CN108103444A - A kind of fabric that can realize antiultraviolet - Google Patents
A kind of fabric that can realize antiultraviolet Download PDFInfo
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- CN108103444A CN108103444A CN201810108780.XA CN201810108780A CN108103444A CN 108103444 A CN108103444 A CN 108103444A CN 201810108780 A CN201810108780 A CN 201810108780A CN 108103444 A CN108103444 A CN 108103444A
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- Prior art keywords
- fabric
- base fabric
- antiultraviolet
- ultraviolet
- vacuum degree
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- 239000004744 fabric Substances 0.000 title claims abstract description 102
- 238000000151 deposition Methods 0.000 claims abstract description 9
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 238000001704 evaporation Methods 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 27
- 239000010410 layer Substances 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000004804 winding Methods 0.000 claims description 10
- 238000001771 vacuum deposition Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 8
- 238000001514 detection method Methods 0.000 claims description 5
- 238000001755 magnetron sputter deposition Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000002203 pretreatment Methods 0.000 claims description 5
- 238000005070 sampling Methods 0.000 claims description 5
- 238000007747 plating Methods 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 3
- 238000000313 electron-beam-induced deposition Methods 0.000 claims description 3
- 238000002207 thermal evaporation Methods 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 description 8
- 229920004933 Terylene® Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- 239000004753 textile Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 230000006750 UV protection Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- 206010002198 Anaphylactic reaction Diseases 0.000 description 1
- 201000009030 Carcinoma Diseases 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 102000016942 Elastin Human genes 0.000 description 1
- 108010014258 Elastin Proteins 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 206010041303 Solar dermatitis Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000036783 anaphylactic response Effects 0.000 description 1
- 208000003455 anaphylaxis Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 201000010251 cutis laxa Diseases 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920002549 elastin Polymers 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
A kind of fabric that can realize antiultraviolet, it includes base fabric and ultraviolet reflecting layer, the ultraviolet reflecting layer is formed using evaporating deposition technique, and target includes one or more of Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt element.The product uses evaporating deposition technique, fabric surface can be made to form ultraviolet reflecting layer, which has ultraviolet light very strong reflection and scattering power, therefore improves the anti-ultraviolet function of fabric.
Description
Technical field
The invention belongs to textile field more particularly to a kind of fabrics that can realize antiultraviolet.
Background technology
People constantly rise the functional requirement of textile with development in science and technology and the raising of quality of life, except relaxing
Suitable, health, safety basic demand, antiultraviolet are increasingly becoming one of hot spot demand of fabric.
According to the difference of wavelength, ultraviolet light can be divided into UVC (wavelength 200-280nm), UVB (wavelength 280-320nm) and UVA
(wavelength 315-340nm) three classes.Wherein, UVA can be directed through to skin skin corium, destroyed collagen and elastin laminin, led
It causes cutis laxa and generates wrinkle.And UVB energy is very strong, easily causes the solar dermatitis of ultraviolet light allergy initiation, and cause black
The formation of pigment triggers the symptoms such as color spot, obscure, skin photoage, coarse, cutaneum carcinoma.On the whole, ultraviolet light irradiation can be led
It causes red skin, bright, hot, pain and skin is made to lose activity, the resistance of skin declines, and triggers anaphylaxis skin quality, to human body skin
Skin harm is larger.
Existing Uvr Protective Fabric using absorption of the textile to ultraviolet light and principle of reflection, is hidden using ultraviolet light
Agent is covered, i.e., a kind of substance that can reflect or absorb ultraviolet light, to achieve the purpose that antiultraviolet protects skin.Main technique is to adopt
With technologies such as dipping, stamp, resin, microcapsules by screening uv-ray agent processing to textile, another method is that production is anti-
Ultraviolet light spins, then woven into fabric.
Screening uv-ray agent is divided into two kinds of organic ultra-violet absorber and inorganic ultraviolet reflection agent.Organic includes
Salicylic acid esters, benzophenone class, benzotriazole, group-substituted acrylonitrile, triazines and hindered amines, the organic compound absorb purple
Energy conversion is carried out after outside line, is released energy with thermal energy or other low-energy radiations.Inorganic includes titanium dioxide, zinc oxide, cunning
Mountain flour, clay, calcium carbonate, these material refractive indexes are high, mainly to ultraviolet reflection and scattering.
However organic ultra-violet absorber is mainly aromatics organic compound, strong toxicity causes environment serious dirt
Dye, and do great harm to human body.And inorganic UV smoke agent for shielding coating on the textile is handled, it is necessary to which adhesive is solved with having
The problem of machine textile raw material compatibility is poor, while disperse uneven easy reunion.In addition can with the increase of washing times and
Peeling causes sun-proof result to weaken until disappearing.The method processing step that sol-gal process prepares titanium deoxid film is numerous and diverse, into
This height is unfavorable for daily life application.And at present sell on the market sun-proof clothing generally existing poor air permeability the defects of thus
Influence comfort level and skin-friendly.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of fabric that can realize antiultraviolet.The product uses vacuum
Deposition technique, can make fabric surface formed ultraviolet reflecting layer, the ultraviolet reflecting layer to ultraviolet light have very strong reflection and
Scattering power, therefore improve the anti-ultraviolet function of fabric.
The present invention technical solution be：
A kind of fabric that can realize antiultraviolet, including base fabric and ultraviolet reflecting layer, the ultraviolet reflecting layer is adopted
It is formed with evaporating deposition technique, target is included in Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt
One or more of elements.
Preferably, the thickness of the ultraviolet reflecting layer is 1-200nm.
Preferably, the evaporating deposition technique is splashed including vacuum thermal evaporation deposition, electron beam deposition, ion film plating, magnetic control
It penetrates.
Preferably, the ultraviolet reflecting layer is single-layer or multi-layer.
A kind of preparation method of the above-mentioned fabric that can realize antiultraviolet, including：
Pre-treatment is carried out to base fabric, removes surface blot；
It is involved in base fabric and unreels room, unreeled room vacuum degree and be maintained at 0.5-1E-9Pa sections；
Base fabric makes base fabric temperature rise to 2-180 DEG C, heating chamber vacuum degree is maintained at 0.5-1E into heating chamber-9Pa sections；
Base fabric is maintained at 0.5-1E into prechamber, house vacuum degree-9Pa sections；
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to be formed in base fabric into coating chamber using vacuum deposition method
Ultraviolet reflecting layer, target include Ti, Fe, Al, Zn, Cu, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt in one kind or
Several elements, power interval 50-30000W；
Base fabric is maintained at 0.5-1E into winding room, winding room vacuum degree-9Pa sections；
Take out finished fabric, sampling detection.
Whole process is pipelined operation, and the cloth speed of service is 0.3m/min to 100m/min.
Beneficial effects of the present invention are：
Before handling base fabric, most of UV transmission base fabric is irradiated to human body, ultraviolet ray transmissivity ＞ 85%, according to the present invention
After the method processing base fabric, ultraviolet ray transmissivity≤5% of prepared plating film fabric, UV protection factor grade is commented
Surely it is more than 40, and ultraviolet reflection rate can reach four times of base fabric or more.The anti-uv of fabric of the present invention is extremely bright
Aobvious, ultraviolet resistance is greatly improved.
The ultraviolet reflecting layer of fabric of the present invention and base fabric combination degree are higher.
The pliability of fabric of the present invention is higher, and gas permeability is preferable, and dress experience is preferable.
The method of the invention reduces the base fabric weave specification requirement of fabric.
The method of the invention uses vacuum deposition method, and no any solid-state, liquid, gaseous pollutant are discharged, greatly
It reduces in fabric antiultraviolet treatment process to the demand of water, meets the requirement of environmentally protective production.
Description of the drawings
Fig. 1 is the process flow chart of the method for the invention.
Fig. 2 is fabric construction schematic diagram of the present invention.
Reference numeral：1- ultraviolet reflecting layers, 2- base fabrics.
Specific embodiment
Embodiment is described in detail below in conjunction with attached drawing.
Embodiment 1
As shown in Figure 1, a kind of preparation method for the fabric that can realize antiultraviolet, including：
Base fabric is cotton, carries out pre-treatment to base fabric, removes surface blot；
It is involved in base fabric and unreels room, unreeled room vacuum degree and be maintained at 1-1.5E-1Pa sections；
Base fabric makes base fabric temperature rise to 75 DEG C, heating chamber vacuum degree is maintained at 1-1.5E into heating chamber-1Pa；
Base fabric is maintained at 5E into prechamber, house vacuum degree-2Pa；
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to be formed in base fabric into coating chamber using vacuum deposition method
Ultraviolet reflecting layer, target TiO2Target, magnetron sputtering power 1800W；
Base fabric is maintained at 1-1.5E into winding room, winding room vacuum degree-1Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 38m/min.
Embodiment 2
As shown in Figure 1, a kind of preparation method for the fabric that can realize antiultraviolet, including：
Base fabric is cotton, carries out pre-treatment to base fabric, removes surface blot；
It is involved in base fabric and unreels room, unreeled room vacuum degree and be maintained at 2E-1Pa sections；
Base fabric makes base fabric temperature rise to 58 DEG C, heating chamber vacuum degree is maintained at 2E into heating chamber-1Pa sections
Base fabric is maintained at 3E into prechamber, house vacuum degree-2Pa sections；
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to be formed in base fabric into coating chamber using vacuum deposition method
Ultraviolet reflecting layer, target are respectively Ti, Ag, and sputtering power is respectively 2500W, 3000W；
Base fabric is maintained at 2E into winding room, winding room vacuum degree-1Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 23m/min.
Embodiment 3
As shown in Figure 1, a kind of preparation method for the fabric that can realize antiultraviolet, including：
Base fabric is terylene, carries out pre-treatment to base fabric, removes surface blot；
It is involved in base fabric and unreels room, unreeled room vacuum degree and be maintained at 0.7E-1Pa sections；
Base fabric makes base fabric temperature rise to 89 DEG C, heating chamber vacuum degree is maintained at 0.7E into heating chamber-1Pa sections
Base fabric is maintained at 8E into prechamber, house vacuum degree-2Pa sections；
When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to be formed in base fabric into coating chamber using vacuum deposition method
Ultraviolet reflecting layer, target are respectively Zn, TiN, Ag, and magnetron sputtering power is respectively 5000W, 7000W, 2500W；
Base fabric is maintained at 0.7E into winding room, winding room vacuum degree-1Pa sections；
Take out finished fabric, sampling detection；
Whole process is pipelined operation, and the cloth speed of service is 46m/min.
With reference to national standard GB/T18830-2009《The evaluation of ultraviolet resistance of fabric》To embodiment 1-3 and cotton, terylene
Two kinds of base fabrics carry out UPF values and measure, and before processing, cotton base fabric UPF values are 3, and terylene 17 is handled according to the method for the invention
Afterwards, embodiment 1,2,3, UPF values are all higher than 40, and ultraviolet ray transmissivity is less than 5%.
As shown in table 1,
After being handled by the method for the invention, embodiment 1, the ultraviolet reflection rate score of embodiment 2 are than cotton base fabric
It increases substantially.
Table 1
| Concrete example | Cotton | Embodiment 1 | Embodiment 2 |
| Opposing UV reflectivity | 100% | 410% | 442% |
As shown in table 2,
After being handled by the method for the invention, ultraviolet reflection rate score significantly the carrying than terylene base fabric of embodiment 3
It is high.
Table 2
| Concrete example | Terylene | Embodiment 3 |
| Opposing UV reflectivity | 100% | 453% |
Base fabric described in above-described embodiment 1-3 is cotton, terylene, the poor cotton of present invention selection anti-ultraviolet function, terylene
Base fabric as a comparison, to prove that the ultraviolet resistance of fabric of the present invention is higher.It will be understood by those skilled in the art that it is base
Cloth includes natural fiber and artificial fiber.
Vacuum deposition method described in above-described embodiment 1-3 includes magnetron sputtering, but is not limited to magnetron sputtering.Art technology
Personnel are it will be appreciated that vacuum deposition method further includes vacuum thermal evaporation deposition, electron beam deposition, ion film plating.
Target described in embodiment 1-3 includes Zn, TiN, Ag, Ti, TiO2, but not limited to the examples target described in 1-3 is implemented
Target described in example 1-3 is used to prove the ultraviolet resistance of fabric of the present invention；It will be understood by those skilled in the art that it is target
Including one or more of Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt element.
The present invention elaborates and has been cited embodiment, but those skilled in the art made according to above-described embodiment it is aobvious
And be clear to various schemes, modification, change, these schemes, modification, change should all belong to the present invention claim protection
Scope.
Claims (5)
- A kind of 1. fabric that can realize antiultraviolet, including base fabric and ultraviolet reflecting layer, which is characterized in that the ultraviolet light Reflecting layer is formed using evaporating deposition technique, target include Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, one or more of Si, Pt element.
- A kind of 2. fabric that can realize antiultraviolet as described in claim 1, which is characterized in that the thickness of the ultraviolet reflecting layer It spends for 1-200nm.
- 3. a kind of fabric that can realize antiultraviolet as described in claim 1, which is characterized in that the evaporating deposition technique includes Vacuum thermal evaporation deposition, electron beam deposition, ion film plating, magnetron sputtering.
- 4. a kind of fabric that can realize antiultraviolet as described in claim 1, which is characterized in that the ultraviolet reflecting layer is single Layer or multilayer.
- 5. a kind of preparation method for the fabric that can realize antiultraviolet as described in claim 1, including：Pre-treatment is carried out to base fabric, removes surface blot；It is involved in base fabric and unreels room, unreeled room vacuum degree and be maintained at 0.5-1E-9Pa sections；Base fabric makes base fabric temperature rise to 2-180 DEG C, heating chamber vacuum degree is maintained at 0.5-1E into heating chamber-9Pa sectionsBase fabric is maintained at 0.5-1E into prechamber, house vacuum degree-9Pa sections；When coating chamber vacuum degree reaches 1E-3During more than Pa, base fabric makes to be formed in base fabric ultraviolet into coating chamber using vacuum deposition method Line reflection layer, target include one kind or several in Ti, Fe, Al, Zn, Cu, W, Mg, Au, Ag, Cr, Ni, V, Co, C, N, O, Si, Pt Kind element, power interval 50-30000W；Base fabric is maintained at 0.5-1E into winding room, winding room vacuum degree-9Pa sections；Take out finished fabric, sampling detection.Whole process is pipelined operation, and the cloth speed of service is 0.3m/min to 100m/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810108780.XA CN108103444A (en) | 2018-02-05 | 2018-02-05 | A kind of fabric that can realize antiultraviolet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810108780.XA CN108103444A (en) | 2018-02-05 | 2018-02-05 | A kind of fabric that can realize antiultraviolet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108103444A true CN108103444A (en) | 2018-06-01 |
Family
ID=62221819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810108780.XA Pending CN108103444A (en) | 2018-02-05 | 2018-02-05 | A kind of fabric that can realize antiultraviolet |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108103444A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110629569A (en) * | 2018-06-22 | 2019-12-31 | 广东欣丰科技有限公司 | Fabric coloring method and colored fabric |
| CN112301735A (en) * | 2020-11-18 | 2021-02-02 | 上海婉静纺织科技有限公司 | Processing technology of anti-ultraviolet pure cotton fabric |
| CN112323484A (en) * | 2020-11-18 | 2021-02-05 | 上海婉静纺织科技有限公司 | Ultraviolet-resistant modification method for fabric |
| CN113699784A (en) * | 2021-08-12 | 2021-11-26 | 广东欣丰科技有限公司 | Fabric with ultraviolet-proof function and preparation method and application thereof |
| CN114606761A (en) * | 2022-03-22 | 2022-06-10 | 武汉纺织大学 | Long-acting light aging resistant fiber material and preparation method thereof |
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2018
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110629569A (en) * | 2018-06-22 | 2019-12-31 | 广东欣丰科技有限公司 | Fabric coloring method and colored fabric |
| US11505860B2 (en) | 2018-06-22 | 2022-11-22 | Guangdong Rising Well Science & Technology Co., Ltd. | Fabric coloring method and colored fabric |
| CN112301735A (en) * | 2020-11-18 | 2021-02-02 | 上海婉静纺织科技有限公司 | Processing technology of anti-ultraviolet pure cotton fabric |
| CN112323484A (en) * | 2020-11-18 | 2021-02-05 | 上海婉静纺织科技有限公司 | Ultraviolet-resistant modification method for fabric |
| CN112301735B (en) * | 2020-11-18 | 2022-07-29 | 胜利科技集团有限公司 | Processing technology of anti-ultraviolet pure cotton fabric |
| CN112323484B (en) * | 2020-11-18 | 2022-08-16 | 湖州优淘服饰有限公司 | Ultraviolet-resistant modification method for fabric |
| CN113699784A (en) * | 2021-08-12 | 2021-11-26 | 广东欣丰科技有限公司 | Fabric with ultraviolet-proof function and preparation method and application thereof |
| CN114606761A (en) * | 2022-03-22 | 2022-06-10 | 武汉纺织大学 | Long-acting light aging resistant fiber material and preparation method thereof |
| CN114606761B (en) * | 2022-03-22 | 2024-06-11 | 武汉纺织大学 | Long-acting photo-aging resistant fiber material and preparation method thereof |
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Application publication date: 20180601 |