CN108106325A - Suitable for marine natural gas liquefaction system - Google Patents
Suitable for marine natural gas liquefaction system Download PDFInfo
- Publication number
- CN108106325A CN108106325A CN201810014919.4A CN201810014919A CN108106325A CN 108106325 A CN108106325 A CN 108106325A CN 201810014919 A CN201810014919 A CN 201810014919A CN 108106325 A CN108106325 A CN 108106325A
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- Prior art keywords
- heat exchanger
- main
- deep cooling
- cooling
- precooling
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 239000003345 natural gas Substances 0.000 title claims abstract description 31
- 238000001816 cooling Methods 0.000 claims abstract description 137
- 239000003507 refrigerant Substances 0.000 claims abstract description 57
- 239000007789 gas Substances 0.000 claims abstract description 43
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 23
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 23
- 239000001294 propane Substances 0.000 claims abstract description 19
- 235000019628 coolness Nutrition 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims description 47
- 210000000038 chest Anatomy 0.000 claims description 37
- 238000000926 separation method Methods 0.000 claims description 36
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000498 cooling water Substances 0.000 claims description 11
- 239000007791 liquid phase Substances 0.000 claims description 9
- 230000006835 compression Effects 0.000 claims description 8
- 238000007906 compression Methods 0.000 claims description 8
- 239000012071 phase Substances 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000007792 gaseous phase Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 15
- 239000003949 liquefied natural gas Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 238000007667 floating Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0209—Natural gas or substitute natural gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0238—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/08—Separating gaseous impurities from gases or gaseous mixtures or from liquefied gases or liquefied gaseous mixtures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/02—Processes or apparatus using separation by rectification in a single pressure main column system
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/70—Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
- F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/60—Natural gas or synthetic natural gas [SNG]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2260/00—Coupling of processes or apparatus to other units; Integrated schemes
- F25J2260/20—Integration in an installation for liquefying or solidifying a fluid stream
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation By Low-Temperature Treatments (AREA)
Abstract
The present invention provides a kind of natural gas liquefaction system for being suitable for sea, including lighter hydrocarbons separator, mix refrigerant pre-cooling cycle, the main cryogenic heat exchanger of precooling, mix refrigerant deep cooling cycles, the main cryogenic heat exchanger of No.1 deep cooling and No. two main cryogenic heat exchangers of deep cooling, the lighter hydrocarbons separator includes domethanizing column, the tower overhead gas of the domethanizing column is through domethanizing column ice chest, after expansion compressor successively with the main cryogenic heat exchanger of the precooling, the main cryogenic heat exchanger of No.1 deep cooling and the main cryogenic heat exchanger of No. two deep coolings form heat exchange contact, again by entering LNG flash tanks after primary throttle valve, the LNG and BOG that LNG flash tanks can be isolated;The mix refrigerant pre-cooling cycle cryogenic heat exchanger main with the precooling forms heat exchange and contacts;The mix refrigerant deep cooling cycles cryogenic heat exchanger main with the No.1 deep cooling and No. two main cryogenic heat exchangers of deep cooling are respectively formed heat exchange and contact.The present invention can reduce the energy expenditure of liquefaction system, reduce system pressure, reduce propane disclosure risk.
Description
Technical field
The present invention relates to a kind of FLNG (Floating Liquefied Natural Gas are also known as LNG-FPSO) systems.
Background technology
Natural gas resource is widely distributed in the land and ocean in the whole world, is world's oil-gas exploration and development from land to ocean
Inexorable trend.FLNG (Floating Liquefied Natural Gas are also known as LNG-FPSO) is ocean engineering in recent years
What boundary proposed, integrate the new offshore installation of production, storage and the handling of liquefied natural gas, the exploitation for offshore gas field
With construction period is short, development risk is small, convenient for migration and it is safe the features such as.
Operation on the sea need to consider the unfavorable factors such as typhoon, wave, space limitation so that the skill of floating natural gas liquefaction process
Art difficulty is higher than land.As the core technology of FLNG, the reasonability of natural gas liquefaction process to the cost of investment of engineering project,
Operating cost, operation reliability and production safety are most important.For the particularity of marine operating mode, due to cascade type liquefaction work
Number of devices is more needed for skill, and compactedness is not high, and the storage capacity of refrigerant is larger, and being accordingly used in offshore natural gas liquefaction has centainly
Difficulty.And mix refrigerant liquefaction process and nitrogen expansion liquefaction process seaworthiness are preferable.
Propane pre-cooling dinitrogen expansion natural gas liquefaction system largely uses pentane as refrigerant, propane tool in the prior art
There is the characteristics of low boiling point, easily vaporization, when driving and parking operates, there are a large amount of propane in equipment and pipeline can cause pressure rise, increase
The risk that big propane is released or leaked.Once leaking, since the density of propane is more than air, the product of fuel gas can be caused
It is poly-, and FLNG Texas decks space is limited, facility compact, and diffusion conditions is poor, and the accidents such as burning, explosion easily occur.For
Marine natural gas liquefaction system, security can be improved by avoiding the use of propane, reduce the investment of safety devices.
The yield and component of offshore gas field natural gas constantly change, and external environment is changing always, and FLNG devices should
With transportable property, this requires natural gas liquefaction systems with flexible controllability, can be adjusted according to actual conditions pre-
Cold section, cryogenic load reduce the heat transfer temperature difference of cold fluid and hot fluid, reduce liquefaction power consumption.Dinitrogen expansion cycles in the prior art
Pressure is 8MPa, can not adjust the heat transfer temperature difference of different warm areas, and controllability is poor, high energy consumption.
The nitrogen pressure after expanded machine supercharger and compressor boost is up to 8MPa in the prior art, equipment and pipeline
Pressure rating is high, and the weight of process equipment increases, and the load-carrying of the support constructions such as pipe support increases, to propositions such as the intensity of Ship Structure
Requirements at the higher level cause the cost of top technical module and hull to be substantially increased, and reduce the economy of project.
The content of the invention
To overcome, existing floating liquefaction Technology of Natural Gas security is low, controllability is poor, high energy consumption, less economical lacks
Point, the present invention propose a kind of natural gas liquefaction system, can realize the lighter hydrocarbons of stability and high efficiency under the conditions of different waters, different makings
Separation and liquefied natural gas (LNG) production.
To achieve the above object, the technical solution adopted by the present invention is:
It is a kind of to be suitable for marine natural gas liquefaction system, it is characterized in that pre- including lighter hydrocarbons separator, mix refrigerant
SAPMAC method, the main cryogenic heat exchanger of precooling, mix refrigerant deep cooling Xun Huan, the main cryogenic heat exchanger of No.1 deep cooling are low with No. two deep cooling masters
Warm heat exchanger, wherein:
The lighter hydrocarbons separator includes domethanizing column, the tower overhead gas of the domethanizing column successively with the main low temperature of the precooling
Heat exchanger, the main cryogenic heat exchanger of No.1 deep cooling and the main cryogenic heat exchanger of No. two deep coolings form heat exchange contact, then pass through main throttling
Into LNG flash tanks after valve, the LNG and BOG that LNG flash tanks can be isolated;
The mix refrigerant pre-cooling cycle cryogenic heat exchanger main with the precooling forms heat exchange and contacts;
The mix refrigerant deep cooling cycles cryogenic heat exchanger main with the No.1 deep cooling and No. two main low temperature of deep cooling change
Hot device is respectively formed heat exchange contact.
Described is suitable for marine natural gas liquefaction system, wherein:The mix refrigerant pre-cooling cycle is included successively
Cycle connection precooling surge tank, pre- cold compressor, precooling water cooler and precooled throttling valve, the precooling water cooler with it is described
Pipeline between precooled throttling valve cryogenic heat exchanger main with the precooling forms heat exchange and contacts, the precooled throttling valve with it is described pre-
Also cryogenic heat exchanger formation heat exchange main with the precooling contacts pipeline between cold buffer tank.
Described is suitable for marine natural gas liquefaction system, wherein:The mix refrigerant deep cooling Xun Huan includes deep cooling
Surge tank, deep freeze compressor, deep cooling water cooler, cryogenic separation tank, No.1 copious cooling throttle valve and No. two copious cooling throttle valves, the depth
Cold buffer tank, deep freeze compressor, deep cooling water cooler, cryogenic separation tank are sequentially connected, and the deep cooling water cooler and the depth
Pipeline cryogenic heat exchanger main with the precooling between cold knockout drum forms heat exchange and contacts, the liquid phase pipeline of the cryogenic separation tank
Cryogenic heat exchanger main with the No.1 deep cooling forms heat exchange and contacts, then is connected with the No.1 copious cooling throttle valve, the deep cooling
The gas phase pipeline of knockout drum cryogenic heat exchanger main with the No.1 deep cooling and the main cryogenic heat exchanger shape of No. two deep coolings successively
It contacts into heat exchange, then is connected with No. two copious cooling throttle valves, the downstream pipe of No. two copious cooling throttle valves and No. two depths
Cold main cryogenic heat exchanger forms heat exchange contact and then merges with the downstream pipe of the No.1 copious cooling throttle valve, after merging
After return line cryogenic heat exchanger formation heat exchange main with the No.1 deep cooling contacts, the deep cooling surge tank is back to.
Described is suitable for marine natural gas liquefaction system, wherein:The mix refrigerant pre-cooling cycle uses pre-
Cold mixing refrigerant contains ethane to the lighter hydrocarbons of pentane, does not contain the component of propane and carbon more than six;The mix refrigerant
Deep cooling recycle deep cooling mix refrigerant in the lighter hydrocarbons containing nitrogen, methane to pentane, do not contain propane and carbon six with
On component.
Described is suitable for marine natural gas liquefaction system, wherein:The lighter hydrocarbons separator includes one section of ice chest, two
Section ice chest, cryogenic separation tank and expansion compressor, the air inlet all the way of one section of ice chest enter for unstripped gas, and one section cold
The gas outlet all the way of case connects with the cryogenic separation tank, gaseous phase outlet and the expansion compressor of the cryogenic separation tank
Expanding end is connected, then converges the rear entrance with the domethanizing column with the liquid-phase outlet of the cryogenic separation tank and be connected;It is described low
All the way air inlet of the gaseous phase outlet of warm knockout drum also with two sections of ice chests connects, the gas outlet all the way of two sections of ice chests
It is connected to the domethanizing column;The tower top of the domethanizing column is connected to the another way air inlet of two sections of ice chests, and described two
Another way air inlet of the another way gas outlet of section ice chest then with one section of ice chest is connected, the another way of one section of ice chest
Gas outlet is connected to the compression end of the expansion compressor, then cryogenic heat exchanger main with the precooling, No.1 deep cooling master are low successively
Warm heat exchanger and the main cryogenic heat exchanger of No. two deep coolings form heat exchange contact.
Described is suitable for marine natural gas liquefaction system, wherein:The lighter hydrocarbons separator, which further includes, to be sequentially connected
Dethanizer, depropanizing tower and debutanizing tower, the bottom of towe gas of the domethanizing column successively with the dethanizer, depropanizing tower
Connect with debutanizing tower, the overhead product re-injection of the depropanizing tower enters unstripped gas.
The present invention is based on the particularity of sea effect, it is proposed that a kind of to be suitable for marine natural gas liquefaction system, optimization
Mix refrigerant pre-cooling cycle, mix refrigerant deep cooling cycle, the technological parameter of lighter hydrocarbons knockout tower;Precooling mix refrigerant and
Deep cooling mix refrigerant does not include propane, improves security;Reduce the energy expenditure of liquefaction system, for different gas
Matter condition and marine environment, liquefied fraction reach 96%, compared with the prior art propane pre-cooling dinitrogen expansion natural gas liquefaction system,
Than lower power consumption about 10%.
Description of the drawings
Fig. 1 is the structure principle chart provided by the invention for being suitable for marine natural gas liquefaction system.
Reference sign:1 lighter hydrocarbons separator, 11 domethanizing columns, 12 dethanizers, 13 depropanizing towers, 14 debutanizations
Tower, 15 one section of domethanizing column ice chests, 16 two sections of domethanizing column ice chests, 17 cryogenic separation tanks, 18 expansion compressors, 2 hybrid refrigerations
Agent pre-cooling cycle, 21 precooling surge tanks, 22 pre- cold compressors, 23 precooling water coolers, 3 mix refrigerant deep coolings Xun Huan, 31 deep coolings
Surge tank, 32 deep freeze compressors, 33 deep cooling water coolers, 34 cryogenic separation tanks, 4 primary throttle valves, 5 precooled throttling valves, 6 No.1 deep coolings
Throttle valve, 7 No. two copious cooling throttle valves, 8-LNG flash tanks, the main cryogenic heat exchanger of 91 precoolings, the 92 main cryogenic heat exchangers of No.1 deep cooling,
93 No. two main cryogenic heat exchangers of deep cooling.
Specific embodiment
As shown in Figure 1, the present invention provides a kind of natural gas liquefaction system for being suitable for sea, including lighter hydrocarbons separator
1st, mix refrigerant pre-cooling cycle 2, the main cryogenic heat exchanger 91 of precooling, mix refrigerant deep cooling Xun Huan 3, the main low temperature of No.1 deep cooling change
Hot device 92 and the main cryogenic heat exchanger 93 of No. two deep coolings, wherein:
The lighter hydrocarbons separator 1 mainly includes sequentially connected domethanizing column 11, dethanizer 12,13 and of depropanizing tower
Debutanizing tower 14, can sequentially remove methane, ethane, propane and butane in natural gas, and the tower top of the dethanizer 12 connects
Ethane storage tank is connect, the tower top and bottom of towe of the debutanizing tower 14 connect butane storage tank and condensation oil tank respectively, and the present invention is not set
Propane storage is put, the propane molar fraction about 96% of the overhead product of depropanizing tower 13, overhead product re-injection enters unstripped gas.It is de-
11 required cold of methane tower comes from one section of ice chest 15 of domethanizing column, two sections of ice chests 16 of domethanizing column, cryogenic separation tank 17
With expansion compressor 18, natural gas liquefaction system is not related to, therefore the technology flow of the invention is simple, equipment arrangement is tight
It gathers, convenient for into sled, and it is big to the variation adaptability of unstripped gas composition.
Wherein, the lighter hydrocarbons separator 1 further includes one section of ice chest, 15, two sections of ice chests 16, cryogenic separation tank 17 and swollen
Swollen compressor 18, the air inlet all the way of one section of ice chest 15 enter for unstripped gas, the gas outlet all the way of one section of ice chest 16 with
The cryogenic separation tank 17 connects, the expanding end phase of the gaseous phase outlet of the cryogenic separation tank 17 and the expansion compressor 18
Even, the liquid-phase outlet after being cooled down by expansion with the cryogenic separation tank 17 converges subsequently into the domethanizing column 11;It is described
All the way air inlet of the gaseous phase outlet of cryogenic separation tank 17 also with two sections of ice chests 16 connects, and two sections of ice chests 16 are all the way
Gas outlet is also connected to the domethanizing column 11;The tower top of the domethanizing column 11 is connected to the another way of two sections of ice chests 16
Air inlet, the another way air inlet of the another way gas outlets of two sections of ice chests 16 then with one section of ice chest 15 are connected, institute
The another way gas outlet for stating one section of ice chest 15 is connected to the compression end of the expansion compressor 18 and is pressurized, after supercharging successively with
The main cryogenic heat exchanger 91 of the precooling, the main cryogenic heat exchanger 92 of No.1 deep cooling and the main formation of cryogenic heat exchanger 93 of No. two deep coolings are changed
After thermo-contact, by the way that, into LNG flash tanks 8, the LNG that LNG flash tanks 8 are isolated stores to wait outer after primary throttle valve 4
Fortune, the BOG isolated enter fuel gas system;The bottom product of the domethanizing column 11 sequentially enters 13 deethanization of depropanizing tower
Tower 12, depropanizing tower 13 and debutanizing tower 14, just repeat no more.So set, 11 required cold of domethanizing column can be made
Come from lighter hydrocarbons separator 1 itself.
The mix refrigerant pre-cooling cycle 2 includes cycling the precooling surge tank 21 of connection, pre- cold compressor 22, pre- successively
Cold water cooler 23 and precooled throttling valve 5, pipeline between the precooling water cooler 23 and the precooled throttling valve 5 with it is described pre-
Cold main cryogenic heat exchanger 91 forms heat exchange contact, the pipeline between the precooled throttling valve 5 and the precooling surge tank 21 also with
The main cryogenic heat exchanger 91 of precooling forms heat exchange contact.
The mix refrigerant deep cooling cycle 3 includes deep cooling surge tank 31, deep freeze compressor 32, deep cooling water cooler 33, depth
Cold knockout drum 34, No.1 copious cooling throttle valve 6 and No. two copious cooling throttle valves 7, the deep cooling surge tank 31, deep freeze compressor 32, depth
Cold water cooler 33, cryogenic separation tank 34 are sequentially connected, and between the deep cooling water cooler 33 and the cryogenic separation tank 34
Pipeline cryogenic heat exchanger 91 main with the precooling forms heat exchange and contacts, liquid phase pipeline and the No.1 of the cryogenic separation tank 34
The main cryogenic heat exchanger 92 of deep cooling forms heat exchange contact, then is connected with the No.1 copious cooling throttle valve 6, the cryogenic separation tank 34
Gas phase pipeline cryogenic heat exchanger 92 main with the No.1 deep cooling and the main cryogenic heat exchanger 93 of No. two deep coolings are formed successively
Heat exchange contact, then be connected with No. two copious cooling throttle valves 7, the downstream pipe of No. two copious cooling throttle valves 7 and No. two depths
Cold main cryogenic heat exchanger 93 forms heat exchange contact and then merges with the downstream pipe of the No.1 copious cooling throttle valve 6, after merging
Main with the No.1 deep cooling cryogenic heat exchanger 92 of return line formed after heat exchange contacts, be back to the deep cooling surge tank
31。
Mix refrigerant pre-cooling cycle 2 is different from refrigerant component used in mix refrigerant deep cooling Xun Huan 3, and precooling mixes
It closes the lighter hydrocarbons that refrigerant contains ethane to pentane to form, does not contain the component of propane and carbon more than six;Deep cooling mix refrigerant
In the lighter hydrocarbons composition containing nitrogen, methane to pentane, do not contain the component of propane and carbon more than six.
Below with a preferred embodiment, the course of work that the present invention is discussed in detail is as follows:
After removing the impurity such as solid particle, water, sour gas, mercury, benzene, unstripped gas enters one section of ice chest 15, and cooling is laggard
Enter cryogenic separation tank 17, the expansion cooling of the expanding end of the expanded compressor 18 of the partial gas phase unstripped gas after separation, with liquid phase
Unstripped gas enters de- into domethanizing column 11, another part phase feed gas after converging after two sections of ice chests 16 of domethanizing column cool down
Methane tower 11, the overhead product methane molar fraction about 96% of domethanizing column 11, overhead product through one section of ice chest 15 of domethanizing column,
Two sections of ice chests 16 of domethanizing column heat up, and are pressurized subsequently into the compression end of expansion compressor 18, and precooling master is flowed into after supercharging
Cryogenic heat exchanger 91, the bottom product of domethanizing column 11 enter dethanizer 12;The ethane of the overhead product of dethanizer 12 rubs
That fraction about 96%, bottom product enters depropanizing tower 13;The propane molar fraction about 96% of the overhead product of depropanizing tower 13,
Overhead product re-injection enters unstripped gas, and bottom product enters debutanizing tower 14;The butane mole point of 14 overhead product of debutanizing tower
Number about 92%, bottom product condensate are stored as byproduct and transported outward.
Unstripped gas after domethanizing column 11 into the main cryogenic heat exchanger 91 of precooling, pre-cooled mix refrigerant be cooled to about-
45 DEG C~-52 DEG C, the main cryogenic heat exchanger 92 of No.1 deep cooling and the main cryogenic heat exchanger 93 of No. two deep coolings are then flowed into successively, through deep cooling
Mix refrigerant is cooled to about -148 DEG C~-156 DEG C, and LNG flash tanks are flowed into after being cooled to -160 DEG C by the throttling of primary throttle valve 4
8, the LNG storages isolated wait outward transport, and BOG enters fuel gas system.
The pre-cooled compressor 22 of precooling mix refrigerant is compressed to about 3.8MPa~4.3MPa, through precooling water cooler after compression
23 coolings, the low-temperature receiver of precooling water cooler 23 use seawater;Enter the main low-temperature heat exchange of precooling after precooling mix refrigerant compression water cooling
Device 91, the pre-cooled throttling of throttle valve 5 cooling, is then back to the main cryogenic heat exchanger 91 of precooling, to cool down unstripped gas, deep cooling mixing
The precooling mix refrigerant of refrigerant and high temperature;Fully after heat exchange, precooling mix refrigerant enters precooling surge tank 21, is formed mixed
Close refrigerant pre-cooling cycle.
Deep cooling mix refrigerant is compressed to about 3.9MPa~4.4MPa through deep freeze compressor 32, through deep cooling water cooler after compression
33 coolings, the low-temperature receiver of deep cooling water cooler 33 use seawater;Enter the main low temperature of No.1 precooling after deep cooling mix refrigerant compression water cooling
Heat exchanger 91 enters cryogenic separation tank 34 after precooling;Liquid phase deep cooling mix refrigerant after gas-liquid separation enters No. two deep cooling masters
Cryogenic heat exchanger throttles through No.1 copious cooling throttle valve 6 and cools down;Gas phase deep cooling mix refrigerant after gas-liquid separation sequentially enters one
Number 92, No. two main cryogenic heat exchangers 93 of deep cooling of the main cryogenic heat exchanger of deep cooling through No. two throttling coolings of copious cooling throttle valves 7, then return
Cooling unstripped gas and gas phase deep cooling mix refrigerant are returned, is mixed after flowing out the main cryogenic heat exchanger 93 of deep cooling with the liquid phase deep cooling after throttling
It closes refrigerant and returns to the main cryogenic heat exchanger 92 of deep cooling together, to cool down unstripped gas and deep cooling mix refrigerant;Fully after heat exchange,
Deep cooling mix refrigerant enters deep cooling surge tank 31, forms mix refrigerant deep cooling Xun Huan.
Stable operation under the conditions of at sea being rocked for guarantee liquefaction system, it is as follows to key equipment, technical module requirement:
The main cryogenic heat exchanger of precooling, using uniform fluid distribution component, optimizes internal heat structure, ensures heat exchange with the main cryogenic heat exchanger of deep cooling
The stability and high efficiency of process;Gas-liquid separator ensures separating effect by the setting of internals;It is set according to technological process, key
The factors such as standby gauge size, deck space rationally carry out modular division, shorten construction period.
Described above to be merely exemplary for the purpose of the present invention, and not restrictive, those of ordinary skill in the art understand,
In the case where not departing from the spirit and scope that claim is limited, can many modifications may be made, variation or equivalent, but will all fall
Enter within protection scope of the present invention.
Claims (6)
1. a kind of be suitable for marine natural gas liquefaction system, it is characterized in that including lighter hydrocarbons separator, mix refrigerant precooling
Xun Huan, the main cryogenic heat exchanger of precooling, mix refrigerant deep cooling Xun Huan, the main cryogenic heat exchanger of No.1 deep cooling and No. two main low temperature of deep cooling
Heat exchanger, wherein:
The lighter hydrocarbons separator includes domethanizing column, the tower overhead gas of the domethanizing column successively with the main low-temperature heat exchange of the precooling
Device, the main cryogenic heat exchanger of No.1 deep cooling and the main cryogenic heat exchanger of No. two deep coolings form heat exchange contact, then by primary throttle valve it
Afterwards into LNG flash tanks, the LNG and BOG that LNG flash tanks can be isolated;
The mix refrigerant pre-cooling cycle cryogenic heat exchanger main with the precooling forms heat exchange and contacts;
The mix refrigerant deep cooling Xun Huan and the main cryogenic heat exchanger of the No.1 deep cooling and No. two main cryogenic heat exchangers of deep cooling
It is respectively formed heat exchange contact.
2. according to claim 1 be suitable for marine natural gas liquefaction system, it is characterised in that:The mix refrigerant
Pre-cooling cycle includes the precooling surge tank, pre- cold compressor, precooling water cooler and the precooled throttling valve that cycle connection successively, described
Pipeline cryogenic heat exchanger main with the precooling between precooling water cooler and the precooled throttling valve forms heat exchange and contacts, described pre-
Also cryogenic heat exchanger formation heat exchange main with the precooling contacts pipeline between cold throttle valve and the precooling surge tank.
3. according to claim 1 or 2 be suitable for marine natural gas liquefaction system, it is characterised in that:The mixing system
Cryogen deep cooling cycle include deep cooling surge tank, deep freeze compressor, deep cooling water cooler, cryogenic separation tank, No.1 copious cooling throttle valve and
No. two copious cooling throttle valves, the deep cooling surge tank, deep freeze compressor, deep cooling water cooler, cryogenic separation tank are sequentially connected, Er Qiesuo
The cryogenic heat exchanger formation heat exchange main with the precooling of the pipeline between deep cooling water cooler and the cryogenic separation tank is stated to contact, it is described
Main with the No.1 deep cooling cryogenic heat exchanger of the liquid phase pipeline of cryogenic separation tank forms heat exchange and contacts, then with the No.1 deep cooling section
Stream valve is connected, the gas phase pipeline of cryogenic separation tank cryogenic heat exchanger main with the No.1 deep cooling and No. two described successively
The main cryogenic heat exchanger of deep cooling forms heat exchange contact, then is connected with No. two copious cooling throttle valves, under No. two copious cooling throttle valves
The cryogenic heat exchanger formation heat exchange main with No. two deep coolings of play pipe road contacts and then the downstream with the No.1 copious cooling throttle valve
Pipeline merges, and after the cryogenic heat exchanger formation heat exchange main with the No.1 deep cooling of the return line after merging contacts, is back to institute
State deep cooling surge tank.
4. according to claim 1 be suitable for marine natural gas liquefaction system, it is characterised in that:The mix refrigerant
The precooling mix refrigerant that pre-cooling cycle uses contains ethane to the lighter hydrocarbons of pentane, does not contain the group of propane and carbon more than six
Part;Lighter hydrocarbons containing nitrogen, methane to pentane in the deep cooling mix refrigerant that the mix refrigerant deep cooling recycles, are free of
There is the component of propane and carbon more than six.
5. according to claim 1 be suitable for marine natural gas liquefaction system, it is characterised in that:The lighter hydrocarbons separation dress
Put including one section of ice chest, two sections of ice chests, cryogenic separation tank and expansion compressor, the air inlet all the way of one section of ice chest for
Unstripped gas enters, and the gas outlet all the way of one section of ice chest connects with the cryogenic separation tank, the gaseous phase outlet of the cryogenic separation tank
It is connected with the expanding end of the expansion compressor, then converges the rear and domethanizing column with the liquid-phase outlet of the cryogenic separation tank
Entrance be connected;All the way air inlet of the gaseous phase outlet of the cryogenic separation tank also with two sections of ice chests connects, described two sections
The gas outlet all the way of ice chest is also connected to the domethanizing column;The tower top of the domethanizing column is connected to the another of two sections of ice chests
Air inlet all the way, the another way air inlet of the another way gas outlets of two sections of ice chests then with one section of ice chest are connected, institute
The another way gas outlet for stating one section of ice chest is connected to the compression end of the expansion compressor, then is changed successively with the main low temperature of the precooling
Hot device, the main cryogenic heat exchanger of No.1 deep cooling and the main cryogenic heat exchanger of No. two deep coolings form heat exchange contact.
6. it is suitable for marine natural gas liquefaction system according to claim 1 or 5, it is characterised in that:The lighter hydrocarbons point
Further include sequentially connected dethanizer, depropanizing tower and debutanizing tower from device, the bottom of towe gas of the domethanizing column successively with
The dethanizer, depropanizing tower and debutanizing tower connect, and the overhead product re-injection of the depropanizing tower enters unstripped gas.
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CN108759302A (en) * | 2018-06-04 | 2018-11-06 | 中海石油气电集团有限责任公司 | A kind of high-pressure natural gas liquefaction system and method |
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