CN108118523A - A kind of unleaded matter ray radiation protection cloth and preparation method thereof - Google Patents

A kind of unleaded matter ray radiation protection cloth and preparation method thereof Download PDF

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Publication number
CN108118523A
CN108118523A CN201711215609.0A CN201711215609A CN108118523A CN 108118523 A CN108118523 A CN 108118523A CN 201711215609 A CN201711215609 A CN 201711215609A CN 108118523 A CN108118523 A CN 108118523A
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Prior art keywords
radioresistance
tungsten
base fabric
unleaded
radiation protection
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CN201711215609.0A
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CN108118523B (en
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郭立新
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Wuxi Sino Shield Technology Co Ltd
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Wuxi Sino Shield Technology Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06Inorganic compounds or elements
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/106Radiation shielding agents, e.g. absorbing, reflecting agents
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/54Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

A kind of unleaded matter ray radiation protection cloth, preparation process are as follows:(1) tungsten powder is mixed with plastics original grain, the quality of the tungsten powder is the 2~10% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance long filament;(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition car, is vacuumized;Using radioresistance base fabric as carrier, using the tungsten of 90~99% purity as target, the tungsten simple substance inspired is uniformly deposited on to the single side or tow sides of base fabric.The present invention is sputtered material using radioresistance base fabric as carrier, through vacuum magnetic-control sputtering technique, makes the tow sides of base fabric or the tungsten layer of single sided deposition design thickness, has the function of good ray radiation protection.The protective cloth softness that the present invention is prepared is light, and shielding is uniform, can protect the radiation sources such as X-ray, alpha ray, β rays, gamma-rays.

Description

A kind of unleaded matter ray radiation protection cloth and preparation method thereof
Technical field
The present invention relates to radiation protection technical field, more particularly, to a kind of lead-free anti-ray material.
Background technology
The scientific utilization of ray brings immeasurable benefit for scientific and technological progress, economic development and the health and civilization of society Place.But relevant occupational area is radiated with ray, such as the exploitation of core ore deposit, refinement, segmentation, packaging, transport;Nuclear Power Station is set Installation, the operation applied;Radioimmunodiagnosis, analysis;Radiotherapy, industrial flaw detection, the making of radiation imaging apparatus, operation;With And Military Application etc., the measure for the ray that is required for properly protecting to staff.
So far, in terms of the equipment of individual protection, the radiation shielding material still continued to use both at home and abroad is lead rubber system Product, i.e., add in the lead powder of 100~400 mesh in the rubber of melting, it is agitated, rub pressure after be pressed into plate (skin) shape, then by design punching, After cutting, surrounding is wrapped in common cloth, is spliced into protective garment.Such material and correlated product have following technological deficiency:
(1) viscous pasty state after being heated due to rubber, lead button or lead compound monomer are difficult to be uniformly dispersed in rubber, The harmony of shield effectiveness is impacted.(2) protective garment is thick and heavy, and dress is uncomfortable, and work efficiency is poor, by taking 0.35Pb as an example, protective garment weight For:3.75kg, in addition head protector, protector for collar, gloves, leg protector, the weight of a whole set of protector is up to more than 10 jins.(3) in lead rubber Lead molecule can be precipitated from rubber, and lead is toxic to human body.Meanwhile discarded lead rubber can cause it is irreversible Environmental pollution.(4) in lead rubber slab (skin), lead content is higher, and its physical property is poorer, and lead rubber slab can be caused by squeezing repeatedly The fracture of (skin), being especially secretly broken (the middle fracture for referring to offset plate), this will be great security risk to occupational staff.In addition, In natural environment, lead rubber is easy to aging, if folding, standing time is slightly longer, and safety device easily deforms, it is difficult to be continuing with.
CN2129961 provides a kind of low energy radiation protective metal fabric, the metal cladding in textile cloth, thickness of coating 5 ~20 microns, but the energy of below 30KeV can only be protected to radiate.CN103824605A discloses a kind of unleaded anti-ionising radiation Composite material, comprising radiation protection powder body material and moulding material, the powder body material include blanc fixe, brown iron oxide, tungsten and Its compound and cadmium and its compound;But this technology can only prepare the hard radiation protection material such as barrier, wall, door, rubber Material can not make soft clothing and be through on human body.CN106307743A, which provides a kind of multifunctinal antiradiation maternity dress, to be included The outer layer of internal layer and coating extruded on internal layer;Internal layer is metallic fiber and the blended manufactured fabric of textile fabric;Outer layer is containing metal Or the coating of its oxide;The metal is selected from tungsten or bismuth, coating layer thickness 0.05-0.50mm;But prepared by this technology Radiation-proof fabric is not washable, and radiation proof material will come off after washing several times.
The content of the invention
In view of the above-mentioned problems existing in the prior art, this application provides a kind of unleaded matter ray radiation protection cloth and its systems Preparation Method.The present invention is sputtered material using radioresistance base fabric as carrier, through vacuum magnetic-control sputtering technique, makes positive and negative the two of base fabric Face or the tungsten layer of single sided deposition design thickness have the function of good ray radiation protection.The protective cloth that the present invention is prepared Soft light, shielding is uniform, can protect the radiation sources such as X-ray, alpha ray, β rays, gamma-rays.
Technical scheme is as follows:
A kind of unleaded matter ray radiation protection cloth, preparation process are as follows:
(1) radioresistance long filament is prepared:Tungsten powder is mixed with plastics original grain, the quality of the tungsten powder for plastics original grain 2~ 10%, heating, stir to plastics original grain melt molten, tungsten particle it is homodisperse when, spray is drawn wire, and obtains radioresistance long filament;
(3) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -1pa~-7pa;It, will using the tungsten of 90~99% purity as target using radioresistance base fabric as carrier The tungsten simple substance inspired is uniformly deposited on the single side or tow sides of base fabric.
Preferably, the tungsten powder described in step (1) was the tungsten powder of 200~400 mesh sieves.
Preferably, the plastics original grain described in step (1) is nylon, acrylic fibers or terylene Plastic section.
Preferably, single-face plating thickness of step (2) the tungsten simple substance in base fabric is 30~350 microns;Two-sided thickness of coating For 600~700 microns.
Preferably, the tungsten target timber-used tin of step (2), lanthanum, neodymium, praseodymium monomer target or their mixture target are replaced.
The present invention is beneficial to be had technical effect that:
The present invention through vacuum magnetic-control sputtering technique, can be wanted using radioresistance base fabric as carrier (being sputtered material) according to design It seeks customization single side magnetron sputtering deposition or two-sided magnetron sputtering deposition, makes the tow sides of base fabric or single sided deposition design thickness Tungsten layer has the function of good ray radiation protection.Protective mechanism is:Have one after accelerating in the electric field using electrically charged particle The characteristics of determining kinetic energy guides tungsten particle the target electricity grade (cathode) for the substance to be sputtered into and sputters out target atom, because The special distribution in magnetic field controls the trajectory of electron motion in electric field that it can be made to be moved to along certain direction in base fabric and deposits, By the control of the deposition velocity to metal and sedimentation time and the running speed of base fabric, metal layer thickness is made to reach certain and is wanted It asks.Make base fabric that there is good anti-ray.
The present invention is in condition of high vacuum degree, high-intensity magnetic field, high-power current density and rational targeting is set and positive and negative direction Under the collective effect of the base material running orbit technological design of continuous magnetron sputtering, make the tungsten ion in tungsten target material, in high-pressure electronic Under the bombardment effect of beam, the substantial amounts of, effusion of high speed, and it is continuous, equably deposit to design thickness.The atomic mass of tungsten is 183.8, lead atom quality is 207.2, and excellent shielding action can be played to the protection of ray, and harmless to the human body.
Specific embodiment
With reference to embodiment, the present invention is specifically described.
The metal layer thickness of magnetron sputtering technique is usually 5~9 μm, no matter using which kind of material as target, product It is shield effectiveness to X, γ, β, alpha ray protection, is extremely faint or inoperative.It is well known that a certain amount of ray, wears Saturating power be it is extremely strong, and improved, specific magnetron sputtering apparatus, it can be achieved that target metal successive sedimentation thickness 30~ 350μm。
Embodiment 1:
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 200 mesh sieves is mixed with nylon plastic(s) section, the quality of the tungsten powder For the 2% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -7pa;Using radioresistance base fabric as carrier, using the tungsten of 90% purity as target, the tungsten that will inspire Simple substance is uniformly deposited on the single side of base fabric;Single-face plating thickness is 110 microns.After testing, the lead of the material and 0.1mmPb are worked as The radiation resistance of amount is consistent.
Embodiment 2:
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 250 mesh sieves is mixed with nylon plastic(s) section, the quality of the tungsten powder For the 5% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -5pa;Using radioresistance base fabric as carrier, using the tungsten of 92% purity as target, the tungsten that will inspire Simple substance is uniformly deposited on the single side of base fabric;Single-face plating thickness is 220 microns.After testing, the lead of the material and 0.2mmPb are worked as The radiation resistance of amount is consistent.
Embodiment 3
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 300 mesh sieves is mixed with nylon plastic(s) section, the quality of the tungsten powder For the 10% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -3pa;Using radioresistance base fabric as carrier, using the tungsten of 95% purity as target, the tungsten that will inspire Simple substance is uniformly deposited on the single side of base fabric;Single-face plating thickness is 380 microns.After testing, the lead of the material and 0.35mmPb The radiation resistance of equivalent is consistent.
Embodiment 4
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 400 mesh sieves is mixed with nylon plastic(s) section, the quality of the tungsten powder For the 3% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -1pa;Using radioresistance base fabric as carrier, using the tungsten of 99% purity as target, the tungsten that will inspire Simple substance is uniformly deposited on the single side of base fabric;Single-face plating thickness is 550 microns.After testing, the lead of the material and 0.5mmPb are worked as The radiation resistance of amount is consistent.
Embodiment 5
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 200 mesh sieves is mixed with acrylic fibers Plastic section, the quality of the tungsten powder For the 10% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -1pa;Using radioresistance base fabric as carrier, using the tungsten of 99% purity as target, the tungsten that will inspire Simple substance is uniformly deposited on the tow sides of base fabric;Two-sided thickness of coating is 600 microns.After testing, the material and 0.5mmPb The radiation resistance of lead equivalent is consistent.
Embodiment 6
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 300 mesh sieves is mixed with acrylic fibers Plastic section, the quality of the tungsten powder For the 6% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -2pa;Using radioresistance base fabric as carrier, using the tungsten of 90% purity as target, the tungsten that will inspire Simple substance is uniformly deposited on the tow sides of base fabric;Two-sided thickness of coating is 650 microns.After testing, the material and 0.55mmPb Lead equivalent radiation resistance it is consistent.
Embodiment 7
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 400 mesh sieves is mixed with acrylic fibers Plastic section, the quality of the tungsten powder For the 2% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -6pa;Using radioresistance base fabric as carrier, using the tungsten of 97% purity as target, the tungsten that will inspire Simple substance is uniformly deposited on the tow sides of base fabric;Two-sided thickness of coating is 700 microns.After testing, the material and 0.6mmPb The radiation resistance of lead equivalent is consistent.
Embodiment 8
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 200 mesh sieves is mixed with terylene Plastic section, the quality of the tungsten powder For the 5% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -4pa;Using radioresistance base fabric as carrier, using the tin of 96% purity as target, the tin that will inspire Simple substance is uniformly deposited on the single side of base fabric;Single-face plating thickness is 200 microns.After testing, the lead of the material and 0.2mmPb are worked as The radiation resistance of amount is consistent.
Embodiment 9
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 300 mesh sieves is mixed with terylene Plastic section, the quality of the tungsten powder For the 2% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -7pa;Using radioresistance base fabric as carrier, using the neodymium of 93% purity as target, the neodymium that will inspire Simple substance is uniformly deposited on the single side of base fabric;Single-face plating thickness is 350 microns.After testing, the lead of the material and 0.3mmPb are worked as The radiation resistance of amount is consistent.
Embodiment 10
The unleaded matter ray radiation protection cloth preparation process that the application provides is as follows:
(1) radioresistance long filament is prepared:The tungsten powder for crossing 300 mesh sieves is mixed with terylene Plastic section, the quality of the tungsten powder For the 7% of plastics original grain, heating, stir to plastics original grain melt that molten, tungsten particle is homodisperse when, spray is drawn wire, and obtains radioresistance Long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition Car is evacuated to pressure as -4pa;Using radioresistance base fabric as carrier, with the tungsten of 91% purity and the mixture (mass ratio of tin For 1:1) it is target, the tungsten inspired and tin is uniformly deposited on to the tow sides of base fabric;Two-sided thickness of coating is micro- for 700 Rice.After testing, the material is consistent with the radiation resistance of the lead equivalent of 0.5mmPb.
The anti-ray product of individual being prepared with radiation proof material of the present invention, the comparison with lead rubber, with 0.35mmPb lead rubber just wears vest, exemplified by protective garment prepared by tungsten hardware cloth (i.e. embodiment 3) equal with 0.35mmPb, comparison As shown in table 1.
Table 1
Lead rubber Tungsten hardware cloth (embodiment 3)
Weight 3.75kg 1.24kg
Material thickness 2mm Less than or equal to 750 μm
It is whether toxic Have Nothing
Wearing comfort Difference It is good
Shielding construction Generally It is excellent
Use Limitation 3~4 years 5 years or more
Lead equivalent 0.35mmPb 0.35mmPb
It can see from the comparison of table 1, at most only 700 μm of the thickness of tungsten hardware cloth, and lead rubber plate thickness, up to 4~5mm, i.e., the former is the 1/4~1/5 of the latter to be less than.The protection of equal style, equal lead equivalent is prepared with tungsten hardware cloth It is the 1/3 of the latter's weight to be less than to take its former weight.
In order to improve the water-wash resistance of antiradiation protection cloth of the present invention, after magnetron sputtering, carry out at once at tempering Antiradiation protection, i.e., be arranged in 150~180 DEG C of baking ovens and place 20~40 minutes, then cooled down rapidly in 5~10 minutes by reason To room temperature;In order to cool down rapidly, the taking-up of the antiradiation protection cloth in baking oven can be placed in 0~4 DEG C of refrigerating box and cooled down. The coating carried out on the antiradiation protection cloth after temper is tightly combined with base fabric, and washable 50~100 times or more holdings are former The radiation resistance of beginning;And the common pregnant woman's radiation-proof fabric sold on the market can only be washed 5~10 times, and wash 3 times Its later radiation resistance is just gradually reduced.

Claims (5)

1. a kind of unleaded matter ray radiation protection cloth, it is characterised in that preparation process is as follows:
(1) radioresistance long filament is prepared:Tungsten powder is mixed with plastics original grain, the quality of the tungsten powder is the 2~10% of plastics original grain, Heating, stir to plastics original grain melt molten, tungsten particle it is homodisperse when, spray is drawn wire, and obtains radioresistance long filament;
(2) prepared radioresistance long filament weaving is known as radioresistance base fabric into cloth;Radioresistance base fabric is packed into Vacuum Deposition vehicle It is interior, pressure is evacuated to as -1pa~-7pa;Using radioresistance base fabric as carrier, using the tungsten of 90~99% purity as target, will swash The tungsten simple substance sent is uniformly deposited on the single side or tow sides of base fabric.
2. unleaded matter ray radiation protection cloth according to claim 1, it is characterised in that the tungsten powder described in step (1) is Cross the tungsten powder of 200~400 mesh sieves.
3. unleaded matter ray radiation protection cloth according to claim 1, it is characterised in that the plastics described in step (1) are former Grain is nylon, acrylic fibers or terylene Plastic section.
4. unleaded matter ray radiation protection cloth according to claim 1, it is characterised in that step (2) tungsten simple substance is in base fabric Single-face plating thickness be 30~350 microns;Two-sided thickness of coating is 600~700 microns.
5. unleaded matter ray radiation protection cloth according to claim 1, it is characterised in that the tungsten target timber-used tin of step (2), Lanthanum, neodymium, praseodymium monomer target or their mixture target are replaced.
CN201711215609.0A 2017-11-28 2017-11-28 Lead-free radiation protection cloth and preparation method thereof Active CN108118523B (en)

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CN115012054A (en) * 2022-07-08 2022-09-06 中国核动力研究设计院 X-ray shielding material, preparation method and application

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Publication number Priority date Publication date Assignee Title
CN109267333A (en) * 2018-08-22 2019-01-25 北京镭蒙泰克科技有限公司 Anti-radiation composite material and preparation method
CN109267333B (en) * 2018-08-22 2023-10-24 北京镭蒙泰克科技有限公司 Anti-radiation composite material and preparation method thereof
CN115012054A (en) * 2022-07-08 2022-09-06 中国核动力研究设计院 X-ray shielding material, preparation method and application

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