier, 16 parts of diisocyanate, 3 parts of iron oxygroup magnetic fluid, polyalkyl methacrylate 10 parts, 67 parts of base oil, 10 parts of sorbierite, 3 parts of di-iso-octyldiphenylamine, 8 parts of glyceryl monostearate.
In above-mentioned formula, detergent-dispersant additive is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene synthesizes Sulfoacid calcium, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene High base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutenyl succinyl Imines, high molecular weight polyisobutylene base succimide, one kind in boronation high molecular weight polyisobutylene base succimide or More than one mixing of person;Oxidation and corrosion inhibitor is the pungent primary alkyl zinc salt of sulphur phosphorus fourth, the double pungent primary alkyl zinc salts of sulphur phosphorus, alkali formula sulphur phosphorus pair One or more than one kinds of mixing in the pungent secondary primary alkyl zinc salt of pungent primary alkyl zinc salt, sulphur phosphorus third, sulphur phosphorus brothers alkyl zinc salt; Extreme pressure anti-wear additives are olefine sulfide, phosphate or nitride;Tackifier for polyvinyl n-butyl ether, polymethacrylates, One or more kinds of mixing in polyacrylate, polyisobutene, random polypropylene, ethylene-propylene copolymer, butadiene rubber.
Embodiment 3
The novel lubricating ointment parts by weights number proportioning of the present invention is made of following components:
Score proportioning by weight is made of following components:
25 parts of detergent-dispersant additive, 15 parts of hydroxyphenylmethyl aldehyde, 15 parts of oxidation and corrosion inhibitor, 11 parts of polyethylene, extreme pressure anti-wear additives 7 Part, 6 parts of silica, 23 parts of tackifier, 13 parts of diisocyanate, 2 parts of iron oxygroup magnetic fluid, polyalkyl methacrylate 6 Part, 51 parts of base oil, 8 parts of sorbierite, 2 parts of di-iso-octyldiphenylamine, 5 parts of glyceryl monostearate.
In above-mentioned formula, detergent-dispersant additive is low alkali value synthesized calcium alkyl benzene sulfonate, high base number linear alkyl benzene synthesizes Sulfoacid calcium, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number synthesis dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene High base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutylene succinamide, boronation polyisobutenyl succinyl Imines, high molecular weight polyisobutylene base succimide, one kind in boronation high molecular weight polyisobutylene base succimide or More than one mixing of person;Oxidation and corrosion inhibitor is the pungent primary alkyl zinc salt of sulphur phosphorus fourth, the double pungent primary alkyl zinc salts of sulphur phosphorus, alkali formula sulphur phosphorus pair One or more than one kinds of mixing in the pungent secondary primary alkyl zinc salt of pungent primary alkyl zinc salt, sulphur phosphorus third, sulphur phosphorus brothers alkyl zinc salt; Extreme pressure anti-wear additives are olefine sulfide, phosphate or nitride;Tackifier for polyvinyl n-butyl ether, polymethacrylates, One or more kinds of mixing in polyacrylate, polyisobutene, random polypropylene, ethylene-propylene copolymer, butadiene rubber.
Lubricating oil of the present invention is arranged in pairs or groups by multiple additives common combination, substantially improves the performance of lubricating oil various aspects, is increased Add lubrication oil-proofness, enhance lubricant effect, extend the service life of lubricating oil, this lubricating oil can be widely applied to mechanical profit It is sliding, machinery, and energy-saving consumption-reducing can be protected well, therefore are with a wide range of applications.
This kind of lubricating cream stable structure, raw material is cheap and easy to get, and production cost is relatively low, has good high-temperature behavior and resistance to Performance is ground, resistance to frost, viscosity are preferable, and service life is long.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention It is defined by the appending claims and its equivalent thereof.

Claims (5)

1. a kind of novel lubricating ointment, it is characterised in that:Score proportioning by weight is made of following components:
23-28 parts of detergent-dispersant additive, 10-20 parts of hydroxyphenylmethyl aldehyde, 13-17 parts of oxidation and corrosion inhibitor, 7-16 parts of polyethylene, pole Press 3-11 parts of antiwear additive, 3-10 parts of silica, 21-25 parts of tackifier, 10-16 parts of diisocyanate, iron oxygroup magnetic fluid 2-3 Part, 3-10 parts of polyalkyl methacrylate, 35-67 parts of base oil, 5-10 parts of sorbierite, 2-3 parts of di-iso-octyldiphenylamine, firmly 2-8 parts of resin acid monoglyceride.
2. novel lubricating ointment according to claim 1, it is characterised in that:The detergent-dispersant additive synthesizes alkane for low alkali value Base benzene sulfonic acid calcium, high base number linear alkyl benzene calcium alkylbenzenesulfonate, long-chain linear alkyl benzene high base number calcium alkylbenzenesulfonate, high base number close Into dialkyl benzene sulfonic acids calcium, long-chain linear alkyl benzene high base number synthesis sulfonic acid magnesium, SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER, polyisobutenyl Succimide, boronation polyisobutylene succinamide, high molecular weight polyisobutylene base succimide, boronation high molecular weight One or more than one kinds of mixing in polyisobutylene succinamide.
3. novel lubricating ointment according to claim 1, it is characterised in that:The oxidation and corrosion inhibitor is sulphur phosphorus Ding Xinbai alkane The double pungent primary alkyl zinc salts of base zinc salt, sulphur phosphorus, alkali formula sulphur phosphorus double pungent primary alkyl zinc salt, the pungent secondary primary alkyl zinc salt of sulphur phosphorus third, sulphur phosphorus primary One or more than one kinds of mixing in secondary alkyl zinc salt.
4. novel lubricating ointment according to claim 1, it is characterised in that:The extreme pressure anti-wear additives are olefine sulfide, phosphorus Acid esters or nitride.
5. novel lubricating ointment according to claim 1, it is characterised in that:The tackifier are polyvinyl normal-butyl One kind in ether, polymethacrylates, polyacrylate, polyisobutene, random polypropylene, ethylene-propylene copolymer, butadiene rubber Or more than one mixing.
CN201711415377.3A 2017-12-25 2017-12-25 A kind of novel lubricating ointment Pending CN108130164A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040743A (en) * 2019-12-23 2020-04-21 中国石油集团渤海钻探工程有限公司 Comb-shaped polyurethane lubricant and water-based drilling fluid

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CN104031722A (en) * 2014-05-22 2014-09-10 丘寿勇 Lubricating oil
CN104449970A (en) * 2014-11-15 2015-03-25 柳州市莫尔斯汽配制造有限公司 Lubricating oil
CN107083267A (en) * 2017-05-08 2017-08-22 安徽晶鹏智能装备科技有限公司 A kind of lubricating cream
CN107474905A (en) * 2017-08-30 2017-12-15 南通润德机械科技有限公司 A kind of modified extruder lubricating oil

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Publication number Priority date Publication date Assignee Title
CN104031722A (en) * 2014-05-22 2014-09-10 丘寿勇 Lubricating oil
CN104449970A (en) * 2014-11-15 2015-03-25 柳州市莫尔斯汽配制造有限公司 Lubricating oil
CN107083267A (en) * 2017-05-08 2017-08-22 安徽晶鹏智能装备科技有限公司 A kind of lubricating cream
CN107474905A (en) * 2017-08-30 2017-12-15 南通润德机械科技有限公司 A kind of modified extruder lubricating oil

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040743A (en) * 2019-12-23 2020-04-21 中国石油集团渤海钻探工程有限公司 Comb-shaped polyurethane lubricant and water-based drilling fluid

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