CN108118346B - High tenacity gold article fabrication methods - Google Patents

High tenacity gold article fabrication methods Download PDF

Info

Publication number
CN108118346B
CN108118346B CN201711433637.XA CN201711433637A CN108118346B CN 108118346 B CN108118346 B CN 108118346B CN 201711433637 A CN201711433637 A CN 201711433637A CN 108118346 B CN108118346 B CN 108118346B
Authority
CN
China
Prior art keywords
gold
acid solution
semi
finished product
bracelet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201711433637.XA
Other languages
Chinese (zh)
Other versions
CN108118346A (en
Inventor
邵锦兴
刘旺枝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Gold Dragon Jewelry And Accessories Co Ltd
Original Assignee
Dongguan Gold Dragon Jewelry And Accessories Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Gold Dragon Jewelry And Accessories Co Ltd filed Critical Dongguan Gold Dragon Jewelry And Accessories Co Ltd
Priority to CN201711433637.XA priority Critical patent/CN108118346B/en
Publication of CN108118346A publication Critical patent/CN108118346A/en
Application granted granted Critical
Publication of CN108118346B publication Critical patent/CN108118346B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/10Other heavy metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Adornments (AREA)

Abstract

The invention discloses high tenacity gold article fabrication methods.The high tenacity gold article fabrication methods include the following steps: the second acid solution containing nitrate ion and gold bracelet semi-finished product that the first acid solution containing sulfate ion that offer concentration is 95%-99%, concentration are 95%-99%;First acid solution is mixed with second acid solution with volume ratio 8.5-9:1-1.5, pickling solution is formed;The pickling solution is heated up to 70 DEG C -90 DEG C, gold bracelet semi-finished product are placed in the pickling solution and soak 2-5s, are then taken out;The gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, are then taken out;The gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment, obtain gold bracelet.High tenacity gold article fabrication methods of the present invention, can be improved gold jewellery toughness, gold jewellery are prevented to be cracked, and extend gold jewellery service life.

Description

High tenacity gold article fabrication methods
Technical field
The present invention relates to gold manufacture technology fields, and in particular to high tenacity gold article fabrication methods.
Background technique
Gold as beautiful golden yellow non-ferrous metal, have it is rare it is valuable, density is big, hardness is low, good ductility and can Oxidation, and pure gold face do not occur at any temperature with oxygen for the characteristics of plasticity and quite high chemical stability For color in golden yellow, gloss is bright but very soft, therefore, is usually used in making jewellery.More importantly in Chinese mind, gold Exactly worship and rich and honour symbol, and the characteristics of gold exclusive cultural connotation and value preserving and appreciation, so that everybody goes after like a flock of ducks.
The method that gold bracelet molding in the prior art mostly uses manual processing greatly had also been introduced some machinery in recent years and had been added Construction equipment.But either manual processing is still machined, and after wearing long-time, mostly tortoise not enough can occur due to toughness It splits, affects the normal wearing of jewellery.
Summary of the invention
Based on this, the present invention, which provides one kind, can be improved gold jewellery toughness, the high tenacity gold product production side for preventing it to be cracked Method.
In order to achieve the object of the present invention, the invention adopts the following technical scheme:
A kind of high tenacity gold article fabrication methods, include the following steps:
There is provided the first acid solution containing sulfate ion, concentration that concentration is 95%-99% is containing for 95%-99% The second acid solution and gold bracelet semi-finished product of nitrate ion;
First acid solution is mixed with second acid solution with volume ratio 8.5-9:1-1.5, acid is formed Dilution;
The pickling solution is heated up to 70 DEG C -90 DEG C, gold bracelet semi-finished product are placed in the pickling solution and soak 2- 5s then takes out;
The gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, are then taken out;
The gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment, obtain gold bracelet.
Above-mentioned high tenacity gold article fabrication methods, by the gold bracelet semi-finished product tentatively to complete be placed in sulfate radical with In the pickling solution that nitrate anion is made into, after mixing pickling, test finds that the toughness of golden product greatly improves, and finds cracking Probability substantially reduces, and extends the service life of gold ornaments.
Wherein in an embodiment, first acid solution is sulfuric acid solution.Sulfuric acid solution can provide purer sulfate radical from Son, the pickling solution concentration being made into are more accurate.
Wherein in an embodiment, the concentration of the sulfuric acid solution is 98%.
Wherein in an embodiment, second acid solution is nitric acid solution.Nitric acid solution can provide purer nitrate anion from Son, the pickling solution concentration being made into are more accurate.
Wherein in an embodiment, the concentration of the nitric acid solution is 98%.
Wherein in an embodiment, the volume ratio of first acid solution and second acid solution is 8.5:1.
Wherein in an embodiment, the pickling solution is heated up to 75 DEG C -85 DEG C.
Wherein in an embodiment, the gold bracelet semi-finished product are placed in 40 DEG C of water and are washed.
Wherein in an embodiment, the gold bracelet semi-finished product are dried in 50 DEG C of environment.
The present invention there is a need to provide another high tenacity gold article fabrication methods, include the following steps:
There is provided nitric acid solution that sulfuric acid solution, concentration that concentration is 95%-99% are 95%-99% and gold bracelet half at Product;
The sulfuric acid solution is mixed with the nitric acid solution with volume ratio 8.5-9:1-1.5, it is molten to form pickling Liquid;
The pickling solution is heated up to 75 DEG C -85 DEG C, gold bracelet semi-finished product are placed in the pickling solution and soak 2- 5s then takes out;
The gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, are then taken out;
The gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment;
The gold bracelet semi-finished product are again placed in the pickling solution and soak 2-5s, are then taken out, such recurring number Secondary, last gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment, obtain gold bracelet.
Specific embodiment
It to facilitate the understanding of the present invention, below will be to invention is more fully described.But the present invention can be to be permitted Mostly different form is realized, however it is not limited to embodiment described herein.On the contrary, purpose of providing these embodiments is makes It is more thorough and comprehensive to the understanding of the disclosure.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.
The present invention provides a kind of high tenacity gold article fabrication methods, for processing golden product, especially gold jewelry for example Gold bracelet improves the toughness of gold ornaments, prevents to be cracked, and extends the service life of jewellery.
Wherein in an embodiment, gold bracelet semi-finished product be gold bracelet half after being processed early period at the present invention one compared with The high tenacity gold article fabrication methods of good embodiment, include the following steps.
One, providing the first acid solution containing sulfate ion, concentration that concentration is 95%-99% is 95%-99%'s The second acid solution containing nitrate ion and gold bracelet semi-finished product.
Two, the first acid solution is mixed with the second acid solution with volume ratio 8.5-9:1-1.5, it is molten forms pickling Liquid;
Three, pickling solution is heated up to 70 DEG C -90 DEG C, gold bracelet semi-finished product is placed in pickling solution and soak 2-5s, so After take out;
Four, gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, then taken out;
Five, gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment, obtains gold bracelet.
Product.For example, it may be using gold block through tabletting, volume ring, treated this finished product such as trombone slide.Tabletting therein is Refer to and gold is first pressed into sheet, the size of needs can also be cut into.Volume ring, which refers to, is rolled into ring-shaped for the gold piece of sheet, with It is handled convenient for the later period.Trombone slide, which refers to, pulls into hollow annular for cricoid gold, forms the shape of the jewellery of needs.
It is to be appreciated that in other embodiments, if the not instead of bracelet of processing, the jewelry of other shapes, such as Animals shaped gold bullion then will carry out die casting by mold and be formed, also be semi-finished product.
First acid solution is sulfuric acid solution, and sulfuric acid solution can provide purer sulfate ion, and the pickling solution being made into is dense It spends more accurate.Sulfate relative to others containing sulfate radical, the pickling solution purity being made into is higher, is more conducive to acid Wash journey.
Similarly, the second acid solution is nitric acid solution, and nitric acid solution can provide purer nitrate ion, and the pickling being made into is molten Liquid concentration is more accurate.Nitrate relative to others containing nitrate anion, the pickling solution purity being made into is higher, advantageously In acid cleaning process.
Wherein in an embodiment, the concentration of sulfuric acid solution is 98%, and the concentration of nitric acid solution is 98%.What the concentration was made into The golden product toughness of pickling solution, wash-off is higher.
Wherein in an embodiment, the first acid solution is mixed with the second acid solution with volume ratio 8.5-9:1-1.5, example Such as with the mixing of 8.5:1,8.5:1.5,9:1,9:1.5 equal proportion.Optionally, the volume of the first acid solution and second acid solution Than for 8.5:1.The golden product toughness of the pickling solution that the ratio is made into, wash-off is higher.
Wherein in an embodiment, pickling solution is heated up to such as 70 DEG C, 75 DEG C, 80 DEG C, 85 DEG C, 90 DEG C.Optionally, pickling Solution is heated up to 75 DEG C -85 DEG C, such as can be 75 DEG C, 80 DEG C, 85 DEG C.
Wherein in an embodiment, gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, for example, be placed in 30 DEG C, 35 DEG C, 40 DEG C, 45 DEG C, 50 DEG C, 55 DEG C, wash in 60 DEG C of water.Optionally, gold bracelet semi-finished product are placed in 40 DEG C of water and carry out Washing.
Wherein in an embodiment, gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment, for example, be placed in 40 DEG C, 45 DEG C, 50 DEG C, 55 DEG C, dry in 60 DEG C of environment.Optionally, gold bracelet semi-finished product are dried in 50 DEG C of environment.
Another embodiment provides high tenacity gold article fabrication methods, and obtained golden product toughness is obtained higher than above scheme The golden product arrived, the high tenacity gold article fabrication methods include the following steps:
One, provide concentration be 95%-99% sulfuric acid solution, concentration be 95%-99% nitric acid solution and gold bracelet Semi-finished product.
Two, sulfuric acid solution and nitric acid solution are mixed with volume ratio 8.5-9:1-1.5, forms pickling solution;
Three, pickling solution is heated up to 75 DEG C -85 DEG C, gold bracelet semi-finished product is placed in the pickling solution and soak 2- 5s then takes out;
Four, gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, then taken out;
Five, gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment;
Six, gold bracelet semi-finished product are again placed in pickling solution and soak 2-5s, then taken out, so recycled for several times, most Gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment afterwards, obtain gold bracelet.
Above-mentioned high tenacity gold article fabrication methods, by the gold bracelet semi-finished product tentatively to complete be placed in sulfate radical with In the pickling solution that nitrate anion is made into, after mixing pickling, test finds that the toughness of golden product greatly improves, and finds cracking Probability substantially reduces, and extends the service life of gold ornaments.
Embodiment one
The golden article fabrication methods of the present embodiment include the following steps: that providing sulfuric acid solution, concentration that concentration is 98% is 98% nitric acid solution and gold bracelet semi-finished product;Sulfuric acid solution and nitric acid solution are mixed with volume ratio 8.5:1, shape At pickling solution;Pickling solution is heated up to 80 DEG C, gold bracelet semi-finished product are placed in pickling solution and soak 3s, are then taken out; Gold bracelet semi-finished product are placed in 45 DEG C of water and are washed, are then taken out.Gold bracelet semi-finished product are dried in 50 DEG C of environment It is dry, gold bracelet semi-finished product are again placed in pickling solution and soak 3s, are then taken out, are so recycled twice, last gold bracelet Semi-finished product are dried in 50 DEG C of environment, obtain gold bracelet.
Embodiment two
The golden article fabrication methods of the present embodiment include the following steps: that providing sulfuric acid solution, concentration that concentration is 98% is 98% nitric acid solution and gold bracelet semi-finished product;Sulfuric acid solution and nitric acid solution are mixed with volume ratio 8.5:1, shape At pickling solution;Pickling solution is heated up to 80 DEG C, gold bracelet semi-finished product are placed in pickling solution and soak 3s, are then taken out; Gold bracelet semi-finished product are placed in 45 DEG C of water and are washed, are then taken out.Gold bracelet semi-finished product are dried in 50 DEG C of environment It is dry, obtain gold bracelet.
Embodiment three
The golden article fabrication methods of the present embodiment include the following steps: to provide metabisulfite solution, the concentration that concentration is 98% For 98% sodium nitrate solution and gold bracelet semi-finished product;Metabisulfite solution is mixed with sodium nitrate solution with volume ratio 8.5:1 Together, pickling solution is formed;Pickling solution is heated up to 80 DEG C, gold bracelet semi-finished product are placed in pickling solution and soak 3s, It then takes out;Gold bracelet semi-finished product are placed in 45 DEG C of water and are washed, are then taken out.By gold bracelet semi-finished product at 50 DEG C It is dried in environment, obtains gold bracelet.
Example IV
The golden article fabrication methods of the present embodiment include the following steps: that providing sulfuric acid solution, concentration that concentration is 95% is 95% nitric acid solution and gold bracelet semi-finished product;Sulfuric acid solution and nitric acid solution are mixed with volume ratio 9:1, formed Pickling solution;Pickling solution is heated up to 80 DEG C, gold bracelet semi-finished product are placed in pickling solution and soak 3s, are then taken out;It will Gold bracelet semi-finished product are placed in 45 DEG C of water and are washed, and then take out.Gold bracelet semi-finished product are dried in 50 DEG C of environment, Obtain gold bracelet.
Comparative example one
The golden article fabrication methods of the present embodiment are to mix 98% sulfuric acid with the volume ratio of 8.5:1 with water, form acid The gold bracelet semi-finished product completed the process are soaked 3s in the pickling solution for being heated up to 80 DEG C, are subsequently placed in 45 DEG C by dilution It is washed in water, is then dried, obtain gold bracelet finished product.
Comparative example two
The golden article fabrication methods of the present embodiment are to mix 98% nitric acid with the volume ratio of 8.5:1 with water, form acid The gold bracelet semi-finished product completed the process are soaked 3s in the pickling solution for being heated up to 80 DEG C, are subsequently placed in 45 DEG C by dilution It is washed in water, is then dried, obtain gold bracelet finished product.
Comparative example three
The golden article fabrication methods of the present embodiment are that the gold bracelet semi-finished product that will be completed the process are placed in 80 DEG C of water and carry out Washing, is subsequently placed in 45 DEG C of water and is washed, then dry, obtain gold bracelet finished product.
The toughness of above several embodiments and comparative example will be tested below, data are shown in Table one.
The toughness of above-mentioned golden product is tested using following methods:
Cricoid gold bracelet is subjected to deformation process, the case where which includes bending etc., observe its reinstatement.
Table one
It restores to the original state the time
Embodiment one 2min
Embodiment two 3min
Embodiment three 4min
Example IV 3.5min
Comparative example one 10min
Comparative example two 10min
Comparative example three 20min or longer
As can be seen from Table I, golden article fabrication methods of the present invention, it is compared with the existing technology, restorable Better performances are demonstrate,proved its toughness and are higher by compared with the existing technology very much, cracking can be better protected from during routine use, It prolongs its service life.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (8)

1. a kind of high tenacity gold article fabrication methods, which comprises the steps of:
There is provided concentration be 95%-99% the first acid solution containing sulfate ion, concentration be 95%-99% containing nitrate anion from The second acid solution and gold bracelet semi-finished product of son;First acid solution is sulfuric acid solution, and second acid solution is nitric acid Solution;
First acid solution is mixed with second acid solution with volume ratio 8.5-9:1-1.5, it is molten to form pickling Liquid;
The pickling solution is heated up to 70 DEG C -90 DEG C, gold bracelet semi-finished product are placed in the pickling solution and soak 2-5s, so After take out;
The gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, are then taken out;
The gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment, obtain gold bracelet.
2. high tenacity gold article fabrication methods according to claim 1, it is characterised in that: the concentration of the sulfuric acid solution is 98%。
3. high tenacity gold article fabrication methods according to claim 1, it is characterised in that: the concentration of the nitric acid solution is 98%。
4. high tenacity gold article fabrication methods according to claim 1, it is characterised in that: first acid solution with it is described The volume ratio of second acid solution is 8.5:1.
5. high tenacity gold article fabrication methods according to claim 1, it is characterised in that: the pickling solution is heated up to 75 ℃-85℃。
6. high tenacity gold article fabrication methods according to claim 1, it is characterised in that: the gold bracelet semi-finished product are set It is washed in 40 DEG C of water.
7. high tenacity gold article fabrication methods according to claim 1, it is characterised in that: the gold bracelet semi-finished product exist It is dried in 50 DEG C of environment.
8. a kind of high tenacity gold article fabrication methods, which comprises the steps of:
There is provided concentration be 95%-99% sulfuric acid solution, concentration be 95%-99% nitric acid solution and gold bracelet semi-finished product;
The sulfuric acid solution is mixed with the nitric acid solution with volume ratio 8.5-9:1-1.5, pickling solution is formed;
The pickling solution is heated up to 75 DEG C -85 DEG C, gold bracelet semi-finished product are placed in the pickling solution and soak 2-5s, so After take out;
The gold bracelet semi-finished product are placed in 30 DEG C of -60 DEG C of water and are washed, are then taken out;
The gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment;
The gold bracelet semi-finished product are again placed in the pickling solution and soak 2-5s, are then taken out, are so recycled for several times, most Gold bracelet semi-finished product are dried in 40 DEG C of -60 DEG C of environment afterwards, obtain gold bracelet.
CN201711433637.XA 2017-12-26 2017-12-26 High tenacity gold article fabrication methods Active CN108118346B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711433637.XA CN108118346B (en) 2017-12-26 2017-12-26 High tenacity gold article fabrication methods

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711433637.XA CN108118346B (en) 2017-12-26 2017-12-26 High tenacity gold article fabrication methods

Publications (2)

Publication Number Publication Date
CN108118346A CN108118346A (en) 2018-06-05
CN108118346B true CN108118346B (en) 2019-11-12

Family

ID=62231876

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711433637.XA Active CN108118346B (en) 2017-12-26 2017-12-26 High tenacity gold article fabrication methods

Country Status (1)

Country Link
CN (1) CN108118346B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114457340A (en) * 2022-01-25 2022-05-10 深圳市金安盛首饰有限公司 Cleaning agent for removing impurities on surface of gold ornament and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560676A (en) * 2009-04-24 2009-10-21 武汉金凰珠宝股份有限公司 Method for electroforming hard gold product
CN102660748A (en) * 2012-05-03 2012-09-12 莆田市金伯爵珠宝首饰有限公司 Processing process for gold products
CN105193018A (en) * 2015-09-10 2015-12-30 深圳市金百泰珠宝实业有限公司 Manufacturing process of gold bracelet and gold bracelet
CN106108297A (en) * 2016-07-28 2016-11-16 山东招金金银精炼有限公司 A kind of purity is the processing technique of 999.99 ‰ reverse mould class gold jewelries
CN106213705A (en) * 2016-07-28 2016-12-14 山东招金金银精炼有限公司 A kind of purity is the processing technique of 999.99 ‰ chain class gold jewelries
CN106213706A (en) * 2016-07-28 2016-12-14 山东招金金银精炼有限公司 A kind of purity is the processing technique of 999.99 ‰ oil pressure class gold jewelries

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560676A (en) * 2009-04-24 2009-10-21 武汉金凰珠宝股份有限公司 Method for electroforming hard gold product
CN102660748A (en) * 2012-05-03 2012-09-12 莆田市金伯爵珠宝首饰有限公司 Processing process for gold products
CN105193018A (en) * 2015-09-10 2015-12-30 深圳市金百泰珠宝实业有限公司 Manufacturing process of gold bracelet and gold bracelet
CN106108297A (en) * 2016-07-28 2016-11-16 山东招金金银精炼有限公司 A kind of purity is the processing technique of 999.99 ‰ reverse mould class gold jewelries
CN106213705A (en) * 2016-07-28 2016-12-14 山东招金金银精炼有限公司 A kind of purity is the processing technique of 999.99 ‰ chain class gold jewelries
CN106213706A (en) * 2016-07-28 2016-12-14 山东招金金银精炼有限公司 A kind of purity is the processing technique of 999.99 ‰ oil pressure class gold jewelries

Also Published As

Publication number Publication date
CN108118346A (en) 2018-06-05

Similar Documents

Publication Publication Date Title
CN108118346B (en) High tenacity gold article fabrication methods
CN106544494A (en) A kind of online soft annealing method suitable for 1Cr17Ni2 rustless steel cold pull wires
CN108994544A (en) A kind of production technology of high-strength fastening bolt
JPS5620136A (en) Copper alloy member
CN117165809A (en) Titanium copper alloy pipe and preparation method thereof
CN109022700B (en) Heat treatment method of high-nitrogen high-corrosion-resistance plastic die steel
CN111304483B (en) Pure gold and preparation method and application thereof
CN109778108A (en) A kind of Fe-Ni-Cr system high temperature alloy nitriding method
CN105420645B (en) The forging and stamping handling process of aluminium
GB912524A (en) Improved high strength steels and method for producing same
CN101591792A (en) Nickel-free electroplating technology
CN108588300A (en) A kind of production method of improved breathable environment-protective leather
CN105648742B (en) A kind of human hair substitute and preparation method thereof
CN106893835A (en) A kind of Technology for Heating Processing of rocking arm
CN106757059A (en) A kind of Technology for Heating Processing of rocking arm
CN107675105A (en) A kind of stainless steel with superplastic ability
CN102115976B (en) Wig nursing and setting agent, preparation process thereof and method for wig arrangement
US20220195610A1 (en) Martensitic stainless steel pipe and method of manufacturing the same
CN106312453A (en) Method for processing fastening part
US498214A (en) Process of tawing skins
Rani et al. The History of Hinduism and Islam in Indonesia: A Review on Western Perspective
CN105925932A (en) Micro-carbonitriding process for 1215-free-cutting-steel fastener
AT101009B (en) Process for the production of fermentation citric acid.
CN112575129A (en) Environment-friendly rabbit fur leather integrated manufacturing method
CN112239824A (en) High-nickel lead-containing free-cutting material and grain structure densification production process thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant