CN108117144A - It is a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component - Google Patents

It is a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component Download PDF

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Publication number
CN108117144A
CN108117144A CN201611086507.9A CN201611086507A CN108117144A CN 108117144 A CN108117144 A CN 108117144A CN 201611086507 A CN201611086507 A CN 201611086507A CN 108117144 A CN108117144 A CN 108117144A
Authority
CN
China
Prior art keywords
chitosan
sewage
parts
environment protection
inorganic agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611086507.9A
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Chinese (zh)
Inventor
张炜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Superior Environmental Protection Technology Co Ltd
Original Assignee
Ningbo Superior Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo Superior Environmental Protection Technology Co Ltd filed Critical Ningbo Superior Environmental Protection Technology Co Ltd
Priority to CN201611086507.9A priority Critical patent/CN108117144A/en
Publication of CN108117144A publication Critical patent/CN108117144A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5263Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds

Abstract

The invention discloses a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component, contain chitosan, organic flocculant and flocculation aid.Environment protection biological compound sewage inorganic agent disclosed by the invention handles Lu Yuan sewage, ocean sewage and marine culture wastewater and works well, and can remove various pollutants, water body is made to obtain high-efficient purification, and will not generate secondary pollution.

Description

It is a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component
Technical field
It is more particularly to a kind of compound using chitosan as the environment protection biological of key component the invention belongs to sewage treatment field Sewage-treating agent.
Background technology
China Lu Yuan sewage, ocean sewage and marine culture wastewater pollution are very serious at present, such as China's coastal areas pollution Seriously, many immediate offshore areas are inferior to national IV classes sea water quality standard substantially, belong to serious pollution marine site, seriously affect periphery residence People's quality of life and city coastline landscape;And for breeding water body self-pollution is on the rise, disease takes place frequently, simultaneously because outside The influence of source contact scar object, breeding environment quality increasingly decline.This not only directly damages to breed variety, but also bad water Prime factor is also the main inducement that explosive disease frequently occurs.
But it is unsatisfactory that the presently disclosed sewage-treating agent in China handles above-mentioned sewage effect.As Lu Yuan sewage flocculants are more Using polyacrylamide, polyaluminium sulfate etc., there is certain treatment effect, but be present with certain secondary pollution;Offshore The flocculant that marine site sewage disposal uses contains some bio-toxicities and and can cause secondary pollution;Marine culture wastewater is due to one As the technology of used physico-chemical method control water quality have a variety of drawbacks, therefore, BIOLOGICAL CONTROL is just paid attention to.But current state Inside and outside general mutually adjusted using algae is mutually adjusted with bacterium, wherein, it is one of current most technology used for aquiculture that bacterium, which is mutually adjusted, But it, which is operated, has comparable complexity and difficulty to control, and effectively reduces harmful substance since these preparations are unable to reach Effect can cause most of high density shrimp ponds to lie dormant the crisis of infectiousness prawn disease or prawn harmful substance nosotoxicosis, and meeting Cause secondary pollution.
Sewage-treating agent is often with flocculant, the research to flocculant, with efficient, cheap, environmentally friendly for target at present.Environmental protection is Nontoxic or less toxic efficient flocculant is pointedly developed, makes it in drinking water and other use water process related with physical activity It reduces bio-toxicity and residual quantity no longer causes secondary pollution, be an important directions of flocculant research and development from now on.Flocculation Agent developing direction from low molecule to macromolecule, by it is inorganic to organic and microorganism, by single type to composite flocculant.It is inorganic and Organic polymer composite flocculant has also at home and abroad obtained extensive development because combining the advantages of inorganic and organic, into For the hot spot of current flocculant research, the trend of safe and nontoxic, the efficient more substituted traditional flocculant of microbial flocculant.
But still do not develop at present a kind of can not only handle Lu Yuan sewage, ocean sewage and sea-farming and give up simultaneously Water, and the sewage-treating agent of secondary pollution will not be caused.
The content of the invention
To overcome above-mentioned technological deficiency, the invention discloses it is a kind of efficiently, environmental protection can be used for simultaneously handle Lu Yuan dirt The environment protection biological compound sewage inorganic agent of water, ocean sewage and marine culture wastewater.
Environment protection biological compound sewage inorganic agent disclosed by the invention, key component are chitosans, also containing organic wadding Solidifying agent and flocculation aid.
The organic flocculant is bodied ferric sulfate, and the flocculation aid is oyster shell powder.
By the use of distilled water as solvent, by weight, contain 1~20 part of chitosan, 5~10 parts of bodied ferric sulfate, oyster shell powder 10~200 parts, 100~120 parts of distilled water.
Preferably, by weight, containing 5~20 parts of chitosan, 5~10 parts of bodied ferric sulfate, 50~100 parts of oyster shell powder, 100~120 parts of distilled water.
Environment protection biological compound sewage inorganic agent disclosed by the invention using chitosan as key component can be handled simultaneously Lu Yuan sewage, ocean sewage and marine culture wastewater, treatment effect well to the removal rate of SS and turbidity up to 85%, wherein strengthening Removal rate of the removal rate more than 75%, COD is 72.5%, wherein the removal rate that reinforcing removal rate is 63.8%, BOD5 is 56.4%, wherein it is 43.5% to strengthen removal rate, strengthen with obvious effects.The COD of flocculation treatment dyeing waste water also has higher go Except rate, 95% is more than to the COD removal rates of anionic dyes, to the COD removal rates of other waste water from dyestuff also up to more than 92%. And the oyster shell powder in composite flocculation agent has porosity, while there is bactericidal effect.
Specific embodiment
It below will the present invention is described in detail by specific embodiment.
Embodiment 1:
5 parts of chitosan, 10 parts of bodied ferric sulfate, 50 parts of oyster shell powder, 120 parts of distilled water.
Embodiment 2:
20 parts of chitosan, 10 parts of bodied ferric sulfate, 200 parts of oyster shell powder, 120 parts of distilled water.
Embodiment 3:
10 parts of chitosan, 8 parts of bodied ferric sulfate, 50 parts of oyster shell powder, 100 parts of distilled water.
Implement 4:
5 parts of chitosan, 10 parts of bodied ferric sulfate, 50 parts of oyster shell powder, 100 parts of distilled water.
Embodiment 5:
Sewage is carried out to Shenzhen great Chan gulfs sewage water body to environment protection biological compound sewage inorganic agent prepared by embodiment 1-4 It administers, specific method is:Pick up from the black foul sewage water before 10-11 months big shovel gulf flood tide.Water intaking adds in multiple to 50kg drums on the spot Flocculant is closed, injected volume can be 0.5ppm-1000ppm.In the present embodiment injected volume be respectively 0.5ppm, 10ppm, 50ppm, 100ppm, 500ppm, 1000ppm, with bailer gentle agitation it is several under, refer to launching the water quality before and after environmentally friendly compound sewage inorganic agent Mark is detected.
Embodiment 6:
The environment protection biological compound sewage inorganic agent of embodiment 1-4 is put into the urban industry sewage water of acquisition respectively Sample, injected volume is respectively 0.5ppm, 10ppm, 50ppm, 100ppm, 500ppm, 1000ppm, to launching at environmentally friendly compound sewage Water quality index before and after reason agent is detected, and water quality substantially gets a promotion.
Embodiment 7:
The environment protection biological compound sewage inorganic agent of embodiment 1-4 is put into the aquaculture sewage draining exit of acquisition respectively In water body, injected volume is respectively 0.5ppm, 10ppm, 50ppm, 100ppm, 500ppm, 1000ppm, to launching the compound dirt of environmental protection Water quality index before and after water treatment agent is detected, and water quality substantially gets a promotion.
By detection, environmentally friendly compound sewage inorganic agent of the invention is 48~72%, Ab series to SS removal rates in sewage It is 64~76% for 64~72%, Pb series, and is that 25ppm is optimal;TP removal rates 61.5~92%;TN removal rates 65.9 ~87.2%;NH3-N removal rates 46.1~59.6%;COD removal rates 41.2~66.4%;DO growth rates 52.8~63.1%.
Therefore environment protection biological compound sewage inorganic agent processing Lu Yuan sewage, ocean sewage and seawater of the invention Breeding wastewater works well, and can remove various pollutants, and water body is made to obtain high-efficient purification, and will not generate secondary pollution.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the invention as claimed with Modification should all belong to the covering scope of the claims in the present invention.

Claims (4)

  1. It is 1. a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component, it is characterised in that:Containing chitosan, Organic flocculant and flocculation aid.
  2. 2. as described in claim 1 using chitosan as the environment protection biological compound sewage inorganic agent of key component, feature exists In:The organic flocculant is bodied ferric sulfate, and the flocculation aid is oyster shell powder.
  3. 3. as claimed in claim 2 using chitosan as the environment protection biological compound sewage inorganic agent of key component, feature exists In:By the use of distilled water as solvent, by weight, containing 1~20 part of chitosan, 5~10 parts of bodied ferric sulfate, oyster shell powder 10~ 200 parts, 100~120 parts of distilled water.
  4. 4. as claimed in claim 3 using chitosan as the environment protection biological compound sewage inorganic agent of key component, feature exists In:By weight, containing 5~20 parts of chitosan, 5~10 parts of bodied ferric sulfate, 50~100 parts of oyster shell powder, distilled water 100~ 120 parts.
CN201611086507.9A 2016-11-28 2016-11-28 It is a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component Pending CN108117144A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611086507.9A CN108117144A (en) 2016-11-28 2016-11-28 It is a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611086507.9A CN108117144A (en) 2016-11-28 2016-11-28 It is a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component

Publications (1)

Publication Number Publication Date
CN108117144A true CN108117144A (en) 2018-06-05

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CN201611086507.9A Pending CN108117144A (en) 2016-11-28 2016-11-28 It is a kind of using chitosan as the environment protection biological compound sewage inorganic agent of key component

Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109133309A (en) * 2018-10-10 2019-01-04 江苏京牧生物技术有限公司 A kind of preparation method of compound sewage-treating agent
CN112028166A (en) * 2020-08-28 2020-12-04 南京传业环保科技有限公司 Environment-friendly biological composite sewage treatment agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109133309A (en) * 2018-10-10 2019-01-04 江苏京牧生物技术有限公司 A kind of preparation method of compound sewage-treating agent
CN112028166A (en) * 2020-08-28 2020-12-04 南京传业环保科技有限公司 Environment-friendly biological composite sewage treatment agent

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Application publication date: 20180605

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