CN108117752A - A kind of automobile using heat-resistant antifriction rubber hose - Google Patents

A kind of automobile using heat-resistant antifriction rubber hose Download PDF

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Publication number
CN108117752A
CN108117752A CN201611065533.3A CN201611065533A CN108117752A CN 108117752 A CN108117752 A CN 108117752A CN 201611065533 A CN201611065533 A CN 201611065533A CN 108117752 A CN108117752 A CN 108117752A
Authority
CN
China
Prior art keywords
parts
heat
rubber hose
resistant antifriction
automobile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611065533.3A
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Chinese (zh)
Inventor
刘梦菲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENYANG SAIYA RUBBER PRODUCTS CO Ltd
Original Assignee
SHENYANG SAIYA RUBBER PRODUCTS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENYANG SAIYA RUBBER PRODUCTS CO Ltd filed Critical SHENYANG SAIYA RUBBER PRODUCTS CO Ltd
Priority to CN201611065533.3A priority Critical patent/CN108117752A/en
Publication of CN108117752A publication Critical patent/CN108117752A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/017Additives being an antistatic agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

Abstract

The invention discloses a kind of automobile using heat-resistant antifriction rubber hoses, are prepared from the following raw materials in parts by weight:10 15 parts of silicon rubber powder, 5 10 parts of styrene butadiene block copolymer, 39 parts of titanium dioxide, 13 17 parts of triisobutyl aluminium, 25 parts of toluene heptane, 69 parts of sericite, 9 15 parts of propylene, 46 parts of diatomite, 5 12 parts of clay, 5 13 parts of iron oxide red, 35 parts of ethylidene norbornene, 5.5 8.5 parts of triacetin, 79 parts of anhydrous calcium chloride, 11 16 parts of zinc oxide, 15 18 parts of chalk, 7 12 parts of barite, 7 15 parts of carbon black, 13 parts of antioxidant, 28 parts of color masterbatch, 58 parts of thermoplastic elastomer (TPE), 26 parts of ethylene propylene diene rubber, 48 parts of antistatic agent.The present invention has good resistance to acid and alkali and wearability, while environmentally safe;The aging action of sebific duct can effectively be delayed, not only further increase the toughness of sebific duct, but also improve its heat resistance, compared to similar product, 2 times of heat-resistance coefficient can be improved.

Description

A kind of automobile using heat-resistant antifriction rubber hose
Technical field
The invention belongs to rubber hose technical fields, particularly relate to a kind of automobile using heat-resistant antifriction rubber hose.
Background technology
Rubber hose mainly connects engine and air cleaner, engine and radiator system, automotive air-conditioning system Deng.Its component as gas handling system, it is nearer from engine, it is therefore desirable to high temperature resistant, oil resistant, corrosion-resistant, ageing-resistant, resistance to Low temperature etc., there are many species, such as NBR nitrile rubbers to be widely used in brake vacuum pipe according to processing technology different for material, The good gel content of oil resistivity is high, but resistance to ozone is relatively poor;EPDM ethylene propylene diene rubbers are for automobile water pipe series.Such as radiator Sebific duct, air-conditioner pipe etc., the material for also having some performances higher, such as AEM acrylic ester high-temperatures, each rubber have his Characteristic, thus it is particularly important on sebific duct the selection of material.
At present, fluid sealant species of the prior art is various, but the fluid sealant on automobile is seldom, and currently on the market Automobile sealant stability is poor, caking property is bad and easy money as gift comes off in high temperature environments, has seriously affected automotive sealant Bonding.On automobile, the place such as air-conditioning, cooling, electronic-controlled power steering uses sebific duct more, and fuel oil, brake portion use metal more Pipe also has part to use rubber hose;Automobile rubber sebific duct is flexible article, is cut according to length, and prefabricated simple, shape can Become, assembling arrangement is easy, but easy to aging is not durable.
The content of the invention
The present invention addresses the above problem, makes up the deficiencies in the prior art, provides a kind of automobile using heat-resistant antifriction rubber Sebific duct.
To achieve the above object, the present invention adopts the following technical scheme that.
A kind of automobile using heat-resistant antifriction rubber hose of the present invention, it is characterised in that:The heat-resistant antifriction rubber hose by The raw material of following parts by weight is made:10-15 parts of silicon rubber powder, 5-10 parts of styrene-butadiene block copolymer, titanium dioxide 3-9 parts, 13-17 parts of triisobutyl aluminium, toluene -2-5 parts of heptane, 6-9 parts of sericite, 9-15 parts of propylene, 4-6 parts of diatomite, pottery It is 5-12 parts native, 5-13 parts of iron oxide red, 3-5 parts of ethylidene norbornene, 5.5-8.5 parts of triacetin, anhydrous calcium chloride 7-9 Part, 11-16 parts of zinc oxide, 15-18 parts of chalk, 7-12 parts of barite, 7-15 parts of carbon black, 1-3 parts of antioxidant, 2-8 parts of color masterbatch, heat 5-8 parts of thermoplastic elastic, 2-6 parts of ethylene propylene diene rubber, 4-8 parts of antistatic agent.
As a preferred embodiment of the present invention, the heat-resistant antifriction rubber hose by following parts by weight raw material system Into:13 parts of silicon rubber powder, 8 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, 15 parts of triisobutyl aluminium, toluene- 4 parts of heptane, 8 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 10 parts of clay, 8 parts of iron oxide red, 4 parts of ethylidene norbornene are sweet Oily 7 parts of triacetate, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 9 parts of barite, 11 parts of carbon black, 2 parts of antioxidant, 5 parts of color masterbatch, 6.5 parts of thermoplastic elastomer (TPE), 5 parts of ethylene propylene diene rubber, 7 parts of antistatic agent.
As the present invention another preferred embodiment, the heat-resistant antifriction rubber hose by following parts by weight raw material It is made:13 parts of silicon rubber powder, 8 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, 15 parts of triisobutyl aluminium, toluene- 4 parts of heptane, 8 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 10 parts of clay, 12 parts of iron oxide red, 3 parts of ethylidene norbornene are sweet Oily 6 parts of triacetate, 9 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 11 parts of barite, 13 parts of carbon black, antioxidant 2.5 Part, 6 parts of color masterbatch, 7 parts of thermoplastic elastomer (TPE), 4 parts of ethylene propylene diene rubber, 7 parts of antistatic agent.
As the present invention another preferred embodiment, the heat-resistant antifriction rubber hose by following parts by weight raw material It is made:12.5 parts of silicon rubber powder, 7.6 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, 15 parts of triisobutyl aluminium, 3.5 parts of toluene-heptane, 7.5 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 8.5 parts of clay, 9 parts of iron oxide red, ethylidene drop ice 4 parts of piece alkene, 7.5 parts of triacetin, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 11 parts of barite, carbon black 13 Part, 2 parts of antioxidant, 6 parts of color masterbatch, 6 parts of thermoplastic elastomer (TPE), 6 parts of ethylene propylene diene rubber, 6 parts of antistatic agent.
As the present invention another preferred embodiment, the heat-resistant antifriction rubber hose by following parts by weight raw material It is made:12.5 parts of silicon rubber powder, 7.6 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, 15 parts of triisobutyl aluminium, 3.5 parts of toluene-heptane, 7.5 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 8.5 parts of clay, 8 parts of iron oxide red, ethylidene drop ice 4 parts of piece alkene, 7 parts of triacetin, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 9 parts of barite, 11 parts of carbon black, 2 parts of antioxidant, 5 parts of color masterbatch, 6.5 parts of thermoplastic elastomer (TPE), 5 parts of ethylene propylene diene rubber, 7 parts of antistatic agent.
Compared with prior art, present invention has the advantages that.
A kind of automobile using heat-resistant antifriction rubber hose disclosed in this invention, it is of the invention with good resistance to acid and alkali and resistance to Mill property, at the same it is environmentally safe;The aging action of sebific duct can effectively be delayed, not only further increase the toughness of sebific duct, and And its heat resistance is improved, compared to similar product, 2 times of heat-resistance coefficient can be improved.
Specific embodiment
Embodiment 1.
A kind of automobile using heat-resistant antifriction rubber hose of the present invention, it is characterised in that:The heat-resistant antifriction rubber hose by The raw material of following parts by weight is made:13 parts of silicon rubber powder, 8 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, three 15 parts of aluminium isobutyl, 4 parts of toluene-heptane, 8 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 10 parts of clay, 8 parts of iron oxide red, 4 parts of ethylidene norbornene, 7 parts of triacetin, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 9 parts of barite, 11 parts of carbon black, 2 parts of antioxidant, 5 parts of color masterbatch, 6.5 parts of thermoplastic elastomer (TPE), 5 parts of ethylene propylene diene rubber, 7 parts of antistatic agent.
Embodiment 2.
A kind of automobile using heat-resistant antifriction rubber hose of the present invention, it is characterised in that:The heat-resistant antifriction rubber hose by The raw material of following parts by weight is made:13 parts of silicon rubber powder, 8 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, three 15 parts of aluminium isobutyl, 4 parts of toluene-heptane, 8 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 10 parts of clay, iron oxide red 12 Part, 3 parts of ethylidene norbornene, 6 parts of triacetin, 9 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, barite 11 Part, 13 parts of carbon black, 2.5 parts of antioxidant, 6 parts of color masterbatch, 7 parts of thermoplastic elastomer (TPE), 4 parts of ethylene propylene diene rubber, 7 parts of antistatic agent.
Embodiment 3.
A kind of automobile using heat-resistant antifriction rubber hose of the present invention, it is characterised in that:The heat-resistant antifriction rubber hose by The raw material of following parts by weight is made:12.5 parts of silicon rubber powder, 7.6 parts of styrene-butadiene block copolymer, titanium dioxide 6 Part, 15 parts of triisobutyl aluminium, 3.5 parts of toluene-heptane, 7.5 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 8.5 parts of clay, oxygen Change 9 parts of iron oxide red, 4 parts of ethylidene norbornene, 7.5 parts of triacetin, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, chalk 17 Part, 11 parts of barite, 13 parts of carbon black, 2 parts of antioxidant, 6 parts of color masterbatch, 6 parts of thermoplastic elastomer (TPE), 6 parts of ethylene propylene diene rubber resist quiet Electric 6 parts of agent.
Embodiment 4.
A kind of automobile using heat-resistant antifriction rubber hose of the present invention, it is characterised in that:The heat-resistant antifriction rubber hose by The raw material of following parts by weight is made:12.5 parts of silicon rubber powder, 7.6 parts of styrene-butadiene block copolymer, titanium dioxide 6 Part, 15 parts of triisobutyl aluminium, 3.5 parts of toluene-heptane, 7.5 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 8.5 parts of clay, oxygen 8 parts of iron oxide red of change, 4 parts of ethylidene norbornene, 7 parts of triacetin, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 9 parts of barite, 11 parts of carbon black, 2 parts of antioxidant, 5 parts of color masterbatch, 6.5 parts of thermoplastic elastomer (TPE), 5 parts of ethylene propylene diene rubber are antistatic 7 parts of agent.
It is understood that above with respect to the specific descriptions of the present invention, it is merely to illustrate the present invention and is not limited to this The described technical solution of inventive embodiments, it will be understood by those of ordinary skill in the art that, still the present invention can be carried out Modification or equivalent substitution, to reach identical technique effect;As long as meeting using needs, all protection scope of the present invention it It is interior.

Claims (5)

1. a kind of automobile using heat-resistant antifriction rubber hose, it is characterised in that:The heat-resistant antifriction rubber hose is by following weight The raw material of number is made:10-15 parts of silicon rubber powder, 5-10 parts of styrene-butadiene block copolymer, 3-9 parts of titanium dioxide, three 13-17 parts of aluminium isobutyl, toluene -2-5 parts of heptane, 6-9 parts of sericite, 9-15 parts of propylene, 4-6 parts of diatomite, clay 5-12 Part, 5-13 parts of iron oxide red, 3-5 parts of ethylidene norbornene, 5.5-8.5 parts of triacetin, 7-9 parts of anhydrous calcium chloride, oxygen Change 11-16 parts of zinc, 15-18 parts of chalk, 7-12 parts of barite, 7-15 parts of carbon black, 1-3 parts of antioxidant, 2-8 parts of color masterbatch, thermoplasticity 5-8 parts of elastomer, 2-6 parts of ethylene propylene diene rubber, 4-8 parts of antistatic agent.
2. a kind of automobile using heat-resistant antifriction rubber hose according to claim 1, it is characterised in that:The heat-resistant antifriction Rubber hose is prepared from the following raw materials in parts by weight:13 parts of silicon rubber powder, 8 parts of styrene-butadiene block copolymer, dioxy Change 6 parts of titanium, 15 parts of triisobutyl aluminium, 4 parts of toluene-heptane, 8 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 10 parts of clay, oxygen 8 parts of iron oxide red of change, 4 parts of ethylidene norbornene, 7 parts of triacetin, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 9 parts of barite, 11 parts of carbon black, 2 parts of antioxidant, 5 parts of color masterbatch, 6.5 parts of thermoplastic elastomer (TPE), 5 parts of ethylene propylene diene rubber are antistatic 7 parts of agent.
3. a kind of automobile using heat-resistant antifriction rubber hose according to claim 1, it is characterised in that:The heat-resistant antifriction Rubber hose is prepared from the following raw materials in parts by weight:13 parts of silicon rubber powder, 8 parts of styrene-butadiene block copolymer, dioxy Change 6 parts of titanium, 15 parts of triisobutyl aluminium, 4 parts of toluene-heptane, 8 parts of sericite, 12 parts of propylene, 5 parts of diatomite, 10 parts of clay, oxygen 12 parts of iron oxide red of change, 3 parts of ethylidene norbornene, 6 parts of triacetin, 9 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 11 parts of barite, 13 parts of carbon black, 2.5 parts of antioxidant, 6 parts of color masterbatch, 7 parts of thermoplastic elastomer (TPE), 4 parts of ethylene propylene diene rubber resist quiet Electric 7 parts of agent.
4. a kind of automobile using heat-resistant antifriction rubber hose according to claim 1, it is characterised in that:The heat-resistant antifriction Rubber hose is prepared from the following raw materials in parts by weight:12.5 parts of silicon rubber powder, 7.6 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, 15 parts of triisobutyl aluminium, 3.5 parts of toluene-heptane, 7.5 parts of sericite, 12 parts of propylene, 5 parts of diatomite, pottery 8.5 parts of soil, 9 parts of iron oxide red, 4 parts of ethylidene norbornene, 7.5 parts of triacetin, 8 parts of anhydrous calcium chloride, zinc oxide 14 Part, 17 parts of chalk, 11 parts of barite, 13 parts of carbon black, 2 parts of antioxidant, 6 parts of color masterbatch, 6 parts of thermoplastic elastomer (TPE), ethylene-propylene-diene monomer 6 parts of glue, 6 parts of antistatic agent.
5. a kind of automobile using heat-resistant antifriction rubber hose according to claim 1, it is characterised in that:The heat-resistant antifriction Rubber hose is prepared from the following raw materials in parts by weight:12.5 parts of silicon rubber powder, 7.6 parts of styrene-butadiene block copolymer, 6 parts of titanium dioxide, 15 parts of triisobutyl aluminium, 3.5 parts of toluene-heptane, 7.5 parts of sericite, 12 parts of propylene, 5 parts of diatomite, pottery 8.5 parts of soil, 8 parts of iron oxide red, 4 parts of ethylidene norbornene, 7 parts of triacetin, 8 parts of anhydrous calcium chloride, 14 parts of zinc oxide, 17 parts of chalk, 9 parts of barite, 11 parts of carbon black, 2 parts of antioxidant, 5 parts of color masterbatch, 6.5 parts of thermoplastic elastomer (TPE), ethylene propylene diene rubber 5 Part, 7 parts of antistatic agent.
CN201611065533.3A 2016-11-28 2016-11-28 A kind of automobile using heat-resistant antifriction rubber hose Pending CN108117752A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611065533.3A CN108117752A (en) 2016-11-28 2016-11-28 A kind of automobile using heat-resistant antifriction rubber hose

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611065533.3A CN108117752A (en) 2016-11-28 2016-11-28 A kind of automobile using heat-resistant antifriction rubber hose

Publications (1)

Publication Number Publication Date
CN108117752A true CN108117752A (en) 2018-06-05

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Application Number Title Priority Date Filing Date
CN201611065533.3A Pending CN108117752A (en) 2016-11-28 2016-11-28 A kind of automobile using heat-resistant antifriction rubber hose

Country Status (1)

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CN (1) CN108117752A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112898775A (en) * 2020-11-30 2021-06-04 安徽恒荣高分子科技有限公司 Heat-resistant pressure-resistant automobile silica gel plug and processing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112898775A (en) * 2020-11-30 2021-06-04 安徽恒荣高分子科技有限公司 Heat-resistant pressure-resistant automobile silica gel plug and processing method thereof

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Application publication date: 20180605

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