CN105648742B - A kind of human hair substitute and preparation method thereof - Google Patents

A kind of human hair substitute and preparation method thereof Download PDF

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Publication number
CN105648742B
CN105648742B CN201610016679.2A CN201610016679A CN105648742B CN 105648742 B CN105648742 B CN 105648742B CN 201610016679 A CN201610016679 A CN 201610016679A CN 105648742 B CN105648742 B CN 105648742B
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parts
hair
horse
weight
human hair
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CN105648742A (en
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张曦鹤
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HENAN RUIMEI HAIR CO Ltd
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HENAN RUIMEI HAIR CO Ltd
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Abstract

The present invention relates to hair products technical field, and in particular to a kind of human hair substitute and preparation method thereof.The human hair substitute is made through stripping scale, stretching, setting, post processing successively using horse-hair；It is described to be stretched as：The horse-hair after scale will be shelled to be fixed on stretcher in input stretching liquid, carry out being stretched to elongation under the conditions of 20 50 DEG C and reach 20 40%；By weight in terms of 100 parts of horse-hairs, required stretching liquid is made up of following raw material in parts by weight：Dredge 5 10 parts of base ethanol, 0.5 1 parts of the pungent fat sulfonate of maleic acid di-secondary, 0.6 0.8 parts of glycerine, Tween 80：0.4 0.7 parts, 1,000 3000 parts of soft water.The human hair substitute of the present invention, performance is more nearly in-vitro human hair, soft, comfortable, good permeability, and is easy to arrange.The preparation method of the present invention, preparation technology is simple, easy to operate, and suitable for industrialized production, and gained human hair substitute is soft, comfortable, good permeability.

Description

A kind of human hair substitute and preparation method thereof
Technical field
The present invention relates to hair products technical field, and in particular to a kind of human hair substitute and preparation method thereof.
Background technology
With the continuous improvement of people's living standards, also more and more higher, hair style species are also more next for pursuit of the people to fashion It is more, it is such as volume, straight, long, short, in point, divide partially, etc., but during perming, hair top layer can be caused Scale destroyed, hair internal structure is in unprotect state, make inside moisture and nutrient loss, be harmful to Hair, scalp and hair follicle, it can be denatured more or less the keratoprotein of hair, hair is easily turned to be yellow, embrittlement, it is easily de- Fall, lackluster, no elasticity, damage hair quality.And the various wig of style can then solve this problem well, different Occasion, different needs of work, different moods, and before fashion, wig all provides irreplaceable effect, and false Hair is worn convenient.Therefore, the demand of hair products is also increasingly increased severely, but produces main raw material(s) --- the in vitro people of hair products Hair resource is but petered out.
In traditional hair product industry, it with in-vitro human hair is raw material production hair products to be all, its history is of long standing and well established, but It is the continuous change with thought of people culture life, the people to wear one's hair long is fewer and fewer, prepares the long span people used in hair products Hair is petered out, so the substitute for finding in-vitro human hair has turned into the most important thing of nowadays hair product industry.People adopt earliest Human hair substitute is：The chemical synthetic fiber silks such as acrylics filament, dacron thread, polyvinyl chloride silk.But due to using these changes Learn synthetic fibres substitute human hair production hair products when consumer wears in the presence of the compatibility with contact human skin, breathe freely Having a good sweat property, active sense, elegant property are poor, are not easy the shortcomings of combing and appreciation effect be not true to nature, do not get consumer reception.
Find the great attention that human hair substitute has caused hair products enterprise.Have Some Enterprises up to now using chemistry Synthetic fibres or the chemical fiber wire replacement in-vitro human hair production hair products for being mixed with partially protein, can be due to that these products are present The defects of compatibility, active property with human contact, having a good sweat property difference, rush to wearer uncomfortable, especially summer wears Wear sultry, and such wig is not easy to arrange, fidelity is inadequate, not enough truly, naturally, wearing effect is poor, can not meet consumer Demand.People's Republic of China's Patent Office Publication is：One kind is disclosed in CN1699646A patent specification《Animal protein Matter artificial hair and its production method》Although containing animal protein in " artificial hair " described in it, its content is often Less than the half of its gross weight, acrylonitrile and acrylic nitrile derivates still containing 40-60%, the application properties of this " artificial hair " Although being better than pure chemistry synthetic fibres, but still exist and contact human skin's compatibility, having a good sweat property, active sense, drift Shifting property etc. is still not so good as natural animal protein fibre silk, can not meet consumer demand well.
The content of the invention
It is an object of the invention to provide a kind of human hair substitute, its chemical component more than 95% of the human hair substitute be all by The animal protein fibre silk that natural animal albumen is formed, its performance are more nearly in-vitro human hair, and the human hair substitute is soft, easypro Suitable, good permeability, and be easy to arrange.
The present invention also aims to provide a kind of preparation method of human hair substitute, the preparation method is used based on horse-hair Raw material is wanted, passes sequentially through stretching, setting, post processing, preparation technology is simple, easy to operate, suitable for industrialized production, and gained human hair Substitute is soft, comfortable, good permeability.
In order to realize the above object the present invention adopts the following technical scheme that：
A kind of preparation method of human hair substitute, including horse-hair is made through stripping scale, stretching, setting, post processing successively；
The stripping scale, which is handled, is：Horse-hair is put into the solution 1 containing sodium chloride and potassium permanganate, at 45-55 DEG C Under the conditions of, it is incubated to the purple disappearance of potassium permanganate, then takes out after horse-hair rinses, then that horse-hair is put into sodium hydrogensulfite is molten In liquid, solution is adjusted at 40-50 DEG C, with pH adjusting agent to processing 10-30 minutes under conditions of pH=5-6, is then taken out clean ；By weight in terms of 100 parts of horse-hairs, required solution 1 is made up of following raw material in parts by weight：1000-3000 part quality Concentration is 26-28% sodium-chloride water solution, 3-8 part potassium permanganate, and required solution of sodium bisulfite is in parts by weight by following Raw material forms：5-6 parts sodium hydrogensulfite, 1000-3000 part soft water；
It is described to be stretched as：Horse-hair after the processing of above-mentioned stripping scale is fixed on stretcher and put into stretching liquid, Carry out being stretched to elongation under the conditions of 20-50 DEG C and reach 20-40%；
By weight in terms of 100 parts of horse-hairs, required stretching liquid is made up of following raw material in parts by weight：Dredge base ethanol 5-10 Part, the pungent fat sulfonate 0.5-1 parts of maleic acid di-secondary, glycerine 0.6-0.8 parts, Tween 80：0.4-0.7 parts, soft water 1000- 3000 parts.
It is described be shaped to the horse-hair after stretching being put into shaping liquid 20-120min is soaked under the conditions of 50-90 DEG C, carry out Setting；
By weight in terms of 100 parts of horse-hairs, required shaping liquid is made up of following raw material in parts by weight：Purity be 70% with On tannic acid 30-60 parts, soft water 1000-3000 parts；And shaping liquid pH value is adjusted to 1-3 with pH adjusting agent.
The pH adjusting agent is formic acid or acetic acid.
The post processing is to put into the horse-hair after setting in aftertreatment fluid to be incubated 20-60min under the conditions of 40-50 DEG C；
By weight in terms of 100 parts of horse-hairs, required aftertreatment fluid is made up of following raw material in parts by weight：Solid content is 28-33% terminal hydroxy group silicone emulsion 4-6 parts, hexadecyltrimethylammonium chloride 3-5 parts, AEO 2-3 Part, soft water 1000-3000 parts.
Also include the horse-hair after the post processing at 60-90 DEG C, drying, produce.
A kind of human hair substitute, is made by above-mentioned preparation method.
Use horse-hair to prepare a kind of and natural human hair for raw material it is an object of the invention to provide one kind to tie in chemistry The all very close human hair substitute of structure practical performance etc..Natural horse-hair is in chemical constitution, physical and chemical performance etc. and day Right human hair is quite similar, and their main chemical compositions are animal protein, but horse-hair is compared with human hair, its wool top compared with Slightly, quality is stiff, and feel is coarse, and it is infeasible directly to bring and substitute human hair production hair products.Therefore, the present invention is first by horse The scale on hair on the neck surface is partly or entirely peeled off, its surface is become smooth exquisiteness, and then it is soaked and stretched in liquid is stretched, It is attenuated, it is elongated after, then shaped and post-processed, produce the human hair substitute of the present invention.
The preparation method of the present invention has further the advantage that：
1st, the present invention is partly or entirely peeled the scale on horse-hair surface off using potassium permanganate-neutral sulfity process, makes its surface Become smooth exquisiteness, closer to human hair texture, while do not damage the cortical layer and internal fiber of horse-hair；
2nd, present invention stretching liquid used, makes horse-hair not broken in drawing process, drawing effect is more preferable；
3rd, the horse-hair after aftertreatment fluid processing used in the present invention, more soft, smooth, texture is more preferable, presses close to human hair texture.
Human hair substitute obtained by preparation method of the present invention, its chemical component more than 95% are all by natural animal albumen structure Into animal protein fibre silk, its performance is more nearly in-vitro human hair, and texture is soft, smooth, comfortable, good permeability, and is easy to Arrange, press close to human hair texture.
Embodiment
Embodiment 1
A kind of human hair substitute, is prepared by following methods：
(1) scale is shelled：The sodium-chloride water solution 1000g that mass concentration is 26% is weighed, weighs horse-hair 100g input chlorinations In sodium solution, 6g potassium permanganate is then taken to obtain the permanganic acid solution solution that mass concentration is 6% with 60 DEG C or so of hot water dissolving, And the liquor potassic permanganate is added in sodium chloride solution and stirred evenly, mixed solution is obtained, the mixed solution is then warming up to 50 DEG C, and the purple of isothermal holding to potassium permanganate disappears, and then takes out after horse-hair rinses with soft water, then put into sodium hydrogensulfite The aqueous solution in, specially weigh 5 parts of sodium hydrogensulfites, 1000 parts of soft water are configured to aqueous solution of sodium bisulfite, and use acetic acid The pH value of the aqueous solution of sodium bisulfite is adjusted to pH=5, solution is heated to 45 DEG C ± 1 DEG C, is incubated under occasional agitation After reaction 15 minutes, horse-hair taking-up is cleaned with soft water；
(2) stretch：Configuration stretching liquid：Weigh thin base ethanol 8g, disecoctylmaleate sodium sulfonate 0.6g, glycerine 0.8g, Tween 80：0.7g, is added to stir evenly in 1000g water and produces；
Horse-hair after step (1) stripping scale processing is fixed on stretcher, then puts into being heated to of having configured In 45 DEG C of stretching liquid, and horse-hair is stretched in the case where keeping 45 DEG C ± 2 DEG C of temperature conditionss, attenuate, when stretching increases by 30% When, taking-up is rinsed well with soft water；
(3) shape：Prepare style keeping liquid：The tannic acid 50g that purity is 70% is weighed, is added in 1500g soft water, treats that its is molten Xie Hou, its pH is adjusted to pH=2 with acetic acid, then put into the horse-hair after step (2) stretching in this shaping liquid, by solution Be heated to 80 DEG C, and keep solution temperature under 80 DEG C ± 2 DEG C of situation, immersion 120 minutes when taking-up cleaned with soft water；
(4) post-process：Configure aftertreatment fluid：Weigh the terminal hydroxy group silicone emulsion 5g that solid content is 30%, cetyl Trimethyl ammonium chloride 4g, AEO 2.5g, is added in 1500 soft water, and is heated to 45 DEG C and stirs evenly, and produces； Then the horse-hair after step (3) sizing is put into this solution, keeps solution temperature to be soaked 30 minutes at 45 DEG C, take Go out dehydration；
(5) put the horse-hair after being handled more than into baking room, dried at 80 DEG C, obtain finished product.
Embodiment 2
A kind of human hair substitute, is prepared by following methods：
(1) scale is shelled：The sodium-chloride water solution 2000g that mass concentration is 27% is weighed, weighs horse-hair 100g input chlorinations In sodium solution, 3g potassium permanganate is then taken to obtain the permanganic acid solution solution that mass concentration is 3% with 60 DEG C or so of hot water dissolving, And the liquor potassic permanganate is added in sodium chloride solution and stirred evenly, mixed solution is obtained, the mixed solution is then warming up to 45 DEG C, and the purple of isothermal holding to potassium permanganate disappears, and then takes out after horse-hair rinses with soft water, then put into sodium hydrogensulfite The aqueous solution in, specially weigh 6 parts of sodium hydrogensulfites, 2000 parts of soft water are configured to aqueous solution of sodium bisulfite, and use acetic acid The pH value of the aqueous solution of sodium bisulfite is adjusted to pH=6, solution is heated to 40 DEG C, the insulation reaction 30 under occasional agitation After minute, horse-hair taking-up is cleaned with soft water；
(2) stretch：Horse-hair after step (1) shells scale processing is fixed on stretcher, then puts into and configures Be heated in 20 DEG C of stretching liquid, and horse-hair is stretched in the case where keeping 20 DEG C ± 2 DEG C of temperature conditionss, attenuate, work as stretching When increasing by 20%, taking-up is rinsed well with soft water, wherein the stretching liquid is configured to：Weigh thin base ethanol 7g, maleic two Sour di-sec-octyl sodium sulfonate 0.8g, glycerine 0.7g, Tween 80：0.5g is added to stir evenly in 1500g soft water and produced；
(3) shape：Prepare style keeping liquid：The tannic acid 55g that purity is 75% is weighed, is added in 2000g soft water, treats that its is molten Xie Hou, its pH is adjusted to pH=1.5 with acetic acid, then put into the horse-hair after step (2) stretching in this shaping liquid, will be molten Liquid is heated to 50 DEG C, and keeps solution temperature under 50 DEG C ± 2 DEG C of situation, immersion 118 minutes when taking-up cleaned with soft water；
(4) post-process：Configure aftertreatment fluid：Weigh the terminal hydroxy group silicone emulsion 6g that solid content is 32%, cetyl Trimethyl ammonium chloride 4.5g, AEO 3g, is added in 2000 soft water, and is heated to 40 DEG C and stirs evenly, and produces； Then the horse-hair after step (3) sizing is put into this solution, keeps solution temperature to be soaked 60 minutes at 40 DEG C, take Go out dehydration；
(5) put the horse-hair after being handled more than into baking room, dried at 90 DEG C, obtain finished product.
Embodiment 3
A kind of human hair substitute, is prepared by following methods：
(1) scale is shelled：The sodium-chloride water solution 3000g that mass concentration is 28% is weighed, weighs horse-hair 100g input chlorinations In sodium solution, 8g potassium permanganate is then taken to obtain the permanganic acid solution solution that mass concentration is 8% with 60 DEG C or so of hot water dissolving, And the liquor potassic permanganate is added in sodium chloride solution and stirred evenly, mixed solution is obtained, the mixed solution is then warming up to 55 DEG C, and the purple of isothermal holding to potassium permanganate disappears, and then takes out after horse-hair rinses with soft water, then put into sodium hydrogensulfite The aqueous solution in, specially weigh 6 parts of sodium hydrogensulfites, 3000 parts of soft water are configured to aqueous solution of sodium bisulfite, and use acetic acid The pH value of the aqueous solution of sodium bisulfite is adjusted to pH=5, solution is heated to 50 DEG C, the insulation reaction 10 under occasional agitation After minute, horse-hair taking-up is cleaned with soft water；
(2) stretch：Horse-hair after step (1) shells scale processing is fixed on stretcher, then puts into and configures Be heated in 48 DEG C of stretching liquid, and horse-hair is stretched in the case where keeping 48 DEG C ± 2 DEG C of temperature conditionss, attenuate, work as stretching When increasing by 40%, taking-up is rinsed well with soft water, wherein the stretching liquid is configured to：Weigh thin base ethanol 9g, maleic two Sour di-sec-octyl sodium sulfonate 0.7g, glycerine 0.6g, Tween 80：0.4g is added to stir evenly in 2000g soft water and produced；
(3) shape：Prepare style keeping liquid：The tannic acid 60g that purity is 85% is weighed, is added in 1300g soft water, treats that its is molten Xie Hou, its pH is adjusted to pH=1.6 with acetic acid, then put into the horse-hair after step (2) stretching in this shaping liquid, will be molten Liquid is heated to 88 DEG C, and keeps solution temperature under 88 DEG C ± 2 DEG C of situation, immersion 20 minutes when taking-up cleaned with soft water；
(4) post-process：Configure aftertreatment fluid：Weigh the terminal hydroxy group silicone emulsion 4.5g that solid content is 33%, hexadecane Base trimethyl ammonium chloride 3.5g, AEO 2.2g, is added in 1800 soft water, and is heated to 48 DEG C and stirs evenly, Produce；Then the horse-hair after step (3) sizing is put into this solution, keeps solution temperature to soak 20 points at 48 DEG C Clock, take out dehydration；
(5) put the horse-hair after being handled more than into baking room, dried at 60 DEG C, obtain finished product.
Embodiment 4
A kind of human hair substitute, is prepared by following methods：
(1) scale is shelled, specifically with embodiment 1；
(2) stretch：Horse-hair after step (1) shells scale processing is fixed on stretcher, then puts into and configures Be heated in 48 DEG C of stretching liquid, and horse-hair is stretched in the case where keeping 48 DEG C ± 2 DEG C of temperature conditionss, attenuate, work as stretching When increasing by 40%, taking-up is rinsed well with soft water, wherein the stretching liquid is configured to：Weigh thin base ethanol 5g, maleic two Sour di-sec-octyl sodium sulfonate 1g, glycerine 0.8g, Tween 80：0.6g is added to stir evenly in 3000g soft water and produced；
(3) shape：Prepare style keeping liquid：The tannic acid 30g that purity is 80% is weighed, is added in 3000g soft water, treats that its is molten Xie Hou, its pH is adjusted to pH=2.5 with acetic acid, then put into the horse-hair after step (2) stretching in this shaping liquid, will be molten Liquid is heated to 65 DEG C, and keeps solution temperature under 65 DEG C ± 2 DEG C of situation, immersion 70 minutes when taking-up cleaned with soft water；
(4) post-process：Configure aftertreatment fluid：Weigh the terminal hydroxy group silicone emulsion 4g that solid content is 28%, cetyl Trimethyl ammonium chloride 5g, AEO 2g, is added in 2500 soft water, and is heated to 50 DEG C and stirs evenly, and produces；So The horse-hair after step (3) sizing is put into this solution afterwards, keeps solution temperature to be soaked 22 minutes at 50 DEG C, is taken out Dehydration；
(5) put the horse-hair after being handled more than into baking room, dried at 70 DEG C, obtain finished product.
Embodiment 5
A kind of human hair substitute, is prepared by following methods：
(1) scale is shelled, specifically with embodiment 2；
(2) stretch：Horse-hair after step (1) shells scale processing is fixed on stretcher, then puts into and configures Be heated in 48 DEG C of stretching liquid, and horse-hair is stretched in the case where keeping 48 DEG C ± 2 DEG C of temperature conditionss, attenuate, work as stretching When increasing by 40%, taking-up is rinsed well with soft water, wherein the stretching liquid is configured to：Weigh thin base ethanol 10g, maleic two Sour di-sec-octyl sodium sulfonate 0.5g, glycerine 0.8g, Tween 80：0.7g is added to stir evenly in 2500g soft water and produced；
(3) shape：Prepare style keeping liquid：The tannic acid 40g that mass concentration is 88% is weighed, is added in 2500g soft water, treats After it dissolves, its pH is adjusted to pH=3 with acetic acid, then put into the horse-hair after step (2) stretching in this shaping liquid, will Solution is heated to 72 DEG C, and keeps solution temperature under 72 DEG C ± 2 DEG C of situation, immersion 80 minutes when taking-up cleaned with soft water；
(4) post-process：Configure aftertreatment fluid：Weigh the terminal hydroxy group silicone emulsion 6g that solid content is 29%, cetyl Trimethyl ammonium chloride 3g, AEO 3g, is added in 3000 soft water, and is heated to 47 DEG C and stirs evenly, and produces；So The horse-hair after step (3) sizing is put into this solution afterwards, keeps solution temperature to be soaked 40 minutes at 47 DEG C, is taken out Dehydration；
(5) put the horse-hair after being handled more than into baking room, dried at 75 DEG C, obtain finished product.
Horse-hair used in embodiment 1-5, it also can be replaced the mixture or horse hair of horse-hair and horse hair.

Claims (6)

  1. A kind of 1. preparation method of human hair substitute, it is characterised in that including by horse-hair successively through stripping scale, stretching, setting, after Processing is made；
    The stripping scale, which is handled, is：Horse-hair is put into the solution 1 containing sodium chloride and potassium permanganate, in 45-55 DEG C of condition Under, it is incubated to the purple disappearance of potassium permanganate, then takes out after horse-hair rinses, then horse-hair put into solution of sodium bisulfite In, solution is adjusted at 40-50 DEG C, with pH adjusting agent to processing 10-30 minutes under conditions of pH=5-6, then takes out and cleans i.e. Can；By weight in terms of 100 parts of horse-hairs, required solution 1 is made up of following raw material in parts by weight：1000-3000 part quality is dense The sodium-chloride water solution for 26-28%, 3-8 part potassium permanganate are spent, required solution of sodium bisulfite is in parts by weight by following original Material composition：5-6 parts sodium hydrogensulfite, 1000-3000 part soft water；
    It is described to be stretched as：Horse-hair after stripping scale is fixed on stretcher and put into stretching liquid, is entered under the conditions of 20-50 DEG C Row is stretched to elongation and reaches 20-40%；
    By weight in terms of 100 parts of horse-hairs, required stretching liquid is made up of following raw material in parts by weight：Base ethanol 5-10 parts are dredged, The pungent fat sulfonate 0.5-1 parts of maleic acid di-secondary, glycerine 0.6-0.8 parts, Tween 80：0.4-0.7 parts, soft water 1000-3000 Part.
  2. 2. the preparation method of human hair substitute according to claim 1, it is characterised in that described to be shaped to after stretching Horse-hair is put into shaping liquid soaks 20-120min under the conditions of 50-90 DEG C, is shaped；
    By weight in terms of 100 parts of horse-hairs, required shaping liquid is made up of following raw material in parts by weight：Purity is more than 70% Tannic acid 30-60 parts, soft water 1000-3000 parts；And shaping liquid pH value is adjusted to 1-3 with pH adjusting agent.
  3. 3. the preparation method of human hair substitute according to claim 2, it is characterised in that the pH adjusting agent be formic acid or Acetic acid.
  4. 4. the preparation method of human hair substitute according to claim 1, it is characterised in that the post processing is after shaping Horse-hair input aftertreatment fluid in 20-60min is incubated under the conditions of 40-50 DEG C；
    By weight in terms of 100 parts of horse-hairs, required aftertreatment fluid is made up of following raw material in parts by weight：Solid content is 28- 33% terminal hydroxy group silicone emulsion 4-6 parts, hexadecyltrimethylammonium chloride 3-5 parts, AEO 2-3 parts, Soft water 1000-3000 parts.
  5. 5. the preparation method of human hair substitute according to claim 1, it is characterised in that also include after the post processing Horse-hair at 60-90 DEG C, drying, produce.
  6. 6. a kind of human hair substitute, it is characterised in that be made as the preparation method described in claim 1-5.
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