CN108129971A - A kind of anti-scraping coating of environmental protection resistance and fingerprint resistance and its application method - Google Patents
A kind of anti-scraping coating of environmental protection resistance and fingerprint resistance and its application method Download PDFInfo
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- CN108129971A CN108129971A CN201711447912.3A CN201711447912A CN108129971A CN 108129971 A CN108129971 A CN 108129971A CN 201711447912 A CN201711447912 A CN 201711447912A CN 108129971 A CN108129971 A CN 108129971A
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- Prior art keywords
- resistance
- coating
- scraping
- fingerprint
- environmental protection
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- 238000000576 coating method Methods 0.000 title claims abstract description 85
- 239000011248 coating agent Substances 0.000 title claims abstract description 79
- 238000007790 scraping Methods 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 17
- 230000007613 environmental effect Effects 0.000 title claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229920002635 polyurethane Polymers 0.000 claims abstract description 32
- 239000004814 polyurethane Substances 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 15
- 239000006184 cosolvent Substances 0.000 claims abstract description 15
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 15
- -1 vinyl compound Chemical class 0.000 claims description 30
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 125000005670 ethenylalkyl group Chemical group 0.000 claims description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 6
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 4
- 239000004005 microsphere Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- NBKXIQAGLFPJCA-UHFFFAOYSA-N 1-butoxypropyl acetate Chemical compound CCCCOC(CC)OC(C)=O NBKXIQAGLFPJCA-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical group [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000005052 trichlorosilane Substances 0.000 claims description 3
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical class CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 claims description 2
- OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical class CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 150000001345 alkine derivatives Chemical class 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 235000011114 ammonium hydroxide Nutrition 0.000 claims 1
- 150000002009 diols Chemical class 0.000 claims 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 238000007639 printing Methods 0.000 abstract description 11
- 230000003678 scratch resistant effect Effects 0.000 abstract description 10
- 230000035699 permeability Effects 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 abstract description 3
- 239000002985 plastic film Substances 0.000 abstract 1
- 229920006255 plastic film Polymers 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 6
- 229920006267 polyester film Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 238000007761 roller coating Methods 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000004417 polycarbonate Substances 0.000 description 5
- 229920003009 polyurethane dispersion Polymers 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 229920006289 polycarbonate film Polymers 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 150000002222 fluorine compounds Chemical class 0.000 description 3
- 238000007373 indentation Methods 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910002808 Si–O–Si Inorganic materials 0.000 description 2
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 2
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 230000002500 effect on skin Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 235000021588 free fatty acids Nutrition 0.000 description 2
- 231100000734 genotoxic potential Toxicity 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000011806 microball Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229940031439 squalene Drugs 0.000 description 2
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000007774 anilox coating Methods 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000004643 cyanate ester Substances 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 150000003728 wax monoesters Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1681—Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of anti-scraping coating of environmental protection resistance and fingerprint resistance and its application methods.The anti-scraping coating of the environmental protection resistance and fingerprint resistance includes following component by mass percentage：Aqueous polyurethane 5~90%, organosilicon-modified acrylic 5~90%, pH adjusting agent 0.1~1%, moistening flatting agent 0.1~0.8%, antifoaming agent 0.1~1%, curing agent 1~5%, cosolvent 1~40%.The coating of the present invention has the advantages that fluorin environment protection, surface gloss are low, permeability is excellent, anti-finger printing and scratch resistant property are good, simple for process, widely applicable to plastic film substrate.
Description
Technical field
The present invention relates to coatings art more particularly to a kind of anti-scraping coating of environmentally friendly resistance and fingerprint resistance and its application methods.
Background technology
Consumer often leaves the spots such as fingerprint and slight scratch, seriously when buying contact product in packaging
Product appearance is affected, is upgraded with universal and China the consumption of 3C electronic products, industry carries the packaging material of product
Go out the performance requirements such as higher resistance and fingerprint resistance, scratch resistant.The anti-scraping coating of resistance and fingerprint resistance is the coating that a kind of organic polymer is composed, main
Possess the characteristics such as hydrophobic, oleophobic, scratch resistance.At present, anti-finger printing can be realized mainly by two ways：First, using low table
Face can chemical material, it is classic for organic fluoride class substance at present, but in system fluorine component genotoxic potential and expensive price
Its application in commodity packaging is seriously affected.2nd, using physical arrangement, lotus leaf effect is imitated, but this structure is often
The problems such as in the presence of processing difficulties, shortage durability degree and the bad transparency is manufactured.In recent years, single-component water-based polyurethane is from delustring tree
Fat is due to properties such as excellent dumb lights and permeability, starting to be paid close attention to by coating circle.It is but aqueous from delustring tree at present
The defects of fat generally existing film forming is insufficient, resistance to scraping is poor.
Invention content
Based on this, the object of the present invention is to provide a kind of anti-scraping coatings of environmentally friendly resistance and fingerprint resistance, are imitated with good dumb light
Fruit, permeability, anti-finger printing and scratch resistant property.
Another object of the present invention is to provide a kind of application methods of the anti-scraping coating of environmentally friendly resistance and fingerprint resistance, have simple
It is easy, adhesion is good, applicability is wide on all kinds of base materials the advantages of.
The purpose of the present invention is what is be achieved through the following technical solutions：The anti-scraping coating of a kind of environmental protection resistance and fingerprint resistance, by quality hundred
Divide and include following component than meter：Aqueous polyurethane 5~90%, organosilicon-modified acrylic 5~90%, pH adjusting agent 0.1~
1%, moistening flatting agent 0.1~0.8%, antifoaming agent 0.1~1%, curing agent 1~5%, cosolvent 1~40%.
The main component of finger sweat is water, accounts for about the 98% of total ingredient, finger sweat further include a small amount of urea and
Grease accounts for about the 1~2% of total ingredient.Wherein, lubricant component is mainly by 40% triglyceride (triglycerides), 25%
Monoester wax (wax monoesters), 15% free fatty acids (free fatty acids), 12% squalene (squalene) and
7% other materials form, these are all very easy in product surface fingerprints trace, must in order to achieve the purpose that resistance and fingerprint resistance
It must make product surface that there is hydrophobic, oleophobic.
The surface of product surface can be the key factor for determining resistance and fingerprint resistance, and the surface of water can (γw) it is 72mN/m, it is most of
It the surface of grease can (γl) in 20~40mN/m, when the surface of the product of preparation can (γa) less than the surface energy (γ of sweats)
When, the sweat of finger surface is just not easy to be attached to product surface, so as to achieve the effect that resistance and fingerprint resistance.Currently used low-surface-energy
Material is organosilicon, organic fluoride class.The surface of organic fluoride class substance-CF3 groups can as low as 10mN/m, be current minimum surface energy
Resistance and fingerprint resistance material, but the genotoxic potential of fluorine component and expensive price have seriously affected it in commodity packaging in system
Using.Organic siliconresin is containing the high polymer that organic group is connected on Si-O-Si structures, silicon atom, silicon atom in strand
Electronegativity is relatively low, and Si-O-Si bond energys, bond angle are bigger than C-C key, and strand compliance is high, and this special valence bond structure makes it
With many excellent physics for being different from carbon-based polymer, chemical property, such as high temperature resistant, wear-resisting, corrosion-resistant, surface can it is small,
The features such as film forming ability is strong, organosilicon-modified acrylic film coated surface can be about 23mN/m, and there is no poison for organic silicon substance
The release loss problem of object, has good anti-fouling effect.
For a hydrophobic surface of solids, product surface and water contact angle not only with surface energy it is related also and table
Surface roughness is related, when there is microspike on surface, has some air between water and the surface of solids, to be caused by " pass is arrived "
Small water droplet is largely contacted with air, and be in direct contact area with solid greatly reduces instead, since the surface tension effects of water make
Water is shunk in this rough surface, and such surface is just provided with the ability of anti-pollution.On the surface of material after aqueous polyurethane film forming
It with concave-convex alternate micro-sphere structure, can make incident light that diffusing reflection occur, so as to achieve the effect that from delustring, and study hair
It is existing, when the depth at surface indentation position is relatively larger than the height of finger dermal papilla streakline, finger contact coating surface phase interaction
Used time can only leave less clearly fingerprint form at surface indentation position, weaken the trace and retention time of fingerprint significantly.
Relative to the prior art, the present invention is combined using organosilicon-modified acrylic with aqueous polyurethane component, makes low table
Face energy organosilicon-modified acrylic is evenly coated at aqueous polyurethane microsphere surface by chemical crosslinking, so as to gather low-surface-energy
It closes the chemical anti-pollution effect of object and the physics anti-pollution effect of concaveconvex structure plays mutually synergistic effect, and coordinates pH adjusting agent, wetting
Levelling agent, antifoaming agent, curing agent and co-solvent component rationally adjust each group distribution ratio, so as to keep coating good print
While, make coating that there are good permeability (light transmittance is more than 90%), good matte effect (60 ° of lower glossiness ＜
2.5), good scratch resistant property (after rubbing 1000 times under 1000g weights pressure, the variation of only slight glossiness,
60 ° of lower glossiness variations<0.5, and scratch completely disappears after a period of time) and good anti-finger printing.
Further, the anti-scraping coating of the environmentally friendly resistance and fingerprint resistance includes following component by mass percentage：Aqueous polyurethane
50~90%, organosilicon-modified acrylic 5~40%, pH adjusting agent 0.1~1%, moistening flatting agent 0.5~0.8%, antifoaming agent
0.4~0.8%, curing agent 1~5%, cosolvent 2~40%.
Further, the polyaminoester microball grain size in the aqueous polyurethane is 700nm~10 μm.Preferably, the water
Property polyurethane be the aqueous polyurethane dispersion, in the particle size range, aqueous polyurethane dispersion film forming after in material
Surface has concave-convex alternate micron-nanometer micro-sphere structure, makes the depth at surface indentation position relatively larger than finger dermal papilla
The height of streakline so as to weaken the fingerprint trace left during finger contact coating surface, improves the anti-finger printing of coating.
Further, the aqueous polyurethane is polycarbonate polyurethane or the one or two of polyester polyurethane.
Preferably, the polycarbonate polyurethane is fatty poly-ester carbonate type polyurethane.Fatty poly-ester carbonate or polyester molecule
Structure assigns excellent wear-resisting, the suitable hardness of coating and good permeability.Compared with other polyurethane from delustring, poly- carbonic acid
Containing-[O-R-O-CO]-structure in the strand of ester structure, penylene base, ester group in strand make strand belong to rigid chain,
Glass transition temperature (Tg) 150 DEG C are up to, make it have excellent mechanical property, while urea groups in polyurethane structural (-
NHCONH-, cohesive energy ＞ 36.5kJ/mol) and carbamate groups (- NHCOO-, cohesive energy 36.4kJ/mol) cohesive energy
Height is not easily broken after film forming, good with base material adhesive force, and the coating so as to be formed has excellent wearability and resistance to scraping.
Further, 10 DEG C of the minimum film formation temperature ＜ of the organosilicon-modified acrylic, glass transition temperature ＜ 10
℃.Preferably, the organosilicon-modified acrylic is organosilicon-modified acrylic emulsion.
Further, the organosilicon-modified acrylic is organic-silicon-modified self-crosslinking acrylic.Self-crosslinking acrylic into
The acrylic acid of reticular structure can be voluntarily cross-linked into during film between polymer chain, the mechanical strength of polymer can be improved.
Further, the organosilicon modifier in the organosilicon-modified acrylic is siliceous vinyl compound, is wrapped
Include vinyl alkyl trichlorosilane, vinyl alkyl methoxy silane, vinyl alkyl Ethoxysilane, the third oxygen of vinyl alkyl
One or more of base silane, vinyl alkyl polysiloxanes.Siliceous vinyl compound passes through free radical as modifying agent
In polymerization methods access self-crosslinking acrylic Type of Collective object, enable polymer that there is relatively low surface.
Further, the pH adjusting agent be ammonium hydroxide, triethylamine, triethanolamine, N, in N- dimethylethanolamines, AMP-95
It is one or more.The AMP-95 is the 2-amino-2-methyl-1-propanol containing 5% moisture.Using above-mentioned substance conduct
PH adjusting agent can adjust the acidity of coating, and act synergistically with aqueous polyurethane and organosilicon-modified acrylic, improve coating
Viscosity and film forming.
Further, the moistening flatting agent for organosilicon compound, one kind in acetylenic glycols ethoxy compound or
Two kinds.Using above-mentioned substance as moistening flatting agent, the surface tension of coating can be reduced, and with aqueous polyurethane and organosilicon
Modified acroleic acid acts synergistically, and improves the flatness and uniformity of coating.
Further, the antifoaming agent is one or both of organosilicon compound, acetylenic glycols ethoxy compound.
Using above-mentioned substance as antifoaming agent, the surface tension of coating can be reduced, foam is inhibited to generate, and with aqueous polyurethane and having
Machine fluorine-silicon modified acrylic acts synergistically, and improves the flatness and uniformity of coating.
Further, the curing agent be to carboxyl, hydroxyl, ketone carbonyl chemically reactive compound, including different
It is one or more in cyanate esters, adipic dihydrazide, aziridine cpd, carbodiimide compound.Using above-mentioned
Substance can promote polymerisation, and act synergistically with aqueous polyurethane and organosilicon-modified acrylic, improve and apply as curing agent
The hardness and adhesive force of layer.
Further, the cosolvent includes ethyl alcohol, ethylene glycol, isopropanol, N-Methyl pyrrolidone, N- N-ethyl pyrrole Ns
Alkanone, butyl glycol ether, butyl, propandiol butyl ether acetate, diethylene glycol ether, diethylene glycol ether acetate
In it is one or more.Using above-mentioned substance as cosolvent, act synergistically with aqueous polyurethane and organosilicon-modified acrylic,
Improve solubility.
The present invention also provides a kind of application methods of the anti-scraping coating of environmentally friendly resistance and fingerprint resistance, include the following steps：
S1：Each component is mixed according to mass percent of the present invention, is configured to coating aqueous dispersion；
S2：By the coating aqueous dispersion to base material；
S3：To being applied to the coating after base material into the preliminary drying that trip temperature is 60~110 DEG C, the time is 40s~5min；
S4：To pre-baked coating into trip temperature be 45~130 DEG C, the time be 1h~5d curing, so as to obtain environmental protection
Resistance and fingerprint resistance preventing from scraping film.
Relative to the prior art, coating of the invention meets the ripe industrialization process such as traditional roller coating, spraying, blade coating,
Application method is simple and practicable；Also, the coating of the present invention is suitable for polypropylene film (PP), polyester film (PET), polyvinyl chloride
A variety of film substrates such as film (PVC), polycarbonate film (PC), are respectively provided with good adhesion on all kinds of base materials, are applicable in
Property it is wide, have stronger practicability and commercial promise；In addition, the coating of the present invention is floride-free, non-volatility organic matter (VOC) discharge,
Free from extraneous odour generates, environmentally protective.
In order to better understand and implement, the invention will now be described in detail with reference to the accompanying drawings.
Description of the drawings
Fig. 1 is the structure diagram of environmentally friendly resistance and fingerprint resistance preventing from scraping film prepared by the present invention.
Fig. 2 is environmentally friendly resistance and fingerprint resistance preventing from scraping film and the anti-finger printing contrast test figure of common Matte film prepared by embodiment 1.
Specific embodiment
The anti-scraping coating of environmentally friendly resistance and fingerprint resistance of the present invention, by mass percentage including following component：Aqueous polyurethane 5~
90%, organosilicon-modified acrylic 5~90%, pH adjusting agent 0.1~1%, moistening flatting agent 0.1~0.8%, antifoaming agent 0.1
~1%, curing agent 1~5%, cosolvent 1~40%.
As what is advanced optimized, the anti-scraping coating of the environmental protection resistance and fingerprint resistance includes following component by mass percentage：Water
Property polyurethane 50~90%, organosilicon-modified acrylic 5~40%, pH adjusting agent 0.1~1%, moistening flatting agent 0.5~
0.8%, antifoaming agent 0.4~0.8%, curing agent 1~5%, cosolvent 2~40%.
Specifically, the aqueous polyurethane is aqueous from delustring dispersions of polyurethanes, preferably fatty poly-ester carbonate type
The one or two of polyurethane or polyester polyurethane, polyaminoester microball grain size therein are 700nm~10 μm.
Specifically, the organosilicon-modified acrylic be organosilicon-modified acrylic emulsion, preferably it is organic-silicon-modified from
Crosslinking acrylic acid emulsion, 10 DEG C of 10 DEG C of minimum film formation temperature ＜, glass transition temperature ＜, organosilicon modifier therein are
Siliceous vinyl compound, including vinyl alkyl trichlorosilane, vinyl alkyl methoxy silane, vinyl alkyl ethyoxyl
It is one or more in silane, vinyl alkyl npropoxysilane, vinyl alkyl polysiloxanes.
Specifically, the pH adjusting agent is ammonium hydroxide, triethylamine, triethanolamine, N, in N- dimethylethanolamines, AMP-95
It is one or more of.The moistening flatting agent is one or both of organosilicon compound, acetylenic glycols ethoxy compound.Institute
Antifoaming agent is stated as one or both of organosilicon compound, acetylenic glycols ethoxy compound.The curing agent is to carboxylic
Base, hydroxyl, ketone carbonyl chemically reactive compound, including isocyanate compound, adipic dihydrazide, aziridine chemical combination
It is one or more in object, carbodiimide compound.The cosolvent includes ethyl alcohol, ethylene glycol, isopropanol, N- methylpyrroles
Alkanone, N- ethyl pyrrolidones, butyl glycol ether, butyl, propandiol butyl ether acetate, diethylene glycol ether, two
It is one or more in ethylene glycol ether acetate.
A kind of application method of the anti-scraping coating of environmentally friendly resistance and fingerprint resistance of the present invention, includes the following steps：
(1) each component of coating is mixed according to mass percent of the present invention, is configured to coating aqueous dispersion.Tool
Body, each component of coating according to aqueous polyurethane, organosilicon-modified acrylic, pH adjusting agent, moistening flatting agent, antifoaming agent,
The order addition mixing of curing agent, cosolvent.
(2) by coating aqueous dispersion obtained by step (1) to base material.Specifically, using roller coating technology by the coating
Aqueous dispersion is transferred to base material, and wherein applicator roll is the steel anilox roll of chrome-faced, in base material PP, PET, PVC, PC film
It is a kind of.
(3) to being applied to the coating after base material into the preliminary drying that trip temperature is 60~110 DEG C, the time is 40s~5min.
(4) it is 45~130 DEG C into trip temperature to the coating after preliminary drying surface drying, the time is the curing of 1h~5d, so as to be crosslinked
Film forming obtains environmentally friendly resistance and fingerprint resistance preventing from scraping film.
Referring to Fig. 1, it is the structure diagram of environmentally friendly resistance and fingerprint resistance preventing from scraping film of the invention prepared, including base material 1 and apply
The anti-scraping coating 2 of environmentally friendly resistance and fingerprint resistance being distributed on base material 1.
With reference to embodiment, test and attached drawing, the present invention is described in further detail, but the embodiment party of the present invention
Formula is without being limited thereto.
Embodiment 1
Under the mixing speed of 600~1000rpm, by following mass fraction, each component sequentially adds, resistance to produced environment friendly
The anti-scraping coating aqueous dispersion of fingerprint：67 parts of aqueous polyurethane dispersion, 20 parts of organosilicon-modified acrylic emulsion, pH adjusting agent
0.5 part, 0.8 part of moistening flatting agent, 0.7 part of antifoaming agent, 2.2 parts of curing agent, 10 parts of cosolvent.
Using the method for scraper roller coating by the anti-scraping coating aqueous dispersion of the environmentally friendly resistance and fingerprint resistance of above-mentioned preparation in two-way drawing
Polypropylene stretched film (BOPP) surface；Preliminary drying is carried out to being applied to the coating after BOPP, preliminary drying temperature is 70 DEG C, time 60s；
Coating after preliminary drying surface drying is cured, curing temperature is 50 DEG C, time 2d, forms environmentally friendly resistance and fingerprint resistance preventing from scraping film.
Embodiment 2
Under the mixing speed of 800~1000rpm, by following mass fraction, each component sequentially adds, resistance to produced environment friendly
The anti-scraping coating aqueous dispersion of fingerprint：70 parts of aqueous polyurethane dispersion, 15 parts of organosilicon-modified acrylic emulsion, pH adjusting agent
0.3 part, 0.8 part of moistening flatting agent, 0.4 part of antifoaming agent, 2.5 parts of curing agent, 6 parts of cosolvent.
Using the method for scraper roller coating by the anti-scraping coating aqueous dispersion of the environmentally friendly resistance and fingerprint resistance of above-mentioned preparation in two-way drawing
Stretched polyester film (BOPET) surface；Preliminary drying is carried out to being applied to the coating after BOPET, preliminary drying temperature is 110 DEG C, and the time is
40s；Coating after preliminary drying surface drying is cured, curing temperature is 60 DEG C, time 1d, forms environmentally friendly resistance and fingerprint resistance preventing from scraping film.
Embodiment 3
Under the mixing speed of 700~800rpm, by following mass fraction, each component sequentially adds, resistance to produced environment friendly
The anti-scraping coating aqueous dispersion of fingerprint：75 parts of aqueous polyurethane dispersion, 15 parts of organosilicon-modified acrylic emulsion, pH adjusting agent
0.4 part, 0.9 part of moistening flatting agent, 0.8 part of antifoaming agent, 2.7 parts of curing agent, 6 parts of cosolvent.
Using the method for scraper roller coating by the anti-scraping coating aqueous dispersion of the environmentally friendly resistance and fingerprint resistance of above-mentioned preparation in two-way drawing
Stretched polyester film (BOPET) surface；Preliminary drying is carried out to being applied to the coating after BOPET, preliminary drying temperature is 100 DEG C, and the time is
50s；Coating after preliminary drying surface drying is cured, curing temperature is 45 DEG C, time 2d, forms environmentally friendly resistance and fingerprint resistance preventing from scraping film.
Test
The anti-scraping coating of environmentally friendly resistance and fingerprint resistance of embodiment 1-3 is tested for the property, test result is as shown in table 1.
The performance test results of the anti-scraping coating of environmentally friendly resistance and fingerprint resistance of 1 embodiment 1-3 of table
| Test event | Standard | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Viscosity (mPas) | - | 380 | 365 | 385 |
| Solid content (%) | GB/T 1725 | 31 | 30 | 30 |
| pH | GB/T 8325 | 8.0 | 8.5 | 8.0 |
The environmentally friendly resistance and fingerprint resistance preventing from scraping film of embodiment 1-3 is tested for the property, test result is as shown in table 2.
The performance test results of the environmentally friendly resistance and fingerprint resistance preventing from scraping film of 2 embodiment 1-3 of table
| Test event | Standard | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Light transmittance (%) | GB/T2410 | 90.0 | 90.5 | 90.1 |
| Mist degree (%) | GB/T2410 | 85.0 | 86.1 | 85.1 |
| Glossiness (60 °) | GB/T8807 | 1.9 | 2.0 | 1.7 |
| Scratch resistant property (secondary/1000g) | - | 1000 | 1000 | 1000 |
Wherein, scratch resistant property, which is tested, is specially：It, will with self-locking band using ZJ-339 type rubber alcohol abrasion-resistant testing machines
Four layers of non-dust cloth are fixed on one section of a diameter of 10mm of friction hammer, with the speed of about 30mm/s in scratch resistant film surface the same area
Linear reciprocation friction, and be primary back and forth with one, rub 1000 later preventing from scraping film tables under 1000g weights pressure
Face only has slight glossiness variation, and (60 °, glossiness changes<0.5), and after being placed at room temperature for 5h scratch completely disappears, and illustrates this
Coating prepared by invention has excellent scratch resistant property.
Other performance test of the present invention is carried out according to country or professional standard.From the test result in table as it can be seen that this hair
Bright environmentally friendly resistance and fingerprint resistance preventing from scraping film also has good permeability (light transmittance is more than 90%) and good matte effect (under 60 °
Glossiness ＜ 2.5).
In addition, the environmentally friendly resistance and fingerprint resistance preventing from scraping film to embodiment 1 carries out anti-finger printing test, fingerprint liquid is pressed on finger
Film surface, and visual evaluation is done, test result is as shown in Figure 2.Wherein, A is state of the fingerprint in common dumb light film surface, and B is
Fingerprint is in the state of the film surface of the embodiment of the present invention 1, it is seen then that compared to normal film, stays in the film surface of the embodiment of the present invention 1
Fingerprint trace it is very shallow, illustrate that the coating for preparing of the present invention has good anti-finger printing.
Relative to the prior art, the invention has the advantages that：(1) present invention incorporates low surface energy polymerics
Chemical anti-pollution effect and the physics anti-pollution effect of micro/nano level concaveconvex structure, while coating good print is kept, make it
With excellent anti-finger printing and scratch resistant property.(2) the present invention overcomes surface roughness cause coating permeability problem, really
The printed matter protected after packaging fitting has no blind spot loss, and color rendition degree is good, while matte effect, good anti-finger printing and excellent
Scratch resistant property make coating high-grade packages printing coatings art have certain application prospect.(3) coating of the invention has water
Property, floride-free, VOC free discharge, no any peculiar smell generates, it is environmentally protective the advantages of.(4) coating of the invention meet traditional roller coating,
The ripe industrialization process such as spraying, blade coating, application method is simple and practicable, and the coating of the present invention can be used for PP, PET, PVC,
More kinds of film substrates of PC, are respectively provided with good adhesion, applicability is wide on all kinds of base materials.
Embodiment described above only expresses the several embodiments of the present invention, and description is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that those of ordinary skill in the art are come
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Range.
Claims (10)
1. a kind of anti-scraping coating of environmental protection resistance and fingerprint resistance, it is characterised in that：Include following component by mass percentage：Aqueous polyurethane
5~90%, organosilicon-modified acrylic 5~90%, pH adjusting agent 0.1~1%, moistening flatting agent 0.1~0.8%, antifoaming agent
0.1~1%, curing agent 1~5%, cosolvent 1~40%.
2. the anti-scraping coating of environmental protection resistance and fingerprint resistance according to claim 1, it is characterised in that：Poly- ammonia in the aqueous polyurethane
Ester microsphere grain size is 700nm~10 μm.
3. the anti-scraping coating of environmental protection resistance and fingerprint resistance according to claim 1, it is characterised in that：The aqueous polyurethane is poly- carbonic acid
The one or two of ester type polyurethane or polyester polyurethane.
4. the anti-scraping coating of environmental protection resistance and fingerprint resistance according to claim 1, it is characterised in that：The organosilicon-modified acrylic
10 DEG C of 10 DEG C of minimum film formation temperature ＜, glass transition temperature ＜.
5. the anti-scraping coating of environmental protection resistance and fingerprint resistance according to claim 1, it is characterised in that：The organosilicon-modified acrylic is
Organic-silicon-modified self-crosslinking acrylic.
6. the anti-scraping coating of environmental protection resistance and fingerprint resistance according to claim 1, it is characterised in that：In the organosilicon-modified acrylic
Organosilicon modifier for siliceous vinyl compound, including vinyl alkyl trichlorosilane, vinyl alkyl methoxyl group silicon
Alkane, vinyl alkyl Ethoxysilane, vinyl alkyl npropoxysilane, one kind in vinyl alkyl polysiloxanes or several
Kind.
7. according to any anti-scraping coatings of environmentally friendly resistance and fingerprint resistance of claim 1-6, it is characterised in that：The pH adjusting agent is ammonia
Water, triethylamine, triethanolamine, N, it is one or more in N- dimethylethanolamines, AMP-95.
8. according to any anti-scraping coatings of environmentally friendly resistance and fingerprint resistance of claim 1-6, it is characterised in that：The moistening flatting agent is
One or both of organosilicon compound, acetylenic glycols ethoxy compound；The antifoaming agent is organosilicon compound, alkynes
One or both of diol ethoxylate chemical combination object.
9. according to any anti-scraping coatings of environmentally friendly resistance and fingerprint resistance of claim 1-6, it is characterised in that：The curing agent is pair
Carboxyl, hydroxyl, ketone carbonyl chemically reactive compound, including isocyanate compound, adipic dihydrazide, aziridine
It closes one or more in object, carbodiimide compound；The cosolvent includes ethyl alcohol, ethylene glycol, isopropanol, N- methyl pyrroles
Pyrrolidone, N- ethyl pyrrolidones, butyl glycol ether, butyl, propandiol butyl ether acetate, diethylene glycol ether,
It is one or more in diethylene glycol ether acetate.
10. a kind of application method of the anti-scraping coating of environmental protection resistance and fingerprint resistance, it is characterised in that：Include the following steps：
S1：Each component is mixed according to claim 1-6 any mass percents, is configured to coating aqueous dispersion；
S2：By the coating aqueous dispersion to base material；
S3：To being applied to the coating after base material into the preliminary drying that trip temperature is 60~110 DEG C, the time is 40s~5min；
S4：Into trip temperature it is 45~130 DEG C to pre-baked coating, the time is the curing of 1h~5d, so as to obtain the resistance to finger of environmental protection
Line preventing from scraping film.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109266200A (en) * | 2018-09-19 | 2019-01-25 | 蔡中发 | A kind of aqueous dumb light skin sense coating and preparation method thereof |
| CN109868043A (en) * | 2019-01-23 | 2019-06-11 | 深圳市诺美斯新材料有限公司 | A kind of aqueous scratch resistant mute oil |
| CN110205008A (en) * | 2019-05-24 | 2019-09-06 | 上海丰野表面处理剂有限公司 | A kind of chromium-free fingerprint-resistant inorganic agent |
| CN112011076A (en) * | 2020-08-10 | 2020-12-01 | 江门市玛斯特包装有限公司 | Packaging bag with rough surface and preparation method thereof |
| CN116622285A (en) * | 2023-05-16 | 2023-08-22 | 湖南松井新材料股份有限公司 | Water-based UV hand feeling coating and preparation method and application thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007314608A (en) * | 2006-05-23 | 2007-12-06 | Matsushita Electric Works Ltd | Fingerprint-resistant coating |
| CN101914344A (en) * | 2010-09-09 | 2010-12-15 | 上海丰野表面处理剂有限公司 | Non-chrome water-based organic fingerprint-resistant coating and preparation method thereof |
| CN102634267A (en) * | 2012-04-12 | 2012-08-15 | 番禺南沙殷田化工有限公司 | Antifouling and anti-fingerprint coating composite capable of being applied to touch screen panel and preparation method of antifouling and anti-fingerprint coating |
| CN104015438A (en) * | 2014-05-22 | 2014-09-03 | 太湖金张科技股份有限公司 | Anti-blue light and fingerprint resistant film and preparation method thereof |
| CN104403538A (en) * | 2014-12-08 | 2015-03-11 | 上海涂料有限公司技术中心 | High-corrosion-resistance, high-weather-resistance and excellent-hydrophobicity chromium-free fingerprint-resistant coating used for galvanized steel sheet |
| CN104974324A (en) * | 2015-06-30 | 2015-10-14 | 中科院广州化学有限公司南雄材料生产基地 | Reactive self-delustering waterborne polyurethane resin, and preparation method and application thereof |
| US20160032141A1 (en) * | 2014-07-14 | 2016-02-04 | Enki Technology, Inc. | High gain durable anti-reflective coating |
| CN106188407A (en) * | 2016-07-29 | 2016-12-07 | 同光（江苏）新材料科技有限公司 | The synthetic method of organic-silicon-modified hud typed room temperature dual self-crosslinking acrylic emulsion |
| CN107033761A (en) * | 2017-03-17 | 2017-08-11 | 广州大学 | A kind of aqueous floride-free anti-fingerprint antifouling polymeric composite coating and its application method |
| CN107163743A (en) * | 2017-07-14 | 2017-09-15 | 广东伊思曼新材料科技股份有限公司 | A kind of container roller coat aqueous wooden ware floor paint and preparation method thereof |
-
2017
- 2017-12-27 CN CN201711447912.3A patent/CN108129971B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007314608A (en) * | 2006-05-23 | 2007-12-06 | Matsushita Electric Works Ltd | Fingerprint-resistant coating |
| CN101914344A (en) * | 2010-09-09 | 2010-12-15 | 上海丰野表面处理剂有限公司 | Non-chrome water-based organic fingerprint-resistant coating and preparation method thereof |
| CN102634267A (en) * | 2012-04-12 | 2012-08-15 | 番禺南沙殷田化工有限公司 | Antifouling and anti-fingerprint coating composite capable of being applied to touch screen panel and preparation method of antifouling and anti-fingerprint coating |
| CN104015438A (en) * | 2014-05-22 | 2014-09-03 | 太湖金张科技股份有限公司 | Anti-blue light and fingerprint resistant film and preparation method thereof |
| US20160032141A1 (en) * | 2014-07-14 | 2016-02-04 | Enki Technology, Inc. | High gain durable anti-reflective coating |
| CN104403538A (en) * | 2014-12-08 | 2015-03-11 | 上海涂料有限公司技术中心 | High-corrosion-resistance, high-weather-resistance and excellent-hydrophobicity chromium-free fingerprint-resistant coating used for galvanized steel sheet |
| CN104974324A (en) * | 2015-06-30 | 2015-10-14 | 中科院广州化学有限公司南雄材料生产基地 | Reactive self-delustering waterborne polyurethane resin, and preparation method and application thereof |
| CN106188407A (en) * | 2016-07-29 | 2016-12-07 | 同光（江苏）新材料科技有限公司 | The synthetic method of organic-silicon-modified hud typed room temperature dual self-crosslinking acrylic emulsion |
| CN107033761A (en) * | 2017-03-17 | 2017-08-11 | 广州大学 | A kind of aqueous floride-free anti-fingerprint antifouling polymeric composite coating and its application method |
| CN107163743A (en) * | 2017-07-14 | 2017-09-15 | 广东伊思曼新材料科技股份有限公司 | A kind of container roller coat aqueous wooden ware floor paint and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| ÖMER KESMEZ ET.AL.: "《Fingerprint resistant coatings for stainless steel substrates》", 《PROGRESS IN ORGANIC COATINGS》 * |
| 王海人等: "《钢板耐指纹涂料及其涂膜表征方法的研究进展》", 《材料保护》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109266200A (en) * | 2018-09-19 | 2019-01-25 | 蔡中发 | A kind of aqueous dumb light skin sense coating and preparation method thereof |
| CN109868043A (en) * | 2019-01-23 | 2019-06-11 | 深圳市诺美斯新材料有限公司 | A kind of aqueous scratch resistant mute oil |
| CN110205008A (en) * | 2019-05-24 | 2019-09-06 | 上海丰野表面处理剂有限公司 | A kind of chromium-free fingerprint-resistant inorganic agent |
| CN112011076A (en) * | 2020-08-10 | 2020-12-01 | 江门市玛斯特包装有限公司 | Packaging bag with rough surface and preparation method thereof |
| CN112011076B (en) * | 2020-08-10 | 2022-09-30 | 江门市玛斯特包装有限公司 | Packaging bag with rough surface and preparation method thereof |
| CN116622285A (en) * | 2023-05-16 | 2023-08-22 | 湖南松井新材料股份有限公司 | Water-based UV hand feeling coating and preparation method and application thereof |
| CN116622285B (en) * | 2023-05-16 | 2024-07-19 | 湖南松井新材料股份有限公司 | Water-based UV hand feeling coating and preparation method and application thereof |
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